CN202113760U - Alkaline washing tank, washing tower and adsorption tank system - Google Patents

Alkaline washing tank, washing tower and adsorption tank system Download PDF

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Publication number
CN202113760U
CN202113760U CN2011201731701U CN201120173170U CN202113760U CN 202113760 U CN202113760 U CN 202113760U CN 2011201731701 U CN2011201731701 U CN 2011201731701U CN 201120173170 U CN201120173170 U CN 201120173170U CN 202113760 U CN202113760 U CN 202113760U
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China
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waste gas
adsorption tank
alkaline
alkali
scrubbing tower
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Expired - Fee Related
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CN2011201731701U
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Chinese (zh)
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冯翼飞
刘兴亚
黄波
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倪加明
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Abstract

An alkaline washing tank, washing tower and adsorption tank system comprises a gas inlet and an exhaust outlet. Waste gas generated in viscose fiber production is sucked from the gas inlet of the alkaline washing tank by a fan unit and then is subjected to alkaline washing and spraying uniformly, and residual waste gas is sucked into the washing tower from the gas inlet and is sprayed by the aid of a water washing stage and an alkaline washing stage. The waste gas and liquid medium are in contact reaction, the waste gas contacts with washing liquid flowing on the surface of a filling material sufficiently so that acid or alkaline sewage in the waste gas can be adsorbed. The residual waste gas is sucked into the adsorption tank via the gas inlet arranged at the bottom of the adsorption tank and contacts with activated carbon sufficiently after being adsorbed by activated carbon packing, and after being processed, qualified gas is exhausted to the atmosphere from the exhaust outlet arranged at the top end of the adsorption tank directly. Since the system utilizes high-efficiency air blower, energy efficiency is better. Adsorption effect is fine due to large specific surface area of the filling material. In addition, acid or alkaline waste gas effectively can be treated effectively, and acid and alkaline removal rate can be over 90%.

Description

A kind of alkaline bath, scrubbing tower, adsorption tank system
Technical field:
The utility model relates to the chemical fibre chemical industry.The carbon disulfide that particularly relates in the viscose rayon manufacture process reclaims a kind of alkaline bath of nucleus equipment, scrubbing tower, adsorption tank system.
Background technology:
Viscose rayon is one of chemical fibre that drops into the earliest suitability for industrialized production.Because good hygroscopicity, comfortable and easy to wear, spinnability is good, Chang Yumian, hair or various synthetic fibers blending, interweaves, is used for all kinds of clothes and decorative textile product.High tenacity staple fibre also can be used for industrial goods such as tire cord, conveyer belt.Viscose rayon is that a kind of application is than the wide chemical fiber.The preparation method of viscose rayon is to extract pure alpha-cellulose by cellulosic material to be called pulp, handles with caustic soda, carbon disulfide; Obtain orange-yellow sodium cellulose xanthate; Be dissolved in again in the diluted sodium hydroxide solution, become the spinning solution of thickness, be called viscose glue.Viscose glue promptly is to place at a certain temperature about 18~30 hours through filtration, maturation, to reduce the esterification degree of cellulose xanthate ester, after the deaeration, carries out wet spinning.Coagulating bath is made up of sulfuric acid, sodium sulphate and zinc sulfate, and sodium cellulose xanthate in the viscose glue and the effect of sulfuric acid in the coagulating bath and decompose are cellulose regenerated and separate out, and the gained cellulose fibre becomes viscose rayon after washing, desulfurization, bleaching, drying.In production process of viscose fiber; Produced a large amount of waste gas; Contain a large amount of poisonous carbon disulfide in the waste gas, have hydrogen sulfide and other of peculiar smell to be prone to catch fire, explosive gas, just have one strong sharp aroma to blow against one's face far away, serious physical and mental health that is endangering people and safety.Country began whole system blowdown enterprise not up to standard in 2010; Present domestic chemical fibre industry has the whole nation of carbon disulfide recovery project and has only 2 families, and a family is Jiangxi Sai Deli, is Sole Proprietorship of group of Singapore GoldenEagle International; Another family is the Nanjing Lenzin, is Austria and joint venture of southization group; The rate of recovery with regard to the carbon disulfide retracting device: the Jiangxi Sai Deli rate of recovery is more than 80%, and the Nanjing Lenzin rate of recovery is about 70%, and recovery technology is that long U.S. company in Taiwan and Lenzin company own.
Summary of the invention:
The purpose of the utility model will provide a kind of alkaline bath, scrubbing tower, adsorption tank system exactly, and it can overcome existing above problem in the viscose rayon manufacture process.The purpose of the utility model is to realize like this; A kind of alkaline bath, scrubbing tower, adsorption tank system; Comprise that air inlet, exhaust outlet form; It is characterized in that: alkaline bath, scrubbing tower, adsorption tank adopt the blower fan group that the waste gas in the production process of viscose fiber is sucked through the uniform alkali washing and spraying from the alkaline bath air inlet respectively, remainder of exhaust gas are sucked in the scrubbing tower from air inlet, through washing section, alkali cleaning section spray; By waste gas, liquid medium haptoreaction, the cleaning solution that flows in waste gas and filler surface is fully contacted, with acid or alkaline dirt contained in the absorption waste gas; Residual gas is sucked in the adsorption tank by the air inlet that the adsorption tank bottom is provided with, and waste gas adsorbs in active carbon filler makes waste gas fully contact with active carbon, with acid or alkaline dirt contained in the absorption waste gas; The qualified back of gas after handling directly is discharged in the atmosphere by the exhaust outlet that the adsorption tank top is provided with.Described alkaline bath, the left side are provided with Butterworth Hatch, peep hole, the import of spray alkali, Butterworth Hatch from bottom to up; The right is provided with sewage draining exit, exhaust gas inlet, two band visor peep holes, peep hole from bottom to up; Back lower face is provided with thermometer hole, sample tap, alkali outlet, dip hatch from left to right, and the left side, middle part, surface, back is provided with refluxing opening, and the right is provided with charging aperture; Be disposed with several liquid level gauge mouths of lower right, the pouring of crown saw profile of tooth plate, two-layer PE hollow float in the inner chamber from bottom to up, be evenly equipped with several spray alkali shower nozzles, PE ripple packing, Butterworth Hatch shower nozzle; The top is provided with exhaust outlet.The left side, bottom is provided with the salkali waste floss hole under the described scrubbing tower, and the right is provided with discharging hole; The scrubbing tower left side is disposed with overfall, inspection opening, overfall, air inlet from bottom to up; The right is disposed with exhaust outlet, 3 cun jet guns, some 2 cun jet guns, alkali outlets from bottom to up, advances alkali lye mouth, 3 cun jet guns, and is provided with several peep holes on left and right both sides; Be disposed with from bottom to up in the scrubbing tower inner chamber that flase floor A is two-layer, distribution plate A, distribution plate B, flase floor B, P.P saddle ring, top be provided with mouth spray; The top, the right of described distribution plate A is provided with into alkali lye mouth, and the below is provided with alkali outlet, and below, the left side is provided with overfall; Described some 2 cun jet guns are distributed in that flase floor A is two-layer, between the distribution plate A, distribution plate B.Described adsorption tank; Following bottom is provided with air inlet; The left side respectively is provided with a sample tap up and down; The right is provided with thermometer mouth, doctor solution mouth from bottom to up, and last top is provided with steam inlet, relief valve port, exhaust outlet, thermometer mouth, pressure gauge connection, peep hole, thermometer mouth from left to right; Be provided with two bleed outlets at front surface; In the adsorption tank inner chamber, be provided with active carbon filler.The direction of motion of the utility model air-flow is intersected with the direction of spray medicament, because structure is tight, greatly reduces the height of treatment system, and the processing air quantity of unit reaches more than the 5000m3/min.Filler adopts P.P saddle ring material, and voidage reaches 95%, and specific area reaches 90 m2/m3.Washing and alkali cleaning head adopt the rotation of 316L120 degree not have the shower nozzle of obstruction, do not have metal assembly in the system.For this reason, total system has high strong acid-base resistance property; System-wide resistance has been practiced thrift the consumption of the energy greatly less than 400Pa.Be applicable to water, alkali cleaning formula exhaust treatment system, low price, processing method are simple; Gaseous state, liquid state, solid-state pollution sources all can be handled; Can adopt the design of multisection type packed layer, handle and mix type pollution sources.Alkali lye after the processing can recycle, and saves the operation water consumption; Adopt automation control running design; The equipment structure is succinct, safeguards that easily operating cost is cheap.The base number Auto-Sensing cooperates chemicals dosing plant, and is easy and simple to handle; Totally-enclosed-type, indoor and outdoor all can use.Handle acid, alkaline waste gas effectively, clearance can be up to more than 90%.
Description of drawings:
Fig. 1 is the utility model alkaline bath structural representation;
Fig. 2 is the utility model scrubbing tower structural representation;
Fig. 3 is the utility model adsorption tank structural representation;
1. sewage draining exit, 2. dip hatch, 3. alkali outlet, 4. sample tap; 5. temperature-measuring port, 6. Butterworth Hatch, 7. peep hole, the 8. import of spray alkali; 9. Butterworth Hatch, 10. exhaust outlet, 11. peep holes, 12. band visor peep holes; 13. the crown saw profile of tooth is drenched plate, 14. exhaust gas inlet, 15. charging apertures, 16. liquid level gauge mouths.
1 '. discharging hole, 2 '. the salkali waste floss hole, 3 '. overfall, 4 '. flase floor A, 5 ' .3 cun jet gun; 6 ' .2 cun jet gun, 7 '. inspection opening, 8 '. overfall, 9 '. air inlet, 10 '. flase floor B; 11 '. 3 cun jet guns, 12 '. mouth spray, 13 '. P.P saddle ring, 14 '. distribution plate B; 15 '. distribution plate A, 16 '. advance the alkali lye mouth, 17 '. alkali outlet, 18 '. exhaust outlet.
1 ". air inlet, 2 ". sample tap, 3 ". sample tap, 4 ". the steam inlet; 5 ". relief valve port, 6 ". exhaust outlet, 7 ". thermometer mouth, 8 ". pressure gauge connection; 9 ". peep hole, 10 ". thermometer mouth, 11 ". doctor solution mouth; 12 ". thermometer mouth, 13 ". active carbon filler, 14 ". bleed outlet.
The specific embodiment:
Below in conjunction with accompanying drawing the utility model is described further;
A kind of alkaline bath, scrubbing tower, adsorption tank system; Comprise that air inlet, exhaust outlet form; It is characterized in that: alkaline bath, scrubbing tower, adsorption tank adopt the blower fan group that the waste gas in the production process of viscose fiber is sucked through the uniform alkali washing and spraying from the alkaline bath air inlet respectively; Remainder of exhaust gas is sucked in the scrubbing tower from air inlet, through washing section, alkali cleaning section spray; By waste gas, liquid medium haptoreaction, the cleaning solution that flows in waste gas and filler surface is fully contacted, with acid or alkaline dirt contained in the absorption waste gas; Residual gas is sucked in the adsorption tank by the air inlet that the adsorption tank bottom is provided with, and waste gas adsorbs in active carbon filler makes waste gas fully contact with active carbon, with acid or alkaline dirt contained in the absorption waste gas; The qualified back of gas after handling directly is discharged in the atmosphere by the exhaust outlet that the adsorption tank top is provided with.Described alkaline bath, the left side are provided with Butterworth Hatch, peep hole, the import of spray alkali, Butterworth Hatch from bottom to up; The right is provided with sewage draining exit, exhaust gas inlet, two band visor peep holes, peep hole from bottom to up; Back lower face is provided with thermometer hole, sample tap, alkali outlet, dip hatch from left to right, and the left side, middle part, surface, back is provided with refluxing opening, and the right is provided with charging aperture; Be disposed with several liquid level gauge mouths of lower right, the pouring of crown saw profile of tooth plate, two-layer PE hollow float in the inner chamber from bottom to up, be evenly equipped with several spray alkali shower nozzles, PE ripple packing, Butterworth Hatch shower nozzle; The top is provided with exhaust outlet.The left side, bottom is provided with the salkali waste floss hole under the described scrubbing tower, and the right is provided with discharging hole; The scrubbing tower left side is disposed with overfall, inspection opening, overfall, air inlet from bottom to up; The right is disposed with exhaust outlet, 3 cun jet guns, some 2 cun jet guns, alkali outlets from bottom to up, advances alkali lye mouth, 3 cun jet guns, and is provided with several peep holes on left and right both sides; Be disposed with from bottom to up in the scrubbing tower inner chamber that flase floor A is two-layer, distribution plate A, distribution plate B, flase floor B, P.P saddle ring, top be provided with mouth spray; The top, the right of described distribution plate A is provided with into alkali lye mouth, and the below is provided with alkali outlet, and below, the left side is provided with overfall; Described some 2 cun jet guns are distributed in that flase floor A is two-layer, between the distribution plate A, distribution plate B.Described adsorption tank; Following bottom is provided with air inlet; The left side respectively is provided with a sample tap up and down; The right is provided with thermometer mouth, doctor solution mouth from bottom to up, and last top is provided with steam inlet, relief valve port, exhaust outlet, thermometer mouth, pressure gauge connection, peep hole, thermometer mouth from left to right; Be provided with two bleed outlets at front surface; In the adsorption tank inner chamber, be provided with active carbon filler.During practical implementation; Described alkaline bath is to adopt: exhaust gas inlet sucks in the alkaline bath alkaline bath system fan group from alkaline bath the right with the waste gas in the production process of viscose fiber; Crown saw profile of tooth through being provided with is drenched plate, two-layer PE hollow float, is uniformly distributed with the uniform alkali washing and spraying of several spray alkali shower nozzles of distribution, PE ripple packing, Butterworth Hatch shower nozzle; By waste gas, liquid medium haptoreaction; The soup that is flowed in waste gas and filler surface is that cleaning solution fully contacts, with acid or alkaline dirt contained in the absorption waste gas.After the washing, the hydrogen sulfide in the waste liquid is collected in the hydrogen sulfide accumulator tank, and waste water drains into waste water system processing place by the lower right sewage draining exit, and all the other waste gas drain into scrubbing tower and handle through the alkaline bath top.Described scrubbing tower is to adopt scrubber system blower fan group that waste gas is sucked in the scrubbing tower from left side air inlet, upwards for washing section, is provided with mouth spray through flase floor B, P.P saddle ring, 3 cun jet guns, tops; Be downwards the alkali cleaning section, two-layer through some 2 cun jet guns, distribution plate A, flase floor A, the top, the right of described distribution plate A is provided with into alkali lye mouth, and the below is provided with alkali outlet, and below, the left side is provided with overfall; By waste gas, liquid medium haptoreaction, the alkali cleaning part of mobile washing in waste gas and filler surface and below is fully contacted, with acid or alkaline dirt contained in the absorption waste gas.After the washing, in waste collection to the carbon disulfide accumulator tank, because of carbon disulfide proportion is heavier than water, all carbon disulfide all can be precipitated to the bottom, and carbon disulfide is disposed to the carbon disulfide storage tank stores, can utilize or sell.Waste water drains into the waste water system processing by discharging hole, the salkali waste floss hole of bottom setting down, and remaining waste gas drains into adsorption tank by the lower right exhaust outlet and handles.Described adsorption tank; Be that the air inlet that adopts adsorption tank system fan group that residual gas is provided with by the adsorption tank bottom sucks in the adsorption tank; Send into steam by the steam inlet, Pressure gauge, thermometer show controlled pressure and temperature; Waste gas adsorbs in active carbon filler makes waste gas fully contact with active carbon, with acid or alkaline dirt contained in the absorption waste gas.After the absorption, noxious materials such as hydrogen sulfide in the waste gas and carbon disulfide adsorbing separation finish, and the gas after handling is taken a sample to check through sample tap, and qualified back directly is discharged in the atmosphere by the exhaust outlet that the adsorption tank top is provided with.At present the utility model be that Shandong sea otter, Anhui Azithromycin, Shandong silver hawk, Jiangsu Xiang are contained, the Jiangxi dragon reaches, Baoding swan, Xinxiang chemical fibre, Australia's ocean science and technology, etc. domestic most chemical fiber factory productions use; And Azithromycin, Jiangsu Xiang Sheng, Shandong sea otter, Australia's ocean science and technology are in process of production; Effect is remarkable, and the carbon disulfide rate of recovery has all reached more than 90%.The utility model is widely used in having the processing of corrosion resistance gas, is applied to the engineering in zones such as chemical industry.Adopt the international norm standard design; Can carry out comprehensive planning and designing according to user's needs fully; The system equipment that adopts high-quality 316L stainless steel to make; Its match appliance adopts protection facility automatically, adapts to 24 hours fully and runs without interruption, and the high request enterprise that is particularly useful for Large Scale and Continuous production uses.Be applicable to the processing of foul gas such as various pernicious gases such as H2S, SOX, NOX, HCI, NH3, CS2; The odor removal in sewage-farm; The processing procedure pump-down process of optical semiconductor electric industry; The water seepage retentio basin exhaust-gas treatment of landfill; Incinerator and industrial furnace exhaust gas discharged are handled.Industries such as the plating of printed circuit board (PCB) industry, electronic component industry, pre-treatment, chemical industry, steel industry, semiconductor manufacturing industry, dyestuff system industry.

Claims (4)

1. an alkaline bath, scrubbing tower, adsorption tank system; Comprise that air inlet, exhaust outlet form; It is characterized in that: alkaline bath, scrubbing tower, adsorption tank adopt the blower fan group that the waste gas in the production process of viscose fiber is sucked through the uniform alkali washing and spraying from the alkaline bath air inlet respectively; Remainder of exhaust gas is sucked in the scrubbing tower from air inlet, through washing section, alkali cleaning section spray; By waste gas, liquid medium haptoreaction, the cleaning solution that flows in waste gas and filler surface is fully contacted, with acid or alkaline dirt contained in the absorption waste gas; Residual gas is sucked in the adsorption tank by the air inlet that the adsorption tank bottom is provided with, and waste gas adsorbs in active carbon filler makes waste gas fully contact with active carbon, with acid or alkaline dirt contained in the absorption waste gas; The qualified back of gas after handling directly is discharged in the atmosphere by the exhaust outlet that the adsorption tank top is provided with.
2. a kind of alkaline bath according to claim 1, scrubbing tower, adsorption tank system is characterized in that: described alkaline bath, the left side are provided with Butterworth Hatch, peep hole, the import of spray alkali, Butterworth Hatch from bottom to up; The right is provided with sewage draining exit, exhaust gas inlet, two band visor peep holes, peep hole from bottom to up; Back lower face is provided with thermometer hole, sample tap, alkali outlet, dip hatch from left to right, and the left side, middle part, surface, back is provided with refluxing opening, and the right is provided with charging aperture; Be disposed with several liquid level gauge mouths of lower right, the pouring of crown saw profile of tooth plate, two-layer PE hollow float in the inner chamber from bottom to up, be evenly equipped with several spray alkali shower nozzles, PE ripple packing, Butterworth Hatch shower nozzle; The top is provided with exhaust outlet.
3. a kind of alkaline bath according to claim 1, scrubbing tower, adsorption tank system is characterized in that: the left side, bottom is provided with the salkali waste floss hole under the described scrubbing tower, and the right is provided with discharging hole; The scrubbing tower left side is disposed with overfall, inspection opening, overfall, air inlet from bottom to up; The right is disposed with exhaust outlet, 3 cun jet guns, some 2 cun jet guns, alkali outlets from bottom to up, advances alkali lye mouth, 3 cun jet guns, and is provided with several peep holes on left and right both sides; Be disposed with from bottom to up in the scrubbing tower inner chamber that flase floor A is two-layer, distribution plate A, distribution plate B, flase floor B, P.P saddle ring, top be provided with mouth spray; The top, the right of described distribution plate A is provided with into alkali lye mouth, and the below is provided with alkali outlet, and below, the left side is provided with overfall; Described some 2 cun jet guns are distributed in that flase floor A is two-layer, between the distribution plate A, distribution plate B.
4. a kind of alkaline bath according to claim 1, scrubbing tower, adsorption tank system; It is characterized in that: described adsorption tank; Following bottom is provided with air inlet; The left side respectively is provided with a sample tap up and down, and the right is provided with thermometer mouth, doctor solution mouth from bottom to up, and last top is provided with steam inlet, relief valve port, exhaust outlet, thermometer mouth, pressure gauge connection, peep hole, thermometer mouth from left to right; Be provided with two bleed outlets at front surface; In the adsorption tank inner chamber, be provided with active carbon filler.
CN2011201731701U 2011-05-27 2011-05-27 Alkaline washing tank, washing tower and adsorption tank system Expired - Fee Related CN202113760U (en)

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CN2011201731701U CN202113760U (en) 2011-05-27 2011-05-27 Alkaline washing tank, washing tower and adsorption tank system

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Application Number Priority Date Filing Date Title
CN2011201731701U CN202113760U (en) 2011-05-27 2011-05-27 Alkaline washing tank, washing tower and adsorption tank system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103239976A (en) * 2013-05-02 2013-08-14 国家电网公司 Simple device for removing volatile gas produced by sewage treatment
WO2019095371A1 (en) * 2017-11-20 2019-05-23 江苏宏大环保科技有限公司 Waste gas discharge apparatus

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103239976A (en) * 2013-05-02 2013-08-14 国家电网公司 Simple device for removing volatile gas produced by sewage treatment
WO2019095371A1 (en) * 2017-11-20 2019-05-23 江苏宏大环保科技有限公司 Waste gas discharge apparatus

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C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120118

Termination date: 20140527