CN202045931U - Organic and inorganic composite super hydrophobic membrane - Google Patents
Organic and inorganic composite super hydrophobic membrane Download PDFInfo
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- CN202045931U CN202045931U CN2011201109022U CN201120110902U CN202045931U CN 202045931 U CN202045931 U CN 202045931U CN 2011201109022 U CN2011201109022 U CN 2011201109022U CN 201120110902 U CN201120110902 U CN 201120110902U CN 202045931 U CN202045931 U CN 202045931U
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Abstract
The utility model discloses an organic and inorganic composite super hydrophobic membrane which comprises a base luminous powder layer, a middle resin layer and a low-surface energy surface layer, wherein the base luminous powder layer and the low-surface energy surface layer are respectively stuck on two surfaces of the middle resin layer. Therefore, the organic polymer resin and inorganic material luminous powders are well combined, the high-polymer resin is introduced on the basis of not damaging the optical property of the original inorganic particles, and the super hydrophobic membrane with the excellent mechanical property and luminous functionality can be obtained. The membrane has the super hydrophobic property, the water contact angle of the surface of the super hydrophobic membrane can reach 158 plus or minus 1 degrees, the roll angle can reach 4 plus or minus 1 degrees, and the super hydrophobic membrane has excellent super hydrophobicity and self-cleaning property; and meanwhile, the super hydrophobic membrane also has excellent optical property.
Description
Technical field
The utility model relates to a kind of laminated film technical field, relates in particular to the compound super-hydrophobic film of a kind of organic-inorganic.
Background technology
The laser material that modern laser equipment uses, because its special nature, finish in the instrument assembling, artificial cleaning is comparatively difficult in the process of using, will influence the optical property of equipment like this after the long-term use of laser equipment, clear up and have to take apart machine, waste time and energy and can cause unnecessary damage, also need the professional to safeguard equipment; And existing heatproof equipment is normally carrying out of guaranteeing to produce after using, need carry out regular cleaning to equipment and safeguard, wastes time and energy equally, influences production efficiency.
The utility model content
Technical problem to be solved in the utility model provides and a kind ofly can be applied to laser equipment and heatproof equipment, and can not change the luminescent properties of luminaire, have the compound super-hydrophobic film of organic-inorganic of outstanding elevated temperature strength, superior creep-resistant property, ultra-hydrophobicity and self-cleaning property.
For solving the problems of the technologies described above, the technical solution of the utility model is: the compound super-hydrophobic film of a kind of organic-inorganic, comprise luminescent powder basic unit, resin interlayer and low-surface-energy material top layer, described luminescent powder basic unit and described low-surface-energy material top layer are bonded in the two sides of described resin interlayer respectively.
As optimized technical scheme, described luminescent powder basic unit is a nanometer yttrium aluminum garnet luminescent powder basic unit, yttrium-aluminium-garnet is as laser material, the photophore and the correlation window material that are widely used in optical system and all kinds of light fixtures, and its outstanding elevated temperature strength that has and superior creep-resistant property.
As optimized technical scheme, described resin interlayer is, epoxylite intermediate layer, acrylic resin intermediate layer, siliceous high temperature resistant resinoid intermediate layer, fluorine-containing corrosion-resistant resinoid intermediate layer or ECA resin interlayer, epoxylite intermediate layer, acrylic resin intermediate layer, siliceous high temperature resistant resinoid intermediate layer, fluorine-containing corrosion-resistant resinoid intermediate layer or ECA resin interlayer have the favorable mechanical performance.
As optimized technical scheme, described low-surface-energy material top layer is natural wax top layer, paraffin top layer, manually synthetic fluorinated low-surface-energy material top layer or manually synthetic siliceous class low-surface-energy material top layer.
Water droplet and solid-state interface contact angle are greater than 150 °, and roll angle is called super-hydrophobic film less than 10 ° film.
Owing to adopted technique scheme, the compound super-hydrophobic film of a kind of organic-inorganic, comprise luminescent powder basic unit, resin interlayer and low-surface-energy material top layer, described luminescent powder basic unit and described low-surface-energy material top layer are bonded in the two sides of described resin interlayer respectively; Good like this with organic polymer resin and the combination of inorganic material luminescent powder, under the prerequisite of not destroying former inorganic particulate optical characteristics, macromolecule resin is introduced, thereby obtain satisfactory mechanical property, and have functional luminous based superhydrophobic thin films concurrently, the film of formation has ultra-hydrophobicity, this kind super-hydrophobic film surface water droplet contact angle can reach 158 ± 1 °, roll angle reaches 4 ± 1 °, presents good super-hydrophobicity and self-cleaning performance, has the good optical performance simultaneously.
Description of drawings
Accompanying drawing is the structural representation of the utility model embodiment;
Among the figure: 1-luminescent powder basic unit; The 2-resin interlayer; 3-low-surface-energy material top layer.
The specific embodiment
Below in conjunction with drawings and Examples, further set forth the utility model.Should be understood that these embodiment only to be used to the utility model is described and be not used in the restriction scope of the present utility model.Should be understood that in addition those skilled in the art can make various changes or modifications the utility model after the content of having read the utility model instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment:
The compound super-hydrophobic film of a kind of organic-inorganic comprises luminescent powder basic unit, resin interlayer and low-surface-energy material top layer, and described luminescent powder basic unit and described low-surface-energy material top layer are bonded in the two sides of described resin interlayer respectively.
Described luminescent powder basic unit is a nanometer yttrium aluminum garnet luminescent powder basic unit, yttrium-aluminium-garnet is as laser material, be widely used in the photophore and the correlation window material of optical system and all kinds of light fixtures, and have outstanding elevated temperature strength and superior creep-resistant property.
Described resin interlayer is, epoxylite intermediate layer, acrylic resin intermediate layer, siliceous high temperature resistant resinoid intermediate layer, fluorine-containing corrosion-resistant resinoid intermediate layer or ECA resin interlayer, epoxylite intermediate layer, acrylic resin intermediate layer, siliceous high temperature resistant resinoid intermediate layer, fluorine-containing corrosion-resistant resinoid intermediate layer or ECA resin interlayer have the favorable mechanical performance.
Described low-surface-energy material top layer is natural wax top layer, paraffin top layer, manually synthetic fluorinated low-surface-energy material top layer or manually synthetic siliceous class low-surface-energy material top layer.
More than show and described basic principle of the present utility model, principal character and advantage of the present utility model.The technical staff of the industry should understand; the utility model is not restricted to the described embodiments; that describes in the foregoing description and the specification just illustrates principle of the present utility model; under the prerequisite that does not break away from the utility model spirit and scope; the utility model also has various changes and modifications, and these changes and improvements all fall in claimed the utility model scope.The claimed scope of the utility model is defined by appending claims and equivalent thereof.
All are from design of the present utility model, and the structure conversion of having done without creative work all drops within the protection domain of the present utility model.
Claims (4)
1. compound super-hydrophobic film of organic-inorganic, it is characterized in that: comprise luminescent powder basic unit, resin interlayer and low-surface-energy material top layer, described luminescent powder basic unit and described low-surface-energy material top layer are bonded in the two sides of described resin interlayer respectively.
2. the compound super-hydrophobic film of a kind of organic-inorganic as claimed in claim 1 is characterized in that: described luminescent powder basic unit is a nanometer yttrium aluminum garnet luminescent powder basic unit.
3. the compound super-hydrophobic film of a kind of organic-inorganic as claimed in claim 1 is characterized in that: described resin interlayer is epoxylite intermediate layer, acrylic resin intermediate layer, siliceous high temperature resistant resinoid intermediate layer, fluorine-containing corrosion-resistant resinoid intermediate layer or ECA resin interlayer.
4. the compound super-hydrophobic film of a kind of organic-inorganic as claimed in claim 1, it is characterized in that: described low-surface-energy material top layer is natural wax top layer, paraffin top layer, manually synthetic fluorinated low-surface-energy material top layer or manually synthetic siliceous class low-surface-energy material top layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011201109022U CN202045931U (en) | 2011-04-15 | 2011-04-15 | Organic and inorganic composite super hydrophobic membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011201109022U CN202045931U (en) | 2011-04-15 | 2011-04-15 | Organic and inorganic composite super hydrophobic membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202045931U true CN202045931U (en) | 2011-11-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011201109022U Expired - Fee Related CN202045931U (en) | 2011-04-15 | 2011-04-15 | Organic and inorganic composite super hydrophobic membrane |
Country Status (1)
| Country | Link |
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| CN (1) | CN202045931U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109265719A (en) * | 2018-09-28 | 2019-01-25 | 蔡菁菁 | It is a kind of with super-hydrophobic, self-cleaning function fluorescent glass and preparation method |
-
2011
- 2011-04-15 CN CN2011201109022U patent/CN202045931U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109265719A (en) * | 2018-09-28 | 2019-01-25 | 蔡菁菁 | It is a kind of with super-hydrophobic, self-cleaning function fluorescent glass and preparation method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111123 Termination date: 20120415 |