CN202297901U - High-temperature resistant anti-ultraviolet composite fiber material - Google Patents

High-temperature resistant anti-ultraviolet composite fiber material Download PDF

Info

Publication number
CN202297901U
CN202297901U CN2011204112686U CN201120411268U CN202297901U CN 202297901 U CN202297901 U CN 202297901U CN 2011204112686 U CN2011204112686 U CN 2011204112686U CN 201120411268 U CN201120411268 U CN 201120411268U CN 202297901 U CN202297901 U CN 202297901U
Authority
CN
China
Prior art keywords
temperature resistant
performance
fiber
fiber material
high temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2011204112686U
Other languages
Chinese (zh)
Inventor
李光
莫鑫
金俊弘
杨胜林
江建明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Donghua University
Original Assignee
Donghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Donghua University filed Critical Donghua University
Priority to CN2011204112686U priority Critical patent/CN202297901U/en
Application granted granted Critical
Publication of CN202297901U publication Critical patent/CN202297901U/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Abstract

The utility model relates to a composite fiber material, in particular to a high-temperature resistant anti-ultraviolet composite fiber material which is a high-performance fiber material comprising a PBO (polybenzoxazole) fiber sandwich layer and a polyimide outer layer. The high-temperature resistant anti-ultraviolet composite fiber material adopts a coating structure. The coating structure comprises the PBO fiber sandwich layer and the polyimide outer layer, wherein the polyimide outer layer is coated on the PBO fiber sandwich layer. The high-performance fiber material can be used as a textile fiber composite material for making a rope, a net and woven fabric used in special environments, so as to remarkably improve the heat resistance and the anti-ultraviolet performance while ensuring the fine performance of the PBO fiber. Therefore, the high-performance fiber material can be extensively applied to the fields of the aeronautics and astronautics industry, the petrochemical industry, the power industry and the like, and has a favorable protective performance and a favorable protective effect.

Description

A kind of high temperature resistant uvioresistant composite fibre
Technical field
The utility model relates to a kind of compound fibrous material, particularly relates to a kind of high temperature resistant uvioresistant composite fibre with high temperature resistant uvioresistant performance, specifically relates to the outer high performance fibre material of forming of pbo fiber sandwich layer and a kind of polyimides
Background technology
Polyparaphenylene Ben Bing Er oxazole fiber (be called for short pbo fiber, down with) is in the present high-performance fiber field, and one of high-performance fiber that combination property is the most excellent has excellent mechanical property, heat-resisting, fire resistance, solvent resistance etc.As being example with pbo fiber
Figure BDA0000101185250000011
; Its TENSILE STRENGTH is 5.8GPa; Stretch modulus is 300GPa; Be respectively the twice of PPTA fiber, Zylon also has excellent heat endurance (heat decomposition temperature is up to 650 ℃) and anti-flammability (LOI=68).Pbo fiber has very wide application prospect and important use to be worth at aspects such as Aero-Space, protective materials, national defense and military, sports equipments, the irreplaceable effect of other material is arranged.
Though pbo fiber has mechanical property and heat resistance preferably, pbo fiber is under UV-irradiation, and decline by a relatively large margin can appear in the mechanical property of fiber, and this greatly influences or has limited the application of pbo fiber in advanced field of compound material.For this reason, how to produce uvioresistant pbo fiber composite and become the key issue that letter need solve.
Summary of the invention
The purpose of the utility model provides a kind of fibrous material with excellent properties, is specifically to be applicable to general processing and manufacturing equipment, can widely usedly have high temperature resistant uvioresistant fibrous material.The utility model problem to be solved provides a kind of fibrous material; Be particularly related to a kind of fiber with high temperature resistant uvioresistant performance; Specifically relate to the outer high performance fibre material of forming of pbo fiber sandwich layer and polyimides; Structure is a clad structure, and described clad structure comprises pbo fiber sandwich layer and polyimides skin.The high performance fibre material of the utility model; Can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.
For realizing above purpose, a kind of high temperature resistant uvioresistant composite fibre of the utility model is a clad structure, and described clad structure comprises pbo fiber sandwich layer and polyimides skin, and described polyimides skin is coated on the pbo fiber sandwich layer.
As optimized technical scheme:
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the denier range of described pbo fiber is 5~500D.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, described pbo fiber sandwich layer and polyimides skin are coaxial.
A kind of high temperature resistant uvioresistant composite fibre of the utility model is made up of a sandwich layer and a clad, and it is the pbo fiber of 5~500D that heart yarn adopts denier range, and clad adopts polyimides.
A kind of high temperature resistant uvioresistant composite fibre of the utility model can adopt following production method to make, and comprises the steps:
A: the preparation of coating layer material
The preparation of polyimides: by the polyimides that polyalkyl-substituted aromatic diamine monomer makes, the polyimide structures formula of gained is:
Figure BDA0000101185250000031
B: the preparation of high temperature resistant uvioresistant composite fibre
The polyimides and the pbo fiber of preparation are extruded coating with twin-screw, and extrusion temperature is controlled at about 175 ℃, obtains the high temperature resistant uvioresistant composite fibre of different thicknesses through the denier range that changes synnema.Add a tensometer before the spray silk template and the concentricity of composite fibre is controlled in the fine setting of bag core mold plate through getting into, polyimides is coated on the pbo fiber equably at synnema.
Beneficial effect
The high performance fibre material of the utility model; Can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.
Description of drawings
Accompanying drawing is the structural representation of a kind of high temperature resistant uvioresistant composite fibre of the utility model
Wherein 1 is that pbo fiber sandwich layer 2 is that polyimides is outer
The specific embodiment
Below in conjunction with the specific embodiment, further set forth the utility model.
Shown in accompanying drawing, be a kind of high temperature resistant uvioresistant composite fibre of the utility model, be clad structure, described clad structure comprises pbo fiber sandwich layer 1 and polyimides skin 2, described polyimides outer 2 is coated on the described pbo fiber sandwich layer 1.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the denier range of described high temperature resistant uvioresistant composite fibre is 5~500D.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, described pbo fiber sandwich layer 1 is coaxial with polyimides outer 2.
Through evidence; A kind of high temperature resistant uvioresistant composite fibre of the utility model is a high performance fibre material, can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.

Claims (4)

1. high temperature resistant uvioresistant composite fibre; It is characterized in that: described high temperature resistant uvioresistant composite fibre is a clad structure; Described clad structure comprises pbo fiber sandwich layer and polyimides skin, and described polyimides skin is coated on the described pbo fiber sandwich layer.
2. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that the denier range of described pbo fiber is 5~500D.
3. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
4. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that, described pbo fiber sandwich layer and polyimides skin are coaxial.
CN2011204112686U 2011-10-22 2011-10-22 High-temperature resistant anti-ultraviolet composite fiber material Expired - Lifetime CN202297901U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011204112686U CN202297901U (en) 2011-10-22 2011-10-22 High-temperature resistant anti-ultraviolet composite fiber material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011204112686U CN202297901U (en) 2011-10-22 2011-10-22 High-temperature resistant anti-ultraviolet composite fiber material

Publications (1)

Publication Number Publication Date
CN202297901U true CN202297901U (en) 2012-07-04

Family

ID=46366835

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011204112686U Expired - Lifetime CN202297901U (en) 2011-10-22 2011-10-22 High-temperature resistant anti-ultraviolet composite fiber material

Country Status (1)

Country Link
CN (1) CN202297901U (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108794943A (en) * 2017-05-03 2018-11-13 江苏先诺新材料科技有限公司 A kind of antifriction self-lubricating composite and its preparation method and application
CN110845345A (en) * 2019-11-26 2020-02-28 中国科学院长春应用化学研究所 Aromatic diamine monomer and preparation method thereof
CN112647155A (en) * 2020-11-26 2021-04-13 中蓝晨光化工有限公司 Preparation method of PIPD (Poly ethylene-propylene-diene monomer) coated PBO (Poly ethylene-propylene-diene monomer) composite fiber and spinning equipment thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108794943A (en) * 2017-05-03 2018-11-13 江苏先诺新材料科技有限公司 A kind of antifriction self-lubricating composite and its preparation method and application
CN108794943B (en) * 2017-05-03 2020-08-21 江苏先诺新材料科技有限公司 Wear-resistant self-lubricating composite material and preparation method and application thereof
CN110845345A (en) * 2019-11-26 2020-02-28 中国科学院长春应用化学研究所 Aromatic diamine monomer and preparation method thereof
CN112647155A (en) * 2020-11-26 2021-04-13 中蓝晨光化工有限公司 Preparation method of PIPD (Poly ethylene-propylene-diene monomer) coated PBO (Poly ethylene-propylene-diene monomer) composite fiber and spinning equipment thereof

Similar Documents

Publication Publication Date Title
Das et al. Preparation, development, outcomes, and application versatility of carbon fiber-based polymer composites: a review
TWI567118B (en) Composite materials
CN101910480B (en) Processes for producing flameproof fiber and carbon fiber
CN102444023B (en) Method for preparing polyaniline composite nano silver conductive fibers
CN202297901U (en) High-temperature resistant anti-ultraviolet composite fiber material
JP2020033542A (en) Conductive compositions of conductive polymer and metal coated fiber
JP2015074844A (en) Carbon fiber and method for producing the same
KR20230060513A (en) Aramid nanofiber composite unidirectional fabric and manufacturing method thereof
CN102555103B (en) Preparation method for domestic carbon cloth pre-impregnated adhesive tape
Shioya et al. Synthetic textile fibres: non-polymer fibres
JP5561446B1 (en) Carbon fiber bundle manufacturing method and carbon fiber bundle
CN105648807A (en) Production method of high-tenacity fiber pulling rope
Zhu et al. Joule heating synthesis of carbon fiber/graphene 3D crosslinked structure for lightning strike protection and electromagnetic interference in aerospace composites
Tang et al. Flexible metalized polyimide nonwoven fabrics for efficient electromagnetic interference shielding
TWI793219B (en) Manufacturing method of carbon fiber
CN105506785B (en) A kind of low-density high-strength high-modulus acrylonitrile base carbon fiber and preparation method thereof
US20160145775A1 (en) Single yarn, single yarn product, and preparation method therefor
CN104177827A (en) Polysulfonamide-based carbon fiber reinforced composite material and preparation method thereof
CN111256539B (en) Bulletproof stab-resistant material and manufacturing method thereof
CN201420130Y (en) Basalt fiber sewing thread
AU2017352687B2 (en) Train window structure and train having same
CN107794749B (en) Graphene-reinforced para-position aromatic polyamide fiber bundle and preparation method thereof
CN104611820A (en) Basalt fiber woven fabric and manufacturing method thereof
KR101729034B1 (en) Power cables with cross-functional protective clothing
KR20150069163A (en) A method of preparing thermoplastic prepreg

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20120704