CN202039109U - Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation - Google Patents
Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation Download PDFInfo
- Publication number
- CN202039109U CN202039109U CN2011200885172U CN201120088517U CN202039109U CN 202039109 U CN202039109 U CN 202039109U CN 2011200885172 U CN2011200885172 U CN 2011200885172U CN 201120088517 U CN201120088517 U CN 201120088517U CN 202039109 U CN202039109 U CN 202039109U
- Authority
- CN
- China
- Prior art keywords
- rid
- pond
- tin
- ground
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The utility model relates to a spraying and spinning-leaching device for tin-plating copper granule copper-tin separation. The device comprises copper-tin separating spinning-leaching devices (1), a special orbit (2), a detinning tank (3), spraying devices (4, 8 and 11), a spinning-leaching ground pond (5), a rinsing tank (6), a rinsing ground pond (7), a water rinsing tank (9) and a water rinsing dewatering ground pond (10). The spraying and spinning-leaching device has the characteristics of short technological process, simple equipment, short time for leaching, continuous production and high leaching rate.
Description
Technical field
The utility model belongs to the recycling of tin-coated copper material, and particularly the isolating spray of tin-coated copper rice copper tin gets rid of bath unit.
Background technology
Telecommunications industry and solar cell use tinned wird and zinc-plated copper strips (band confluxes) in a large number, in the production and use of tinned wird (band), inevitably produce a large amount of useless tinned wire and tin-coated copper rice, processing to this part tinned wird and tin-coated copper rice, except that a part is used to produce the bell metal, utilize occasion for other, all require to remove the tin coating on the copper cash.About the about 1wt% of tin content, copper content is more than 98% in the tinned wird, and tin content has very high recovery value more than 8% in the tin-coated copper rice that produces in the zinc-plated copper strips production use.
At present, main both at home and abroad pyrogenic process, pyrogenic process electrolysis process, electrochemical method and the chemical process recovery tinned wird of adopting.China's utility model patent 95111809.9 utilizes pyrogenic process to reclaim tin in the particular melt medium, reaches the isolating effect of copper tin.But there is the energy consumption height, separates problems such as not thorough.The pyrogenic process electrolysis process is that waste material is smelted into the electrolysis copper coin, reaches separating copper tin effect by electrolysis, and there is the energy consumption height in this method, and operational path is long, the shortcoming that production cost is high.Electrochemical method can not etch copper matrix, and can reclaim spongy tin, and the melting removal of impurities of washing back can obtain 99.9% tin, but since in the tinned wird tin content differ, be difficult to control electrochemistry and reclaim technology, be difficult to scale operation.Part enterprise places technical hydrochloric acid to waste and old tinned wird, utilize oxygenant separating copper tin such as iron trichloride or hydrogen peroxide, reach the effect that reclaims copper, but this method subsequent treatment cost height, there is certain corrosion in copper, and in the follow-up immersion liquid copper, tin and iron separate purification ratio the difficulty.
China's utility model patent 200910090636.9 proposition copper sulfate displacement-heap leaching method reclaim the copper tin in the waste and old tinned wird, solve tinned wird suitability for industrialized production problem.Because tin-coated copper grain of rice degree is little, wetting property is poor, utilizes the very difficult copper tin separation that realize tin-coated copper rice of technology such as dump leaching.The 201010601227.1 proposition employings of China's utility model patent are got rid of bath unit specially and are separated with the copper tin that gets rid of soaking technology realization tin-coated copper rice, adopt electrolysis process directly to obtain metallic tin.This utility model can effectively be carried out the separation of copper tin to tin-coated copper rice, but this device can only be realized discontinuous production, and production efficiency is not high.The utility model will adopt spray to get rid of the method and apparatus that soaks tin-coated copper rice copper tin is effectively separated, and can realize continuity production, and extraction time is short, tin decreasing ratio height.
Chinese patent application number: in 201010279564.5 " a kind of method and apparatus of tin-coated copper rice Separation and Recovery metal copper tin ", the detin process is described in detail, quoted in full at this, among the application, the reagent of detin process is identical with above-mentioned application with consumption.
The utility model content
The purpose of this utility model mainly solves tin-coated copper rice copper tin and separates, proposing spray gets rid of soaking technology and separates copper tin in the tin-coated copper rice with device, not only can guarantee effective separating copper tin, and processing technological flow is short, equipment is simple, extraction time is short, continuity production, less investment, go up detective.
The isolating device of a kind of copper tin described in the utility model is characterized in that:
This device comprises that copper tin separates and gets rid of bath unit (1), dedicated track (2), detin groove (3), spray equipment (4,8,11), get rid of pond (10) with soaking pond (5), ground, rinse tank (6), pond (7), rinsing ground, washing bath (9) and washing dehydration;
Described detin groove (3), spray equipment (4) and getting rid of soaks pond, ground (5) and forms to get rid of and soak the district;
Described rinse tank (6), spray equipment (8) and rinsing pond, ground (7) form the rinsing district;
Described washing bath (9), spray equipment (11) and washing dehydration pond, ground (10) form the water elution pool;
Described detin groove (3) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (4) by pipeline; Get rid of and soak pond, ground (5) and link to each other with detin groove (3), get rid of immersion liquid and soak that realization circulates in pond, ground (5) and the detin groove (3) getting rid of with acid proof pump and pipeline.
Described rinse tank (6) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (8) by pipeline; Rinsing pond, ground (7) links to each other with rinse tank (6) with acid proof pump and pipeline, and rinsing liquid is realized circulation in rinsing pond, ground (7) and rinse tank (6).
Described washing bath (9) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (11) by pipeline; Wash the pond, ground (10) of dewatering and link to each other with washing bath (9) with acid proof pump and pipeline, water lotion is being realized circulating in pond (10) and the washing bath (9) with washing dehydration.
Described copper tin separation is got rid of bath unit (1) and is placed dedicated track (2) can push loading area, get rid of and soak district, water elution pool, rinsing district and discharge zone, on dedicated track (2), park many copper tin separation simultaneously and get rid of bath unit (1), loading area, get rid of the copper tin that soaks district, water elution pool, rinsing district and discharge zone and separate and get rid of bath unit (1) operation simultaneously, realize continuous production.
Described getting rid of in the process of soaking, copper tin are separated and to be got rid of bath unit (1) and place fully to get rid of and soak on the pond, ground (5), get rid of to soak process copper tin and separate to get rid of and effusively in the bath unit (1) get rid of immersion liquid and flow directly into to get rid of and soak pond (5), ground; In rinse cycle, copper tin separates and to get rid of bath unit (1) and place fully on the rinsing pond, ground (7), and rinse cycle gets rid of and soaks process copper tin and separate and get rid of that effusive rinsing liquid flows directly into pond (7), rinsing ground in the bath unit (1); In the washing dehydration, copper tin separates and to get rid of bath unit (1) and place fully on the washing pond, ground (10), and water dumping eluting water process copper tin separates and gets rid of that effusive washing dehydration liquid flows directly into pond (10), washing ground in the bath unit (1).
Characteristics such as the utlity model has that simple for process, liquid circulation is used and pollution-free, tin decreasing ratio height, leaching velocity be fast.
Description of drawings
Fig. 1 represents tin-coated copper rice copper tin tripping device.
Embodiment
The utility model implementation of processes is for example following:
200 kilograms of tin-coated copper rice in loading area is packed copper tin tripping device into, are pushed into to get rid of by dedicated track and soak the district and get rid of and soak, and the time is 5 minutes, and rotating speed is 100rpm, and spray rate is 10m3/h, and spray time is 5 minutes; Push the rinsing district and carry out rinsing getting rid of copper tin tripping device after soaking, the time is 1 minute, and rotating speed is 100rpm, and spray rate is 50m3/h, and spray time is 1 minute; Copper tin tripping device after the rinsing is pushed the water elution pool wash dehydration, the washing time is 2 minutes, and rotating speed is 100rpm, and spray rate is 70m3/h, and spray time is 2 minutes, and dewatering time is 5 minutes, and rotating speed is 100rpm; Copper tin tripping device after the washing dehydration is pushed discharge zone carry out discharging and obtain detin copper rice, the tin decreasing ratio is 98.3%.
Embodiment 2
200 kilograms of tin-coated copper rice in loading area is packed copper tin tripping device into, are pushed into to get rid of by dedicated track and soak the district and get rid of and soak, and the time is 2 minutes, and rotating speed is 1000rpm, and spray rate is 2m3/h, and spray time is 2 minutes; Push the rinsing district and carry out rinsing getting rid of copper tin tripping device after soaking, the time is 2 minutes, and rotating speed is 1000rpm, and spray rate is 30m3/h, and spray time is 2 minutes; Copper tin tripping device after the rinsing is pushed the water elution pool wash dehydration, the washing time is 1 minute, and rotating speed is 1000rpm, and spray rate is 10m3/h, and spray time is 1 minute, and dewatering time is 3 minutes, and rotating speed is 1000rpm; Copper tin tripping device after the washing dehydration is pushed discharge zone carry out discharging and obtain detin copper rice, the tin decreasing ratio is 98.5%.
Embodiment 3
200 kilograms of tin-coated copper rice in loading area is packed copper tin tripping device into, are pushed into to get rid of by dedicated track and soak the district and get rid of and soak, and the time is 4 minutes, and rotating speed is 600rpm, and spray rate is 50m3/h, and spray time is 4 minutes; Push the rinsing district and carry out rinsing getting rid of copper tin tripping device after soaking, the time is 3 minutes, and rotating speed is 600rpm, and spray rate is 2m3/h, and spray time is 3 minutes; Copper tin tripping device after the rinsing is pushed the water elution pool wash dehydration, the washing time is 1 minute, and rotating speed is 600rpm, and spray rate is 100m3/h, and spray time is 1 minute, and dewatering time is 3 minutes, and rotating speed is 600rpm; Copper tin tripping device after the washing dehydration is pushed discharge zone carry out discharging and obtain detin copper rice, the tin decreasing ratio is 97.8%.
Embodiment 4
200 kilograms of tin-coated copper rice in loading area is packed copper tin tripping device into, are pushed into to get rid of by dedicated track and soak the district and get rid of and soak, and the time is 3 minutes, and rotating speed is 400rpm, and spray rate is 30m3/h, and spray time is 3 minutes; Push the rinsing district and carry out rinsing getting rid of copper tin tripping device after soaking, the time is 3 minutes, and rotating speed is 400rpm, and spray rate is 10m3/h, and spray time is 3 minutes; Copper tin tripping device after the rinsing is pushed the water elution pool wash dehydration, the washing time is 3 minutes, and rotating speed is 400rpm, and spray rate is 40m3/h, and spray time is 3 minutes, and dewatering time is 4 minutes, and rotating speed is 400rpm; Copper tin tripping device after the washing dehydration is pushed discharge zone carry out discharging and obtain detin copper rice, the tin decreasing ratio is 98.1%.
The copper tin tripping device of a kind of tin-coated copper rice Separation and Recovery metal copper tin described in the utility model, as shown in Figure 1: this device comprises that copper tin separates and gets rid of bath unit 1, dedicated track 2, detin groove 3, spray equipment 4,8,11, get rid of and soak pond 5, ground, rinse tank 6, pond 7, rinsing ground, washing bath 9 and pond 10, washing dehydration ground.Detin groove 3, spray equipment 4 and getting rid of soaks pond, ground 5 and forms to get rid of and soak the district.Rinse tank 6, spray equipment 8 and pond, rinsing ground 7 form the rinsing district.Washing bath 9, spray equipment 11 and pond, washing dehydration ground 10 form the water elution pool.Detin groove 3 bottoms link to each other with acid proof pump, and acid proof pump links to each other with spray equipment 4 by pipeline; Get rid of and soak pond 5, ground and link to each other with detin groove 3, get rid of immersion liquid and realize circulating getting rid of to soak in pond 5, ground and the detin groove 3 with acid proof pump and pipeline.Rinse tank 6 bottoms link to each other with acid proof pump, and acid proof pump links to each other with spray equipment 8 by pipeline; Pond 7, rinsing ground links to each other with rinse tank 6 with acid proof pump and pipeline, and rinsing liquid is realized circulation in pond 7, rinsing ground and rinse tank 6.Washing bath 9 bottoms link to each other with acid proof pump, and acid proof pump links to each other with spray equipment 11 by pipeline; Wash the pond 10, ground of dewatering and link to each other with washing bath 9 with acid proof pump and pipeline, water lotion is being realized circulating in pond 10 and the washing bath 9 with washing dehydration.The separation of copper tin is got rid of bath unit 1 and is placed dedicated track 2 can push loading area, get rid of and soak district, water elution pool, rinsing district and discharge zone, on dedicated track 2, park many copper tin separation simultaneously and get rid of bath unit 1, loading area, get rid of the copper tin that soaks district, water elution pool, rinsing district and discharge zone and separate and get rid of bath unit 1 operation simultaneously, realize continuous production.
Claims (3)
1. the isolating spray of tin-coated copper rice copper tin gets rid of bath unit, it is characterized in that:
This device comprises that copper tin separates and gets rid of bath unit (1), dedicated track (2), detin groove (3), spray equipment (4,8,11), get rid of pond (10) with soaking pond (5), ground, rinse tank (6), pond (7), rinsing ground, washing bath (9) and washing dehydration;
Described detin groove (3), spray equipment (4) and getting rid of soaks pond, ground (5) and forms to get rid of and soak the district;
Described rinse tank (6), spray equipment (8) and rinsing pond, ground (7) form the rinsing district;
Described washing bath (9), spray equipment (11) and washing dehydration pond, ground (10) form the water elution pool;
Described detin groove (3) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (4) by pipeline; Get rid of and soak pond, ground (5) and link to each other with detin groove (3), get rid of immersion liquid and soak that realization circulates in pond, ground (5) and the detin groove (3) getting rid of with acid proof pump and pipeline;
Described rinse tank (6) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (8) by pipeline; Rinsing pond, ground (7) links to each other with rinse tank (6) with acid proof pump and pipeline, and rinsing liquid is realized circulation in rinsing pond, ground (7) and rinse tank (6);
Described washing bath (9) bottom links to each other with acid proof pump, and acid proof pump links to each other with spray equipment (11) by pipeline; Wash the pond, ground (10) of dewatering and link to each other with washing bath (9) with acid proof pump and pipeline, water lotion is being realized circulating in pond (10) and the washing bath (9) with washing dehydration.
2. the isolating spray of a kind of tin-coated copper rice copper tin as claimed in claim 1 gets rid of bath unit, it is characterized in that: the separation of copper tin is got rid of bath unit (1) and is placed dedicated track (2) can push loading area, get rid of and soak district, water elution pool, rinsing district and discharge zone, on dedicated track (2), park many copper tin separation simultaneously and get rid of bath unit (1), loading area, get rid of the copper tin that soaks district, water elution pool, rinsing district and discharge zone and separate and get rid of bath unit (1) operation simultaneously, realize continuous production.
3. the isolating spray of a kind of tin-coated copper rice copper tin as claimed in claim 1 gets rid of bath unit, it is characterized in that: in getting rid of the process of soaking, copper tin separates and to get rid of bath unit (1) and place fully to get rid of and soak on the pond, ground (5), gets rid of to soak process copper tin and separate to get rid of and effusively in the bath unit (1) get rid of immersion liquid and flow directly into to get rid of and soak pond (5), ground; In rinse cycle, copper tin separates and to get rid of bath unit (1) and place fully on the rinsing pond, ground (7), and rinse cycle gets rid of and soaks process copper tin and separate and get rid of that effusive rinsing liquid flows directly into pond (7), rinsing ground in the bath unit (1); In the washing dehydration, copper tin separates and to get rid of bath unit (1) and place fully on the washing pond, ground (10), and water dumping eluting water process copper tin separates and gets rid of that effusive washing dehydration liquid flows directly into pond (10), washing ground in the bath unit (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011200885172U CN202039109U (en) | 2011-03-30 | 2011-03-30 | Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011200885172U CN202039109U (en) | 2011-03-30 | 2011-03-30 | Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202039109U true CN202039109U (en) | 2011-11-16 |
Family
ID=44966564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011200885172U Expired - Fee Related CN202039109U (en) | 2011-03-30 | 2011-03-30 | Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202039109U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113061729A (en) * | 2021-03-19 | 2021-07-02 | 石家庄绿色再生资源有限公司 | Device and method for leaching indium from waste liquid crystal display screen in spraying manner |
| CN113234927A (en) * | 2021-03-19 | 2021-08-10 | 石家庄绿色再生资源有限公司 | Device and method for recycling indium in waste liquid crystal display |
-
2011
- 2011-03-30 CN CN2011200885172U patent/CN202039109U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113061729A (en) * | 2021-03-19 | 2021-07-02 | 石家庄绿色再生资源有限公司 | Device and method for leaching indium from waste liquid crystal display screen in spraying manner |
| CN113234927A (en) * | 2021-03-19 | 2021-08-10 | 石家庄绿色再生资源有限公司 | Device and method for recycling indium in waste liquid crystal display |
| CN113234927B (en) * | 2021-03-19 | 2022-05-20 | 石家庄绿色再生资源有限公司 | Device and method for recycling indium in waste liquid crystal display |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101838736B (en) | Wet separation method for valuable metals in purified liquid cobalt slags of wet zinc smelting system | |
| CN102061382A (en) | Method for recycling zinc from zinc leaching slag cleaning solution | |
| CN108910966B (en) | Method for extracting tungsten carbide and cobalt from waste hard alloy | |
| CN106185954B (en) | A kind of large-scale quartz sand acid removes iron impurity removal process | |
| CN102228746A (en) | Method for removing fluorine from zinc sulfate solution with active alumina | |
| CN202039109U (en) | Spraying and spinning-leaching device for tin-plating copper granule copper-tin separation | |
| CN113896361B (en) | Stainless steel pickling acid waste liquid cleaning treatment and resource recycling method | |
| CN104841691A (en) | Repair method of heavy metal nickel contaminated soil | |
| CN101899583B (en) | Integrative method of two-stage acid leaching, washing and filter pressing for manganese powder pickle liquor | |
| CN101260471B (en) | Complete set of cleaning producing technique for extracting soluble manganese from manganese residue by using anode liquor | |
| CN106185953B (en) | A kind of large-scale quartz sand pickling impurity removal whitening process | |
| CN202039110U (en) | Spraying device for separating copper and tin of tinplated copper billet | |
| CN102280225B (en) | Spraying, throwing and leaching method and device for separating copper and tin from tinned grain-like copper | |
| CN101937742B (en) | Method and device for separating and recovering metallic copper and tin in tinplating copper | |
| CN102127643B (en) | Spraying method and device for separating copper from tin in tin-plated copper block | |
| CN105645706A (en) | Method for harmlessly treating high-zinc and high-lead sludge | |
| CN201785462U (en) | Dedicated copper and tin separation device for separating and recovering metallic copper and metallic tin of tinned copper nodules | |
| CN205741153U (en) | Heavy metal the device of recycling in a kind of waste acid recovery | |
| CN111792642B (en) | Method and equipment for stripping negative plate of retired battery and deeply removing impurities from graphite | |
| CN108396365A (en) | A kind of electronickelling is water-saving and the method for nickel recycling | |
| CN103420438A (en) | Electroplating-rinse-water recycling and reusing method | |
| CN209024646U (en) | A kind of PCB moves back tin system | |
| CN201567359U (en) | Device for recovery of solution in hydrometallurgical residue | |
| CN112403028A (en) | Method for purifying lead electrolyte by using columnar activated carbon | |
| CN101905932B (en) | Process for treating and recycling wastewater generated by performing chrome-free passivation on electrolytic manganese |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111116 Termination date: 20140330 |