Background technology:
Solar panel is a laminated construction normally, mainly comprises surface layer of glass, EVA sealant, solar cell piece, EVA sealant and solar cell notacoria, and wherein solar cell piece is by two-layer EVA sealant sealed envelope.The main effect of solar cell notacoria is the overall mechanical strength that improves solar panel, can prevent that in addition water vapor permeable from sealant, influencing the useful life of battery sheet.In order to improve the overall performance of notacoria, occurred in the prior art carrying out improved plan at notacoria in a large number.For example, Chinese patent application number was that May 14, publication number in 2008 are the application for a patent for invention of CN101177514 for CN200710185202.8 number, open day, a kind of solar cell backboard and preparation method thereof is disclosed, this backboard comprises basic unit and fluoropolymer layer, and each component of fluoropolymer layer is counted by weight: 25~45 parts of fluorine resins; 1.5~3 parts of modified resin; 0.5~3 part of polymer filler; 0.1~1 part of inorganic filler; 50~70 parts of solvents.The production cost of such scheme is low, function admirable, and its peel strength height, block-water performance is good, good weatherability.Again for example, the EP1938967 european patent application, open day is on July 2nd, 2008, international application no PCT/JP2006/312501, international publication number is WO2007/010706, and date of publication is on January 25th, 2007, discloses a kind of solar cell backboard with good waterproof plate, this solar cell back board module has coating material solidified film at least on a surface of splash guard, this coating material solidified film comprises the coating of the fluorochemical polymers with curable functional group.Such scheme reaches ageing-resistant and purpose that block water by the fluorine material that employing has the excellent in resistance ageing properties, but adopt fluorine material shielding of ultraviolet to need enough thickness, according to scientific validation, in order to make ultraviolet complete attenuation, the thickness of fluorine material should reach 0.45~50mm, and product in the market, in order to reduce cost, thickness having reduced the fluorine film has caused the decline of properties of product.
The utility model content:
Technical problem to be solved in the utility model overcomes the deficiency of above-mentioned prior art, and a kind of solar cell notacoria with high ultraviolet isolating performance, high printing opacity is provided.
According to a kind of high printing opacity solar cell notacoria that the utility model provides, comprise high printing opacity basic unit, the outside of described basic unit or both sides have the UV-absorbing layer based on acrylic resin.
A kind of high printing opacity solar cell notacoria that provides according to the utility model also has following attached technical characterictic:
The thickness of described basic unit is 0.05mm~0.35mm.
The thickness of described basic unit is 0.15mm~0.2mm.
The thickness of described UV-absorbing layer is 0.001mm~0.01mm.
The thickness of described UV-absorbing layer is 0.003mm~0.005mm.
Described basic unit inboard or be positioned at and be formed with fluorosilicone on the inboard UV-absorbing layer and change into rete.
The thickness that described fluorosilicone changes into rete is 0.01 micron to 5 microns.
A kind of high printing opacity solar cell notacoria that provides according to the utility model has following advantage: at first, the utility model makes the outer surface of notacoria have the ultraviolet function increase of absorption to the compound UV-absorbing layer that is added with the acroleic acid polymerization resin of ultra-violet absorber and UV stabilizer of high printing opacity substrate surface; Secondly, the inner surface of notacoria is carried out the fluorosilicone processing, make the adhesive property raising of notacoria and EVA, rete of the present utility model is closely knit, has improved barrier property, especially to the better obstruct of having of steam, humidity resistance is good, and electric property and weather resistance are better.
Embodiment:
Embodiment 1:
As shown in Figure 1, a kind of high printing opacity solar cell notacoria, comprise high printing opacity basic unit 1 of making and the UV-absorbing layer 2 that is positioned at described basic unit 1 both sides by one or more polyester materials, described basic unit 1 handles through the nanometer modification, has block-water performance preferably, and light transmittance is more than or equal to 88%, it is in light weight, shape easily, light transmission is good, satisfies the needs of solar cell notacoria fully.Basic unit of the present utility model both sides are equipped with UV-absorbing layer 2, and described UV-absorbing layer is the acrylate copolymer coating, and the acroleic acid polymerization resin is that one-component solidifies or two component cured resin.The content of acroleic acid polymerization resin is 40~60%, wherein also be added with hindered amine light stabilizer, and Nano titanium dioxide light absorber, this UV-absorbing layer is shielding ultraviolet rays effectively, make notacoria have longer useful life, avoid intensification and long-term use aging in the assembly use.Basic unit of the present utility model 1 inboard is after applying UV-absorbing layer 2, also using plasma activates its surface, and add one or more mixture such as silane coupler, fluorosilicone polysiloxanes as modifier, the surface is formed with fluorosilicone and changes into rete 3 within it, make notacoria have higher caking property, be more prone to bond with EVA.
Embodiment 2:
As shown in Figure 2, a kind of high printing opacity solar cell notacoria, comprise the high printing opacity basic unit 1 of making and be positioned at the UV-absorbing layer 2 in the described basic unit outside by one or more polyester materials, described basic unit 1 handles through the nanometer modification, has block-water performance preferably, and light transmittance is more than or equal to 88%, it is in light weight, shape easily, light transmission is good, satisfies the needs of solar cell notacoria fully.The basic unit of the present utility model outside is provided with UV-absorbing layer 2, and described UV-absorbing layer is the acrylate copolymer coating, and the acroleic acid polymerization resin is that one-component solidifies or two component cured resin.The content of acroleic acid polymerization resin is 40~60%, wherein also be added with hindered amine light stabilizer, and Nano titanium dioxide light absorber, this UV-absorbing layer 2 is shielding ultraviolet rays effectively, make notacoria have longer useful life, avoid intensification and long-term use aging in the assembly use.Basic unit of the present utility model 1 inboard using plasma activates its surface, and add one or more mixture such as silane coupler, fluorosilicone polysiloxanes as modifier, side is formed with fluorosilicone and changes into rete 3 within it, make notacoria have higher caking property, be more prone to bond with EVA.
In two above-mentioned embodiment that the utility model provides, the thickness of described UV-absorbing layer 2 is 0.001mm~0.01mm, preferred 0.003mm~0.005mm.Concrete numerical value can be elected 0.002mm, 0.003mm, 0.004mm, 0.005mm and 0.008mm as, and when wherein selecting 0.003mm, 0.004mm and 0.005mm for use, cost performance is the highest, also more can satisfy the requirement of technology.
In above-mentioned two embodiment that the utility model provides, the thickness that described fluorosilicone changes into rete 3 is 0.01 micron to 5 microns, preferred scheme is between 0.1 micron to 2 microns, and concrete numerical value can be elected 0.01 micron, 0.05 micron, 0.1 micron, 0.2 micron, 0.5 micron, 0.8 micron, 1 micron, 1.5 microns, 2 microns as.The thickness that fluorosilicone is changed into rete 3 is limited in the above-mentioned size range and can better meets close-burning demand, and selects above-mentioned concrete one-tenth-value thickness 1/10, can better meet technological requirement.
In above-mentioned two embodiment that the utility model provides, the thickness of described basic unit 1 is 0.05mm~0.35mm, preferred scheme is 0.15mm~0.2mm, and concrete numerical value can be elected 0.10mm, 0.15mm, 0.18mm, 0.20mm, 0.25mm, 0.30mm, 0.35mm as.Select the basic unit 1 of above-mentioned thickness can make notacoria have higher intensity, and have higher light transmission, be beneficial to the daylighting of solar cell, generally can adopt polyester material PET, the light transmittance of PET is good greater than 88%.And the selection of above-mentioned concrete one-tenth-value thickness 1/10, the better relation between balance light transmission and the intensity.Make and satisfying under the requirement of strength to have higher light transmission.
Select above-mentioned material for use, can fully satisfy the demand of notacoria, can be made into solar cell notacoria, satisfy the demand of the solar cell of special shape with flexibility.
Following table is a concrete test parameters of the present utility model:
Project |
Unit |
Numerical value |
Xanthochromia index (QUVB irradiation 2000h) |
Δδ |
≤0.5 |
Breakdown voltage strength |
KV/mm |
≥50 |
Moisture-vapor transmission |
g/m
2.d
|
≤1 |
With the EVA bonding action |
N/cm |
≥30 |