CN201860889U

CN201860889U - Environment-friendly type sole

Info

Publication number: CN201860889U
Application number: CN2010202407382U
Authority: CN
Inventors: 万贤能
Original assignee: Individual
Current assignee: Individual
Priority date: 2010-06-25
Filing date: 2010-06-25
Publication date: 2011-06-15
Anticipated expiration: 2020-06-25

Abstract

The utility model provides an environment-friendly type sole, which comprises an abrasion resistant bottom layer and a body layer made of composite material; wherein the body made of composite material is disposed on the abrasion resistant bottom layer. The environment-friendly type sole provided in the utility model saves production cost, has environmental protection effect and improves resource utilization ratio.

Description

The environment-friendly type sole

Technical field

The utility model relates to a kind of commodity sole, particularly a kind of preparation method of the composite with waste recovery utilization and adopt this composite environment-friendly type sole that make, that have environment-friendly function.

Background technology

The sole of Chu Xianing mainly adopts reclaimed rubber to form as raw material manufacturing in the market, if major part is made sole with the reclaimed rubber after the desulfurization, it can discharge the gas that contains sulfur dioxide or the like in the process of carrying out desulfurization, environment and atmosphere thereof on every side caused substantial pollution, and production cost is bigger; And, caused the wasting of resources, and these defective works can cause unlimited accumulation and pollution or the like harmful effect to environment owing to discarded articles for daily use, plastic products and latex product or the like defective work is not recycled in the prior art.

Thus, provide a kind of can effectively avoid polluting can guarantee product quality again, and have the waste recovery utilization composite preparation method and adopt this composite environment-friendly type sole that make, that have environment-friendly function to necessitate.

The utility model content

The utility model provides a kind of preparation method of composite and the environment-friendly type sole made from this composite, this manufacture method environmental protection, and energy savings; This sole is environmental and durable, quality good.

In order to solve the problems of the technologies described above, a kind of environment-friendly type sole that the utility model provides, it comprises wear-resisting bottom and the body layer of being made by composite, wherein the described body layer of making by composite be arranged on described wear-resisting bottom above.

Further, described wear-resisting bottom is the tire section.

Further, described wearing layer is one deck rubber sheet.

Further, be provided with the glue intermediate layer of adhesion effect between described wear-resisting bottom and the described body layer.

Preferably, described wear-resisting bottom and described body layer adopt vulcanizer to vulcanize simultaneously to combine together.

Further, described wear-resisting bottom can be adopted in the method for paste with described body layer and combine.

The beneficial effects of the utility model are: by the recycling to defective work, particularly Fei Qi everyday general purpose article, rubber plastic article, rubber and plastic chemical substance and latex article or the like do not have the article of use value, can recycle by the method that the utility model provides, be made into a kind of composite that can be used for doing sole, thereby avoided above-mentioned discarded object that environment is caused unlimited accumulation and pollution, also saved production cost simultaneously; And its physical property of sole and non-skid property that the employing above-mentioned material that provides of the utility model manufactures all be greatly improved, have wear-resisting, quality is hard, the quality at the continuous end; Simultaneously owing in gum, added a lot of recovery resources, so when vulcanizing, the toxic gas that produces when the toxic gas that contains sulphur of its generation vulcanizes than the sole that all is gum is wanted much less, thereby further reduced pollution, improved utilization resource to environment.

Description of drawings

The structural representation of the environment-friendly type sole that Fig. 1 provides for the utility model.

The specific embodiment

Below with reference to accompanying drawing preferred embodiment of the present utility model is described, it is as the part of this specification, by embodiment principle of the present utility model is described, other aspects of the present utility model, feature and advantage thereof will become very clear by this detailed description.

As shown in Figure 1, the environment-friendly type sole 1 that the utility model provides comprises two-layer, wherein one deck is the wear-resisting bottom 3 that contacts with ground, and another layer is a sole body layer 2, and wherein the additive made by the defective work in rubber mass and the treated life of this sole body layer 2 is made.Described wear-resisting bottom 3 adopts vulcanizer to vulcanize simultaneously with described body layer 2 and combines together, also can adopt in the method for paste in conjunction with (will describe in detail below).

In order to reach the purpose of environmental protection and energy saving, body layer 2 in the sole of the present utility model adopts the defective work that can utilize again in the life to handle (below will be described in detail) through processing and is made into additive, forming correspondingly by additive and other some raw materials again, batching processes, when having solved house refuse, defective work pollution problems, the production cost and the energy have also been saved greatly.Wherein this defective work that can utilize again (chemistry, not tractable, not perishable) mainly comprises:

A: discarded everyday general purpose thing ornaments as: footwear, clothing, cap, accessory, leather, sponge ... etc.;

B: the discarded object of rubber plastic goods is as discarded kids toys, toy for animal, sports equipment, Tire ﹠ Tube, rubber driving belt, rubber leather hose, rubber leftover pieces and the scrap of discarded steam turbine bicycle, the rubber discarded object of office usefulness ... etc.;

C: the film of making after the devulcanization of rubber, rubber directly are crushed to rubber grain in small, broken bits ... etc.;

D: the daily discarded object of other rubber and plastic chemical products as, cullet, waste electric wire, mat applying foot pad ... etc.;

E: latex product is as: therapeutic medical gloves defective products or the Washing gloves that uses defective products, family or the specialty of discarded object, condom to use ... etc.

Basically the like waste rubbish such as fiber-like, rubber-like that belong to commonly used may be used to make body layer 2 in the utility model sole in the life.

Body layer mainly comprises following batching, finishes through a series of banburyings, mixing and other processing and fabricating operation in the utility model.

The batching of body layer 2 is (using deal can geometric ratio to amplify or dwindle): the paraffin of the silane coupling agent of the diethylene glycol (DEG) (DEG) of the zinc oxide of the rubber mass of 1000g, the white carbon of 100-500g, 30-70g, the stearic acid of 5-20g, 10-50g, the age resistor of 10-20g, 10-70 part, the dispersant of 10-20g, 10-15g, the Petropols of 10-100g, the promoter of 10-30g, the additive of 100-2000g and the sulphur of 10-30g.Above-mentioned batching just can be made into the extremely strong body layer of rerum natura and solidity 2 (its processing and fabricating method will be done detailed description below) through rubber mixing machine processing.

This rubber mass can form for independent cis-butadiene cement, butyronitrile rubber or natural gum also can be cooperated arbitrarily by cis-butadiene cement, butyronitrile rubber and natural gum.

Compare as the sole of body layer with using gum, the sole that the utility model provides is owing to the effect of body layer and wear-resisting bottom, and its hardness, abrasion resistance, non-skid property and gum are suitable, surmount country and international standard far away.And its maximum advantage of body layer is the rubbish in the life to be carried out recycling, and produces quality and meets that national standard is good, the measured body layer sole of matter; It has not only possessed practical condition, and also played and saved the energy, the effect of protection environment, we have made things convenient for life by the earth of inhabitation the protection of bigger meaning.

The wear-resisting bottom 3 that the utility model provides can be cut into slices for tire, through to waste tire cutting, make not only wear-resisting, but also the convenient processing of the wear-resisting bottom made, but also recycling obsolete material has further improved the environment protecting of this product.

The wear-resisting bottom 3 that the utility model provides also can be rubber sheet, and wherein this rubber sheet batching is (using deal can geometric ratio to amplify or dwindle): 1000 parts by butyronitrile rubber, cis-butadiene cement; the thin slice rubber mass that butadiene-styrene rubber and natural gum are formed; the carbon black of 0-200 part; the white carbon of 100-700 part; the zinc oxide of 30-60 part; the stearic acid of 6-12 part; the diethylene glycol (DEG) of 10-70 part; the silane coupling agent of 10-70 part; the age resistor of 5-40 part; the dispersant of 5-40 part; the paraffin of 5-10 part; the Petropols of 20-70 part; the sulphur of the promoter of 10-30 part and 10-30 part.

Wherein, this thin slice rubber mass can also can be combined arbitrarily by cis-butadiene cement, butyronitrile rubber and natural gum for independent cis-butadiene cement, butyronitrile rubber or natural gum.

Better combine in order to make between wear-resisting bottom 3 and the body layer 2, the sole 1 that the utility model provides has scribbled the glue intermediate layer of adhesion effect between wear-resisting bottom 3 and body layer 2, further reinforce being connected between body layer 2 and the wear-resisting bottom 3, thereby guaranteed the quality of product, do not broken off the base, the continuous end.

The sole that the utility model provides, described wear-resisting bottom can be adopted in the method for paste with described body layer and directly combine.Wear-resisting bottom and described body layer can be adopted in the method for paste and be combined into:

At first, body layer and wear-resisting bottom are carried out surface breakdown with steel wire or emery wheel, and in 24 hours, embrocate rubber finishing agent and guarantee the effect of surface breakdown and avoid pollution, just can embrocate the surface glue stick between 24 hours to 120 hours after embrocating rubber finishing agent, otherwise must embrocate rubber finishing agent again, in order to avoid influence pasting effect.

Comprise that further described surperficial binding agent is intermediary's binding agent of described wear-resisting skid resistant course and described rubber body layer to the step of described wear-resisting bottom and described body layer difference obliterating surface glue stick.

Put the body layer of obliterating binding agent and wear-resisting bottom into 50 °-70 ° of about temperature baking box 5-10 minute, purpose is that binding agent is become dry, and increases adhesiveness simultaneously, behind the obliterating binding agent, must use immediately.

Comprise further that with the adhesion of fitting of described wear-resisting skid resistant course and described rubber body layer the adhesion of fitting is to carry out having under the situation of temperature.The position that wearing layer and body layer the are fitted compacting of exerting oneself so can help finally forming the sole body layer and combine with wear-resisting skid resistant course, with the realization the purpose of this utility model so that combine with the rubber body layer of being more prone to of wearing layer is more firm.

Introduce the processing and fabricating method of body layer below in detail:

It mainly comprises the steps (using deal can geometric ratio to amplify or dwindle):

A: the rubber mass of getting 1000 weight portions is put into rubber internal mixer middling speed refining 1-2 minute;

B: the silane coupling agent of getting white carbon, 10-70 part of 100-500 weight portion is put into rubber internal mixer middling speed refining 1-2 minute

C: the promoter of getting Petropols, the 10-30 weight portion of paraffin, the 10-100 weight portion of dispersant, the 10-15 weight portion of age resistor, the 10-20 weight portion of diethylene glycol (DEG), the 10-20 weight portion of stearic acid, the 10-50 weight portion of zinc oxide, the 5-20 weight portion of 30-70 weight portion was put into the mixing 5-10 of rubber internal mixer minute and was evenly mixed;

D: above-mentioned even mixed batching put into put the district temporarily at least 48 hours;

E: get the above-mentioned batching of 1000 weight portions, the additive of 100-2000 weight portion and the sulphur of 10-30 weight portion and make its even mixing, it is mixing to put into rubber mixing mill;

F: obtain body layer composite material forming product, finish the making of described body layer.

The body layer 2 that is made by said method, it will well be merged, reacts last wear-resisting, the soft body layer that forms mutually by the additive that discarded object causes with other materials, in recycling waste material, its method of operating is simple, has also improved operating efficiency.

To introduce the manufacturing process of the described additive of making by discarded object below in detail:

A: at first collect recycling defective work, use discarded object later in the nearly all as mentioned above life of this defective work, mainly comprise fiber-like discarded object in the daily life, rubber-like discarded object or the like uncorruptible discarded object;

B: then with the crushing of above-mentioned defective work or cut into fine grained chippings shape, graininess in small, broken bits or Powdered;

C: more above-mentioned chunky shape, graininess or pulverous defective work are used the chemical agent cleaning and dipping, with attachment and the greasy dirt stain of removing the surface, increase above-mentioned discarded object and link, be beneficial to strengthen the adhesion strength between discarded object and the rubber with chemical synthesis interface between the elastomeric material;

D: after finishing making, obtain an amount of additive, carry out mixed uniformly additive with the mode and the rubber synthetic material of filling to above-mentioned defective work.

For the purpose of the realization energy-saving and environmental protection of maximum efficiency, the weight of above-mentioned discarded object additive preferably accounts between the 1%-70% of gross weight of above-mentioned composite.So both reduced the use of gum greatly, and saved cost, the generation of the dusty gas when also having reduced the sole sulfuration has been carried out recyclingly simultaneously to refuse, play environmental-protection function.

Thus, a kind of environment-friendly type sole that the utility model provides and the manufacture method of body layer thereof, simple, by recycling to defective work, be made into a kind of composite that can be used for doing sole, thereby avoided above-mentioned discarded object that environment is polluted, also saved production cost simultaneously; And its physical property of sole and on-slip Practical Performance that the employing above-mentioned material that provides of the utility model manufactures all be greatly improved, and has more particularity quality wear-resisting, that quality is hard, continuous end is sliding; Simultaneously owing in gum, added a lot of recovery resources, so when vulcanizing, the toxic gas that produces when the toxic gas that contains sulphur of its generation vulcanizes than the sole that all is gum is wanted much less, thereby further reduced pollution to environment, improved utilization, and reached the purpose of environmental protection resource.

The above only is preferred embodiment of the present utility model; not in order to restriction the utility model; all within spirit of the present utility model and principle, any modification of being done, be equal to replacement, improvement etc., all should be included within the protection domain of the present utility model.

Claims

1. environment-friendly type sole, it comprises wear-resisting bottom and the body layer of being made by composite, wherein the described body layer of making by composite be arranged on described wear-resisting bottom above.

2. environment-friendly type sole according to claim 1 is characterized in that: described wear-resisting bottom is the tire section.

3. environment-friendly type sole according to claim 1 is characterized in that: described wearing layer is one deck rubber sheet.

4. environment-friendly type sole according to claim 1 is characterized in that: the glue intermediate layer that has been provided with the adhesion effect between described body layer and the described wear-resisting bottom.

5. environment-friendly type sole according to claim 1 is characterized in that: described wear-resisting bottom and described body layer adopt vulcanizer to vulcanize simultaneously and combine together.

6. environment-friendly type sole according to claim 1 is characterized in that: described wear-resisting bottom can be adopted in the method for paste with described body layer and combine.