CN201949806U - Dechlorination device in process of producing chlorinated paraffin - Google Patents
Dechlorination device in process of producing chlorinated paraffin Download PDFInfo
- Publication number
- CN201949806U CN201949806U CN2011200028140U CN201120002814U CN201949806U CN 201949806 U CN201949806 U CN 201949806U CN 2011200028140 U CN2011200028140 U CN 2011200028140U CN 201120002814 U CN201120002814 U CN 201120002814U CN 201949806 U CN201949806 U CN 201949806U
- Authority
- CN
- China
- Prior art keywords
- dechlorination
- hydrogen chloride
- chlorinated paraffin
- still
- kettle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Abstract
The utility model relates to a dechlorination device in the process of producing chlorinated paraffin. A tail gas exhaust pipe of a chlorinated reaction kettle is communicated with a dechlorination kettle, the dechlorination kettle is connected to a liquid wax input pipe, the upper end of the dechlorination kettle is provided with a hydrogen chloride outlet, and the lower end of the dechlorination kettle is connected with the dechlorination kettle through a transferring pump. With the adoption of the dechlorination device in the process of producing chlorinated paraffin, the utilization rate of chlorine and the purity of hydrogen chloride gas can be improved, impurities in liquid wax can be eliminated, the product quality of the chlorinated paraffin can be improved, and considerable economic benefit and practicability are available. With the adoption of the technology, the chlorine content in hydrogen chloride is less than or equal to 0.1%, the purity of the hydrogen chloride gas is improved so as to meet the use requirement of a chlorosulfonic acid device, the quality of the liquid wax is improved at the same time, and the comprehensive product quality is beneficially improved.
Description
Technical field:
The utility model relates to the device that removes the chlorine in the hydrogen chloride gas in the chlorinated paraffin wax production process.
Background technology:
In the chlorinated paraffin wax chlorination reaction process, there is part chlorine excessive, the one, cause chlorine consumption big, the 2nd, the reaction chlorinated exhaust needs to absorb with liquid caustic soda, increased production cost, the 3rd, pollute surrounding environment, hydrogen chloride can be sent to the chlorosulfonic acid device and produce chlorosulfonic acid, but purity, the chlorinity of chlorine are had relatively high expectations, and the hydrogen chloride that the conventional chlorinated paraffin wax mode of production is produced can not satisfy the production of chlorosulfonic acid.
Summary of the invention:
The purpose of this utility model is to overcome above-mentioned technical deficiency, and a kind of liquid wax dechlorination device is provided.
Dechlorination device in a kind of chlorinated paraffin wax production process, the exhaust pipe of chlorination reaction still is communicated with the dechlorination still, the dechlorination still is connected with liquid wax input pipe, the hydrogen chloride outlet is established in the upper end of dechlorination still, the lower end links to each other with the chlorination reaction still by transfering material pump, and annular gas distributor and feed liquor tetrafluoro bend pipe are installed in the described dechlorination still.
The hydrogen chloride outlet of described dechlorination still upper end links to each other with the chlorosulfonic acid device.
The chlorinated exhaust that chlorination reaction is produced feeds dechlorination reaction in the hot liquid wax, and the gas behind the dechlorination reaction is got rid of from the hydrogen chloride outlet, and the liquid that contains liquid wax of generation is got rid of the raw material that the back conduct continues chlorination reaction.
Successive reaction under described dechlorination reaction pressure 0.02-0.03MPa, temperature 70-90 ℃ and the light-initiated condition.
Gas behind the described dechlorination reaction enters the chlorosulfonic acid production system.
Liquid wax after the heating is squeezed in the dechlorination still continuously by certain flow, and the chlorinated exhaust with the generation in the chlorinated paraffin wax production process feeds the dechlorination still again.For improving removal effect, annular gas distributor and feed liquor tetrafluoro bend pipe are installed in still.Under certain pressure, temperature and light-initiated condition, purification hydrogen chloride gas and improve the quality of liquid wax.Contain hydrogen chloride, chlorine and steam in the chlorinated exhaust.Hydrogen chloride is emitted in chlorine in the tail gas, wax oil reaction, and chlorine is deviate from, and has improved the purity of tail gas hydrogen chloride; Because the still temperature is than higher, water vapor condensation is a moisture in the tail gas, behind the absorbing hydrogen chloride, forms hydrochloric acid (concentration reaches more than 33%), is sunken to the bottom of wax oil automatically.Moisture in the wax oil is also because the temperature height is separated.Generate ferric trichloride behind iron ion and chlorine, the hcl reaction, because the density of ferric trichloride own is big, soluble in water, its solubility in wax oil is much smaller than the solubility in hydrochloric acid, so ferric trichloride is easy to be extracted from wax oil by hydrochloric acid.The reaction of aromatic hydrocarbons and chlorine, basic nitrogen and hydrogen chloride, product density is all greater than 1, and this moment, oily density was about 0.8, so be easy to be sunken to the bottom of wax oil, the bottom separator is discharged system by sewage draining exit, wax oil through so handling enters system again, has improved the purity of hydrogen chloride and liquid wax, helps the lifting of product quality.
The utility model is two separating substances technology of gas gas, can improve the utilization rate of chlorine and the purity of hydrogen chloride gas, can remove the impurity in the liquid wax again, improves the product quality of chlorinated paraffin wax, has considerable economic and practicality.
The utilization of this technology makes content≤0.1% of chlorine in the hydrogen chloride, has improved hydrogen chloride gas purity to satisfy the use of chlorosulfonic acid device, improves the quality of liquid wax simultaneously, helps the lifting of product comprehensive quality.
Description of drawings
Fig. 1 is the utility model structure drawing of device;
Fig. 2 is the structure chart of the utility model dechlorination still;
Wherein: 1 chlorination reaction still, 2 dechlorination stills, 3 liquid wax input pipes, the outlet of 4 hydrogen chloride, 5 transfering material pumps, 6 annular gas distributors, 7 feed liquor tetrafluoro bend pipes, 8 circulating pumps
The specific embodiment
Dechlorination device in a kind of chlorinated paraffin wax production process communicates the exhaust pipe of chlorination reaction still 1 with dechlorination still 2, dechlorination still 2 is connected with liquid wax input pipe 3, and hydrogen chloride outlet 4 is established in the upper end of dechlorination still 2, and the lower end links to each other with chlorination reaction still 1 by transfering material pump 5.Annular gas distributor 6 and feed liquor tetrafluoro bend pipe 7 are installed in the described dechlorination still 2.
The hydrogen chloride of described dechlorination still 2 upper ends outlet 4 links to each other with the chlorosulfonic acid device.
Claims (3)
1. the dechlorination device in the chlorinated paraffin wax production process is characterized in that, the exhaust pipe of chlorination reaction still is communicated with the dechlorination still, and the dechlorination still is connected with liquid wax input pipe, and the hydrogen chloride outlet is established in the upper end of dechlorination still, and the lower end links to each other with the chlorination reaction still by transfering material pump.
2. the dechlorination device in the chlorinated paraffin wax production process according to claim 1 is characterized in that, annular gas distributor and feed liquor tetrafluoro bend pipe are installed in the described dechlorination still.
3. the dechlorination device in the chlorinated paraffin wax production process according to claim 1 is characterized in that, the hydrogen chloride outlet of described dechlorination still upper end links to each other with the chlorosulfonic acid device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011200028140U CN201949806U (en) | 2011-01-06 | 2011-01-06 | Dechlorination device in process of producing chlorinated paraffin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011200028140U CN201949806U (en) | 2011-01-06 | 2011-01-06 | Dechlorination device in process of producing chlorinated paraffin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201949806U true CN201949806U (en) | 2011-08-31 |
Family
ID=44493935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011200028140U Expired - Fee Related CN201949806U (en) | 2011-01-06 | 2011-01-06 | Dechlorination device in process of producing chlorinated paraffin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201949806U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102145251A (en) * | 2011-01-06 | 2011-08-10 | 鲁西化工集团股份有限公司氯碱化工分公司 | Dechloridation device and process in chlorinated paraffin production process |
| CN104415580A (en) * | 2013-08-27 | 2015-03-18 | 丹阳市助剂化工厂有限公司 | Method and device for removing hydrogen chloride and residual chlorine from liquid chlorinated paraffin |
| CN107312567A (en) * | 2017-08-03 | 2017-11-03 | 江西塑星材料有限公司 | A kind of method of purification of chlorinated paraffin raw material wax oil |
-
2011
- 2011-01-06 CN CN2011200028140U patent/CN201949806U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102145251A (en) * | 2011-01-06 | 2011-08-10 | 鲁西化工集团股份有限公司氯碱化工分公司 | Dechloridation device and process in chlorinated paraffin production process |
| CN104415580A (en) * | 2013-08-27 | 2015-03-18 | 丹阳市助剂化工厂有限公司 | Method and device for removing hydrogen chloride and residual chlorine from liquid chlorinated paraffin |
| CN104415580B (en) * | 2013-08-27 | 2016-04-27 | 丹阳市助剂化工厂有限公司 | A kind of liquid chlorinated paraffin dehydrochlorination and chlorine residue method and apparatus |
| CN107312567A (en) * | 2017-08-03 | 2017-11-03 | 江西塑星材料有限公司 | A kind of method of purification of chlorinated paraffin raw material wax oil |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102145251B (en) | Dechloridation device and process in chlorinated paraffin production process | |
| CN104560197B (en) | The tail gas treatment process of chlorinated paraffin | |
| CN103613126B (en) | A kind of method and system removing vanadium impurity from titanic tetrachloride | |
| CN201949806U (en) | Dechlorination device in process of producing chlorinated paraffin | |
| CN103588615B (en) | Device and technology for recovery of tetrachloroethylene | |
| CN111635293A (en) | Sodium methoxide production device and method | |
| CN203803139U (en) | Thionyl chloride differential pressure thermal coupling distillation equipment | |
| CN211393845U (en) | Siloxane-containing dilute hydrochloric acid analysis and purification device | |
| CN105480948A (en) | Method and system for recycling by-product hydrogen chloride in fatty acid or fatty acyl chloride chlorination production process | |
| CN203938477U (en) | The chlorine dioxide generator under vacuum condition with evaporation, reactive crystallization | |
| CN203440262U (en) | Device for producing trans-1, 2-dichloroethylene with acetylene by adopting catalytic chlorination method | |
| CN104163832A (en) | Glyphosate continuous production device and glyphosate continuous production method | |
| CN103896747A (en) | Backpack type circulation production process device of high-concentration methylal | |
| CN203602357U (en) | Heat energy circulation device for producing sulfoxide chloride | |
| CN105037078B (en) | A kind of method reclaiming dichloromethane in chlorine ketone mother solution | |
| CN110078023B (en) | Method for improving thermal efficiency in hydrochloric acid deep analysis | |
| CN201463628U (en) | Chlorine washing and cooling system | |
| CN207793117U (en) | A kind of improved refining of crude phenol system | |
| CN102001658B (en) | Novel method for purifying gaseous phosgene | |
| CN203007173U (en) | Preparation device of ultra-high-purity difluoromonochloroethane | |
| CN202072665U (en) | Combination reaction kettle device for negative pressure production of modified pitch | |
| CN101608872B (en) | Device for washing and cooling chlorine | |
| CN205759789U (en) | The novel bromine rectifying column that a kind of filler and column plate are combined | |
| CN203478167U (en) | Residual heat recovery device | |
| CN103303868A (en) | Bromine distillation tower |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110831 Termination date: 20130106 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |