CN201603516U - Slurry pond combined oxidization device for wet-process desulphurization - Google Patents

Slurry pond combined oxidization device for wet-process desulphurization Download PDF

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Publication number
CN201603516U
CN201603516U CN2010290441047U CN201029044104U CN201603516U CN 201603516 U CN201603516 U CN 201603516U CN 2010290441047 U CN2010290441047 U CN 2010290441047U CN 201029044104 U CN201029044104 U CN 201029044104U CN 201603516 U CN201603516 U CN 201603516U
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China
Prior art keywords
air
oxidation
slurry pond
pond
coil
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Expired - Fee Related
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CN2010290441047U
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Chinese (zh)
Inventor
缪明烽
徐晓亮
于爱华
王文超
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Nanjing No7425 Factory Of Zhongche Group
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Nanjing No7425 Factory Of Zhongche Group
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Priority to CN2010290441047U priority Critical patent/CN201603516U/en
Application granted granted Critical
Publication of CN201603516U publication Critical patent/CN201603516U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model relates to a slurry pond forced oxidization device in a wet-process flue gas desulphurization system. A coil air ejector pipe is arranged in a slurry pond and a plurality of oxidization air spray guns which are evenly distributed around the slurry pond are arranged below the coil air ejector pipe. The amount of air sprayed by the coil air ejector pipe accounts for 50-70 percent of total air amount and the amount of air sprayed by the air spray guns accounts for 30-50 percent of the total air amount. Since the device effectively combines the coil air ejector pipe and the air spray guns and reasonably optimizes the arrangement of the pipe network and the spray nozzles of the coil air ejector pipe, the gas-liquid flow field in the slurry pond can fully satisfy the requirements on the full oxidization of calcium sulfite and the fouling prevention during operation. The utility model has the advantages that the oxygen utilization ratio is improved, the operation energy consumption is reduced, the system structure is very simple and the maintenance is easy.

Description

A kind of slurry pond compound oxidation device that is applicable to wet desulphurization
Technical field
The utility model relates to a kind of wet flue gas desulfurization absorption tower, particularly a kind of oxidation air feedway of limestone-gypsum wet flue gas desulfurization tower.
Background technology
The SO of coal-fired process discharging 2Environment is caused serious harm, adopted flue gas desulfurization technique to control usually.Limestone-gypsum method is the most stable, the most ripe, most widely used wet flue gas desulfurization technology, and the oxidation of sulphite is wherein important chemical process.Flue gas self contains the oxidable part calcium sulfite of oxygen, and autoxidation promptly takes place, but oxygenation efficiency do not reach and to a certain degree easily cause fouling, and autoxidation also is subjected to oxygen to the liquid interface diffusion slowly and be absorbed SO 2Restriction.And forced oxidation has overcome above-mentioned shortcoming, and by blasting excess air, strong mixing makes the abundant oxidation of calcium sulfite, and the control fouling improves reliability of system operation, finally can produce gypsum.
The performance of forced oxidation device is subjected to influence of various factors, and wherein the pH value is a key parameter that influences the forced oxidation performance.The slurry environments of high pH helps SO 2Absorption, low pH then helps the oxidation of calcium sulfite, and in the absorption tower from top to bottom the pH value raise gradually, so the position of oxidation air feedway is most important in the forced oxidation type wet flue gas desulfurization absorption tower.According to the difference at slurries pond position, the oxidation air feedway mainly contains 2 kinds: (1) torch-type oxidation air feedway.This device is traditional oxidation unit, is positioned at bottom, slurries pond.Spray gun is ejected into the place ahead of side-feeding type slurry mixer rotary blade with oxidation air, utilizes the agitator paddle rotational kinetic energy that the oxidation air bubble is smashed, and then oxidation air is evenly distributed in the absorption slurries in the absorption tower.This oxygen feedway has obtained extensive use because form is simple relatively.Yet along with coming into operation of middle and high sulphur coal, single tower smoke treatment amount and SO 2Concentration increases, and the diameter in slurries pond and highly also thereupon increasing causes this feedway may be in slurries pond central authorities formation dead band, in this zone the oxidation air time of staying shorter, the slurries oxidation effectiveness is poor; In addition, oxidation fan generally adopts roots blower, and this blower fan oxygen utilization rate is low, pressure head is high, not only increase investment and operating cost, and the equipment noise is big, the maintenance management difficulty.(2) oxidation air pipe air feeder.This device is the process characteristic of the limestone-gypsum wet process of FGD technology of German Shandong strange energy environment protection limited company.The zoneofoxidation of this technology is positioned at the top in slurries pond, and huge pond separator separates itself and bottom reaction tank, and being arranged in pond separator oxidation air pipe at interval provides oxidation air.This forced oxidation device arrangement can improve oxidation efficiency and obtain highly purified gypsum.But this arrangement easily causes oxidation air to inject insufficient imperfection that causes gypsum crystallization, also may cause the fouling of absorption tower inwall.
Summary of the invention
Technical problem: in order to overcome the shortcoming that existing oxidation unit exists, the utility model proposes a kind of multi-layer combined oxidation unit that is applicable to wet desulphurization, this device is the oxidation unit by coiled air jet pipe (being similar to the oxidation air pipe) and air gun combined type, can effectively improve the utilization rate of oxygen, reduce operation energy consumption, simplied system structure also is easy to safeguard.
Technical scheme: the key problem of slurries pond, limestone/gypsum wet method fume desulfurizing system absorption tower oxidative system is as minimum cost how, and the oxidation air that oxidation fan is carried obtains utilization rate efficiently.The utility model is coiled air jet pipe and air gun reasonable Arrangement, connection and reasonable arrangement optimization to the pipe network and the nozzle of coiled air jet pipe, make to be in operation, make full use of slurry pH value gradient characteristic distributions, reach the abundant oxidation of calcium sulfite and prevent the requirement of desulphurization system fouling.Specifically, the technical scheme of this device employing comprises:
A kind of slurry pond compound oxidation device, comprise the slurries pond, it is characterized in that: equally distributed some oxidation air spray guns around in described slurries pond, being provided with the coiled air jet pipe and being positioned at below it along the slurries pond, wherein coiled air jet pipe ejection air capacity accounts for 50%~70% of total air, and air gun ejection air capacity accounts for 30%~50% of total air.
Described coiled air jet pipe comprises the coil pipe of 2~6 parallel and even layouts, at the staggered up and down air nozzle that evenly is furnished with of described every coil pipe.
The quantity of described oxidation air spray gun is 4.
1. the oxidation fan air-supply is divided into two strands, and one enters the slurries pond by coiled air jet pipe nozzle, and the coiled air jet pipe is arranged on the cross section, slurries pond, and another strand enters the slurries pond by air gun, and air gun is evenly arranged some all around along the slurries pond.
2. the coiled air jet pipe is positioned on the cross section on top, slurries pond, is made up of the some coil pipes that have air nozzle, and the coil pipe level is evenly arranged, makes every effort to the oxidation air maximum magnitude and covers the cross section, absorption tower.The air gun arrangement is consistent with traditional oxidation unit, is positioned at the bottom in slurries pond.
3. the two-way interlaced arrangement up and down of the nozzle on the coiled air jet pipe, oxidation air, is formed suitable flow field, thereby makes oxidation air be uniformly distributed in the slurries pond with certain flow velocity and pressure ejection by nozzle in the slurries pond, and effectively prevents the slurries precipitation.
Beneficial effect: coiled air jet pipe and air gun compound oxidation device that the utility model adopts, slurries fully mix under the turbulent flow power effect that contains bubble, and bubble can evenly distribute, and forms very big material exchange surface.The coiled air jet pipe is arranged in top, slurries pond, helps improving O 2Utilization rate makes calcium sulfite obtain abundant oxidation, has reduced operation energy consumption, and the certain flow velocity of jet expansion air-flow assurance, produces sufficient disturbance in the slurries pond, has effectively prevented the precipitation of slurries.The air of air gun ejection simultaneously is stirred the device impeller and smashes, and guarantees that bottom, slurries pond stirs, and effectively prevents the absorption tower fouling, and system architecture is comparatively simple, is easy to safeguard.
Description of drawings
Below in conjunction with accompanying drawing the utility model is further specified.
Fig. 1 is the structural representation of compound oxidation device;
Fig. 2 is that the pipeline and the spout of coiled air jet pipe arranged schematic diagram;
Have among Fig. 1: 1. coiled air jet pipe, 2. air gun, 3. agitator, 4. absorption tower slurries pond;
Have among Fig. 2: 1 a. coil pipe, 1 b. air port (up), 1 c. air nozzle (down).
The specific embodiment
In Fig. 1, the oxidation fan air-supply is divided into two stocks and does not enter the slurries pond by coiled air jet pipe 1 and air gun 2, wherein coiled air jet pipe ejection air capacity accounts for 50%~70% of total air, and correspondingly, air gun ejection air capacity accounts for 30%~50% of total air.Vertical range LL/H=0.6~0.8 below the liquid level of distance slurries pond, H is height place, slurries pond, horizontally disposed one deck coiled air jet pipe, oxidation air sprays into the slurries pond via the nozzle of coiled air jet pipe with certain speed and pressure.Air gun 2 is stretched into by the tower wall, and arrangement is similar to traditional oxidation unit, and oxidation air sprays into the slurries pond with certain speed and pressure from the air gun outlet.
In Fig. 2, evenly arrange 2~6 coil pipes 1 on the coiled air jet pipe cross section a, have air nozzle on the coil pipe, comprise to nozzle 1 bWith down to nozzle 1 c, go up to nozzle with down to the even interlaced arrangement of nozzle.Oxidation air enters air duct, sprays into the slurries pond by air nozzle.Wherein, the diameter of section of coiled air jet pipe is decided according to the absorption tower diameter.Coiled air jet pipe 1 adopts FRP or similar material manufacturing;
Air gun 2 adopts FRP or similar material manufacturing.

Claims (3)

1. slurry pond compound oxidation device that is applicable to wet desulphurization, comprise the slurries pond, it is characterized in that: in described slurries pond, be provided with coiled air jet pipe (1) and be positioned at its below along the slurries pond around equally distributed some oxidation air spray guns (2), wherein coiled air jet pipe (1) ejection air capacity accounts for 50%~70% of total air, and air gun (2) ejection air capacity accounts for 30%~50% of total air.
2. slurry pond compound oxidation device according to claim 1 is characterized in that: described coiled air jet pipe (1) comprises the coil pipe (1 of 2~6 parallel and even layouts a), at described every coil pipe (1 a) the staggered up and down air nozzle (1 that evenly is furnished with b, 1 c).
3. slurry pond compound oxidation device according to claim 1 is characterized in that: the quantity of described oxidation air spray gun (2) is 4.
CN2010290441047U 2010-02-04 2010-02-04 Slurry pond combined oxidization device for wet-process desulphurization Expired - Fee Related CN201603516U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010290441047U CN201603516U (en) 2010-02-04 2010-02-04 Slurry pond combined oxidization device for wet-process desulphurization

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010290441047U CN201603516U (en) 2010-02-04 2010-02-04 Slurry pond combined oxidization device for wet-process desulphurization

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CN201603516U true CN201603516U (en) 2010-10-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102580511A (en) * 2011-04-21 2012-07-18 庄建中 Liquid oxidation and solid concentration tower

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102580511A (en) * 2011-04-21 2012-07-18 庄建中 Liquid oxidation and solid concentration tower
CN102580511B (en) * 2011-04-21 2014-07-23 庄建中 Liquid oxidation and solid concentration tower

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GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20101013

Termination date: 20160204