CN202054810U - Wet desulfurizer for methane desulfurization - Google Patents
Wet desulfurizer for methane desulfurization Download PDFInfo
- Publication number
- CN202054810U CN202054810U CN2011201439713U CN201120143971U CN202054810U CN 202054810 U CN202054810 U CN 202054810U CN 2011201439713 U CN2011201439713 U CN 2011201439713U CN 201120143971 U CN201120143971 U CN 201120143971U CN 202054810 U CN202054810 U CN 202054810U
- Authority
- CN
- China
- Prior art keywords
- desulfurizer
- methane
- biogas
- thionizer
- desulfurization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 23
- 230000003009 desulfurizing Effects 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000007921 spray Substances 0.000 claims abstract description 11
- 239000003595 mist Substances 0.000 claims abstract description 10
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- 230000002745 absorbent Effects 0.000 abstract 1
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- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound 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[S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 231100000614 Poison Toxicity 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- -1 is desulfurization Chemical compound 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001172 regenerating Effects 0.000 description 1
Abstract
The utility model relates to the technical field of a methane desulfurizer, particularly a wet desulfurizer for methane desulfurization. A liquid storage tank is arranged at the bottom of the desulfurizer; a methane inlet pipeline is inserted at the waist part of the desulfurizer; the methane inlet pipeline is inserted to the center of the desulfurizer to be connected with a blast cap; a liquid distribution pipe is arranged above the blast cap; the liquid distribution pipe is provided with an atomization spray device; an atomization spray port is connected with the liquid distribution pipe; a mist eliminator is arranged at the top of the desulfurizer and is provided with a methane outlet pipeline; the bottom of the liquid storage tank is connected with an inlet of a water pump through a pipeline; and an outlet of the water pump is connected with the atomization spray port through a pipeline, so that one whole body is formed. In the utility model, by changing a flowing path of gas in the desulfurizer, prolonging the residence time of methane in the desulfurizer and prolonging the contact time of the methane and an absorbent, the methane desulfurization efficiency is further improved; and fillers are not used in the desulfurizer, so that processes are reduced, the weight of a desulfurizer body is reduced and the cost is also saved.
Description
[technical field]
The utility model relates to biogas desulfurization tower technology field, specifically a kind of wet desulfuration tower that is used for biogas desulfurization.
[background technology]
The purification purification techniques of biogas is a very important link in the biogas recycling, CO
2, H
2The existence of non-combustible gas such as S and water vapour reduces the biogas calorific value greatly, therefore, before using biogas it is purified the efficient utilization that purification can realize biogas.At present the purification purification techniques of biogas mainly is desulfurization, decarburization, dewaters and remove other not combustion-supporting impurity.
Sulphur is mainly with H in the biogas
2The S form exists, H
2S is poisonous, and very strong corrodibility is arranged, and the rotten egg taste of be difficult to hearing is arranged, although its content must be removed because the difference of fermentation raw material changes to some extent, in order to avoid corrode compressor, gas storage tank and engine etc.; Environmental Protection in China standard strict regulation, when utilizing biogas, H in the biogas
2S content must not surpass 0.02g/m
3Therefore, desulfurization becomes a requisite important step in the marsh gas purifying.
Desulfurization technology mainly contains dry method, wet method and biological process desulfurization etc.Wherein wet method is simple with its less investment technical process, operation is continuous and the desulfuration efficiency advantages of higher causes people's great attention.The wet desulphurization technology is to utilize specific solvent to contact with back flow of gas and remove wherein H
2S, solvent is reuptaked after regenerating, and is applicable to that the processing gas quantity is big, the gas sweetening engineering that sulphur content is high.
[utility model content]
At sweetening process in the marsh gas purifying thionizer, the utility model proposes a kind ofly change biogas fortune path, make enter thionizer biogas in the shape of a spiral shape slowly rise, make that biogas is longer with the duration of contact of absorption agent, sweetening effectiveness is than the better a kind of modified version thionizer structure of traditional wet desulfuration tower.
Designed a kind of wet desulfuration tower that is used for biogas desulfurization for achieving the above object, it is characterized in that:
A, described thionizer bottom are provided with fluid storage tank, described thionizer waist is inserted with the biogas intake ducting, the biogas intake ducting is inserted to the thionizer inside center and is connected with blast cap, the blast cap top is provided with liquid distributor, liquid distributor is provided with atomizing sprayer, the atomizing spray mouth links to each other with liquid distributor, described thionizer top is provided with mist eliminator, mist eliminator is provided with the methane outlet pipeline, described fluid storage tank bottom and pump entrance are by pipe connection, its outlet of described water pump and atomizing spray mouth constitute whole by pipe connection;
When b, work, biogas enters blast cap by the biogas intake ducting, blast cap slow rotation at the uniform velocity, biogas goes out behind the blast cap that curl slowly rises in thionizer, absorption agent is beaten to the atomizing spray mouth by water pump, enters thionizer through liquid distributor to the spraying gun atomizing, slowly descends under action of gravity, meet with the biogas that rises, with the H of biogas in rising and absorption biogas
2S, after moving to behind the cat head through gas-liquid separator separates, absorbing, gas up to standard is discharged after by the mist eliminator demist, and liquid-absorbant absorbs H
2Descend behind the S, to fluid storage tank, recycle, and in the decline process, contact with the biogas that rises once more, absorb H
2S.
Described atomizing sprayer is the upper-spraying type atomizing sprayer.
The utility model improves thionizer according to desulfurization characteristic in the biogas wet desulfuration tower.On the basis that does not change other performances of thionizer itself, by changing the movement path of gas in thionizer, increase the residence time of biogas in thionizer and increase it and the duration of contact of absorption agent, further improve biogas desulfurization efficient; The window of filler bracing or strutting arrangement and dismounting filler is saved without filler in thionizer inside, avoids having reduced technology because of filler generation blockage problem, also saves cost when alleviating tower body weight.
[description of drawings]
Fig. 1 is a structural representation of the present utility model;
Among the figure: 1, methane outlet pipeline 2, mist eliminator 3, atomizing sprayer 4, liquid distributor 5, biogas inlet pipeline 6, atomizing spray mouth 7, water pump 8, fluid storage tank 9, blast cap
[embodiment]
Further specify below below in conjunction with accompanying drawing the utility model being done:
As shown in drawings, thionizer described in the utility model bottom is provided with fluid storage tank, described thionizer waist is inserted with the biogas intake ducting, the biogas intake ducting is inserted to the thionizer inside center and is connected with blast cap, the blast cap top is provided with liquid distributor, liquid distributor is provided with atomizing sprayer, the atomizing spray mouth links to each other with liquid distributor, described thionizer top is provided with mist eliminator, mist eliminator is provided with the methane outlet pipeline, described fluid storage tank bottom and pump entrance are by pipe connection, and its outlet of described water pump and atomizing spray mouth constitute whole by pipe connection.
Reactions steps in the thionizer is:
Biogas enters blast cap from the inlet mouth of thionizer bottom, blast cap slow rotation at the uniform velocity, biogas goes out behind the blast cap that curl slowly rises in thionizer, absorption agent enters thionizer top after atomizing through spraying gun, under action of gravity, slowly descend, meet with the biogas that rises, to rising, move to behind the cat head through gas-liquid separator with biogas.Gas up to standard after the absorption enters air compressor machine after by the mist eliminator demist.And liquid-absorbant is absorbing H
2Enter fluid storage tank behind the S, and in the decline process, contact with the biogas that rises once more, absorb H
2S.
And with water pump it is taken away, this liquid-absorbant can be regenerated it, recycles again then.
Claims (2)
1. wet desulfuration tower that is used for biogas desulfurization, it is characterized in that: described thionizer bottom is provided with fluid storage tank, described thionizer waist is inserted with the biogas intake ducting, the biogas intake ducting is inserted to the thionizer inside center and is connected with blast cap, the blast cap top is provided with liquid distributor, liquid distributor is provided with atomizing sprayer, the atomizing spray mouth links to each other with liquid distributor, described thionizer top is provided with mist eliminator, mist eliminator is provided with the methane outlet pipeline, described fluid storage tank bottom and pump entrance are by pipe connection, and its outlet of described water pump and atomizing spray mouth constitute whole by pipe connection.
2. a kind of wet desulfuration tower that is used for biogas desulfurization as claimed in claim 1 is characterized in that described atomizing sprayer is the upper-spraying type atomizing sprayer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011201439713U CN202054810U (en) | 2011-05-09 | 2011-05-09 | Wet desulfurizer for methane desulfurization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011201439713U CN202054810U (en) | 2011-05-09 | 2011-05-09 | Wet desulfurizer for methane desulfurization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202054810U true CN202054810U (en) | 2011-11-30 |
Family
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| CN2011201439713U Expired - Lifetime CN202054810U (en) | 2011-05-09 | 2011-05-09 | Wet desulfurizer for methane desulfurization |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660342A (en) * | 2012-05-18 | 2012-09-12 | 常熟理工学院 | Method and device for atomizing and purifying marsh gas |
| CN104818069A (en) * | 2015-05-19 | 2015-08-05 | 农业部沼气科学研究所 | Multistage-spray biogas biological desulfurizing unit |
| CN105126594A (en) * | 2015-09-17 | 2015-12-09 | 大唐环境产业集团股份有限公司 | Variable-diameter desulfurizing tower |
-
2011
- 2011-05-09 CN CN2011201439713U patent/CN202054810U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102660342A (en) * | 2012-05-18 | 2012-09-12 | 常熟理工学院 | Method and device for atomizing and purifying marsh gas |
| CN104818069A (en) * | 2015-05-19 | 2015-08-05 | 农业部沼气科学研究所 | Multistage-spray biogas biological desulfurizing unit |
| CN105126594A (en) * | 2015-09-17 | 2015-12-09 | 大唐环境产业集团股份有限公司 | Variable-diameter desulfurizing tower |
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