CN201233929Y - Accumulator electrode with internal particle movable - Google Patents
Accumulator electrode with internal particle movable Download PDFInfo
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- CN201233929Y CN201233929Y CNU2008201223331U CN200820122333U CN201233929Y CN 201233929 Y CN201233929 Y CN 201233929Y CN U2008201223331 U CNU2008201223331 U CN U2008201223331U CN 200820122333 U CN200820122333 U CN 200820122333U CN 201233929 Y CN201233929 Y CN 201233929Y
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- electrode
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- accumulator
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Abstract
A storage battery electrode, the internal particles of which can move, belongs to the technical field of battery electrodes. The storage battery electrode is characterized in that the electrode comprises an electrode frame arranged in a battery; movable electrode particles accumulate in the electrode frame; the electrode particles are cathode particles or anode particles which are made of solid electrode materials; the electrode frame is a net-shaped structure; and an input duct and an output duct which extend outside the battery, and an electrode terminal are connected with and arranged on the electrode frame. The electrode breaks the traditional mode that a storage battery electrode is fixed in a storage battery; and the electrode particles of the electrode can be input into and output from the battery so that electrode can be not only charged in the battery, but also charged outside the battery. The utility model is characterized in that the production automation of the battery electrode can be realized, the battery volume can be reduced, the battery service performance can be improved, and the fast charge can be realized.
Description
Technical field
The utility model belongs to the battery terminal technical field, is specially accumulator electrode with internal particle movable.
Background technology
Existing storage battery comprises the electrode of a pair of internal storage battery that is fixed: negative electrode (positive pole) and anode (negative pole), the discharge of this storage battery and the charging course of work are between this a pair of electrode oxidation and reduction reaction to take place respectively, in discharge process, the oxidized electronics that loses of anode, negative electrode is reduced and obtains electronics, and in charging process, this reaction is converse.In case after the process of charging is finished, enter the process of putting charging of next round again, the work period of finishing battery by this.Production of storage battery at present and use all are fixed on the traditional mode of internal storage battery at the electrode of following internal storage battery, the pair of electrodes of storage battery is forever to be installed in the cell body under this pattern, and certain limitation is arranged, and shows as:
One, charging and discharging efficiency instability during battery uses.Efficiency for charge-discharge, the useful life of people in order to improve battery electrode, constantly improving material and the production technology of making electrode always, but the battery production technology does not break away from all the time and is confined to install and fix electrode in battery, and this design cycle of charging-discharge is not left and is confined in the battery use all the time.Battery in continuous use, inevitably electrode can wear out gradually, charging times with charge efficiency can be inversely proportional to, along with the wearing out of battery, the charging interval can more and more be grown and charging and discharging efficiency can be more and more lower.And limit when the charging interval of storage battery is also by deisgn product under this pattern and be fixed up, people are in order to shorten the charging interval, to prolong discharge time, exploring always and attempting electrode that uses new material to serve as storage battery and the manufacture craft of improving electrode, and at every turn in charging interval stage, breakthrough the shortening, the cost that improves charging and discharging efficiency often: raising materials used cost or cost of manufacture, increase volume or weight are realized.Key to the issue is that design concept is not jumped out the inertia that installs and fixes electrode and set this intrinsic thinking of constant parameter of charge in batteries time in storage battery all the time.
Two, the charging interval is long and unalterable.Because the charge in batteries time under the technology is grown partially and immobilizes at present, there is the storage battery of particular requirement the charging interval at some, electric automobile as having relatively high expectations in charging interval restriction aspect is difficult to promote because of the defective that has short time charging apace makes the storage battery dedicated use of electric automobile.
Three, the production process of existing internal storage battery fixed electrode is too complicated.Its production process can't realize automation, still rests on the manual stage as the present technology of the installation of battery terminal, and the electrode of each battery is all installed in later process, not only complicated production capacity of technology but also low and contaminated environment.
Four, the pole plate heaviness and the volume of existing storage battery are bigger than normal.Owing to will prolong the useful life of battery electrode as much as possible, that often battery pole plates is done is thick as far as possible big, and the result is that the battery product under this pattern is all bigger than normal than heaviness and volume relatively.
Five, electrode life and service efficiency can not guarantee.Because the production standard of manufacturing enterprise differs, the environment for use of the battery product of being produced requires different, does not cause export license because of improper use makes the work of battery in the service area, thereby can make the greatly shortening of the useful life of battery than designing requirement.
Six, existing storage battery is difficult to adapt to the marketization of electric automobile.The use of electric automobile be unable to do without this necessary condition that in time charges the battery easily, batteries of electric automobile under the prior art is long owing to the charging interval, do not meet and obtain in time that electric power energy replenishes and the requirement that makes the convenient use of electric automobile, make using and universal can not the popularization of electric automobile, the development of ev industry is hindered.
The utility model content
At the above-mentioned problems in the prior art, the purpose of this utility model is to design the technical scheme that a kind of accumulator electrode with internal particle movable is provided, electrode particle in this electrode is movably arranged in the electrode frame, and can move on to cell body and charge outward, safeguard.
Described accumulator electrode with internal particle movable, it is characterized in that comprising the electrode frame that is installed in the cell body, pile up mobilizable electrode particle in the electrode frame, cathode particles or anode particle that described electrode particle is made for the solid electrode material, described electrode frame is a network structure, connection setting is stretched out cell body outer input channel, output channel on the electrode frame, also connects on the electrode frame electrode terminal is set.
Described accumulator electrode with internal particle movable is characterized in that described electrode particle comprises particle core, adherent layer, between particle core and the adherent layer clearance layer is set, and the ion channel that runs through evenly is set on the adherent layer.
Described accumulator electrode with internal particle movable is characterized in that described input channel, output channel have angle of inclination up or down, and input critical point, output critical point are set respectively.
Described accumulator electrode with internal particle movable is characterized in that electrode frame adopts metal material, conductive rubber or conductive plastics to make.
Described accumulator electrode with internal particle movable is characterized in that described particle core is a spherical structure, and its diameter is 1-3mm, and described clearance layer thickness is 0.01-0.15mm, and described adherent layer thickness is 0.03-0.21mm.
Described accumulator electrode with internal particle movable is characterized in that described particle core is a cube structure, and its volume is 0.5-15mm
3
Described accumulator electrode with internal particle movable is characterized in that described particle core is that negative electrode or anode solid electrode material are made, and described adherent layer is that electric silica gel is made.
Above-mentioned accumulator electrode with internal particle movable, the electrode of having broken storage battery is fixed on the traditional mode of internal storage battery, the electrode particle of this electrode can be input in the cell body easily outside cell body or export outside the cell body, can not only in cell body, charge, and also can move on to cell body and charge outward, safeguard.Its advantage is:
1. can realize the automation that battery electrode is produced.The electrode that adopts said method to make, in the end install before the inner electrode particle, not movable electrode frame is in the production process of storage battery, its shape is to set in advance, be with Battery body in except that the internal electrode particle other various accessories one reinstate full-automatic assembly line production and install, and carry out the plastic housing sealing; The design of electronics particle is unified specification, unified standard, is convenient to produce expeditiously in the environment on the specific streamline, at totally enclosed, safety and environmental protection; And the supporting with it later stage installs also can in totally enclosed environment, and production technology is more economical, convenient, environmental protection.
2. dwindle volume of battery and the quality that alleviates battery.Because the electrode particle in the electrode frame can be movable, so needn't passivation cause that charging and discharging efficiency descend in order to prevent the electrode particle from putting off along with the charging interval, and with the electrode of battery do the bulkiness and the heaviness of trying one's best, it is little and light that the volume of kind electrode and quality can be done relatively.
3. improve the serviceability of battery.Because can change the electrode particle of inside battery often, its electrode particle can be exported at any time on the external proprietary equipment of cell body and safeguard, makes battery electrode be in high performance state all the time.
4. realization quick charge.Because electrode particle of the present utility model can be exported cell body and charge outward, this battery has been not limited to the restriction in charging interval in the charging of charging station, the electrode particle can be charged at proprietary charging station in advance, electrical appliance for the need quick charge, charge as electric automobile, only need time a few minutes, just can import charged electrode particle in the cell body rapidly, the same with automobile fuel filler convenient, make ev industry be able to fast development.
Description of drawings
Fig. 1 is a structural representation of the present utility model;
Fig. 2 is the structural representation of electrode particle;
Among the figure: 1-electrode frame, 2-electrode particle, 201-adherent layer, 202-ion channel, 203-clearance layer, 204-particle core, 3-input channel, 3a-input critical point, 4-output channel, 4a-output critical point, 5-electrode terminal.
Embodiment
The utility model is described in further detail below in conjunction with Figure of description.
As shown in the figure, this accumulator electrode with internal particle movable comprises the electrode frame 1 that is installed in the cell body, pile up mobilizable electrode particle 2 in the electrode frame 1, cathode particles or anode particle that described electrode particle 2 is made for the solid electrode material, described electrode frame 1 is a network structure, connection setting is stretched out cell body outer input channel 3, output channel 4 on the electrode frame 1, also connects on the electrode frame 1 electrode terminal 5 is set.Described input channel 3, output channel 4 have angle of inclination up or down, input critical point 3a, output critical point 4a are set respectively on it, and the size of the caliber of input channel 3, output channel 4 for the individual electrode particle 2 of 3-4 is passed through simultaneously uses the deadweight of particle to make the conveying of electrode particle 2 keep smooth and easy again.Electrode frame 1 adopts cancellated metal material, conductive rubber or conductive plastics to make, and can not only conduct electricity, also in order to make electrolyte pass through electrode frame 1 and 2 reactions of electrode particle.
Described electrode particle 2 comprises particle core 204, adherent layer 201, between particle core 204 and the adherent layer 201 clearance layer 203 is set, and the ion channel 202 that electronics, ion pass through of being convenient to that runs through evenly is set on the adherent layer 201.Described particle core 204 for existing battery electrode or exploitation from now on negative electrode or anode solid electrode material make, be the groundwork part of electrode, be the core of electrode particle 2.Described adherent layer 201 is made for electric silica gel.Input and output are convenient in the unsuitable again adhesion of these electrode particle 2 promptly unsuitable fragmentations like this.The material that clearance layer 203 is set is for the ease of particle core 204 surfaces can react fully with electronics.
Described particle core 204 is a spherical structure, and its diameter is 1-3mm, and described clearance layer 203 thickness are 0.01-0.15mm, and described adherent layer 201 thickness are 0.03-0.21mm.Described particle core 204 is a cube structure, and its volume is 0.5-15mm
3, this particle core 204 also can be made other structure as required.
The production method of this battery terminal may further comprise the steps:
1) adopts metal material, conductive rubber or conductive plastics to make cancellated electrode frame 1, input channel 3, output channel 4 and electrode terminal 5 are set on the electrode frame 1;
2) adopt the solid electrode material to make negative electrode or anode electrode particle 2;
3) under full-closed environment, the electrode particle of making 2 is got final product by piling up in the input channel 3 input electrode frames 1.
Wherein above-mentioned steps 2) electrode particle 2 also can adopt following production method to make: with extrusion process negative electrode or anode solid electrode material are squeezed into negative electrode or anode particle core 204; Method with spraying plating plates the wax layer that available dewax pouring technology is removed on particle core 204 surfaces in postchannel process; Make the adherent layer 201 of full parcel at above-mentioned wax laminar surface with spraying plating process spraying plating electric silica gel, the ion channel 202 that runs through evenly is set on this adherent layer 201; Remove above-mentioned cured layer with the dewax pouring technology, the space of formation is the clearance layer 203 between particle core 204 and the adherent layer 201, and the dewax pouring technology can be with existing physical method and chemical method.
The electrode that adopts said method to make, in the end install before the inner electrode particle 2, not movable electrode frame 1 is in the production process of storage battery, its shape is to set in advance, be with Battery body in except that internal electrode particle 2 other various accessories one reinstate full-automatic assembly line production and install, and carry out the plastic housing sealing; The design of electronics particle 2 is unified specification, unified standard, is convenient to produce expeditiously in the environment on the specific streamline, at totally enclosed, safety and environmental protection; And the supporting with it later stage installs also can in totally enclosed environment, and production technology is more economical, convenient, environmental protection.
Except above-mentioned battery terminal, other various accessories are existing known configurations in the Battery body that relates in the utility model.The storage battery that relates in the utility model can be the storage battery of existing structures such as lead acid accumulator, lithium ion battery.
Active substance for positive electrode of lead-acid accumulator is a brown lead oxide, and negative electrode active material is a lead sponge, and electrolyte is dilution heat of sulfuric acid.Its discharge chemistry reaction generates lead sulfate and water, Pb (negative pole)+PbO for brown lead oxide, lead sponge and electrolyte reaction
2(positive pole)+2H
2SO
4====2PbSO
4+ 2H
2O (exoelectrical reaction); Its charging chemical reaction is that lead sulfate and water are converted into brown lead oxide, lead sponge and dilute sulfuric acid, 2PbSO4+2H
2O====Pb (negative pole)+PbO
2(positive pole)+2H
2SO4 (charging reaction).Lead acid accumulator list lattice rated voltage is 2.0V, and general series connection is for 6V, 12V are used for automobile, the motorcycle initiating illumination is used, single for the general series connection of battery for 48V, 96V, 110 or 220V be used for different occasions.Adopt resistance is extremely low, the few stable components ion of impurity can pass through rubber, PVC, PE or AGM dividing plate in the battery between positive and negative pole plate.
The lithium ion battery lithium is the lightest metal in the world, when constituting battery, and the nearly 4v of output voltage.Lithium ion battery is the novel high-energy storage battery of at first being introduced to the market by Sony corporation of Japan nineteen ninety, and its advantage is the specific energy height, is the highest storage battery of current specific energy, and application has put it in the portable information product.Nineteen ninety-five, Sony is succeeded in developing the lithium-ions battery that is used for electric motor car again, is divided into two types: a kind of is that to be used for pure electric vehicle (EV) capacity be the cylindrical cell of 100Ah, is called the high energy type lithium-ions battery; Another kind is to be used for hybrid vehicle (HEV), and capacity is 22Ah, and 8 are connected into battery module, but its power output is called high power type lithium ion cell for the former 2.7 times.The high energy type battery is on first the lithium-ion electric electrical automobile that was contained in Nissan Motor's exploitation in 1996 (daily output Al-traEV), puts on display in first the international electric motor car exhibition in Beijing.This car 200km that can travel that once charges, F-Zero 120Km/h.Lithium ion battery is generally believed to have following advantage: specific energy is big; The specific power height; Self discharge is little; Memory-less effect; Cycle characteristics is good; But repid discharge, and efficient height; Operating temperature range is wide; Therefore non-environmental-pollutions etc. are expected to enter best electrical source of power ranks of 21 century.Expectation is during 2006～2012 years, and when lithium ion battery further develops, the market share of MH/Ni storage battery will be dwindled, and the lithium ion market share will enlarge.Nickel-hydrogen accumulator and lithium-ions battery are green storage batterys, can not cause secondary pollution because of discarded, and market prospects are preferably arranged.
When the storage battery that relates to when the utility model is lead acid accumulator, electrode particle 2 or its particle core 204 adopt lead acid battery positive electrode or negative pole solid material to make in the present patent application, the positive pole that number is equated is respectively charged into different electrode frame 1 interior formation pair of positive and negative with negative electrode particle 2 then, in the cell body a pair or more of positive and negative electrode can be installed as required.Entire electrode frame 1 is fully immersed in the interior dilution heat of sulfuric acid of battery, makes that negative electrode and the anode electrode particle 2 in each electrode frame 1 carries out sufficient chemical reaction with dilution heat of sulfuric acid.When the storage battery that relates to when the utility model was other storage battery of existing structures such as lithium ion battery, the raw materials for production of battery terminal, mounting means and reaction principle thereof were corresponding with it in the present patent application.
Claims (7)
1, accumulator electrode with internal particle movable, it is characterized in that comprising the electrode frame (1) that is installed in the cell body, pile up mobilizable electrode particle (2) in the electrode frame (1), cathode particles or anode particle that described electrode particle (2) is made for the solid electrode material, described electrode frame (1) is a network structure, electrode frame (1) goes up to connect to be provided with stretches out cell body outer input channel (3), output channel (4), also connects on the electrode frame (1) electrode terminal (5) is set.
2, accumulator electrode with internal particle movable as claimed in claim 1, it is characterized in that described electrode particle (2) comprises particle core (204), adherent layer (201), between particle core (204) and the adherent layer (201) clearance layer (203) is set, adherent layer (201) is gone up the ion channel (202) that runs through evenly is set.
3, accumulator electrode with internal particle movable as claimed in claim 1 is characterized in that described input channel (3), output channel (4) have angle of inclination up or down, and input critical point (3a), output critical point (4a) are set respectively.
4, accumulator electrode with internal particle movable as claimed in claim 1 is characterized in that electrode frame (1) adopts metal material, conductive rubber or conductive plastics to make.
5, accumulator electrode with internal particle movable as claimed in claim 2, it is characterized in that described particle core (204) is spherical structure, its diameter is 1-3mm, and described clearance layer (203) thickness is 0.01-0.15mm, and described adherent layer (201) thickness is 0.03-0.21mm.
6, accumulator electrode with internal particle movable as claimed in claim 2 is characterized in that described particle core (204) is cube structure, and its volume is 0.5-15mm
3
7, accumulator electrode with internal particle movable as claimed in claim 2 is characterized in that described particle core (204) makes for negative electrode or anode solid electrode material, and described adherent layer (201) is made for electric silica gel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2008201223331U CN201233929Y (en) | 2008-07-30 | 2008-07-30 | Accumulator electrode with internal particle movable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2008201223331U CN201233929Y (en) | 2008-07-30 | 2008-07-30 | Accumulator electrode with internal particle movable |
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| Publication Number | Publication Date |
|---|---|
| CN201233929Y true CN201233929Y (en) | 2009-05-06 |
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| CNU2008201223331U Expired - Fee Related CN201233929Y (en) | 2008-07-30 | 2008-07-30 | Accumulator electrode with internal particle movable |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105322209A (en) * | 2014-07-11 | 2016-02-10 | 陈锦棠 | Quickly charged battery |
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2008
- 2008-07-30 CN CNU2008201223331U patent/CN201233929Y/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105322209A (en) * | 2014-07-11 | 2016-02-10 | 陈锦棠 | Quickly charged battery |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090506 Termination date: 20110730 |