CN201217290Y - Metallized biaxial tension polyester precoating film - Google Patents

Metallized biaxial tension polyester precoating film Download PDF

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Publication number
CN201217290Y
CN201217290Y CNU2008200803927U CN200820080392U CN201217290Y CN 201217290 Y CN201217290 Y CN 201217290Y CN U2008200803927 U CNU2008200803927 U CN U2008200803927U CN 200820080392 U CN200820080392 U CN 200820080392U CN 201217290 Y CN201217290 Y CN 201217290Y
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China
Prior art keywords
precoatingfiltration
thickness
polyester
dual
metallized
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Expired - Lifetime
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CNU2008200803927U
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Chinese (zh)
Inventor
钟玉
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BEIJING KANGDE XIN COMPOSITE MATERIAL Co Ltd
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BEIJING KANGDE XIN COMPOSITE MATERIAL Co Ltd
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Priority to CNU2008200803927U priority Critical patent/CN201217290Y/en
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Abstract

Disclosed is a metallized dual-direction tensile polyester precoatingfiltration, which is applied to the printing film covering field; the precoatingfiltration comprises a substrate, a middle layer and a hot melting glue layer; the precoatingfiltration is characterized in that: the substrate is the dual-direction tensile polyester film (BOPET); the middle layer is the polyethyleneimine (PEI); and the hot melting glue layer is the EVA hot melting glue. The middle layer and the hot melting layer are all sequentially coated and combined on a surface of the substrate. The substrate has a thickness of 12 to 25 microns, the middle layer has a thickness of 0.01 to 0.03 microns; and the hot melting glue layer has a thickness of 10 to 40 microns. The metallized dual-direction tensile polyester precoatingfiltration has the beneficial effects that: the polyester precoatingfiltration has high light degree, high tensile strength, high barrier performance (obstructing the air and vapor), opacity, hot sealing performance and printability, so as to improve the exquisite degree of printing products. The metallized dual-direction tensile polyester precoatingfiltration is mainly applied to the coating films for machine packing; and the metallized dual-direction tensile polyester precoatingfiltration has the advantages of stable product quality, environment protecting, secure, convenient, energy saving and high-efficiency, so as to satisfy the users requirements for the covering film.

Description

The metallization biaxial stretching polyester pre-coating film
Technical field
The utility model relates to printing film coating technique field, and particularly the important materials pre-coating film of overlay film is a kind of pre-coating film that adopts the extrusion composite technology technology to make.
Background technology
The printed matter overlay film is the important means of post-press finishing, the final personal value of its decision print product.The coating technique of printed matter is meant with plastic sheeting and covers above the paper printing matter, the middle adhesive that uses, after the heating pressurized treatments, two kinds of materials of different nature of plastic sheeting and paper are bonded together, form paper/the mould incrustation process technology of unification.It plays protection and decorative effect to printed matter, is widely used in the packages printing field, on the Surface Machining as Front cover of book and periodical, propaganda picture album, map, advertising specialty bag, senior packing box etc.Overlay film can divide promptly films and two kinds of pre-coating films.
Promptly be coated with membrane technology and be that the international sixties rise to coating technique behind the seal of printed matter, package.But this technology is directly used in the overlay film process and is contained benzene solvent, thereby has brought the three big drawbacks that can't overcome owing to self technology:
(1) environmental issue: because the volatilization of noxious material benzene and overflowing has caused air pollution and brought very big harm for the producer and user's health; Simultaneously, the harmful substance that residues in the overlay film has harmful effect to consumer's health.
(2) quality problems: owing to still have volatile substance benzene constantly to overflow after the overlay film processing, very easily between film and paper, form bubble, make printing product surface be vaporific, influence fineness, definition and the colour vividness of printing; Sometimes because of bonding strength is not enough, even cause cracking, fold and demoulding.In addition, the production equipment automaticity of promptly filming is low, has reduced the overlay film yield rate.
(3) safety problem: owing to contain volatile organic solvent benzene in the solution, form flammable, explosive atmosphere easily around the liquid bath, and the plastic basis material that the uses generation static that rub causes disaster hidden-trouble in operation process.Such accident number had taken place, and little then the shutdown stops production, and greatly then machine burns, and factory building caves in, casualties.
The pre-coating film film coating technique is the green technology of sustainable development.The pre-coating film film coating technique also can be referred to as environmental friendliness technology or clean technologies, has realized the protection environment, protects the health, has kept the safety in production.In pre-coating film production and the use, the volatilization that toxic gas does not take place is polluted, and therefore, effectively improves working environment, eliminates the disaster hidden-trouble that production site and product are stored; Use the pre-coating film product,, can be widely used on the packing of books and periodicals (especially student textbook), food, tobacco and wine, medicine etc. the consumer not being constituted potential threat owing to wherein do not have the hazard residue material; The process procedures such as allotment, coating and oven dry of binder have been saved simultaneously, the whole film covering process can in seconds be finished, and can not produce pollution to environment, does not have disaster hidden-trouble, do not need to clean automatic double surface gluer etc. yet, can realize high speed, efficient, high-quality overlay film; Pre-coating film has promoted the color saturation of printed matter and definition, has obviously increased its artistic effect; and printed matter played a protective role; make it water-fast, moisture resistance, fast light, prevent pollution, anti-chemical corrosion; increase the service life; improve durability, collection and the ornamental value of printed matter greatly, promoted the commercial competitiveness and the added value of product.
Pre-coating film structure difference, adopt the base material difference different with hot melt adhesive layer, the performance of pre-coating film product has very big-difference, and the effect of product also has very big difference behind the overlay film, as aspects such as color saturation, brightness, tensile strength, wide degree, flatness.
The utility model content
The purpose of this utility model is: a kind of metallization biaxial stretching polyester (BOPET) pre-coating film is provided, improve the exquisite degree of printing, constant product quality, not only environmental protection, safety, convenience, energy-conservation, efficient, and can satisfy some clients to overlay film after the requirement of product with high brightness, high-tensile, high barrier (intercepting air and steam), light-proofness, heat sealability, impressionability.Owing to not with an organic solvent, do not overcome the deficiency of promptly filming and existing.
The technical solution adopted in the utility model is: metallization biaxial stretching polyester (BOPET) pre-coating film, comprise base material, intermediate layer and hot melt adhesive layer, it is characterized in that: on the surface of base material intermediate layer and hot melt adhesive layer are arranged successively, the width of base material, intermediate layer and hot melt adhesive layer is identical.Base material is metallization biaxial stretching polyester (BOPET) film, and the intermediate layer is polymine (PEI), and hot melt adhesive layer is the EVA PUR.Intermediate layer and hot melt adhesive layer evenly apply successively, are compounded on the surface of base material.The thickness of base material is between the 12-25 micron, and (coated weight is 0.009-0.011g/m to the thickness in intermediate layer at the 0.01-0.03 micron 2) between, the compound thickness of hot melt adhesive layer is between the 10-40 micron.
Technical scheme is preferably: the thickness of base material is between the 12-18 micron, and (coated weight is 0.009-0.01g/m to the thickness in intermediate layer at the 0.01-0.02 micron 2) between, the compound thickness of hot melt adhesive layer is between the 10-30 micron.
The composite production line that utilizes extruder and equipment complex to form is coated in the intermediate layer on the surface of base material, at last hot melt adhesive layer is compounded on the intermediate layer, produces metallization biaxial stretching polyester (BOPET) pre-coating film.After the thickness of base material and EVA hot melt adhesive layer carries out suitable combination, can obtain different products.Above-mentioned extruder and equipment complex and combination process are well known to those skilled in the art.
The EVA PUR is a kind of solid meltability polymer that does not need solvent, moisture-free 100%; Be solid at normal temperatures, heating and melting becomes and can flow to uniform temperature, and the liquid of certain viscosity is arranged.EVA PUR after the fusion is light yellow or colourless.The EVA PUR is become to be grouped into by basic resin, tackifier, viscosity modifier and antioxidant etc.At present, apply level EVA PUR product and mainly rely on import, domestic no appropriate level production.
Polymine (PEI) molecular formula is: [CH 2CH 2NH-] n, there is the product supply in Shanghai DiC Ink Co., Ltd, and our company adopts U.S.'s imported product.
Metallization biaxial stretching polyester (BOPET) film is the mode that adopts vacuum evaporating at biaxial stretching polyester (BOPET) film surface, plates that the technology of skim metal produces.At present, domestic have a lot of suppliers, and as three friendly limited companies of Beijing Daheng, all there is supply in the big positive industrial and trading company in Tianjin etc.
The beneficial effects of the utility model: metallization biaxial stretching polyester (BOPET) pre-coating film, with metallization biaxial stretching polyester (BOPET) film as base material, with the pre-coating film of EVA PUR as hot melt adhesive layer, characteristics with high brightness, high-tensile, high barrier (intercepting air and steam), light-proofness, heat sealability, impressionability have improved the exquisite degree of printing.Mainly implement overlay film in fields such as medicine packings.Metallization biaxial stretching polyester (BOPET) pre-coating film constant product quality, and have environmental protection, safety, convenience, energy-conservation, efficient advantage, can satisfy some clients to overlay film after product requirement.Owing to not with an organic solvent, do not overcome the deficiency of promptly filming and existing.Its product will have the field of above-mentioned requirements to be more widely used in medicine packing etc.
Description of drawings
Fig. 1 is metallization biaxial stretching polyester (BOPET) pre-coating film cross section structure schematic diagram.
Among the figure, 1. base material, 2. intermediate layer, 3. hot melt adhesive layer.
The specific embodiment
Embodiment 1: with width is that 1410 millimeters metallization biaxial stretching polyester (BOPET) pre-coating film is an example, is elaborated.
Consult Fig. 1.Metallization biaxial stretching polyester (BOPET) pre-coating film width is 1410 millimeters.Base material 1, intermediate layer 2 are identical with the width of hot melt adhesive layer 3.Metallization biaxial stretching polyester (BOPET) pre-coating film haves three layers, and ground floor is a base material 1, and the second layer is that the intermediate layer is a hot melt adhesive layer 3 for 2, the three layers.Former base material adopts metallization biaxial stretching polyester (BOPET) film, 1430 millimeters of width.Intermediate layer 2 is polymine (PEI), and hot melt adhesive layer 3 is EVA PURs.Intermediate layer 2 and hot melt adhesive layer 3 evenly apply successively, are compounded on the surface of base material 1, compound after through the side cut system, both sides of the edge are cut off 20 millimeters altogether, final products will be narrower 20 millimeters than former base material.At the fabric width edge, thickness deviation≤2 micron.12 microns of the thickness of base material 1, (coated weight is 0.009-0.01g/m to the thickness in intermediate layer 2 at the 0.01-0.02 micron 2) between, the thickness of hot melt adhesive layer 3 is 13 microns.

Claims (2)

1, a kind of metallization biaxial stretching polyester pre-coating film, comprise base material (1), intermediate layer (2) and hot melt adhesive layer (3), it is characterized in that: intermediate layer (2) and hot melt adhesive layer (3) are arranged on the surface of base material (1) successively, base material (1), intermediate layer (2) is identical with the width of hot melt adhesive layer (3), base material (1) is the metallization biaxial stretching polyester film, intermediate layer (2) is a polymine, hot melt adhesive layer (3) is the EVA PUR, the thickness of base material (1) is between the 12-25 micron, the thickness in intermediate layer (2) is between the 0.01-0.03 micron, and the compound thickness of hot melt adhesive layer (3) is between the 10-40 micron.
2, metallization biaxial stretching polyester pre-coating film according to claim 1, it is characterized in that: the thickness of described base material (1) is between the 12-18 micron, the thickness in intermediate layer (2) is between the 0.01-0.02 micron, and the composite thickness of hot melt adhesive layer (3) is between the 10-30 micron.
CNU2008200803927U 2008-05-05 2008-05-05 Metallized biaxial tension polyester precoating film Expired - Lifetime CN201217290Y (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103362225A (en) * 2013-07-16 2013-10-23 安徽国风塑业股份有限公司 Pre-coating film for thermal insulation of buildings and thermal insulation material coated with pre-coating film
CN104191797A (en) * 2014-09-02 2014-12-10 孙礼勇 Production technology for PET film used for packaging paper coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103362225A (en) * 2013-07-16 2013-10-23 安徽国风塑业股份有限公司 Pre-coating film for thermal insulation of buildings and thermal insulation material coated with pre-coating film
CN104191797A (en) * 2014-09-02 2014-12-10 孙礼勇 Production technology for PET film used for packaging paper coating

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C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: JIANGSU KANGDEXIN COMPOSITE MATERIAL CO., LTD.

Free format text: FORMER NAME: BEIJING KANGDE XIN COMPOSITE MATERIAL CO., LTD.

CP03 Change of name, title or address

Address after: Suzhou City, Jiangsu province 215600 Zhangjiagang City Environmental Protection New Material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West

Patentee after: Jiangsu kangdexin composite materials Limited by Share Ltd

Address before: 102200, 26, Zhenxing Road, Changping science and Technology Park, Beijing, Changping District

Patentee before: Beijing kangde xin composite material Co., Ltd.

CX01 Expiry of patent term

Granted publication date: 20090408

CX01 Expiry of patent term