CN202297901U - High-temperature resistant anti-ultraviolet composite fiber material - Google Patents
High-temperature resistant anti-ultraviolet composite fiber material Download PDFInfo
- Publication number
- CN202297901U CN202297901U CN2011204112686U CN201120411268U CN202297901U CN 202297901 U CN202297901 U CN 202297901U CN 2011204112686 U CN2011204112686 U CN 2011204112686U CN 201120411268 U CN201120411268 U CN 201120411268U CN 202297901 U CN202297901 U CN 202297901U
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- temperature resistant
- performance
- fiber
- fiber material
- high temperature
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Abstract
The utility model relates to a composite fiber material, in particular to a high-temperature resistant anti-ultraviolet composite fiber material which is a high-performance fiber material comprising a PBO (polybenzoxazole) fiber sandwich layer and a polyimide outer layer. The high-temperature resistant anti-ultraviolet composite fiber material adopts a coating structure. The coating structure comprises the PBO fiber sandwich layer and the polyimide outer layer, wherein the polyimide outer layer is coated on the PBO fiber sandwich layer. The high-performance fiber material can be used as a textile fiber composite material for making a rope, a net and woven fabric used in special environments, so as to remarkably improve the heat resistance and the anti-ultraviolet performance while ensuring the fine performance of the PBO fiber. Therefore, the high-performance fiber material can be extensively applied to the fields of the aeronautics and astronautics industry, the petrochemical industry, the power industry and the like, and has a favorable protective performance and a favorable protective effect.
Description
Technical field
The utility model relates to a kind of compound fibrous material, particularly relates to a kind of high temperature resistant uvioresistant composite fibre with high temperature resistant uvioresistant performance, specifically relates to the outer high performance fibre material of forming of pbo fiber sandwich layer and a kind of polyimides
Background technology
Polyparaphenylene Ben Bing Er oxazole fiber (be called for short pbo fiber, down with) is in the present high-performance fiber field, and one of high-performance fiber that combination property is the most excellent has excellent mechanical property, heat-resisting, fire resistance, solvent resistance etc.As being example with pbo fiber
; Its TENSILE STRENGTH is 5.8GPa; Stretch modulus is 300GPa; Be respectively the twice of PPTA fiber, Zylon also has excellent heat endurance (heat decomposition temperature is up to 650 ℃) and anti-flammability (LOI=68).Pbo fiber has very wide application prospect and important use to be worth at aspects such as Aero-Space, protective materials, national defense and military, sports equipments, the irreplaceable effect of other material is arranged.
Though pbo fiber has mechanical property and heat resistance preferably, pbo fiber is under UV-irradiation, and decline by a relatively large margin can appear in the mechanical property of fiber, and this greatly influences or has limited the application of pbo fiber in advanced field of compound material.For this reason, how to produce uvioresistant pbo fiber composite and become the key issue that letter need solve.
Summary of the invention
The purpose of the utility model provides a kind of fibrous material with excellent properties, is specifically to be applicable to general processing and manufacturing equipment, can widely usedly have high temperature resistant uvioresistant fibrous material.The utility model problem to be solved provides a kind of fibrous material; Be particularly related to a kind of fiber with high temperature resistant uvioresistant performance; Specifically relate to the outer high performance fibre material of forming of pbo fiber sandwich layer and polyimides; Structure is a clad structure, and described clad structure comprises pbo fiber sandwich layer and polyimides skin.The high performance fibre material of the utility model; Can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.
For realizing above purpose, a kind of high temperature resistant uvioresistant composite fibre of the utility model is a clad structure, and described clad structure comprises pbo fiber sandwich layer and polyimides skin, and described polyimides skin is coated on the pbo fiber sandwich layer.
As optimized technical scheme:
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the denier range of described pbo fiber is 5~500D.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, described pbo fiber sandwich layer and polyimides skin are coaxial.
A kind of high temperature resistant uvioresistant composite fibre of the utility model is made up of a sandwich layer and a clad, and it is the pbo fiber of 5~500D that heart yarn adopts denier range, and clad adopts polyimides.
A kind of high temperature resistant uvioresistant composite fibre of the utility model can adopt following production method to make, and comprises the steps:
A: the preparation of coating layer material
The preparation of polyimides: by the polyimides that polyalkyl-substituted aromatic diamine monomer makes, the polyimide structures formula of gained is:
B: the preparation of high temperature resistant uvioresistant composite fibre
The polyimides and the pbo fiber of preparation are extruded coating with twin-screw, and extrusion temperature is controlled at about 175 ℃, obtains the high temperature resistant uvioresistant composite fibre of different thicknesses through the denier range that changes synnema.Add a tensometer before the spray silk template and the concentricity of composite fibre is controlled in the fine setting of bag core mold plate through getting into, polyimides is coated on the pbo fiber equably at synnema.
Beneficial effect
The high performance fibre material of the utility model; Can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.
Description of drawings
Accompanying drawing is the structural representation of a kind of high temperature resistant uvioresistant composite fibre of the utility model
Wherein 1 is that pbo fiber sandwich layer 2 is that polyimides is outer
The specific embodiment
Below in conjunction with the specific embodiment, further set forth the utility model.
Shown in accompanying drawing, be a kind of high temperature resistant uvioresistant composite fibre of the utility model, be clad structure, described clad structure comprises pbo fiber sandwich layer 1 and polyimides skin 2, described polyimides outer 2 is coated on the described pbo fiber sandwich layer 1.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the denier range of described high temperature resistant uvioresistant composite fibre is 5~500D.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
Aforesaid a kind of high temperature resistant uvioresistant composite fibre, described pbo fiber sandwich layer 1 is coaxial with polyimides outer 2.
Through evidence; A kind of high temperature resistant uvioresistant composite fibre of the utility model is a high performance fibre material, can be used as rope, net that under particular surroundings, uses and the textile fabric composite of weaving lining; When guaranteeing the pbo fiber premium properties; Improve heat resistance and uvioresistant performance significantly, made it can be widely used in fields such as Aero-Space, petrochemical industry and power industry, had excellent protection performance and protective action.
Claims (4)
1. high temperature resistant uvioresistant composite fibre; It is characterized in that: described high temperature resistant uvioresistant composite fibre is a clad structure; Described clad structure comprises pbo fiber sandwich layer and polyimides skin, and described polyimides skin is coated on the described pbo fiber sandwich layer.
2. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that the denier range of described pbo fiber is 5~500D.
3. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that the diameter of described high temperature resistant uvioresistant composite fibre is 0.1~2.5mm.
4. a kind of high temperature resistant uvioresistant composite fibre according to claim 1 is characterized in that, described pbo fiber sandwich layer and polyimides skin are coaxial.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2011204112686U CN202297901U (en) | 2011-10-22 | 2011-10-22 | High-temperature resistant anti-ultraviolet composite fiber material |
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CN2011204112686U CN202297901U (en) | 2011-10-22 | 2011-10-22 | High-temperature resistant anti-ultraviolet composite fiber material |
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CN202297901U true CN202297901U (en) | 2012-07-04 |
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CN2011204112686U Expired - Lifetime CN202297901U (en) | 2011-10-22 | 2011-10-22 | High-temperature resistant anti-ultraviolet composite fiber material |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108794943A (en) * | 2017-05-03 | 2018-11-13 | 江苏先诺新材料科技有限公司 | A kind of antifriction self-lubricating composite and its preparation method and application |
CN110845345A (en) * | 2019-11-26 | 2020-02-28 | 中国科学院长春应用化学研究所 | Aromatic diamine monomer and preparation method thereof |
CN112647155A (en) * | 2020-11-26 | 2021-04-13 | 中蓝晨光化工有限公司 | Preparation method of PIPD (Poly ethylene-propylene-diene monomer) coated PBO (Poly ethylene-propylene-diene monomer) composite fiber and spinning equipment thereof |
-
2011
- 2011-10-22 CN CN2011204112686U patent/CN202297901U/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108794943A (en) * | 2017-05-03 | 2018-11-13 | 江苏先诺新材料科技有限公司 | A kind of antifriction self-lubricating composite and its preparation method and application |
CN108794943B (en) * | 2017-05-03 | 2020-08-21 | 江苏先诺新材料科技有限公司 | Wear-resistant self-lubricating composite material and preparation method and application thereof |
CN110845345A (en) * | 2019-11-26 | 2020-02-28 | 中国科学院长春应用化学研究所 | Aromatic diamine monomer and preparation method thereof |
CN112647155A (en) * | 2020-11-26 | 2021-04-13 | 中蓝晨光化工有限公司 | Preparation method of PIPD (Poly ethylene-propylene-diene monomer) coated PBO (Poly ethylene-propylene-diene monomer) composite fiber and spinning equipment thereof |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20120704 |