CN200951975Y - Apparatus for treating chlorine-containing organic substance, nitrate and heavy metal pollutant in water - Google Patents
Apparatus for treating chlorine-containing organic substance, nitrate and heavy metal pollutant in water Download PDFInfo
- Publication number
- CN200951975Y CN200951975Y CN 200620100325 CN200620100325U CN200951975Y CN 200951975 Y CN200951975 Y CN 200951975Y CN 200620100325 CN200620100325 CN 200620100325 CN 200620100325 U CN200620100325 U CN 200620100325U CN 200951975 Y CN200951975 Y CN 200951975Y
- Authority
- CN
- China
- Prior art keywords
- water
- utility
- model
- column reactor
- nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 13
- 229910002651 NO3 Inorganic materials 0.000 title claims abstract description 12
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000000460 chlorine Substances 0.000 title claims abstract description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 8
- 239000003344 environmental pollutant Substances 0.000 title abstract description 8
- 231100000719 pollutant Toxicity 0.000 title abstract description 8
- 239000000126 substance Substances 0.000 title 1
- 239000000356 contaminant Substances 0.000 claims description 7
- 238000012856 packing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 11
- 239000002699 waste material Substances 0.000 abstract description 11
- 239000000945 filler Substances 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 abstract description 2
- 238000005070 sampling Methods 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 37
- 229910052742 iron Inorganic materials 0.000 description 14
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000001223 reverse osmosis Methods 0.000 description 2
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 208000005135 methemoglobinemia Diseases 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
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- Treatment Of Water By Oxidation Or Reduction (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The utility model discloses a device to harness chlorine organic matters, nitrate and heavy metal pollutants in water, which is sequentially connected with a water tank, a primary flowrate control valve, a pump, a secondary flowrate control valve and a column reactor. The column reactor is provided with a lower sampling hole, a medium sampling hole and an upper sampling hole; a water outlet is provided on top of the column reactor. The utility model has the following advantages: 1) Short process flow but high operation efficiency. Water with pollutants goes through the column reactor, so that purification is finished, reaction time of which is only 0.5-12 hours. 2) Low energy consumption and broad application scope without secondary pollution. The utility model is only necessary to pump the water with pollutants into the column reactor; no additional step is needed, such as heating, acid regulation, feeding medicine and etc. 3) The utility model of the reaction device can work in normal temperature, and no special requirement exists to pollutant density, for which the application scope is rather broad; main fillers include rejected scraps from mechanical factories, so that waste can become treasures and the cost is rather low.
Description
Technical field
The utility model relates to a kind of device of administering water containing chlorine organism, nitrate and heavy metal contaminants.
Background technology
Produce and life process in all contaminations that discharges enter environment by all means, severe contamination atmosphere, soil, underground water and surface water system, serious threat human beings'health and is lived.Chlorinated organics, nitrate and heavy metal etc. are ubiquitous priority pollutants in the underground water, and these pollutents all are to mix to be present in polluted-water or the soil usually.
Quite a few is listed in the environment priority pollutants in the chlorinated organics, especially persistence organic pollutant, as DDT, phenyl-hexachloride, PCBs, multi-chlorophenol, vinylchlorid (VC) etc., these materials have very strong resistivity for the biological metabolism under the natural condition, photodegradation, decomposition etc., in case enter environment, be difficult to be decomposed, particularly enter in the surrounding mediums such as soil, underground water and bed mud and retain several years even many decades or longer time; In addition on the earth annual amount of nitrogen fixation also considerably beyond the nitrogen amount that discharges by denitrification, thereby cause the long-term accumulation of nitrate nitrogen in soil and underground water, NO
3 -Be reduced to NO after entering human body
2 -, NO
2 -Carcinogenesis is arranged or cause infant's methemoglobinemia.Heavy metal be different from other hazardous contaminant, they can not biological degradation, and can accumulate in vivo, thereby causes various diseases, threatens human health.
All there is multiple treatment process to be removed for different pollutents, but all is mostly, adopt certain treatment process under given conditions at a certain pollutent.As, the treatment process that is usually used in the azotate pollution water body has: ion exchange method, reverse osmosis method, biological process etc.But contaminated water body can not be by only being polluted by a kind of pollutent, usually all contain multiple pollutent, common especially pollutent such as chlorinated organics, nitrate, heavy metal etc. are applicable to that the method (as ion exchange method, reverse osmosis method, biological process) of treatment of nitric acid salt pollution water body but can not effectively be removed chlorinated organics.Therefore developing a kind of treatment technology that can remove multiple pollutent cheap, fast and efficiently synchronously has very important significance.
Summary of the invention
The purpose of this utility model provides a kind of device of administering water containing chlorine organism, nitrate and heavy metal contaminants.
It is connected with hopper, first flow control valve, pump, second flowrate control valve, column type reactor in turn, set on the column type reactor thief hole, middle thief hole, on thief hole, be provided with water outlet in the column type reactor upper end.
The utility model has the advantages that:
1) technical process is short, operational efficiency is high.The current that contain pollutent are promptly finished purification through column type reactor, and the reaction times only is 0.5-12 hour.
2) energy consumption low, applied widely, do not produce secondary pollution.Only need to squeeze into column type reactor and get final product, need not to heat, steps such as the adjusting of acid, interpolation medicament with the water that pump will contain pollutent.
3) reaction unit of the present utility model can move at normal temperatures and pressures, and Pollutant levels are not had special requirement yet, and is applied widely; Main charges are the discarded iron filings of machine works, turn waste into wealth, and are with low cost.
Description of drawings
Accompanying drawing is a post continuous reaction apparatus synoptic diagram of the present utility model;
Embodiment
The utility model is to adopt pump that the water that stationary tank contains chlorinated organics, nitrate and the multiple pollutent of heavy metal is squeezed into column type reactor from the bottom, the water of chlorinated organics, nitrate and the multiple pollutent of heavy metal stopped in column type reactor 0.5-12 hour, react with Pd/Fe, Ni/Fe or Cu/Fe bimetal, arrive the purpose of purifying contaminated water.
The utility model reaction unit can be in the common scope operation of 0～40 ℃ of occurring in nature water temperature, and the pH value of water is neutral, need not to be adjusted to potential of hydrogen; The concentration range that is fit to pollutent in the common polluted-water is 0.05～200ppm.
As shown in drawings, administer the device of water containing chlorine organism, nitrate and heavy metal contaminants, be connected with hopper 1, first flow control valve 2, pump 3, second flowrate control valve 4, column type reactor 5 in turn, set on the column type reactor 5 thief hole 6, middle thief hole 7, on thief hole 8, be provided with water outlet 9 in column type reactor 5 upper ends.
The part by weight that is filled with Pd/Fe, Ni/Fe or Cu/Fe bimetal and pottery gravel in the described column type reactor 5 is 1: 1-5.The diameter of column type reactor is 30-3000mm, and the packing layer height is 80-8000mm.
The bimetallic preparation method of Pd/Fe: be that waste iron filing or iron powder are immersed in K
2PdCl
6Make after 4-24 hour in the aqueous solution, the weight ratio of Pd and waste iron filing is 1-100: 100000.
The bimetallic preparation method of Ni/Fe: be that waste iron filing or iron powder are immersed in NiSO
46H
2Make after 4-24 hour in the O aqueous solution, the weight ratio of Ni and waste iron filing is 1-10: 1000.
The bimetallic preparation method of Cu/Fe: be that waste iron filing or iron powder are immersed in CuSO
45H
2Make after 1-4 hour in the O aqueous solution, the weight ratio of Cu and waste iron filing is 1-10: 1000.
Embodiment 1:
Certain contains 50 mg/LNO
3 -Hydromining handle with device described in the utility model after, NO
3 -Concentration drops to 2.261mg/L, and clearance reaches 94.9%.
The column type reactor parameter:
| Diameter (mm) | Pack height (mm) | Hydraulic detention time | The filler composition |
| 140 | ?350 | 4 hours | The Cuization rate is 1.2%, and Cu/Fe bimetal waste iron filing and pottery gravel weight ratio are 1: 2 |
Inlet and outlet water water quality:
| NO 3 -Concentration (mg/L) | ?pH | Temperature (℃) | |
| Water inlet | 50 | ?7.06 | ?25 |
| Water outlet | 2.261 | ?6.7 | ?25 |
Embodiment 2
Certain contains 50mg/L NO
3 -Hydromining handle with device described in the utility model after, NO
3 -Concentration drops to 2.36mg/L, and clearance reaches 94.6%.
The column type reactor parameter:
| Diameter (mm) | Pack height (mm) | Hydraulic detention time | The filler composition |
| 140 | 350 | 4 hours | The Niization rate is 1.2%, and Ni/Fe bimetal waste iron filing and pottery gravel weight ratio are 1: 2 |
Inlet and outlet water water quality:
| NO 3 -Concentration (mg/L) | ?pH | Temperature (℃) | |
| Water inlet | 50 | ?6.7 | ?25 |
| Water outlet | 2.270 | ?6.5 | ?25 |
Certain contains 100mgL
-1NO
3 -, 100mgL
-1Ni
2+, 50mgL
-1After the hydromining of ortho chloro phenol pollutent is handled with device described in the utility model, NO
3 -Concentration drops to 1.6mg/L, and clearance reaches 98.4%; Ni
2+Clearance reach 100%; The clearance of ortho chloro phenol reaches 96.6%, and dechlorination rate reaches 91.8%.
The column type reactor parameter:
| Diameter (mm) | Pack height (mm) | Hydraulic detention time | The filler composition |
| 200 | 800 | 12 hours | The Pdization rate is 0.02%, and Pd/Fe bimetal iron powder and pottery gravel weight ratio are 1: 3 |
Inlet and outlet water water quality:
| NO 3 -Concentration (mg/L) | Ni 2+Concentration (mg/L) | Ortho chloro phenol (mg/L) | ?Cl -Concentration (mg/L) | ?pH | Temperature (℃) | |
| Water inlet | 100 | 100 | 50 | ?3.008 | ?6.17 | 25 |
| Water outlet | 1.61 | Do not detect | 1.7 | ?15.691 | ?7.1 | 25 |
Embodiment 4
Certain contains 100mgL
-1NO
3 -, 100mgL
-1Ni
2+, 100mgL
-1Cu
2+, 50mgL
-1After the hydromining of o-dichlorobenzene pollutent is handled with device described in the utility model, NO
3 -Concentration drops to 2.1mg/L, and clearance reaches 96.9%; Ni
2+, Cu
2+Clearance reach 100%; The clearance of o-dichlorobenzene reaches 97.2%, and dechlorination rate reaches 90.5%.
The column type reactor parameter:
| Diameter (mm) | Pack height (mm) | Hydraulic detention time | The filler composition |
| 100 | 800 | 12 hours | The Pdization rate is 0.01%, and Pd/Fe bimetal waste iron filing and pottery gravel weight ratio are 1: 3 |
Inlet and outlet water water quality:
| NO 3 -Concentration (mg/L) | Ni 2+Concentration (mg/L) | Cu 2+Concentration (mg/L) | O-dichlorobenzene (mg/L) | ?Cl -Concentration (mg/L) | pH | Temperature (℃) | |
| Water inlet | 100 | 100 | 100 | 50 | ?4.387 | 6.0 | 25 |
| Water outlet | 3.1 | Do not detect | Do not detect | 1.4 | ?26.243 | 6.2 | 25 |
Claims (2)
1. device of administering water containing chlorine organism, nitrate and heavy metal contaminants, it is characterized in that, it is connected with hopper (1), first flow control valve (2), pump (3), second flowrate control valve (4), column type reactor (5) in turn, on column type reactor (5), set thief hole (6), middle thief hole (7), go up thief hole (8), be provided with water outlet (9) in column type reactor (5) upper end.
2. a kind of device of administering water containing chlorine organism, nitrate and heavy metal contaminants according to claim 1 is characterized in that the diameter of described column type reactor is 30-3000mm, and the packing layer height is 80-8000mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200620100325 CN200951975Y (en) | 2006-01-13 | 2006-01-13 | Apparatus for treating chlorine-containing organic substance, nitrate and heavy metal pollutant in water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200620100325 CN200951975Y (en) | 2006-01-13 | 2006-01-13 | Apparatus for treating chlorine-containing organic substance, nitrate and heavy metal pollutant in water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN200951975Y true CN200951975Y (en) | 2007-09-26 |
Family
ID=38810272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200620100325 Expired - Fee Related CN200951975Y (en) | 2006-01-13 | 2006-01-13 | Apparatus for treating chlorine-containing organic substance, nitrate and heavy metal pollutant in water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN200951975Y (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817156A (en) * | 2014-01-02 | 2015-08-05 | 天津大学 | Method for degrading polychlorinated biphenyl in water environment by Ni-Fe bimetallic nanoparticles |
| CN104891635A (en) * | 2015-05-12 | 2015-09-09 | 浙江清华长三角研究院 | Wastewater treatment method realized via reductive dehalogenation of iron powder under Pd catalysis |
-
2006
- 2006-01-13 CN CN 200620100325 patent/CN200951975Y/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817156A (en) * | 2014-01-02 | 2015-08-05 | 天津大学 | Method for degrading polychlorinated biphenyl in water environment by Ni-Fe bimetallic nanoparticles |
| CN104891635A (en) * | 2015-05-12 | 2015-09-09 | 浙江清华长三角研究院 | Wastewater treatment method realized via reductive dehalogenation of iron powder under Pd catalysis |
| CN104891635B (en) * | 2015-05-12 | 2017-01-18 | 浙江清华长三角研究院 | Wastewater treatment method realized via reductive dehalogenation of iron powder under Pd catalysis |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |