CN202087187U - Ammonia water recovery device - Google Patents

Ammonia water recovery device Download PDF

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Publication number
CN202087187U
CN202087187U CN2011201259956U CN201120125995U CN202087187U CN 202087187 U CN202087187 U CN 202087187U CN 2011201259956 U CN2011201259956 U CN 2011201259956U CN 201120125995 U CN201120125995 U CN 201120125995U CN 202087187 U CN202087187 U CN 202087187U
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CN
China
Prior art keywords
delivery port
air inlet
gas outlet
absorption tower
water inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2011201259956U
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Chinese (zh)
Inventor
徐建国
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LI SHENG SUZHOU CHEMICAL EQUIPMENT CO Ltd
Original Assignee
LI SHENG SUZHOU CHEMICAL EQUIPMENT CO Ltd
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Priority to CN2011201259956U priority Critical patent/CN202087187U/en
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Publication of CN202087187U publication Critical patent/CN202087187U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model discloses an ammonia water recovery device, comprising a gas buffer tank, a vacuum unit connected with the gas buffer tank, a first adsorption tower connected with the vacuum unit, an adsorption tank connected with the first adsorption tower and a water storage tank. In the utility model, by adopting multi-level ammonia adsorption and ammonia water recovery treatment, the adsorbing and recovery effect is extremely good, the concentration of the discharged waste gas after adsorption is less than or equal to 1mg/m3, the purification efficiency is more than or equal to 99 percent, the concentration of the discharged waste gas is lower than first level 1.0mg/m3 of China (GB14554-93) odor pollutant comprehensive discharge standard, the second level is 1.5mg/m3, and the discharge value is less than or equal to the standard of 4.9kg/hour in 15m height.

Description

A kind of ammoniacal liquor retracting device
Technical field
The utility model relates to a kind of chemical industry equipment, specifically the ammoniacal liquor retracting device.
Background technology
Ammonia, inorganic compound, normal temperature is gas down, the colourless smell that the excitant stench is arranged, soluble in water, be called ammoniacal liquor when ammonia is water-soluble, amino molecule is combined into a hydration ammonia (NH3H20) with hydrone by the * hydrogen bond, one hydration ammonia can fraction be ionized into ammonium ion and hydroxide ion, so ammoniacal liquor shows alkalescent, can make the phenolphthalein solution look that reddens.Ammonia and acid effect can arrive ammonium salt, ammonia is mainly as refrigerant and produce ammonium salt and nitrogenous fertilizer.In fields such as chemical industry and the desulfurization of non-ferrous metal metallurgy industry, dechlorination, denitrations, contain a large amount of ammonias in the exhaust gas discharged, if it is not effectively handled, will cause severe contamination to environment.Present ammoniacal liquor reclaimer only can reach the minimum standard of country to the absorption of ammonia, have in addition do not reach, therefore environment is seriously influenced.
The utility model content
The purpose of this utility model is the deficiency that exists at prior art, thereby provides a kind of ammonia good absorbing effect, can effectively reclaim the ammoniacal liquor retracting device of ammoniacal liquor better protection environment.
For realizing above-mentioned utility model purpose, the technical solution adopted in the utility model is a kind of ammoniacal liquor retracting device, the vacuum unit that comprises the gas buffer jar, joins with the gas buffer jar, first absorption tower that joins with the vacuum unit, the adsorption tanks and the cistern that join with first absorption tower; On the gas buffer jar, be provided with first air inlet, first gas outlet, first water inlet and first delivery port, on the vacuum unit, be provided with second air inlet, second gas outlet, second water inlet and second delivery port, on first absorption tower, be provided with the 3rd air inlet, the 3rd gas outlet, the 3rd water inlet, the 3rd delivery port and the 4th delivery port, on adsorption tanks, be provided with the 6th air inlet and escape pipe, on cistern, be provided with the 6th water inlet and the 9th delivery port; Wherein first gas outlet and second air inlet join, second gas outlet and the 3rd air inlet join, the 3rd gas outlet and the 6th air inlet join, and the 3rd water inlet and the 9th delivery port join, and first delivery port, second delivery port, the 3rd delivery port, the 4th delivery port all join with the 6th water inlet.
Better ammonia absorbs and the effect of ammoniacal liquor recovery in order to reach, and this ammoniacal liquor retracting device also comprises second absorption tower and the 3rd absorption tower, and described the 3rd gas outlet joins by second absorption tower and the 3rd absorption tower and the 6th air inlet; On second absorption tower, be provided with the 4th air inlet, the 4th gas outlet, the 4th water inlet, the 5th delivery port and the 6th delivery port, be provided with the 5th air inlet, the 5th gas outlet, the 5th water inlet, the 7th delivery port and the 8th delivery port on the 3rd absorption tower; Described the 3rd gas outlet and the 4th air inlet join, the 4th gas outlet and the 5th air inlet join, the 5th gas outlet and the 6th air inlet join, the 4th water inlet and the 5th water inlet all join with the 9th delivery port, and the 5th delivery port, the 6th delivery port, the 7th delivery port and the 8th delivery port all join with the 6th water inlet.
Also be provided with the 7th gas outlet between described second gas outlet and the 3rd air inlet, described escape pipe is provided with the 7th air inlet, and described the 7th gas outlet and the 7th air inlet join.
For reaching better adsorption effect, described adsorption tanks are absorbent charcoal adsorption tank.
For ensureing gas buffer jar safety, to avoid it to bear and do not live high pressure and explosion, described gas buffer tank wall also is provided with two circle stiffening rings.
Beneficial effect: the utility model is owing to passed through multistage ammonia absorption and ammoniacal liquor recycling, and therefore absorption and recovering effect are fabulous, exhaust gas discharged concentration≤1mg/m after absorbing 3, purification efficiency 〉=99% is lower than China (GB14554-93) odorant pollutant comprehensive discharge standard one-level 1.0mg/m 3Secondary 1.5mg/m 3, during 15 meters of discharge capacitys height smaller or equal to 4.9 kilograms/hour standard.
Description of drawings
Fig. 1 is the utility model structural representation.
The specific embodiment
Below in conjunction with the drawings and specific embodiments, further illustrate the utility model, present embodiment is being to implement under the prerequisite with technical solutions of the utility model, should understand these embodiment only be used to the utility model is described and be not used in the restriction scope of the present utility model.
As shown in Figure 1, a kind of ammoniacal liquor retracting device, the vacuum unit 2 that comprises gas buffer jar 1, joins with the gas buffer jar, the first absorption tower 3a that joins with vacuum unit 2, the second absorption tower 3b that joins with the first absorption tower 3a, the 3rd absorption tower 3c that joins with the second absorption tower 3b, the absorbent charcoal adsorption tank 4 and the cistern 22 that join with the 3rd absorption tower 3c; On gas buffer jar 1, be provided with first air inlet 5, first gas outlet 6, first water inlet 7 and first delivery port 8, on its outer wall, also be provided with two circle stiffening rings 25, on vacuum unit 2, be provided with second air inlet 9, second gas outlet, 10, second water inlet 11 and second delivery port 12, on the first absorption tower 3a, be provided with the 3rd air inlet 13a, the 3rd gas outlet 14a, the 3rd water inlet 15a, the 3rd delivery port 16a and the 4th delivery port 17a, on the second absorption tower 3b, be provided with the 4th air inlet 13b, the 4th gas outlet 14b, the 4th water inlet 15b, the 5th delivery port 16b and the 6th delivery port 17b, on the 3rd absorption tower 3c, be provided with the 5th air inlet 13c, the 5th gas outlet 14c, the 5th water inlet 15c, the 7th delivery port 16c and the 8th delivery port 17c, on absorbent charcoal adsorption tank 4, be provided with the 6th air inlet 18 and escape pipe 19, on cistern 22, be provided with the 6th water inlet 23 and the 9th delivery port 24, between second gas outlet 10 and the 3rd air inlet 13a, also be provided with the 7th gas outlet 20, on escape pipe 19, be provided with the 7th air inlet 21; Wherein first gas outlet 6 and second air inlet 9 join, second gas outlet 10 and the 3rd air inlet 13a join, the 3rd gas outlet 14a and the 4th air inlet 13b join, the 4th gas outlet 14b and the 5th air inlet 13c join, the 5th gas outlet 14c and the 6th air inlet 18 join, the 3rd water inlet 15a, the 4th water inlet 15b and the 5th water inlet 15c all join with the 9th delivery port 24, first delivery port 8, second delivery port 12, the 3rd delivery port 16a, the 4th delivery port 17a, the 5th delivery port 16b, the 6th delivery port 17b, the 7th delivery port 16c and the 8th delivery port 17c all join with the 6th water inlet 23, and the 7th gas outlet 20 and the 7th air inlet 21 join.
The utility model mainly utilizes hydromechanical relative theory, gas mixes in pipeline with absorption liquid, after mixing with gas, absorption liquid passes through pipeline, at this moment gas-liquid two-phase is big with the tube wall contact-making surface, contact surface liquid constantly obtains cooling, reach efficient chemical exchange reaction, the fierce collision of gas-liquid is so that after gas-liquid fully mixes, along with the gravity effect of liquid falls into cyclic water tank.
Workflow is as follows: the ammonia tail gas of band dust enters in the gas buffer jar under the effect of vacuum, make dust follow gas to separate, pure then ammonia continues to carry out secondary water washing in the water tank that volatilization enters the vacuum unit, because the liquid in the water tank constantly heats up under the ringing of water pump, this moment, ammonia was water insoluble, continuing evaporation and enter first absorption tower, is that absorption liquid absorbs with water.Ammonia in the process that water absorbs along with the raising of absorption strength, the temperature of absorption liquid can be along with rising, in order to ensure assimilation effect, so absorption liquid is fully absorbed with cooling water circulation cooling back, the gas that part does not absorb fully enters second absorption tower to be continued to absorb, the gas that was absorbed subsequently enters the 3rd absorption tower again, this moment, the concentration of ammonia was very low, because gas and liquid are also being absorbed by the water circulation, so volatility is very low, the gas of discharging has been pure air relatively, and entering the final gas of discharging of absorbent charcoal adsorption tank absorption again is pure air basically.When the ammonia concn in first absorption tower reaches capacity, it is squeezed into finished product storage tank, simultaneously the ammoniacal liquor of relative high concentration in second absorption tower is squeezed into and continued in first absorption tower to absorb, the low concentration ammoniacal liquor of the 3rd absorption tower mother liquor tank is squeezed into second absorption tower continue the circulation absorption, in the 3rd absorption tower circulating tank groove, inject clear water and continue to absorb.The circulation that goes round and begins again thus absorbs, and finally reaches recovery ammoniacal liquor, the effect of emission compliance, and promptly the economic benefit of Chuan Zaoing makes environment obtain protection again.

Claims (5)

1. ammoniacal liquor retracting device is characterized in that: the vacuum unit (2) that comprises gas buffer jar (1), joins with the gas buffer jar, first absorption tower (3a) that joins with vacuum unit (2), the adsorption tanks (4) and the cistern (22) that join with first absorption tower (3a); On gas buffer jar (1), be provided with first air inlet (5), first gas outlet (6), first water inlet (7) and first delivery port (8), on vacuum unit (2), be provided with second air inlet (9), second gas outlet (10), second water inlet (11) and second delivery port (12), on first absorption tower (3a), be provided with the 3rd air inlet (13a), the 3rd gas outlet (14a), the 3rd water inlet (15a), the 3rd delivery port (16a) and the 4th delivery port (17a), on adsorption tanks (4), be provided with the 6th air inlet (18) and escape pipe (19), on cistern (22), be provided with the 6th water inlet (23) and the 9th delivery port (24); Wherein first gas outlet (6) join with second air inlet (9), second gas outlet (10) joins with the 3rd air inlet (13a), the 3rd gas outlet (14a) joins with the 6th air inlet (18), the 3rd water inlet (15a) joins with the 9th delivery port (24), and first delivery port (8), second delivery port (12), the 3rd delivery port (16a), the 4th delivery port (17a) all join with the 6th water inlet (23).
2. according to the described a kind of ammoniacal liquor retracting device of claim 1, it is characterized in that: also comprise second absorption tower (3b) and the 3rd absorption tower (3c), described the 3rd gas outlet (14a) joins with the 6th air inlet (18) by second absorption tower (3b) and the 3rd absorption tower (3c); On second absorption tower (3b), be provided with the 4th air inlet (13b), the 4th gas outlet (14b), the 4th water inlet (15b), the 5th delivery port (16b) and the 6th delivery port (17b), on the 3rd absorption tower (3c), be provided with the 5th air inlet (13c), the 5th gas outlet (14c), the 5th water inlet (15c), the 7th delivery port (16c) and the 8th delivery port (17c); Described the 3rd gas outlet (14a) joins with the 4th air inlet (13b), the 4th gas outlet (14b) joins with the 5th air inlet (13c), the 5th gas outlet (14c) joins with the 6th air inlet (18), the 4th water inlet (15b) and the 5th water inlet (15c) all join with the 9th delivery port (24), and the 5th delivery port (16b), the 6th delivery port (17b), the 7th delivery port (16c) and the 8th delivery port (17c) all join with the 6th water inlet (23).
3. according to the described a kind of ammoniacal liquor retracting device of claim 1, it is characterized in that: also be provided with the 7th gas outlet (20) between described second gas outlet (10) and the 3rd air inlet (13a), described escape pipe (19) is provided with the 7th air inlet (21), and described the 7th gas outlet (20) joins with the 7th air inlet (21).
4. according to the described a kind of ammoniacal liquor retracting device of claim 1, it is characterized in that: described adsorption tanks (4) are absorbent charcoal adsorption tank.
5. according to the described a kind of ammoniacal liquor retracting device of claim 1, it is characterized in that: described gas buffer jar (1) outer wall also is provided with two circle stiffening rings (25).
CN2011201259956U 2011-04-26 2011-04-26 Ammonia water recovery device Expired - Fee Related CN202087187U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011201259956U CN202087187U (en) 2011-04-26 2011-04-26 Ammonia water recovery device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011201259956U CN202087187U (en) 2011-04-26 2011-04-26 Ammonia water recovery device

Publications (1)

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CN202087187U true CN202087187U (en) 2011-12-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102179134A (en) * 2011-04-26 2011-09-14 苏州利盛化工设备有限公司 Ammonia water recovery device
CN103877832A (en) * 2012-12-19 2014-06-25 江苏飞亚化学工业有限责任公司 Multi-stage serial absorption equipment of ammonia and non-condensable gas
CN104888581A (en) * 2015-06-05 2015-09-09 江西明兴环境工程有限公司 Preparation method and skid block of micro-negative pressure and high concentration ammonia water

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102179134A (en) * 2011-04-26 2011-09-14 苏州利盛化工设备有限公司 Ammonia water recovery device
CN103877832A (en) * 2012-12-19 2014-06-25 江苏飞亚化学工业有限责任公司 Multi-stage serial absorption equipment of ammonia and non-condensable gas
CN104888581A (en) * 2015-06-05 2015-09-09 江西明兴环境工程有限公司 Preparation method and skid block of micro-negative pressure and high concentration ammonia water

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GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20111228

Termination date: 20140426