CN202246327U - Improved electric Fenton wastewater treatment equipment - Google Patents

Improved electric Fenton wastewater treatment equipment Download PDF

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Publication number
CN202246327U
CN202246327U CN201120400422XU CN201120400422U CN202246327U CN 202246327 U CN202246327 U CN 202246327U CN 201120400422X U CN201120400422X U CN 201120400422XU CN 201120400422 U CN201120400422 U CN 201120400422U CN 202246327 U CN202246327 U CN 202246327U
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China
Prior art keywords
treatment equipment
electrolyzer
sewage treatment
dividing plate
improved
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Expired - Fee Related
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CN201120400422XU
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Chinese (zh)
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张晖
张俊
李江波
张道斌
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Wuhan University WHU
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Wuhan University WHU
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Abstract

The utility model relates to wastewater treatment equipment, in particular to improved electric Fenton wastewater treatment equipment, which is characterized by comprising a wastewater storage tank (1), an electrolysis device (3) and a wastewater precipitation device (5). The electrolysis device (3) is communicated with the wastewater storage tank (1) via a liquid inlet pipe (2), and the wastewater precipitation device (5) is communicated with the electrolysis device (3) via a liquid outlet pipe (4). Accordingly, the improved electric Fenton wastewater treatment equipment has the advantages that 1, the improved electric Fenton wastewater treatment equipment is reasonable in structure and simple in structure and is completely practical, 2, once foam and scum are generated in electric Fenton reaction, the foam and the scum are quickly removed by a slag scraper, and spark is prevented, and 3, generated flocculate is taken away from a liquid surface by bubbles, clear liquid flows out from the lower portion of a flotation tank, precipitation time is shortened, and the quality of outlet water is improved.

Description

A kind of improved Fenton sewage treatment equipment
Technical field
The utility model relates to a kind of sewage treatment equipment, especially relates to a kind of improved Fenton sewage treatment equipment.
Background technology
For the waste water of difficult for biological degradation, generally adopt high-level oxidation technology to handle.The characteristics of high-level oxidation technology are that they all can produce the OH radical.Because the redox potential of OH radical (2.80 v) be much higher than traditional oxygenant (as 1.77 v of 1.36 v of chlorine, ydrogen peroxide 50 and ozone 2.07 v), and it and organic reaction rate constant are 10 8 ~ 10M -1s -1Between, so it can decompose the organism of common oxygenant intractable rapidly.In various high-level oxidation technologies, the Fenton method comes into one's own because of easy and simple to handle, with low cost day by day.The Fenton process generally comprises following four-stage: i.e. pH regulator, oxidizing reaction, neutralization and coagulation and precipitate phase.But, can produce more mud at precipitate phase because Fe (II) ionic adds.For remedying these deficiencies of common Fenton method; People propose electrochemical process and combine with the Fenton method (being the Fenton method), when electrochemical process and Fenton method combine, can produce synergistic effect; Improve the clearance of COD thus, reduce the generation of mud simultaneously.Fenton comprises the four-stage of Fenton equally.
In the Fenton oxidizing reaction stage of even flow, the bubble that cathode and anode produces can form significant foam and scum silica frost from liquid level with the suspended matter band in the waste water, and is deposited on the liquid level, thereby has influenced the rapid diffusion of gas.If what adopt is the electrolyzer of band aerator, foam and scum silica frost more are easy to generate.Along with the carrying out of reaction, foam and scum silica frost constantly increase, and then have wrapped up the tie point of lead and battery lead plate, have caused potential safety hazards such as spark or blast.
Another phenomenon occurs in precipitate phase.Iron mud sedimentation effect in the traditional secondary settling tank is unsatisfactory, in 1 ~ 2 hour, still has small flco in the pond, and has quite a few to accumulate on the liquid level.This certainly will influence effluent quality.
The utility model content
The utility model mainly is to solve the Fenton oxidizing reaction stage of existing in prior technology in even flow; The bubble that cathode and anode produces can form significant foam and scum silica frost from liquid level with the suspended matter band in the waste water; And be deposited on the liquid level, thereby influenced the rapid diffusion of gas.If what adopt is the electrolyzer of band aerator, foam and scum silica frost more are easy to generate.Along with the carrying out of reaction, foam and scum silica frost constantly increase, and then have wrapped up the tie point of lead and battery lead plate, have caused the technical problem of potential safety hazards such as spark or blast etc.; Providing a kind of Fenton to react once producing foam and scum silica frost is just removed by slag scraper rapidly; Lead is connected in the space of sealing with battery lead plate; Lead does not contact with scum silica frost with the foam of liquid, generation with tie point fully, has avoided a kind of improved Fenton sewage treatment equipment of the generation of spark.
It is that solution existing in prior technology iron mud sedimentation effect in the traditional secondary settling tank is unsatisfactory that the utility model also has a purpose, in 1 ~ 2 hour, still has small flco in the pond, and has quite a few to accumulate on the liquid level.This certainly will influence the technical problem of effluent quality etc.; Provide a kind of flco of generation to leave liquid level by the bubble band, clear liquid is flowed out by the air flotation pool bottom, has shortened the ST, has improved a kind of improved Fenton sewage treatment equipment of effluent quality.
The above-mentioned technical problem of the utility model mainly is able to solve through following technical proposals:
A kind of improved Fenton sewage treatment equipment is characterized in that, the electrolyzer that comprise waste water tank, is communicated with through liquid-inlet pipe with said waste water tank and pass through the wastewater sedimentation device that drain pipe is communicated with said electrolyzer.
The utility model is creationary to be provided with slag scraper on the traditional formula of seething electrolyzer; Lead and pole plate connective slot, lead fairlead are set; Substitute the traditional secondary settling tank with air flotation pool.The scum silica frost and the foam that produce during through the scavenge system operation in time of the Fenton device after improving improve processing efficiency; Can guarantee good insulating property, reduce dangerous occurrence probability; Use air flotation pool can under short hydraulic detention time, improve effluent quality.
At above-mentioned a kind of improved Fenton sewage treatment equipment; The slag scraper that described electrolyzer comprises an electrolyzer, is arranged on the some dividing plates in the electrolyzer and is arranged on the dividing plate top; Be provided with one deck battery lead plate at least between the adjacent separator; Groove is embedded on the said dividing plate on the dividing plate through being opened in said battery lead plate both sides, and said dividing plate one end also is provided with electric installation.
At above-mentioned a kind of improved Fenton sewage treatment equipment; Said electric installation comprises the connective slot that is opened in dividing plate one end; The lead fairlead passes aforementioned barriers and puts in the said connective slot, also is provided with in the said connective slot said lead fairlead one end is enclosed in the sealer coat in the connective slot.
At above-mentioned a kind of improved Fenton sewage treatment equipment; The wastewater sedimentation device comprises an air flotation pool; Said air flotation pool bottom communicates with above-mentioned electrolyzer through drain pipe; This air flotation pool bottom also is provided with an end and puts in and be used to the ventpipe of ventilating in the air flotation pool, is provided with valve and air pump successively on the said ventpipe the other end and extraneous that communicate and the ventpipe the other end.
A kind of improved Fenton sewage treatment equipment above-mentioned also is disposed with liquid flowing valve and constant flow pump on the said liquid-inlet pipe.
At above-mentioned a kind of improved Fenton sewage treatment equipment, also be provided with the alkali lye funnel that is used to put into alkali lye entering drain pipe on the said drain pipe, said electrolyzer bottom also is provided with micropore aeration pipe.
Therefore, the utlity model has following advantage: 1. reasonable in design, simple in structure and complete practicality; 2. Fenton reacts once producing foam and scum silica frost and is just removed by slag scraper rapidly, and lead is connected in the space of sealing with battery lead plate, and lead does not contact with scum silica frost with the foam of liquid, generation with tie point fully, has avoided the generation of spark; 3. from liquid level, clear liquid is flowed out by the air flotation pool bottom flco that produces, and has shortened the ST, has improved effluent quality by the bubble band.
Description of drawings
Fig. 1 is the structural principle synoptic diagram of the utility model.
The A place analyses and observe the structure for amplifying synoptic diagram along the B-B line among Fig. 2 Fig. 1.
Embodiment
Pass through embodiment below, and combine accompanying drawing, do further bright specifically the technical scheme of the utility model.Among the figure, waste water tank 1, liquid-inlet pipe 2, electrolyzer 3, drain pipe 4, wastewater sedimentation device 5, electrolyzer 6, dividing plate 7, slag scraper 8, battery lead plate 9, electric installation 10, connective slot 11, lead fairlead 12, air flotation pool 13, ventpipe 14, valve 15, air pump 16, liquid flowing valve 17, constant flow pump 18, alkali lye funnel 20, micropore aeration pipe 21.
Embodiment:
A kind of improved Fenton sewage treatment equipment, the electrolyzer 3 that comprise waste water tank 1, is communicated with through liquid-inlet pipe 2 with waste water tank 1 and pass through the wastewater sedimentation device 5 that drain pipe 4 is communicated with said electrolyzer 3.
Electrolyzer 3 comprises an electrolyzer 6, is arranged on some dividing plates 7 in the electrolyzer 6 and the slag scraper 8 that is arranged on dividing plate 7 tops; Be provided with one deck battery lead plate 9 at least between the adjacent separator 7; Groove is embedded on the dividing plate 7 on the dividing plate 7 through being opened in battery lead plate 9 both sides; Dividing plate 7 one ends also are provided with electric installation 10, and electric installation 10 comprises the connective slot 11 that is opened in dividing plate 7 one ends, and lead fairlead 12 passes dividing plate 7 and puts in the said connective slot 11; Also be provided with in the connective slot 11 lead fairlead 12 1 ends are enclosed in the sealer coat in the connective slot 11; Wastewater sedimentation device 5 comprises an air flotation pool 13, and air flotation pool 13 bottoms communicate with above-mentioned electrolyzer 6 through drain pipe 4, and these air flotation pool 13 bottoms also are provided with an end and put in the ventpipe 14 that is used to ventilate in the air flotation pool 13; Be provided with valve 15 and air pump 16 successively on ventpipe 14 the other ends and extraneous that communicate and ventpipe 14 the other ends; Also be disposed with liquid flowing valve 17 and constant flow pump 18 on the liquid-inlet pipe 2, also be provided with the alkali lye funnel 20 that is used to put into alkali lye entering drain pipe 4 on the drain pipe 4, electrolyzer 6 bottoms also are provided with micropore aeration pipe 21.
When making, should note Material Selection, all parts that contact with solution before the alkali lye funnel 20 all should possess acid-resistant property.Electrolyzer 6 adopts bipolar system to seethe the formula electrolyzer, and the mass transfer in the time of can making reaction is more abundant, and wiring is easy in addition, can be used as first-selection during design.Battery lead plate is adjusted the utmost point water ratio of reaction process for ease in the electrolyzer 6, but the distance calculated in advance between the groove, but groove number should be even number.
As shown in Figure 2, lead is introduced through lead fairlead 12, and battery lead plate 9 has only one jiao to stretch in the groove.During installation, after battery lead plate 9 stretched into groove, sealer coat adopted insulating material to come all slits of closed electrolysis cells 6 to guarantee and extraneous sealing.So an outmost cathode-anode plate all is fixed.Slag scraper is installed on connective slot 11 tops at last.
During operation, at first fill with waste water tank 1, open agitator motor, add acid solution to predetermined pH value.Open liquid flowing valve 17 successively, open constant flow pump 18, when treating that electrolyzer 6 right-hand members begin overflow, add ydrogen peroxide 50, ferrous, alkali lye, open direct supply, electrolyzer air pump, valve 15 and air pump 16 simultaneously, but slag scraper 8 intermittent operatioies.
Specific embodiment described herein only is that the utility model spirit is illustrated.The utility model person of ordinary skill in the field can make various modifications or replenishes or adopt similar mode to substitute described specific embodiment, but can't depart from the spirit of the utility model or surmount the defined scope of appended claims.
Although this paper has used terms such as waste water tank 1, liquid-inlet pipe 2, electrolyzer 3, drain pipe 4, wastewater sedimentation device 5, electrolyzer 6, dividing plate 7, slag scraper 8, battery lead plate 9, electric installation 10, connective slot 11, lead fairlead 12, air flotation pool 13, ventpipe 14, valve 15, air pump 16, liquid flowing valve 17, constant flow pump 18, alkali lye funnel 20, micropore aeration pipe 21 morely, do not get rid of the possibility of using other term.Using these terms only is in order to describe and explain the essence of the utility model more easily; It all is contrary with the utility model spirit being construed to any additional restriction to them.

Claims (6)

1. improved Fenton sewage treatment equipment; It is characterized in that the electrolyzer (3) that comprise waste water tank (1), is communicated with through liquid-inlet pipe (2) with said waste water tank (1) and pass through the wastewater sedimentation device (5) that drain pipe (4) is communicated with said electrolyzer (3).
2. a kind of improved Fenton sewage treatment equipment according to claim 1; It is characterized in that; The slag scraper (8) that described electrolyzer (3) comprises an electrolyzer (6), is arranged on the some dividing plates (7) in the electrolyzer (6) and is arranged on dividing plate (7) top; Be provided with one deck battery lead plate (9) at least between the adjacent separator (7); Said battery lead plate (9) both sides are embedded on the said dividing plate (7) through being opened in the last groove of dividing plate (7), and said dividing plate (7) one ends also are provided with electric installation (10).
3. a kind of improved Fenton sewage treatment equipment according to claim 2; It is characterized in that; Said electric installation (10) comprises the connective slot (11) that is opened in dividing plate (7) one ends; Lead fairlead (12) passes aforementioned barriers (7) and puts in the said connective slot (11), also is provided with in the said connective slot (11) said lead fairlead (12) one ends are enclosed in the sealer coat in the connective slot (11).
4. a kind of improved Fenton sewage treatment equipment according to claim 2; It is characterized in that; Wastewater sedimentation device (5) comprises an air flotation pool (13); Said air flotation pool (13) bottom communicates with above-mentioned electrolyzer (6) through drain pipe (4); This air flotation pool (13) bottom also is provided with an end and puts in the ventpipe (14) that is used to ventilate in the air flotation pool (13), is provided with valve (15) and air pump (16) successively on said ventpipe (14) the other end and extraneous that communicate and ventpipe (14) the other end.
5. a kind of improved Fenton sewage treatment equipment according to claim 1 is characterized in that, also is disposed with liquid flowing valve (17) and constant flow pump (18) on the said liquid-inlet pipe (2).
6. a kind of improved Fenton sewage treatment equipment according to claim 2; It is characterized in that; Also be provided with the alkali lye funnel (20) that is used to put into alkali lye entering drain pipe (4) on the said drain pipe (4), said electrolyzer (6) bottom also is provided with micropore aeration pipe (21).
CN201120400422XU 2011-10-20 2011-10-20 Improved electric Fenton wastewater treatment equipment Expired - Fee Related CN202246327U (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102754614A (en) * 2012-07-19 2012-10-31 中国水产科学研究院渔业机械仪器研究所 Seawater shrimp farming air floatation tank structure capable of removing air floatation foam at any time
CN102838189A (en) * 2012-09-13 2012-12-26 大连海事大学 Device and method for treating ship ballast water multifunctionally by electro-fenton like technology
CN102992453A (en) * 2012-10-09 2013-03-27 南京中衡元环保设备有限公司 Two-phase circulating catalytic oxidation device
CN103539296A (en) * 2013-10-31 2014-01-29 四川凯沃环保科技有限公司 Method and device for treating high-concentration nonbiodegradable organic wastewater
CN104310665A (en) * 2014-10-08 2015-01-28 浙江卓锦工程技术有限公司 Pretreatment method of nonionic surfactant wastewater
CN111422954A (en) * 2020-04-14 2020-07-17 中联西北工程设计研究院有限公司 Advanced wastewater treatment method and system for realizing sludge source reduction

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102754614A (en) * 2012-07-19 2012-10-31 中国水产科学研究院渔业机械仪器研究所 Seawater shrimp farming air floatation tank structure capable of removing air floatation foam at any time
CN102838189A (en) * 2012-09-13 2012-12-26 大连海事大学 Device and method for treating ship ballast water multifunctionally by electro-fenton like technology
CN102838189B (en) * 2012-09-13 2013-08-28 大连海事大学 Device and method for treating ship ballast water multifunctionally by electro-fenton like technology
CN102992453A (en) * 2012-10-09 2013-03-27 南京中衡元环保设备有限公司 Two-phase circulating catalytic oxidation device
CN103539296A (en) * 2013-10-31 2014-01-29 四川凯沃环保科技有限公司 Method and device for treating high-concentration nonbiodegradable organic wastewater
CN103539296B (en) * 2013-10-31 2015-10-28 四川凯沃环保科技有限公司 The method of process high density difficult for biological degradation organic waste water and device thereof
CN104310665A (en) * 2014-10-08 2015-01-28 浙江卓锦工程技术有限公司 Pretreatment method of nonionic surfactant wastewater
CN111422954A (en) * 2020-04-14 2020-07-17 中联西北工程设计研究院有限公司 Advanced wastewater treatment method and system for realizing sludge source reduction

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C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120530

Termination date: 20121020