CN201506861U - A New High Efficiency Electrospinning Nozzle - Google Patents

A New High Efficiency Electrospinning Nozzle Download PDF

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Publication number
CN201506861U
CN201506861U CN2009202226647U CN200920222664U CN201506861U CN 201506861 U CN201506861 U CN 201506861U CN 2009202226647 U CN2009202226647 U CN 2009202226647U CN 200920222664 U CN200920222664 U CN 200920222664U CN 201506861 U CN201506861 U CN 201506861U
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cone
nozzle
melt
efficiency
spinning
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CN2009202226647U
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刘勇
郝明凤
丁玉梅
杨卫民
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Beijing University of Chemical Technology
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Beijing University of Chemical Technology
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Abstract

本实用新型公开了一种新型高效率的静电纺丝喷头,属于静电纺丝领域,它包括喷孔和锥体两部分,锥体与喷孔的配合部分等分切出几个平面,在喷丝锥面上加工出平衡槽,纺丝溶液或熔体从各平面与喷孔的间隙流向喷丝锥面,此时的熔体具有一定的不均匀性,当熔体到达平衡槽处时,会进行二次分流,从而使熔体分布更加均匀,在喷丝锥面大端圆周均匀分布有溶液或熔体时,加上静电场后,喷丝锥面大端圆周就会形成多股喷射流,本实用新型在原来高效喷头的基础上,通过平衡槽的设计大大提高了多股喷射流的均匀性,得到了更加均匀的静电纺丝纤维。

The utility model discloses a novel high-efficiency electrostatic spinning nozzle, which belongs to the field of electrostatic spinning. It includes two parts: a nozzle hole and a cone. A balance groove is processed on the tap surface, and the spinning solution or melt flows from the gap between each plane and the nozzle hole to the spin cone surface. At this time, the melt has certain inhomogeneity. When the melt reaches the balance groove, it will flow Secondary diversion, so that the melt distribution is more uniform. When the solution or melt is evenly distributed on the circumference of the large end of the spinneret cone, after adding an electrostatic field, the circumference of the large end of the spinneret cone will form multiple jet streams. This practical Based on the original high-efficiency nozzle, the new design greatly improves the uniformity of multiple jet streams through the design of the balance groove, and obtains more uniform electrospun fibers.

Description

一种新型高效率的静电纺丝喷头 A New High Efficiency Electrospinning Nozzle

技术领域technical field

本实用新型涉及一种静电纺丝喷头,属于静电纺丝领域。The utility model relates to an electrostatic spinning nozzle, which belongs to the field of electrostatic spinning.

背景技术Background technique

随着纳米技术的升温,静电纺丝方法由于其可以制备出纳米级的纤维而成为当今的研究热点之一。静电纺丝方法已被公认为是制备纳米纤维最简单最有效的方法,目前已有三十多种聚合物通过此方法成功制得超细纤维,最小的直径达到几十纳米。关于静电纺丝的研究结果,这几年来相关文献都呈指数增加。With the heating up of nanotechnology, electrospinning method has become one of the current research hotspots because it can prepare nanoscale fibers. The electrospinning method has been recognized as the simplest and most effective method for preparing nanofibers. At present, more than 30 kinds of polymers have successfully prepared ultrafine fibers through this method, and the smallest diameter reaches tens of nanometers. Regarding the research results of electrospinning, the relevant literature has increased exponentially in recent years.

静电纺丝又包括溶液静电纺丝和熔体静电纺丝。溶液静电纺丝的纺丝溶液中溶剂的比例超过90%,而纺丝过程溶剂蒸发掉,因而其效率极低,一般为0.01g/min;而熔体静电纺丝虽然没有溶剂的蒸发,效率比溶液静电纺丝高很多,并且本实用新型不使用传统的毛细管,而使用一种新型的高效率纺丝喷头,使熔体纺丝效率得到了极大的提高,但是由于高效率喷头的流面为圆锥,只经过切面一次分流,不能很好地保证纺丝的均匀性。Electrospinning includes solution electrospinning and melt electrospinning. The proportion of solvent in the spinning solution of solution electrospinning exceeds 90%, and the solvent evaporates during the spinning process, so its efficiency is extremely low, generally 0.01g/min; while melt electrospinning has no evaporation of solvent, the efficiency It is much higher than solution electrospinning, and the utility model does not use the traditional capillary, but uses a new type of high-efficiency spinning nozzle, which greatly improves the melt spinning efficiency, but due to the flow of the high-efficiency nozzle The surface is conical, and the flow is only divided once through the cutting surface, so the uniformity of spinning cannot be well guaranteed.

实用新型内容Utility model content

本实用新型提出的一种改进的新型高效率的静电纺丝喷头,它不需要用到毛细管,因而避免了毛细管堵塞的问题和加工毛细管的困难,还有通过此喷头可形成多股的喷射流,大大提高了静电纺丝的效率,并且,增加了平衡槽,对熔体进行二次分流,增加了锥体下端熔体的均匀程度,使多股喷丝间的均匀度提高。The utility model proposes an improved new high-efficiency electrostatic spinning nozzle, which does not need to use capillary tubes, thus avoiding the problem of capillary blockage and the difficulty of processing capillary tubes, and can form multiple jet streams through this nozzle , greatly improving the efficiency of electrospinning, and adding a balance groove to perform secondary shunting of the melt, increasing the uniformity of the melt at the lower end of the cone, and improving the uniformity between the multi-strand spinnerets.

本实用新型提供了一种新型高效率的静电纺丝喷头,包括喷孔(1)和锥体(2)两部分,锥体(2)又包括与喷孔(1)内孔配合的配合锥体(4)和用于喷丝的喷丝锥体(7),锥体(2)的配合锥体(4)与喷孔(1)内孔的配合部分等分切出几个平面(5)和倒角(6),未切除部分为配合锥体(4)上的配合锥面(8),配合锥面(8)与喷孔(1)内孔配合,喷丝锥体(7)上设置有用于溶液或熔体二次分流的平衡槽(10)。纺丝溶液或熔体从各平面(5)与喷孔(1)内孔的间隙中流向喷丝锥体(7)的锥面,不均匀的熔体会在平衡槽(10)处进行二次分流、重新混合分布,然后,继续沿喷丝锥体(7)流动,当喷丝锥面大端圆周(9)均匀分布有溶液或熔体时,加上静电场后,在喷丝锥面大端圆周(9)上就会形成多股均匀的喷射流(3)。The utility model provides a novel high-efficiency electrostatic spinning nozzle, which includes two parts: the nozzle hole (1) and the cone (2), and the cone (2) also includes a matching cone that cooperates with the inner hole of the nozzle hole (1) body (4) and the spinneret cone (7) used for spinning, and the matching part of the cone (2) and the inner hole of the nozzle hole (1) to cut out several planes (5) and chamfer (6), the uncut part is the matching cone surface (8) on the matching cone (4), the matching cone surface (8) is matched with the inner hole of the nozzle hole (1), and the nozzle cone (7) is set There is a balance tank (10) for secondary splitting of solution or melt. The spinning solution or melt flows from the gap between each plane (5) and the inner hole of the nozzle hole (1) to the conical surface of the spinneret cone (7), and the uneven melt will be processed twice in the balance tank (10). Split, re-mix and distribute, and then continue to flow along the spinner cone (7). When the solution or melt is evenly distributed on the big end circumference (9) of the spinneret cone surface, after adding an electrostatic field, the large end circumference of the spinneret cone surface (9) will form a plurality of uniform jet streams (3).

本实用新型提出的新型高效率的静电纺丝喷头,为了能够更好的起到分流、混合的作用,其喷丝锥体(7)的平衡槽(10)可为两个或多个的结构形式。并且,其喷丝锥体(7)上的平衡槽(10)的横截面形状可为圆弧状或多边形。The new high-efficiency electrospinning nozzle proposed by the utility model, in order to better play the role of shunting and mixing, the balance groove (10) of the spinneret cone (7) can be two or more structural forms . Moreover, the cross-sectional shape of the balance groove (10) on the spinneret cone (7) can be arc-shaped or polygonal.

本实用新型提出的这种新型高效率的静电纺丝喷头,与一般静电纺丝喷头有明显的区别,它不需要用毛细管。纺丝溶液或熔体是从喷孔(1)与锥体(2)的配合间隙中流出,流出后经过平衡槽(10)进行二次分流。熔体从间隙流出后,要经过平衡槽(10),将原来由于各种因素而分布不均的熔体进行二次分流,最后使熔体可以均匀地流向喷丝锥体(7)锥面的大端。The novel high-efficiency electrostatic spinning nozzle proposed by the utility model is obviously different from the general electrostatic spinning nozzle in that it does not need a capillary. The spinning solution or melt flows out from the matching gap between the nozzle hole (1) and the cone (2), and then passes through the balance tank (10) for secondary branching. After the melt flows out from the gap, it needs to pass through the balance groove (10), and the melt that was originally unevenly distributed due to various factors is divided into secondary flow, and finally the melt can evenly flow to the conical surface of the spinneret cone (7). big endian.

附图说明Description of drawings

图1是本实用新型一种新型高效率的静电纺丝喷头的组装示意图。Figure 1 is a schematic diagram of the assembly of a novel high-efficiency electrospinning nozzle of the present invention.

图2是本实用新型一种新型高效率的静电纺丝喷头的锥体轴测图。Fig. 2 is a cone axonometric view of a novel high-efficiency electrostatic spinning nozzle of the present invention.

图中:1-喷孔;2-锥体;3-喷射流;4-配合锥体;5-平面;6-倒角;7-喷丝锥体;8-配合锥面;9-喷丝锥面大端圆周;10-平衡槽。In the figure: 1-spray hole; 2-cone; 3-jet flow; 4-cooperating cone; 5-plane; 6-chamfer; 7-spraying cone; 8-cooperating cone surface; Big end circumference; 10-balance slot.

具体实施方式Detailed ways

下面结合具体实施例对本实用新型作进一步的详细阐述。Below in conjunction with specific embodiment the utility model is described in further detail.

实施例1Example 1

图1和图2中,喷孔(1)的内径为2mm,锥体(2)的配合锥体(4)等分切出4个平面(5),喷孔(1)与配合锥面(8)的最大间隙为0.1mm,喷丝锥体(7)的锥面的斜度为58°,喷丝锥体(7)小端倒圆角得到45°的倒角(6),平衡槽(10)的深度为1.5mm,喷丝锥面大端圆周(9)直径为6mm。喷孔(1)与配合锥面(8)紧密配合,喷头安装在熔体纺丝装置上,纺丝原料为PP颗粒。当喷丝锥面大端圆周(9)均匀分布有经由熔体纺丝装置熔化的PP熔体时,熔体经过平衡槽(10)的二次分流,再向下流动,加上静电场,多股的喷射流(3)沿着喷丝锥面大端圆周均匀喷出,其纺丝的均匀程度由原来的10μm~100μm,变为10μm~40μm,其均匀性明显提高。In Fig. 1 and Fig. 2, the inner diameter of the spray hole (1) is 2mm, and the matching cone (4) of the cone (2) is equally divided into 4 planes (5), and the spray hole (1) and the matching cone surface ( 8) the maximum gap is 0.1mm, the inclination of the conical surface of the spinneret cone (7) is 58 °, the rounding angle of the small end of the spinneret cone (7) obtains a chamfer (6) of 45 °, and the balance groove (10 ) is 1.5mm in depth, and the diameter of the large end circumference (9) of the spinneret cone is 6mm. The nozzle hole (1) is closely matched with the matching cone surface (8), the nozzle is installed on the melt spinning device, and the spinning raw material is PP particles. When the PP melt melted by the melt spinning device is evenly distributed on the circumference of the large end of the spinneret cone (9), the melt flows through the secondary flow of the balance groove (10), and then flows downwards, adding an electrostatic field, and more The jet flow (3) of the strands is evenly ejected along the circumference of the large end of the spinneret cone, and the uniformity of the spinning is changed from the original 10 μm to 100 μm to 10 μm to 40 μm, and the uniformity is significantly improved.

Claims (3)

1.一种新型高效率的静电纺丝喷头,包括喷孔(1)和锥体(2)两部分,其特征在于,锥体(2)又包括与喷孔(1)内孔配合的配合锥体(4)和用于喷丝的喷丝锥体(7),锥体(2)的配合锥体(4)与喷孔(1)内孔的配合部分等分切出几个平面(5)和倒角(6),未切除部分为配合锥体(4)上的配合锥面(8),配合锥面(8)与喷孔(1)内孔配合,喷丝锥体(7)上设置有用于溶液或熔体二次分流的平衡槽(10)。1. A new type of high-efficiency electrospinning nozzle, comprising two parts, the nozzle hole (1) and the cone (2), and it is characterized in that the cone (2) includes a cooperation with the inner hole of the nozzle hole (1) Cone (4) and the spinneret cone (7) that is used for spinning, the matching portion of cone (4) of cone (2) and nozzle hole (1) inner hole equally cuts out several planes (5 ) and chamfer (6), the uncut part is the matching cone surface (8) on the matching cone (4), the matching cone surface (8) is matched with the inner hole of the nozzle hole (1), and the upper part of the spinning cone (7) Equilibrium tank (10) for secondary distribution of solution or melt is provided. 2.根据权利要求1所述的一种新型高效率的静电纺丝喷头,其特征在于,喷丝锥体(7)上的平衡槽(10)为两个或多个。2. A novel high-efficiency electrospinning nozzle according to claim 1, characterized in that there are two or more balance grooves (10) on the spinneret cone (7). 3.根据权利要求1所述的一种新型高效率的静电纺丝喷头,其特征在于,喷丝锥体(7)上的平衡槽(10)的横截面形状可为圆弧状或多边形。3. A novel high-efficiency electrospinning nozzle according to claim 1, characterized in that the cross-sectional shape of the balance groove (10) on the spinning cone (7) can be arc-shaped or polygonal.
CN2009202226647U 2009-09-16 2009-09-16 A New High Efficiency Electrospinning Nozzle Expired - Fee Related CN201506861U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967687A (en) * 2010-09-20 2011-02-09 北京化工大学 Multi-row electrostatic spinning spray head
CN101985778A (en) * 2010-11-22 2011-03-16 北京化工大学 Electrostatic spinning multi-strand wire spray head
EP2987894A4 (en) * 2013-04-17 2016-08-03 Finetex Ene Inc Electrospinning apparatus
CN110273190A (en) * 2018-07-19 2019-09-24 武汉纺织大学 Based on the uniformly distributed mutliblade open electrospinning nozzle of annular
CN110725018A (en) * 2019-11-07 2020-01-24 吉林大学 Bionic anti-blocking spinning nozzle for electrostatic spinning

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967687A (en) * 2010-09-20 2011-02-09 北京化工大学 Multi-row electrostatic spinning spray head
CN101967687B (en) * 2010-09-20 2012-08-29 北京化工大学 Multi-row electrostatic spinning spray head
CN101985778A (en) * 2010-11-22 2011-03-16 北京化工大学 Electrostatic spinning multi-strand wire spray head
CN101985778B (en) * 2010-11-22 2012-10-17 北京化工大学 An electrostatic spinning multi-filament nozzle
EP2987894A4 (en) * 2013-04-17 2016-08-03 Finetex Ene Inc Electrospinning apparatus
CN110273190A (en) * 2018-07-19 2019-09-24 武汉纺织大学 Based on the uniformly distributed mutliblade open electrospinning nozzle of annular
CN110273190B (en) * 2018-07-19 2021-10-08 武汉纺织大学 Open electrospinning nozzle based on annular uniformly distributed multi-blade
CN110725018A (en) * 2019-11-07 2020-01-24 吉林大学 Bionic anti-blocking spinning nozzle for electrostatic spinning

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Granted publication date: 20100616

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