CN201917553U - Online automatic detection device for sulphitation strength in sugarhouse - Google Patents
Online automatic detection device for sulphitation strength in sugarhouse Download PDFInfo
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- CN201917553U CN201917553U CN2010206766030U CN201020676603U CN201917553U CN 201917553 U CN201917553 U CN 201917553U CN 2010206766030 U CN2010206766030 U CN 2010206766030U CN 201020676603 U CN201020676603 U CN 201020676603U CN 201917553 U CN201917553 U CN 201917553U
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Abstract
The utility model discloses an online automatic detection device for sulphitation strength in a sugarhouse, which comprises a vacuum pump, a vacuum buffering tank, a sample juice cup, a neutral water metering cup, a mixing test cup, an iodine solution metering peristaltic pump, a step counting motor and related connecting pipes, valves and control circuits. The detection device also comprises a sample juice filtering device, a cleaning system which cleans sample juice with cleaning water through related pipes, and a device for precisely metering sample juice. The detection device can clean a system comprehensively and thoroughly, can effectively reduce the scaling and blocking of the pipes, and can eliminate the residual sample juice interference of previous detection, so as to reduce measurement errors. Because of the arrangement of an electromagnetic valve communicated with the vacuum buffering tank and the atmosphere, each measurement and control period is shortened.
Description
Technical field
The utility model relates to the pick-up unit of sulfur dioxide concentration in the solution, specifically relates to the sugarcane juice Sulfitation intensity on-line automatic detection apparatus in the used sulfurous method sugar refining technology of sugar enterprise.
Background technology
In order to make white sugar show pure whitening, improve the quality and the grade of product, in the sulfitation process craft that cane sugar industry the most generally adopts at present, be by adding SO
2, milk of lime and phosphoric acid, thereby formation calcium sulfite precipitation and calcium phosphate precipitation adsorb the colloid in the syrup, pigment and remove, that is: adopt sulfur dioxide gas that sugar-cane juice is fumigated, the oarse-grained sediment that muddy pre-grey sugar-cane juice generates after stove drying neutralization, heating is through sedimentation, perhaps the major part suspension colloid in the sugarcane juice and pigment, impurity come-up are removed, then subsequent processing just can successfully be isolated as clear as crystal and look shallow clear juice.Yet, adopt such technology, for guaranteeing to produce the steady quality white sugar product, in carrying out the stove drying process, need frequent measurements of sulfur dioxide concentrations law, and regulate intensity of sulfitation, otherwise easily cause the residual quantity of sulphur in the white sugar finished product to exceed standard according to measurement result.
Sugar enterprise also adopts traditional manual detection method mostly to the mensuration of intensity of sulfitation at present.The shortcoming that adopts manual method to detect is to be subjected to that human factor influences greatly, the observing and controlling cycle is long, labour intensity is high, and makes the control effect vary with each individual, and error is big, and the accuracy of measurement data is difficult for assurance.
The inventor discloses a kind of intensity of sulfitation automatic detection device in China's patented claim formerly 200710170002.5.This device includes vacuum pump, neutral water jigger, sugarcane juice cup, mixing cup, Dewar bottle, iodine liquid metering peristaltic pump, step-by-step counting motor and relevant pipeline and gauge tap according to the quantitative reaction principle design of sulphurous acid and iodine solution; Described Dewar bottle connects together with vacuum pump evacuation tube and sugarcane juice cup evacuation tube and vacuum pump and sugarcane juice cup respectively, the sugarcane juice cup is also respectively with neutral water rising pipe and sugarcane juice juice yield tube and neutral water jigger with mixes and glass connect together, iodine liquid metering peristaltic pump glass connects together with mixing with iodine liquid efferent duct, stirring machine then places the top of mixing cup, neutral water, three kinds of liquid of sugarcane juice and iodine liquid are transported to host computer in mixing cup data of gained after stirring machine fully mixes and produces chemical reaction by DOL Data Output Line simultaneously and handle, by the intensity of sulfitation data that feedback obtains the input concentration of sulphuric dioxide is controlled, thereby reach the robotization of intensity of sulfitation observing and controlling, shorten the observing and controlling cycle, reduce the technique effect of labour intensity.
The instructions of this application is partly mentioned, this technical scheme adopts pneumatic sampling, because the mobilization of air-flow is arranged, and when gathering sugarcane juice, sugarcane juice also can play the effect of flushing tube wall in flow process, avoided tube wall owing to the obstruction that incrustation causes pipeline appears in long-term the use.Yet, in this technical scheme, because purging system is not set, the sugarcane juice cup is that the neutral water that relies on this detection to flow through washes (water yield is limited), can only rely on the inferior liquid to be checked in back to wash away and mix cup, cause last time the raffinate after detecting to disturb easily like this, cause measuring error detecting next time to produce; And after pick-up unit is using a period of time, may in device, form fouling, stop up pipeline, by-pass valve control and measuring vessel in the proving installation, precision and life-span that influence is measured.In addition, juice feeding tube and the shared mode of juice yield tube in the sugarcane juice cup adopted in the sample juice metering of this pick-up unit, and measuring accuracy is not high, in addition, owing to be subjected to the influence of site specifics such as motor speed, sample juice flow velocity, pipeline size, the adding sugarcane juice amount of sample juice jigger is leaned on time control substantially.
The utility model content
The purpose of this utility model promptly is on the basis of above-mentioned Chinese patent formerly, and a kind of sugar refinery Sulfitation intensity on-line automatic detection apparatus that can solve above-mentioned deficiency is provided.
The utility model Sulfitation intensity on-line automatic detection apparatus comprises vacuum pump, vacuum buffer tank, sample juice cup, neutral water jigger, hybrid test cup, iodine liquid metering peristaltic pump, step-by-step counting motor, and relevant connection pipeline, valve and control circuit; Described vacuum buffer tank is connected with vacuum pump and sample juice cup by pipeline respectively; Described neutral water jigger is provided with neutral water water inlet and water delivering orifice; Described sample juice cup is provided with sample juice juice flow inlet and juice opening; Described juice opening is communicated with the hybrid test cup by pipeline; Described iodine liquid metering peristaltic pump is provided with the input of iodine liquid, efferent duct; Described iodine liquid efferent duct is communicated with the hybrid test cup; Described step-by-step counting motor is electrically connected with this iodine liquid metering peristaltic pump; Test electrode is set in the described hybrid test cup, also is provided with leakage fluid dram; Described test electrode will produce that the test data of gained is sent to computer via DOL Data Output Line behind the chemical reaction; Its special feature is: the water delivering orifice of described neutral water jigger is communicated with the hybrid test cup by pipeline; Also include sample juice filtration unit, adopt rinse water to sample juice flow through purging system that associated pipe cleans, and, the device that sample juice is carried out accurate measurement.
Particularly, the purging system that is adopted includes scavenging pump, cleaning valve that connects rinse water and the cleaning liquor pipe that described scavenging pump, cleaning valve and sample juice cup are connected, and described cleaning valve is a solenoid valve; Described sample juice filtration unit is connected between sample juice sample tap and the sample juice cup juice flow inlet by pipeline.
The described device that sample juice is carried out accurate measurement, its concrete structure can for: be provided with sample juice jigger in the described sample juice cup; The juice opening of described sample juice cup is located at the bottom of described sample juice jigger; Described sample juice juice flow inlet is located at cup between the outer wall of the inwall of described sample juice cup and described sample juice jigger at the end; Liquid-level probe and following liquid-level probe are housed on the described sample juice cup madial wall; Described installation site of going up liquid-level probe is higher than described sample juice jigger rim of a cup; The described installation site of liquid-level probe down is lower than described sample juice jigger rim of a cup.
As improvement to above-mentioned Sulfitation intensity on-line automatic detection apparatus, the neutral water water inlet of described neutral water jigger is connected to the neutral water storage tank, the neutral water storage tank shell is provided with a liquid level tube that is used to observe liquid level, and the neutral water in the neutral water storage tank can pump into this neutral water jigger by a water pump; Before the described iodine liquid input pipe iodine liquid storage tank is installed, this iodine liquid storage tank is provided with a liquid level tube that is used to observe liquid level.
From such scheme as can be known, improvements of the present utility model are:
1, after every test is once finished, be not with liquid to be checked pipeline and measuring vessel to be washed away, but add rinse water, the pipeline that sample juice cup, hybrid test cup and sample juice are passed through cleans.
2, in the increase of this Sulfitation intensity on-line automatic detection apparatus filtration unit is arranged.By this filtration unit, can be the Impurity removal in the sample juice to be measured.
3, as to such scheme further improve again, be provided with sample juice jigger in the described sample juice cup; This sample juice jigger is the interior cup that is total to the end with described sample juice cup, and its glass body is lower than described sample juice cup, and, leave the space between the inwall of its outer wall and described sample juice cup; The sample juice juice flow inlet of described sample juice cup is located at cup between the outer wall of the inwall of described sample juice cup and described sample juice jigger at the end; The rim of a cup of described sample juice jigger opens wide, and is provided with the juice opening that is communicated with sample juice juice yield tube at the bottom of its glass; This sample juice juice yield tube leads on the path of described hybrid measurement cup, is provided with sample juice solenoid valve.After adopting this structure, when device enters the cleaning state, after cleaning fluid entered sample juice cup by scavenging pump, solenoid purge valve, the one tunnel discharged from sample juice sample tap through the outer cup and the filtrator of sample juice cup, and sample juice jigger, sample juice solenoid valve, the hybrid test cup of another road in sample juice cup discharged.Like this, can rinse the raffinate in sample juice cup, filtrator, sample juice jigger, sample juice solenoid valve, hybrid measurement cup and the corresponding pipeline well respectively, in order to measure next time.
4, as to above scheme optimization, liquid-level probe and following liquid-level probe are housed on the described sample juice cup madial wall; The described liquid-level probe installation site of going up is higher than described sample juice jigger rim of a cup; Described liquid-level probe installation site down is lower than described sample juice jigger rim of a cup.By the control of last liquid-level probe and following liquid-level probe, can guarantee that sample juice jigger is that the sample juice of brimmer is used for test, the while also be beneficial to sample juice advance/discharge opeing monitors automatically.
5, for guaranteeing the pick-up unit continuous working, the utility model Sulfitation intensity on-line automatic detection apparatus also is provided with the neutral water liquid storage bottle and is used for neutral water is transported to from this neutral water liquid storage bottle the neutral water water pump of neutral water jigger; And/or, also comprise iodine liquid liquid storage bottle.Iodine liquid is sent into the hybrid test cup by the wriggling volume pump.Neutral water storage tank and iodine liquid storage tank are established a liquid level tube respectively, so that observe the liquid storage consumption at any time.
6, before test, increase presampling juice step, thereby the non-fresh sample juice suction sample juice cup that can reduce/prevent sample juice sample tap place exerts an influence to test.
As to above scheme further optimize again, the utility model Sulfitation intensity on-line automatic detection apparatus also can include the solenoid valve that is communicated with in the described vacuum buffer tank jar with jar outer atmosphere.This solenoid valve plays vacuum regulating valve: after with vacuum mode sample juice being drawn onto the last liquid level of sample juice cup, this vacuum regulating valve is opened in energising, then in the sample juice cup owing to lose negative pressure, the unnecessary sample juice in the sample juice cup can be discharged rapidly along former juice-feeding tube road by the juice flow inlet at the bottom of being positioned at glass.
Existing relatively Sulfitation intensity on-line automatic detection apparatus, the purging system of the utility model by increasing newly:
1) can be comprehensively, up hill and dale to sample juice enter, measurement, discharge line and container clean, and stops up so can effectively reduce pipeline scale, prolongs the serviceable life of Sulfitation intensity on-line automatic detection apparatus;
2) can eliminate the sample juice raffinate that last time detected and disturb, reduce measuring error;
3) to measure the consumption of sample juice reliable and stable at every turn, precision improvement, and then improve the quality of products;
4) by a solenoid valve that is communicated with described vacuum buffer tank and atmosphere is set, shortened each observing and controlling cycle.
Description of drawings
Fig. 1 is structural principle and the measuring method synoptic diagram of an embodiment of the utility model Sulfitation intensity on-line automatic detection apparatus.
Fig. 2 is the structural representation of an embodiment of the utility model Sulfitation intensity on-line automatic detection apparatus.
Description of reference numerals:
1-vacuum pump 2-vacuum buffer tank 3-sample juice cup 4-sample juice jigger 5-hybrid test cup
6-iodine liquid metering peristaltic pump 7-neutral water jigger 8-scavenging pump 9,16-sample juice filtration unit
10-sample juice sample tap 11-vacuum pump gas outlet 21-vacuum solenoid 22-vacuum pump evacuation tube
23-sample juice cup evacuation tube 31-sample juice solenoid valve 32-sample juice juice yield tube 41, the upper and lower liquid-level probe of 42-
43-sample juice cup juice feeding tube 51-draining solenoid valve 52-stirrer 53-test electrode
54-leakage fluid dram 61-iodine liquid storage tank 62, the input of 63-iodine liquid, efferent duct 64-peristaltic pump step-by-step counting motor
65-iodine liquid liquid level tube 71-neutral water solenoid valve 72-neutral water storage tank 73-neutral water water pump
74-neutral water recirculatory pipe 75-neutral water liquid level tube 76-neutral water liquid outlet 77-neutral water metering catheter
81-solenoid purge valve 82-cleaning liquor pipe
Embodiment
Below in conjunction with drawings and Examples the utility model Sulfitation intensity on-line automatic detection apparatus is further described.
Fig. 1 is structural principle and the measuring method synoptic diagram of an embodiment of the utility model Sulfitation intensity on-line automatic detection apparatus.Fig. 2 is the hardware configuration synoptic diagram of an embodiment of the utility model Sulfitation intensity on-line automatic detection apparatus.Sulfitation intensity on-line automatic detection apparatus as shown in the figure, mainly by vacuum pump 1, vacuum buffer tank 2, sample juice cup 3, neutral water jigger 7, hybrid test cup 5, iodine liquid metering peristaltic pump 6 (having step-by-step counting motor 64), sample juice filtration unit 9, adopt rinse water that sample juice purging system and relevant connection pipeline, valve and the control circuit that associated pipe cleans of flowing through formed;
Be provided with sample juice jigger 4 (its capacity is generally elected 10ml as) in the sample juice cup 3, the two common end,, sample juice jigger 4 is equivalent to the interior cup of sample juice cup 3, and sample juice juice opening promptly is located at the bottom of sample juice jigger 4; The sample juice juice flow inlet 43 of sample juice cup 3 is located at cup between the outer wall of the inwall of sample juice cup 3 and sample juice jigger 4 at the end; Liquid-level probe 41 and following liquid-level probe 42 are housed on described sample juice cup 3 madial walls; Last liquid-level probe 41 installation sites are higher than sample juice jigger 4 rims of a cup; Following liquid-level probe 42 installation sites are lower than sample juice jigger 4 rims of a cup.Sample juice juice opening is communicated with hybrid test cup 5 by pipeline 32 and sample juice solenoid valve 31;
Neutral water in the neutral water storage tank 72 pumps into neutral water jigger 7 by water pump 73 through neutral water liquid outlet 76 and neutral water metering catheter 77; Unnecessary neutral water in the neutral water jigger 7 flows back to neutral water storage tank 72 through recirculatory pipe 74; These neutral water storage tank 72 tank skins are provided with the liquid level tube 75 that is used to observe liquid level.The water delivering orifice of neutral water jigger 7 is communicated with hybrid test cup 5 by pipeline and neutral water solenoid valve 71;
Iodine liquid metering peristaltic pump 6 is provided with the input of iodine liquid, efferent duct 62 and 63; Iodine liquid efferent duct 63 is communicated with hybrid test cup 5; Peristaltic pump step-by-step counting motor 64 is electrically connected with this iodine liquid metering peristaltic pump 6; Before the iodine liquid input pipe 62 of iodine liquid metering peristaltic pump 6 iodine liquid storage tank 61 is installed, these iodine liquid storage tank 61 tank skins are provided with the liquid level tube 65 that is used to observe liquid level; Test electrode 53 is set in the described hybrid test cup 5, also is provided with leakage fluid dram 54; Described test electrode 53 will produce that the test data of gained is sent to computer via DOL Data Output Line behind the chemical reaction;
Sample juice filtration unit 9 is connected between sample juice sample tap 10 and sample juice cup 3 juice flow inlets by pipeline 43;
The purging system that is adopted includes scavenging pump 8, solenoid purge valve 81 that connects rinse water and the cleaning liquor pipe 82 that described scavenging pump 8, solenoid purge valve 81 and sample juice cup 3 are connected;
The operation logic of present embodiment Sulfitation intensity on-line automatic detection apparatus and workflow can be provided with as follows:
(1) presampling juice step:
(2) sample juice cup 3 vacuumizes:
(3) detected sample juice enters sample juice cup 3:
Open sample juice solenoid valve 31, detected sample juice through sample juice filtrator 9, enters sample juice cup 3 from sample juice inlet 10;
When sample juice position was elevated to liquid-level probe, vacuum pump 1 quit work;
(4) detected sample juice enters hybrid test cup 4:
(5) neutral water measures and enters the hybrid test cup:
Liquid in the sample juice jigger 4 all flow into after the hybrid test cup 5, and neutral water pump 73 starts allows the water of neutral water storage tank 72, flows in the neutral water jigger 7, and until neutral water jigger brimmer, unnecessary neutral water overflows back neutral water storage tank 72; Open neutral water solenoid valve 71, the liquid in the neutral water jigger 7 all flows into hybrid test cup 5;
(6) iodine liquid adds hybrid test cup 5:
Wriggling volume pump 6 starts, and the iodine liquid in the iodine liquid storage tank 61 is transported to hybrid test cup 5, and the amount of conveying is accurately controlled by computer and stepper motor;
(7) hybrid test and output data:
After above-mentioned three kinds of liquid all add hybrid test cup 5, start stirrer 52.And, reacted data are sent to computerized control system by test electrode 53; Computerized control system is according to the input quantity of the Data Control sulphuric dioxide of gathering; After the data stabilization, open draining solenoid valve 51, reacted liquid is discharged;
(8) clean:
Open sample juice solenoid valve 31 and solenoid purge valve 81, scavenging pump 8 starts, and rinse water enters sample juice cup 3, a tunnel and discharges from sample sweat sample tap through sample juice cup 3, filtrator 9, sample juice jigger 4, sample juice solenoid valve 31, the hybrid test cup 5 of another road in sample juice cup 3 discharged by leakage fluid dram 54.Thereby, respectively sample juice cup 3, filtrator 9, sample juice jigger 4, sample juice solenoid valve 31, hybrid test cup 5 and the corresponding sample juice pipeline of flowing through is rinsed well;
Close sample juice solenoid valve 31 and solenoid purge valve 81, in order to measure next time.
Claims (10)
1. Sulfitation intensity on-line automatic detection apparatus comprises vacuum pump, vacuum buffer tank, sample juice cup, neutral water jigger, hybrid test cup, iodine liquid metering peristaltic pump, step-by-step counting motor, and relevant connection pipeline, valve and control circuit;
Described vacuum buffer tank is connected with vacuum pump and sample juice cup by pipeline respectively;
Described neutral water jigger is provided with neutral water water inlet and water delivering orifice;
Described sample juice cup is provided with sample juice juice flow inlet and juice opening; Described juice opening is communicated with the hybrid test cup by pipeline;
Described iodine liquid metering peristaltic pump is provided with the input of iodine liquid, efferent duct; Described iodine liquid efferent duct is communicated with the hybrid test cup;
Described step-by-step counting motor is electrically connected with this iodine liquid metering peristaltic pump;
Test electrode is set on the described hybrid test cup, also is provided with leakage fluid dram;
Described test electrode will produce that the test data of gained is sent to computer via DOL Data Output Line behind the chemical reaction;
It is characterized in that:
The water delivering orifice of described neutral water jigger is communicated with the hybrid test cup by pipeline;
Also include sample juice filtration unit, adopt rinse water to sample juice flow through purging system that associated pipe cleans, and, the device that sample juice is carried out accurate measurement.
2. Sulfitation intensity on-line automatic detection apparatus according to claim 1 is characterized in that: the purging system that is adopted includes scavenging pump, cleaning valve that connects rinse water and the cleaning liquor pipe that described scavenging pump, cleaning valve and sample juice cup are connected; Described cleaning valve is a solenoid valve.
3. Sulfitation intensity on-line automatic detection apparatus according to claim 1 is characterized in that: described sample juice filtration unit is connected between sample juice sample tap and the sample juice cup juice flow inlet by pipeline.
4. according to the described Sulfitation intensity on-line automatic detection apparatus of one of claim 1 to 3, it is characterized in that, the described concrete structure that sample juice is carried out the device of accurate measurement is: be provided with sample juice jigger in the described sample juice cup, the juice opening of described sample juice cup is located at the bottom of described sample juice jigger; Described sample juice juice flow inlet is located at cup between the outer wall of the inwall of described sample juice cup and described sample juice jigger at the end; Liquid-level probe and following liquid-level probe are housed on the described sample juice cup madial wall; Described installation site of going up liquid-level probe is higher than described sample juice jigger rim of a cup; The described installation site of liquid-level probe down is lower than described sample juice jigger rim of a cup.
5. according to the described Sulfitation intensity on-line automatic detection apparatus of one of claim 1 to 3, it is characterized in that: the neutral water water inlet of described neutral water jigger is connected to the neutral water storage tank, and this neutral water storage tank shell is provided with a liquid level tube that is used to observe liquid level.
6. Sulfitation intensity on-line automatic detection apparatus according to claim 4 is characterized in that: the neutral water water inlet of described neutral water jigger is connected to the neutral water storage tank, and this neutral water storage tank shell is provided with a liquid level tube that is used to observe liquid level.
7. according to the described Sulfitation intensity on-line automatic detection apparatus of one of claim 1 to 3, it is characterized in that: before the described iodine liquid input pipe iodine liquid storage tank is installed, this iodine liquid storage tank is provided with a liquid level tube that is used to observe liquid level.
8. Sulfitation intensity on-line automatic detection apparatus according to claim 4 is characterized in that: before the described iodine liquid input pipe iodine liquid storage tank is installed, this iodine liquid storage tank is provided with a liquid level tube that is used to observe liquid level.
9. according to the described Sulfitation intensity on-line automatic detection apparatus of one of claim 1 to 3, it is characterized in that: described vacuum buffer tank also is provided with one with the solenoid valve that is communicated with the outer atmosphere of jar in the jar.
10. Sulfitation intensity on-line automatic detection apparatus according to claim 4 is characterized in that: described vacuum buffer tank also is provided with one with the solenoid valve that is communicated with the outer atmosphere of jar in the jar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010206766030U CN201917553U (en) | 2010-12-23 | 2010-12-23 | Online automatic detection device for sulphitation strength in sugarhouse |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010206766030U CN201917553U (en) | 2010-12-23 | 2010-12-23 | Online automatic detection device for sulphitation strength in sugarhouse |
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| Publication Number | Publication Date |
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| CN201917553U true CN201917553U (en) | 2011-08-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010206766030U Expired - Lifetime CN201917553U (en) | 2010-12-23 | 2010-12-23 | Online automatic detection device for sulphitation strength in sugarhouse |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102103121A (en) * | 2010-12-23 | 2011-06-22 | 钦州华成自控设备有限公司 | Online automatic detection device for sulphitation intensity of sugar refinery |
| CN109490143A (en) * | 2019-01-13 | 2019-03-19 | 上海务宝智能装备有限公司 | Pickling solution performance online detection system and method |
-
2010
- 2010-12-23 CN CN2010206766030U patent/CN201917553U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102103121A (en) * | 2010-12-23 | 2011-06-22 | 钦州华成自控设备有限公司 | Online automatic detection device for sulphitation intensity of sugar refinery |
| CN102103121B (en) * | 2010-12-23 | 2014-03-26 | 钦州华成自控设备有限公司 | Online automatic detection device for sulphitation intensity of sugar refinery |
| CN109490143A (en) * | 2019-01-13 | 2019-03-19 | 上海务宝智能装备有限公司 | Pickling solution performance online detection system and method |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20110803 Effective date of abandoning: 20140326 |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20110803 Effective date of abandoning: 20140326 |
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| AV01 | Patent right actively abandoned | ||
| AV01 | Patent right actively abandoned |