CN201900016U - Hollow perforated porcelain ball - Google Patents

Hollow perforated porcelain ball Download PDF

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Publication number
CN201900016U
CN201900016U CN2010205696651U CN201020569665U CN201900016U CN 201900016 U CN201900016 U CN 201900016U CN 2010205696651 U CN2010205696651 U CN 2010205696651U CN 201020569665 U CN201020569665 U CN 201020569665U CN 201900016 U CN201900016 U CN 201900016U
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CN
China
Prior art keywords
hollow
ball
porcelain
perforate
porcelain ball
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2010205696651U
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Chinese (zh)
Inventor
张会成
孙万付
赵荣林
耿敬远
刘淑琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
Original Assignee
China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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Application filed by China Petroleum and Chemical Corp, Sinopec Fushun Research Institute of Petroleum and Petrochemicals filed Critical China Petroleum and Chemical Corp
Priority to CN2010205696651U priority Critical patent/CN201900016U/en
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Publication of CN201900016U publication Critical patent/CN201900016U/en
Anticipated expiration legal-status Critical
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Abstract

The utility model discloses a hollow perforated porcelain ball. The hollow perforated porcelain ball is of a hollow ball structure. The surface of the hollow ball is provided with an opening. The hollow perforated porcelain ball has advantages of high permeability, large void fraction, low specific gravity of the porcelain ball and the like. When the hollow perforated porcelain ball is filled to the top of a reactor, a great amount of settlings in the reactor can be accommodated, therefore, the problem of high pressure drop of the reactor is effectively solved, the operation period of a device is prolonged and the hollow perforated porcelain ball has obvious economic benefits.

Description

A kind of hollow Pored ceramic ball
Technical field
The utility model relates to a kind of inserts that is used for field reactors such as petrochemical industry, sewage disposal, specifically a kind of hollow perforate Ceramic Balls ceramic material.
Background technology
At petrochemical industry, be extensive use of a kind of filler of porcelain ball as reactor, it has mechanical strength, acid and alkali-resistance and corrosion resistance preferably, and can improve the redispersibility of material in the reactor, reduce circulating resistance, further improve the filter effect of gas-liquid, but it is than great, hole is little, can only hold impurity by piling up the gap, after the oil product deposit stopped up the gap, reactor pressure decrease increased, and device must be stopped work and be handled.
In order to improve the volume dirt ability of porcelain ball, a large amount of improvements have been done in this area on porcelain ball profile, honeycomb Pored ceramic ball, the CN2837299Y that proposes as CN201053000Y proposes solid Pored ceramic ball, CN2550055Y and propose Lantern porcelain ball, CN2848852Y honeycomb porcelain ball, CN2413787Y and propose Pored ceramic ball, CN2762877Y and propose that the crown porcelain ball of protrusion of surface, CN2535119Y propose the light Pored ceramic ball of bubble, CN2360151Y proposes Slot ceramic ball.These futuramic porcelain balls are compared with pure solid porcelain ball very big improvement, and packing ratio is great, porosity is little but still exist, and holds the deficiency of dirty ability.
Summary of the invention
The utility model has designed a kind of new hollow perforate Ceramic Balls, this porcelain ball has that bulk specific weight is little, porosity is big, holds the strong advantage of dirty ability, can effectively reduce the reactor bed pressure drop, the conditioned reaction logistics distributes, and this hollow Pored ceramic ball has broad application prospects.
The hollow Pored ceramic ball of the utility model is the hollow ball structure, and the hollow ball surface has perforate.
In the hollow Pored ceramic ball of the utility model, the hollow ball diameter can be determined as required, is generally 3~80mm, preferred 5~20mm.The thickness of hollow ball is generally 2%~40% of hollow ball diameter, is preferably 5%~30%.
In the hollow Pored ceramic ball of the utility model, the perforate on hollow ball surface can be various suitable shape, is preferably circle, ellipse, polygon, bar shaped etc.The quantity of perforate specifically is provided with according to the diameter of hollow ball, is generally 2~100, is preferably 4~20.Percent opening (the long-pending ratio of external table of the gross area duty bulbus cordis of perforate) is 0.1%~30%, is preferably 1%~20%.
The hollow Pored ceramic ball of the utility model has more macroporosity and the dirty ability of appearance, is applicable to impure or easy incrustation reaction system, as residual oil hydrocatalyst bed top, and coker gasoline hydrogenation catalyst bed top, the sewage disposal system reactor is medium.
Description of drawings
Fig. 1 is the first kind of hollow porcelain spherical structure of perforate schematic diagram;
Fig. 2 is the second kind of hollow porcelain spherical structure of perforate schematic diagram;
Fig. 3 is the hollow porcelain spherical structure of the third a perforate schematic diagram.
Wherein: 1, porcelain outer surface of ball, 2, the hollow sphere of porcelain ball, 3, the sphere perforate.
The specific embodiment
The hollow Pored ceramic ball of the utility model can adopt suitable method preparation, as preparing as follows:
1, is raw material with alumina dry glue and china clay, adds appropriate amount of addition agent and water and peptizing agent, mix, stir into available porcelain mud.
2, the spherical flammable charcoal with required diameter is hollow dose, outer equably one deck porcelain mud of wrapping up in, and whole spherical in shape or almost spherical, compression moulding in mould is then dried, and forms the porcelain embryo.
3, offer the hole of requirement and size on the porcelain embryo with suitable instrument, the hole evenly distributes on sphere.
4, the porcelain embryo of perforate is put into roaster, under bubbling air, be warmed up to 500 ℃-800 ℃ gradually, make flammable charcoal be converted into carbon dioxide, form hollow ball.
5, continue to be warmed up to 1200 ℃-1600 ℃ again, the hollow ball sintering slowly cools to 300 ℃-500 ℃ then, quickens to be cooled to room temperature and makes hollow perforate Ceramic Balls.
Embodiment 1
In Fig. 1, the hollow porcelain ball of described perforate is raw material with china clay, and the spherical activated charcoal of diameter 14mm is hollow dose, wraps up in the thick porcelain mud of 3mm outward, is pressed into sphere in mould, dries, and forms the porcelain embryo.Open circular hole with suitable instrument on the porcelain embryo, the diameter in hole is 3mm, and the quantity in hole is 10, and the hole evenly distributes on sphere.The porcelain embryo of perforate is put into roaster, under bubbling air, be warmed up to 750 ℃ gradually, make charcoal be converted into carbon dioxide, form hollow ball.Continue to be warmed up to 1400 ℃ again, the hollow ball sintering slowly cools to 300 ℃ then, quickens to be cooled to room temperature and makes hollow perforate Ceramic Balls.
Embodiment 2
In Fig. 2, the hollow porcelain ball of described perforate is raw material with china clay, and the spherical activated charcoal of diameter 10mm is hollow dose, wraps up in the thick porcelain mud of 3mm outward, is pressed into sphere in mould, dries, and forms the porcelain embryo.With specific purpose tool opening square hole on the porcelain embryo, the length of side in hole is 3mm, and the quantity in hole is 10, and the hole evenly distributes on sphere.The porcelain embryo of perforate is put into roaster, under bubbling air, be warmed up to 600 ℃ gradually, make charcoal be converted into carbon dioxide, form hollow ball.Continue to be warmed up to 1500 ℃ again, the hollow ball sintering slowly cools to 300 ℃ then, quickens to be cooled to room temperature and makes hollow perforate Ceramic Balls.
Embodiment 3
In Fig. 3, the hollow porcelain ball of described perforate is raw material with china clay, and the spherical activated charcoal of diameter 5mm is hollow dose, wraps up in the thick porcelain mud of 1mm outward, is pressed into sphere in mould, dries, and forms the porcelain embryo.Open delthyrium with suitable instrument on the porcelain embryo, the length of side in hole is 1mm, and the quantity in hole is 6, and the hole evenly distributes on sphere.The porcelain embryo of perforate is put into roaster, under bubbling air, be warmed up to 700 ℃ gradually, make charcoal be converted into carbon dioxide, form hollow ball.Continue to be warmed up to 1600 ℃ again, the hollow ball sintering slowly cools to 400 ℃ then, quickens to be cooled to room temperature and makes hollow perforate Ceramic Balls.

Claims (10)

1. hollow Pored ceramic ball, it is characterized in that: hollow Pored ceramic ball is the hollow ball structure, and the hollow ball surface has perforate.
2. according to the described hollow Pored ceramic ball of claim 1, it is characterized in that: the hollow ball diameter is 3~80mm.
3. according to the described hollow Pored ceramic ball of claim 1, it is characterized in that: the hollow ball diameter is 5~20mm.
4. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the thickness of hollow ball is 2%~40% of hollow ball diameter.
5. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the thickness of hollow ball is 5%~30% of hollow ball diameter.
6. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the perforate on hollow ball surface is circular, ellipse, polygon or bar shaped.
7. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the quantity of perforate is 2~100.
8. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the quantity of perforate is 4~20.
9. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the percent opening of hollow Pored ceramic ball is 0.1%~30%.
10. according to claim 1 or 2 described hollow Pored ceramic balls, it is characterized in that: the percent opening of hollow Pored ceramic ball is 1%~20%.
CN2010205696651U 2010-10-14 2010-10-14 Hollow perforated porcelain ball Expired - Lifetime CN201900016U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010205696651U CN201900016U (en) 2010-10-14 2010-10-14 Hollow perforated porcelain ball

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010205696651U CN201900016U (en) 2010-10-14 2010-10-14 Hollow perforated porcelain ball

Publications (1)

Publication Number Publication Date
CN201900016U true CN201900016U (en) 2011-07-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010205696651U Expired - Lifetime CN201900016U (en) 2010-10-14 2010-10-14 Hollow perforated porcelain ball

Country Status (1)

Country Link
CN (1) CN201900016U (en)

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Granted publication date: 20110720

CX01 Expiry of patent term