Summary of the invention
The purpose of the utility model provides a kind of high density Nitrilon waste water treatment facility, and the technical problem that solve is to reduce cost for wastewater treatment, improves processing efficiency, and safe and reliable.
The utility model adopts following technical scheme:
The high density Nitrilon waste water treatment facility of the utility model is provided with former fluid cylinder, preheater, first falling-film evaporator, second falling-film evaporator, falling film separator, the climbing-film evaporator that is linked in sequence and rises membrane separation apparatus.
Be serially connected with under meter between said preheater first falling-film evaporator.
Said former fluid cylinder, preheater, under meter, first falling-film evaporator, second falling-film evaporator, falling film separator, climbing-film evaporator and rise membrane separation apparatus and adopt pipe connection.
Said high density Nitrilon waste water treatment facility is provided with vapour compressor; The secondary steam compression back that is used for producing last circulation vapour compressor is as heating steam, is first falling-film evaporator, second falling-film evaporator, falling film separator, climbing-film evaporator and rises membrane separation apparatus and use.
Said high density Nitrilon waste water treatment facility is provided with vacuum pump, is used for seeing the liquid concentrator of the discharge port output that rises membrane separation apparatus off high density Nitrilon waste water treatment facility.
Said high density Nitrilon waste water treatment facility is provided with condensing surface, is used for becoming not condensing discharge after the water quench.
The utility model compared with prior art; Adopt three grades of vaporizers and steam vapour compressor, overcome, cut down the consumption of energy and running cost because of the rising boiling point of Nitrilon waste water owing to concentration rises to influence of evaporation; This low-temperature evaporation; Less scaling, not perishable waste water, the residence time is short, improves processing rate.
Embodiment
Below in conjunction with accompanying drawing and embodiment the technical scheme of the utility model is done further to specify.
As shown in Figure 1; The high density Nitrilon waste water treatment facility of the utility model; Have former fluid cylinder 6, former fluid cylinder 6 is connected the opening for feed of first falling-film evaporator 1 through preheater 5 and under meter 8, and said first falling-film evaporator, 1 discharge port connects the opening for feed of second falling-film evaporator 2; The said second falling-film evaporator discharge port connects falling film separator 10 opening for feeds; Falling film separator 10 discharge ports connect climbing-film evaporator 9 opening for feeds, and the connection of climbing-film evaporator 9 discharge ports rises membrane separation apparatus 11 opening for feeds, rise the discharge port output liquid concentrator of membrane separation apparatus 11.
Vapour compressor 4 uses the secondary steam compression back that vapour compressor in the last circulation 4 produces as heating steam, be first falling-film evaporator 1, second falling-film evaporator 2, falling film separator 10, climbing-film evaporator 9 and rise membrane separation apparatus 11 and export steam.
Vacuum pump 7 is used for seeing the liquid concentrator of the discharge port output that rises membrane separation apparatus 11 off high density Nitrilon waste water treatment facility.
Water coolant becomes not condensing discharge after condensing surface 3 coolings.
Zero(ppm) water is transported to outside the high density Nitrilon waste water treatment facility.
Embodiment; The SUNEVAP-1000 type of former fluid cylinder 6 employing RuiShengHua Science Co., Ltd., Shenzhen City; The only BRF015 type of heat-exchange equipment Manufacturing Co., Ltd is matched in preheater 5 employing Guangzhou; The LDE type of south, under meter 8 employing Guangzhou control automatic equipment ltd, the SUNEVAP-HE02 type of first falling-film evaporator, 1 employing RuiShengHua Science Co., Ltd., Shenzhen City, the SUNEVAP-HE03 type of second falling-film evaporator, 2 employing RuiShengHua Science Co., Ltd., Shenzhen City; The SUNEVAP-SE01 type of falling film separator 10 employing RuiShengHua Science Co., Ltd., Shenzhen City; The SUNEVAP-HE01 type of climbing-film evaporator 9 employing RuiShengHua Science Co., Ltd., Shenzhen City rises the SUNEVAP-SE02 type of membrane separation apparatus 11 employing RuiShengHua Science Co., Ltd., Shenzhen City, the L61LD type of vapour compressor 4 employing Nantong Central-South gas blower ltd; Vacuum pump 7 adopts the CDF type of Guangdong Foshan Water Pump Factory Co., Ltd., and condensing surface 3 specifications are SUNEVAP-1000.
The high density Nitrilon waste water treatment facility of present embodiment, work according to the following steps:
One, before starting outfit, the stoste A (high density Nitrilon waste water) in the former fluid cylinder 6 is input in the preheater 5 through pump.
Two, the bright steam that produces with the outside boiler of high density Nitrilon waste water treatment facility carries out preheating to it, vapor pressure 0.3MPa, and steam is about 500Kg; 66 ℃ of temperature; 30 minutes time, also can adopt electrically heated to replace steam heating, be 2 to 3 hours heat-up time.
Three, when in the preheater 5 during start vaporizer; In the Heat Room of stoste A in pump is admitted to first falling-film evaporator 1 of SS316 stainless steel; Stoste A mode with falling liquid film in Heat Room is evaporated; Steam output is 12 tons/hour, and then with stoste A with in the Heat Room in second falling-film evaporator 2 that is pumped into the SS316 stainless steel, evaporate with the mode of falling liquid film; Steam output is 7.8 tons/hour, and the stoste after evaporation is accomplished in second falling-film evaporator 2 is admitted to and rises membrane separation apparatus 10.
Four, the stoste A after separating is admitted to the Heat Room in the climbing-film evaporator 9 of SS316 stainless steel; In order to prevent the crystallization of inorganic salt in the solution; Adopt the mode that rises film to evaporate; Steam output is 200 liters/hour, reach predefined concentration after, liquid concentrator C squeezes into the liquid concentrator collection cylinder.
Falling film separator 10 is altogether 20031Kg/h with the secondary steam that rises after membrane separation apparatus 11 separates, and temperature is 66 ℃, and rising the liquid concentrator C that membrane separation apparatus 11 separates is 469kg/h, and temperature is 66 ℃.
With falling film separator 10 with rises the secondary steam that membrane separation apparatus 11 separates and then is elevated to 74 ℃ from 66 ℃ through compressing; Squeezing into 5 li on interchanger then heats stoste A; This part vapor condensation Cheng Shui at the same time, its temperature is about 74 ℃, and condensation water quantity is 20031Kg/h.
Water of condensation with preheater 5 in former A liquid carry out heat exchange after, its stoste A temperature is heated to 55 ℃ from 30 ℃.
With preheater 5 in the temperature of the water of condensation of stoste A after carrying out heat exchange drop to 33 ℃ from 74 ℃.
After 55 ℃ stoste A get into preheating chamber, carry out the heat exchange evaporation with the secondary steam that is elevated to 74 ℃ through compression, whole high density Nitrilon waste water treatment facility system reaches thermal equilibrium, does not need this moment outside bright steam to heat.Only need the per hour 360Kw of vapour compressor to keep the thermal equilibrium of total system.
Liquid concentrator C in the high density Nitrilon waste water treatment facility system is discharged to concentrated fluid cylinder in falling film separator 10 with after rising the concentration that reaches design in the membrane separation apparatus 11 by pump.Do not circulate if reach design concentration then return again in the preheating chamber 5, the liquid concentrator C of 469kg/h through detect qualified after discharging.
The evaporation body of the horizontal tube bundle of the utility model is divided into 1,2,3 three parts and adopts single-stage steam vapour compressor, comes to overcome because of acrylic waste water because the rising boiling point of concentration rises increasing to influence of evaporation as far as possible.
In the preconcentration technique of the utility model; Need the stoste A that handles to carry out preheating through over-heat-exchanger and the water of condensation that evaporation produces; Stoste A after the preheating is imitated in the one falling-film evaporator one and is evaporated to 2% concentration from 0.8%; Material is evaporated to 24% by 2% in an effect disome, and material is evaporated to 35% by 24% in an effect trisome.
Imitate regeneration steam that trisome produces after mist eliminator is removed the fine mist that is mingled with in the regeneration steam by one, sucked compression back temperature by the MVR vapour compressor and get a promotion, the boiling point that is enough to overcome 35% acrylic waste water rises.Outlet at vapour compressor is a ultrahigh-temperature steam, utilizes a spot of zero(ppm) water B to spray into, as the usefulness of overheated cooling.This demister can be caught the drop in the steam get off and can not get into the zero(ppm) water B that heat transfer tube internal contamination system produces together with steam, zero(ppm) water B high purity, and vapour compressor can not bring possible etching problem because of a large amount of drops yet simultaneously.
Water of condensation in the pipe is collected into the distillation water pot, heats back discharge system through the distilled water pump pump to zero(ppm) water B heat exchanger liquid in future.After noncondensable gas in the steam and small amount of steam heated through vent condenser liquid in future, noncondensable gas was discharged system, guarantees system's operate continuously.