CN202422588U - Electrochromic anti-counterfeiting label - Google Patents
Electrochromic anti-counterfeiting label Download PDFInfo
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- CN202422588U CN202422588U CN2012200472954U CN201220047295U CN202422588U CN 202422588 U CN202422588 U CN 202422588U CN 2012200472954 U CN2012200472954 U CN 2012200472954U CN 201220047295 U CN201220047295 U CN 201220047295U CN 202422588 U CN202422588 U CN 202422588U
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- electrochromic
- surperficial
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- counterfeiting
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Abstract
The utility model discloses an electrochromic anti-counterfeiting label, which comprises a surface anode layer (1), a surface cathode layer (4), an electrochromic material layer (2) and conducting wires (5) of an external power supply led out from the surface anode layer (1) and the surface cathode layer (4). The electrochromic anti-counterfeiting label is characterized in that an electrolyte conducting layer (3) is also arranged between the surface anode layer (1) and the electrochromic material layer (2), wherein an anti-counterfeiting label pattern is positioned in the electrochromic material layer (2). The sectional structure of the electrochromic anti-counterfeiting label only has four layers, and further, is designed by utilizing the electrochemical property of a material; not only is the structure simple, are manufacturing working procedures decreased greatly and is the production cost reduced greatly, but also the problems brought about by using a nanometer semiconductor material to manufacture an electrochromic anti-counterfeiting identifier is solved; meanwhile, the anti-counterfeiting recognition is convenient and quick; in addition, a recognition process is irreversible; and the electrochromic anti-counterfeiting label can also be prevented from being secondarily utilized to lose an anti-counterfeiting effect.
Description
Technical field
The utility model belongs to color-changing anti-counterfeit label technique field, is specifically related to a kind of based on electrochromic antifalsification label.
Background technology
At present; Existing antifalsification label mainly is divided into five big types of laser scanning label, query formulation digital label, pattern texture label, safety line cheque paper label and wireless electron scanning antifalsification labels, has mainly utilized the characteristic of aspects such as optics that material itself has, calorifics.The consumer is through visual inspection, interactive query or produce by professional instrument detecting label with normality under different variations distinguish that product is true and false.But counterfeit technology of today is increasingly high, and the technological means that the part antifalsification label is used is single; With low content of technology; Causing can the raising of counterfeit property, the reduction of label anti-counterfeit property, a lot of in addition antifalsification labels or need distinguish by instrumentation; Or the label variations effect is complicated, thereby brings bigger difficulty for consumer's identification.In addition, for solve make complicated, problem such as operation is many, somebody (CN2487062) utilization nano semiconductor material is made the electrochromism anti-counterfeiting mark.Though having solved to a certain extent, this electrochromism anti-counterfeiting mark makes complicacy; Problems such as operation is many; But the used nano semiconductor material cost of this anti-counterfeiting mark is expensive, and the security devices that forms still has seven-layer structure, and design is comparatively complicated; Production process is still more, causes production cost higher.
Summary of the invention
The utility model provides a kind of electrochromism antifalsification label that electrochemical properties designed new, that utilize material to the problem that prior art exists.
The electrochromism antifalsification label that the utility model provides; This label comprises surperficial anode layer, surperficial cathode layer, electrochromic material layer and the lead of the external power supply of being drawn by surperficial anode layer, surperficial cathode layer; It is characterized in that also being provided with an electrolyte conductive layer between surperficial anode layer and the electrochromic material layer, wherein the antifalsification label pattern is positioned at the electrochromic material layer.
The inside surface that the surperficial anode layer of above-mentioned label contacts with the electrochromic material layer, surperficial cathode layer are coated with nesa coating with the inside surface that the electrolyte conductive layer contacts.
Wherein surperficial anode layer is to be made up of transparency higher organic polymer film or optical clear glass.The electrochromic material layer can be by inorganic material such as tungstic acid, titania, perhaps adopts methods such as general chemistry is synthesized, electrochemical deposition, sol-gel process to prepare by materials such as organic material such as polyaniline and derivant thereof, smart class of purple sieve, polythiophenes.The color changeable effect and change variable color voltage range of other materials to obtain enriching can also mix in electrochromic material; And the antifalsification label pattern is that query formulation digital label, texture label, word tag can be made the picture and text template; Through the method for etching or coating, make the vestige of corresponding pattern at this layer.This vestige is the water white transparency state because of material itself and surperficial anode and cathode layer and electrolyte conductive layer under common state, do not see the picture and text of inside through naked eyes.But after adding certain voltage, electrochromic material layer change color can show picture and text.The consumer can be according to the picture and text that show, contrast standard collection of illustrative plates or online inquiry bar code wait distinguishes authenticity of products.Can in the certain voltage scope, realize the reversible variation of color because the raw material that the utility model electrochromic material layer is adopted has, but reduce the characteristic that its color of voltage no longer changes behind the magnitude of voltage that oversteps the extreme limit again.For avoiding antifalsification label to be lost antifalse effect by second use, the supply voltage during this searching label should be the limiting voltage of material, in case after its variable color was shown, color relation no longer reversed.The electrolyte conductive layer is by lithium perchlorate solution, potassium chloride-salpeter solution or solid electrolyte material such as LiClO
4The gel rubber system that-PMMA-PC constitutes, TBAP-PMMA-PC gel rubber system constitute.The electrolyte conductive layer is liquid in this way, can be encapsulated in the cavity of electrochromic material layer and surperficial cathode layer formation.The surface cathode layer is to be made up of transparency higher organic polymer film or optical clear glass.The external power supply wire that surface anode layer, surperficial cathode layer are drawn is respectively as the positive and negative electrode external power supply.The nesa coating that inside surface, surperficial cathode layer that the surface anode layer contacts with the electrochromic material layer and the inside surface that the electrolyte conductive layer contacts all apply is indium tin oxide conductive film or zinc paste-aluminium conducting film or tin oxide-titanium dioxide conducting film.External power supply can be the power supply that exchange to change direct current, the direct supply that also can provide by dry cell, silver-colored core battery etc., and can cooperate rheostat to change magnitude of voltage, but also can constant voltage directly supply power.Be to improve antifalse effect, the dedicated variable voltage power supply device of source resistance that can also be the special packaged combination of making as required.
The utility model is the electrochromism antifalsification label that each layer combined closely and formed with the as a whole back of epoxy encapsulation, and this antifalsification label can directly be attached to be needed on the false proof product surface.It is the water white transparency state that outward appearance is observed label, as long as the label additional power source is switched on, can manifest predetermined picture and text when the consumer discerns.
The utility model compared with prior art has the following advantages:
1, because the cross-section structure of the utility model is four layers; And what utilize is that the electrochemical properties of material designs thereby not only simple in structure, production process greatly reduces; Production cost greatly reduces, and has avoided making the problem that the electrochromism anti-counterfeiting mark is brought with nano semiconductor material.
2, because the utility model is the electrochemical properties of the material that utilizes designs, thereby anti-counterfeit recognition is convenient and swift, and this identifying is irreversible in addition, can also avoid being lost antifalse effect by second use.
Description of drawings
Accompanying drawing is the cross-sectional view of the utility model.
Embodiment
Below in conjunction with accompanying drawing and embodiment the utility model is further specified.
Embodiment 1
Shown in accompanying drawing; The electrochromism antifalsification label that present embodiment provides from top to bottom is that the lead 5 of the external power supply of drawing by surperficial anode layer 1, electrochromic material layer 2, electrolyte conductive layer 3, surperficial cathode layer 4 and by surperficial anode layer 1, surperficial cathode layer 4 constitutes successively, and the antifalsification label pattern is arranged in electrochromic material layer 2.
Surperficial anode layer 1, the surperficial cathode layer 4 of present embodiment are optical clear glass, and the inside surface that the inside surface that surperficial anode layer 1 contacts with electrochromic material layer 2, surperficial cathode layer 4 contact with electrolyte conductive layer 3 is coated with the indium tin oxide transparent conducting film.Electrochromic material layer 2 is processed by tungstic acid, and electrolyte conductive layer 3 is LiClO
4The gel rubber system that-PMMA-PC constitutes.
Embodiment 2
Shown in accompanying drawing; The electrochromism antifalsification label that present embodiment provides from top to bottom is that the lead 5 of the external power supply of drawing by surperficial anode layer 1, electrochromic material layer 2, electrolyte conductive layer 3, surperficial cathode layer 4 and by surperficial anode layer 1, surperficial cathode layer 4 constitutes successively, and the antifalsification label pattern etch is in electrochromic material layer 2.
Surperficial anode layer 1, the surperficial cathode layer 4 of present embodiment are optical clear glass, and the inside surface that the inside surface that surperficial anode layer 1 contacts with electrochromic material layer 2, surperficial cathode layer 4 contact with electrolyte conductive layer 3 is coated with zinc paste-aluminium nesa coating.Electrochromic material layer 2 is a polyaniline, and electrolyte conductive layer 3 is LiClO
4-PMMA-PC gel rubber system.
Embodiment 3
Shown in accompanying drawing; The electrochromism antifalsification label that present embodiment provides from top to bottom is that the lead 5 of the external power supply of drawing by surperficial anode layer 1, electrochromic material layer 2, electrolyte conductive layer 3, surperficial cathode layer 4 and by surperficial anode layer 1, surperficial cathode layer 4 constitutes successively, and the antifalsification label pattern etch is in electrochromic material layer 2.
Surperficial anode layer 1, the surperficial cathode layer 4 of present embodiment are mylar, and the inside surface that the inside surface that surperficial anode layer 1 contacts with electrochromic material layer 2, surperficial cathode layer 4 contact with electrolyte conductive layer 3 is coated with tin oxide-titanium dioxide nesa coating.Electrochromic material layer 2 is a polythiofuran derivative PEDOT film, and electrolyte conductive layer 3 is the TBAP-PMMA-PC gel rubber system.
Claims (2)
1. electrochromism antifalsification label; This label comprises surperficial anode layer (1), surperficial cathode layer (4), electrochromic material layer (2) and the lead (5) of the external power supply of being drawn by surperficial anode layer (1), surperficial cathode layer (4); It is characterized in that also being provided with an electrolyte conductive layer (3) between surperficial anode layer (1) and the electrochromic material layer (2), wherein the antifalsification label pattern is positioned at electrochromic material layer (2).
2. electrochromism antifalsification label according to claim 1 is characterized in that inside surface, surperficial cathode layer (4) that the surperficial anode layer (1) of this label contacts with electrochromic material layer (2) are coated with nesa coating with the inside surface that electrolyte conductive layer (3) contacts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012200472954U CN202422588U (en) | 2012-02-14 | 2012-02-14 | Electrochromic anti-counterfeiting label |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012200472954U CN202422588U (en) | 2012-02-14 | 2012-02-14 | Electrochromic anti-counterfeiting label |
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| CN202422588U true CN202422588U (en) | 2012-09-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012200472954U Expired - Fee Related CN202422588U (en) | 2012-02-14 | 2012-02-14 | Electrochromic anti-counterfeiting label |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103971590A (en) * | 2013-02-01 | 2014-08-06 | 比亚迪股份有限公司 | Anti-counterfeiting trademark and manufacturing method thereof |
| CN105608988A (en) * | 2016-03-02 | 2016-05-25 | 闫河 | Intelligent label capable of reminding commodity expiry |
| WO2016165527A1 (en) * | 2015-04-14 | 2016-10-20 | 京东方科技集团股份有限公司 | Anti-counterfeit label and manufacturing method therefor |
| CN106355992A (en) * | 2016-10-16 | 2017-01-25 | 华中科技大学 | Intelligent tag for monitoring product storage life |
| CN107248368A (en) * | 2017-08-16 | 2017-10-13 | 河南科技大学 | One kind can invisible two-dimensional codes mark, Quick Response Code mark preparation method and application method |
| CN107403583A (en) * | 2016-05-20 | 2017-11-28 | 捷尔革科技股份有限公司 | Electroluminescent transfer-type paster and can electroluminescent transfer label |
| CN110262153A (en) * | 2019-06-06 | 2019-09-20 | 济南嘉源电子有限公司 | One one yard of display screen of screen of one kind and preparation method thereof |
-
2012
- 2012-02-14 CN CN2012200472954U patent/CN202422588U/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103971590A (en) * | 2013-02-01 | 2014-08-06 | 比亚迪股份有限公司 | Anti-counterfeiting trademark and manufacturing method thereof |
| CN103971590B (en) * | 2013-02-01 | 2017-02-22 | 比亚迪股份有限公司 | Anti-counterfeiting trademark and manufacturing method thereof |
| WO2016165527A1 (en) * | 2015-04-14 | 2016-10-20 | 京东方科技集团股份有限公司 | Anti-counterfeit label and manufacturing method therefor |
| US10037719B2 (en) | 2015-04-14 | 2018-07-31 | Boe Technology Group Co., Ltd. | Forgery-proof label and fabrication method thereof |
| CN105608988A (en) * | 2016-03-02 | 2016-05-25 | 闫河 | Intelligent label capable of reminding commodity expiry |
| CN107403583A (en) * | 2016-05-20 | 2017-11-28 | 捷尔革科技股份有限公司 | Electroluminescent transfer-type paster and can electroluminescent transfer label |
| CN106355992A (en) * | 2016-10-16 | 2017-01-25 | 华中科技大学 | Intelligent tag for monitoring product storage life |
| CN106355992B (en) * | 2016-10-16 | 2018-04-10 | 华中科技大学 | A kind of intelligent label for being used to monitor product shelf life limit |
| CN107248368A (en) * | 2017-08-16 | 2017-10-13 | 河南科技大学 | One kind can invisible two-dimensional codes mark, Quick Response Code mark preparation method and application method |
| CN110262153A (en) * | 2019-06-06 | 2019-09-20 | 济南嘉源电子有限公司 | One one yard of display screen of screen of one kind and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120905 Termination date: 20170214 |
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| CF01 | Termination of patent right due to non-payment of annual fee |