CN1995251A - Paint for preventing covering ice for insulator and its preparation method - Google Patents
Paint for preventing covering ice for insulator and its preparation method Download PDFInfo
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- CN1995251A CN1995251A CN 200610064503 CN200610064503A CN1995251A CN 1995251 A CN1995251 A CN 1995251A CN 200610064503 CN200610064503 CN 200610064503 CN 200610064503 A CN200610064503 A CN 200610064503A CN 1995251 A CN1995251 A CN 1995251A
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Abstract
The invention discloses an anti-insulator ice-coating paint and making method, which comprises the following parts: 100g polydimethyl siloxane, 100-150g organic solvent, 12-15g conductive fill, 10g carbon fiber powder, 15-30g aluminium hydroxide, 3g silica, 3g zinc oxide and 7g silane coupler, wherein the paint is coated on the insulator surface to prevent ice from covering, which improves stability of electric system operation.
Description
Technical field
The invention belongs to high pressure external insulation field, relate to a kind of at insulator surface coating silicon rubber coating taking precautions against the method for covering ice for insulator on the transmitting line, and the development of paint for preventing covering ice for insulator.
Background technology
Transmitting line exposes in physical environment, and its safe operation and physical environment are closely bound up.Along with climatic conditions change, transmitting line is standing changes in temperature alternately, and the test of exposing to wind and rain can produce to a certain extent influence and destruction inevitably.For example, expose to the sun and rain and to cause the aging of lead; Contamination is gradually understood on power equipment external insulation surface in operational process, form pollution flashover; Thunder and lightning can produce lightning surge or the like to overhead transmission line.In addition, the icing of transmitting line causes very big harm to transmitting line, and recent years is particularly serious, causes increasing attention.
Since the powerline ice-covering accident appearred in the U.S. first in 1932, the transmitting line ice trouble accident of various countries constantly took place.In January, 1998, occurring in Canadian ice damage accident has caused and has comprised that each voltage range circuit more than 1000 basic iron tower of 735kV overhead line structures and 30000 basic bars collapse, ten thousand philtrum cut-off electricity reach a week surplus the accumulative total 170, only the direct economic loss of Quebec just reaches 1,000,000,000 Canadian dollars, and indirect loss surpasses 3,000,000,000 Canadian dollars.
China is one of more country of icing accident, the area of electric transmission line isolator string generation icing flashover comprises Liaoning, northeast, the Shanxi in North China, Beijing-Tianjin area, Inner Mongol and Shandong, the Shaanxi of northwest, (district) economized in the river, Yunnan-Guizhou in the E Xiang Jiangxi, Henan in Central China and southwest etc.There is many ± 500kV DC line in China southwest, as sky (giving birth to bridge)-wide (state) line, and Three Gorges dragon (spring)-political affairs (putting down) line, three (gorges)-wide (east) line and expensive (state)-wide (east) line, these circuits all have part to pass through the icing district.Winter in 1996, multiple protection action has taken place in Pueraria lobota (dam, continent)-Nan (bridge) DC line, finally causes circuit to be stopped transport.Through looking into, to be DC line at the insulator chain of E Dong Dabie Mountain section serious icing has taken place cause of accident causes.On December 3rd, 1998, under the dense fog meteorological conditions, 21 tripping operations took place in area, Yangquan, Shanxi 4 220kV circuits altogether in 2 hours, and system almost disintegrates.The reason that causes current accident is that suspension insulator forms icicle under the foggy weather condition, and icicle causes tripping operation when melting.The ice damage accident is more and more fiery in recent years, and February calendar year 2001, occurrence of large-area icing in Henan Province's fell bar and covering ice for insulator flashover fault, and the 500kV transmitting line ice takes place dodges 34 times between 21 to 28 December in 2004.The Spring Festival in 2005, Hunan Province's electrical network has met with the most serious freezing threat since 51 years in the past.There are many 220 kilovolts and 500 kilovolts of trunk main icing in 8 cities such as xiangtan, hunan province, Changsha, Yueyang, and the icing thickness reaches seventy or eighty millimeters, and the many places wire pole tower dangerous situation occurs and collapses.Freezing time, coverage, circuit icing situation are once the most serious since being 1954.
The effective measure of taking precautions against covering ice for insulator at present are very limited, also do not have a kind of measure to be widely used, and the main precautionary measures have following two kinds: (1) changes the hang of insulator.The insulator chain that dangles forms icicle then with the insulator chain short circuit easily in the edge of umbrella disk.On " V " type insulator chain formed icicle be near perpendicular to insulator chain axially, can not reduce leakage distance.So it is more much higher than suspension insulator that the ice lightning of V-type insulator chain is pressed.(2) array mode that changes insulator also can adopt the insulator chain of specific combination in order to prevent the sleet bridge joint between insulator.More common combination is the insulator that connects the little disk track of a slice between the insulator of two big disk tracks.The insulator of little disk track form icing so the surface is very difficult, and the edge spacing of two big disk track insulators has also increased by one times owing to hidden by big disk track insulator fully, and is also little easily by the sleet bridge joint.
Summary of the invention
The purpose of this invention is to provide a kind of paint for preventing covering ice for insulator, this coating is coated on insulator surface, can significantly reduce the ice cover on the insulator and delay the formation of icing, take precautions against the generation of icing accident effectively, improve the stability of Operation of Electric Systems.
Paint for preventing covering ice for insulator of the present invention is a kind of anti-insulator semi-conductor hydrophobic nature coating, mainly researches and develops thinking and is:
1. select to have the material of good hydrophobicity performance, for example silicon rubber comprises high-temp glue and room temperature glue; Perhaps carry out the processing of material surface, for example use PTFE polytetrafluorethylepowder powder spray treatment, change the surface energy size, or the like, purpose is to reduce the surface energy of insulator surface, reduces the adhesive power of material surface and ice.
2. coating has the heating power performance, improves the coatingsurface temperature, delays or prevent the formation of icing.
Paint for preventing covering ice for insulator provided by the present invention by weight, contains: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.According to the filthy environment of different areas, circuit place, adjust the proportioning of the filler, solvent and the polydimethylsiloxane that are added in the coating.
The viscosity of polydimethylsiloxane is 5000PaS-10000PaS.
Organic solvent can be sherwood oil or industrial naptha etc.
The effect of conductive filler material is to make coating have certain conductive exothermal performance, can select the high electric conductivity carbon black for use, or Shawinigan black.Preferred high electric conductivity carbon black, its nitrogen adsorption specific surface area 300m
2/ g, the content ratio of adjusting carbon black powder can be adjusted the specific conductivity of coating, and the conductivity of the high more coating of sooty content ratio is good more.
The effect of aluminium hydroxide is flame retardant properties and the anti-creepage trace performance that improves coating, and its powder particle surface has carried out silane and coated processing.The effect of metal oxide such as zinc oxide is high temperature resistant, anti-oxidant.
The fineness of silicon-dioxide is a nano level, and the surface has been carried out silane and coated processing, is used to strengthen the mechanical property of silicon rubber.
Silane coupling agent makes basic glue carry out crosslinking reaction, increase simultaneously coating compactness and with the sticking power of glass.
The preparation method of above-mentioned paint for preventing covering ice for insulator may further comprise the steps:
Dry the powdered material in the described component, standby by described each constituent materials of proportioning weighing;
Earlier polydimethylsiloxane and solvent were put into the dispersion machine dispersed with stirring 0.2-0.8 hour, solvent and polydimethylsiloxane are fully merged; Again load weighted carbon black, carbon fiber powder, aluminium hydroxide, silicon-dioxide and zinc oxide are added and stirring in the dispersion machine of sizing material, continue to disperse 0.2-0.8 hour after adding all fillers; Sizing material after will disperseing is then put into basket dispersion mill and was ground 1-2 hour, cooling;
Ground coating is added in the vacuum stirring reactor, stirred 0.2-0.5 hour, reacting kettle inner pressure is remained to-0.7MPa, stirred autoclave is also put into silane coupling agent, stops to stir, and restarts stirrer when reactor temperature is risen to 70 ℃, after being warmed up to 80 ℃, kept 8 hours;
Be cooled to room temperature then, annotate the nitrogen discharge, the coating sealed storage.
The present invention also provides a kind of insulator, it is characterized in that: insulator surface is coated with the anti-icing paint layer of good hydrophobicity performance and heating power performance; Described anti-icing paint by weight, contains: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
The present invention also provides a kind of method of novel preventing covering ice for insulator, and this method is the anti-icing paint that is coated with good hydrophobicity performance and heating power performance at insulator surface; When insulator moved on the line, the dielectric loss that leakage current flows through joule heating, field-effect heating and the insulator itself of coating generation will make insulator surface heat up, and formed at insulator surface thereby effectively stop to ice under cryogenic environment.
In the method for above-mentioned preventing covering ice for insulator, anti-icing paint can adopt the anti-icing paint of following prescription: by weight, this coating contains 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
Anti-icing paint of the present invention is a single-component RTV silicon rubber coating, in air, run into moisture and can be sulfided into solid, after it is coated in insulator surface, sulfuration forms intensity height, slick top coat in air, and the surface of coating has good hydrophobicity performance and the migration of hydrophobicity performance stronger than traditional RTV coating.The size of coatingsurface energy directly has influence on the size with the adhesive power of icing, and surface energy is more little, and contact angle is big more, and is just more little with the adhesive power of ice.The formed coatingsurface of this coating has lower surface energy, and contact angle is 90 °-110 °, even ice cover is also little than ordinary porcelain insulator under not alive situation.Because the adhesive power of coating and ice is smaller, also can be easy to ice cube is come off under the situation of covering ice for insulator.
Because add certain conductive filler material in coating, coating becomes section's semiconductor material, has good electric heating property under the effect of minute leakage electric current.When the insulator that has applied this coating moves on the line, to have leakage current and flow through coating, the maximum leakage electric current is no more than 1mA, coating will make insulator surface heat up by the dielectric loss of joule heating, field-effect heating and insulator itself that leakage current produces, thereby can effectively stop the formation of ice at insulator surface under cryogenic environment.
Anti-icing paint of the present invention is with low cost, not only has the anti-fouling flashover performance that original RTV coating is had, and can also effectively reduce the harm of icing to insulator on the transmitting line.And, since simple with the anti-icing construction of the method for coating, need not to carry out any track remodelling, so application prospect is boundless.
Description of drawings
Fig. 1 is the preparation flow figure of paint for preventing covering ice for insulator of the present invention;
Fig. 2 simulates in the icing test test-results of the insulator chain of uncoated coating for climatizer;
Fig. 3 is coated with the test-results of the insulator chain of embodiment 1 coating in the test of climatizer simulation icing;
Fig. 4 is the insulator sectional view of surface-coated coating.
Embodiment
Paint for preventing covering ice for insulator of the present invention contains: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents by weight, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.The filler main component of being added in the coating has carbon black, aluminium hydroxide, carbon fiber powder, silicon-dioxide, zinc oxide, and solvent is sherwood oil or industrial naptha.Proportioning is adjusted according to the filthy environment of different areas, circuit place.This anti-icing paint is a single-component RTV silicon rubber coating, runs into moisture and can be sulfided into solid in air.
Embodiment 1:
Embodiment 1 paint for preventing covering ice for insulator, by weight, contain: 107 basic glue (polydimethylsiloxanes, viscosity 10000PaS) 100 parts, 150 parts of sherwood oils (or industrial naptha), 15 parts of carbon blacks, 10 parts of carbon fiber powders, 15 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 7 parts of 3 parts in zinc oxide and silane coupling agents.
Polydimethylsiloxane is commonly called as basic glue, it is the sizing of room temperature vulcanized silicone rubber, and molecular weight 10000-80000 belongs to hydroxy-end capped polydiorganosiloxane, under the effect of certain condition and linking agent crosslinking reaction can take place, form the straight chain polysiloxane.
What carbon black was selected for use is the high electric conductivity carbon black, nitrogen adsorption specific surface area 300m
2/ g.
Carbon fiber powder is that the PAN-based carbon fiber continuous filament yarn passes through special cutting facility, and the staple fibre that is cut into several millimeters long grinds and forms.
The effect of aluminium hydroxide is to have improved the flame retardant properties of coating and anti-creepage trace performance, and powder particle surface has carried out silane and coated processing.
The fineness of silicon-dioxide is a nano level, and the surface has been carried out silane and coated processing, is used to strengthen the mechanical property of silicon rubber.
With reference to Fig. 1, this preparation method for coating is as follows:
The major equipment that uses is dispersion machine, basket dispersion mill, Vacuum Magnetic stirred autoclave, baking oven, vacuum pressure pump and constant temperature liquid recycle pump.
1) pre-treatment
The powdered material that coats processing is put into baking oven placed 1-2 hour, 110 ℃ of temperature are to remove moisture.Weighing base glue, solvent, and required various constituent materialss, standby.
2) dispersion grinding
Basic glue and solvent are put into dispersion machine stirring at low speed dispersion 0.5 hour, solvent and sizing material are fully merged.
Use feed hopper, every kind of powdered material is slowly added equably stirring in the dispersion machine of sizing material.Continue to disperse 0.5 hour after adding all fillers.
Sizing material after disperseing is put into basket dispersion mill ground 2 hours, cool off with constant temperature liquid recycle pump.Use coating fineness scraper plate to measure the fineness of coating, traditional RTV coating uses three-roll grinder, and fineness is 90-150 μ m, can reach below the 20 μ m after using basket dispersion mill, and coating is more even, and performance is more stable.
Can add solvent in the process of lapping and adjust the viscosity of coating.
3) reaction
Ground coating is added in the vacuum stirring reactor, stirred 0.5 hour, vacuumize with vacuum pump, after the value that tensimeter is shown remained on-0.7, stirred autoclave was also put into silane coupling agent.(when putting into the total overall reaction thing at first, earlier stirrer is stopped, restart stirrer when equitemperature is raised to 70 ℃) is warmed up to 80 ℃.Kept 8 hours, be cooled to room temperature after, annotate the nitrogen discharge.The coating sealed storage.
The fundamental property test result of embodiment 1 paint for preventing covering ice for insulator sees Table 1.
Table 1
| Test event | Test performance | Remarks |
| Hydrophobic nature | 1 grade, 90 °-110 ° | Water spray staging, Static Contact horn cupping |
| Migration of hydrophobicity (time of recovery) | 2 hours | Diatomite |
| 10 hours | Kaolin | |
| Volume specific resistance | 10 6MΩ·cm |
The test of climatizer simulation icing:
The insulator chain of uncoated coating and the insulator chain of coating coating are carried out charged icing simulation test respectively, two groups of icing simulation test conditionally completes are identical, test conditions sees Table 2, observe its final icing result as shown in Figures 2 and 3, the uncoated coating of the insulator chain among Fig. 2 wherein, the insulator chain among Fig. 3 is coated with the coating of embodiment 1.This test is carried out in large-scale icing simulation climate testing laboratory.
Can see that from Fig. 2 and Fig. 3 the insulator chain of uncoated coating has sleet to form, ice cover is obviously many than the insulator chain that applies coating.After tested, every average ice cover of the insulator chain of uncoated coating is 393g, and the insulator chain that applies coating is 196g.Under the effect of ice-phobic coating, significantly reduce the formation of icing, and stoped the formation of sleet effectively, improved the flash-over voltage of insulator chain.
Table 2
| Test conditions | |
| Insulator | |
| 4 XP-70 | |
| Temperature | -8 |
| Test period | |
| 4 hours | |
| Voltage | AC 20kV |
Embodiment 2:
This coating is applicable to filthy heavier, the close bigger area of salt.This prescription institute coatings formulated has better arc ablation resistance performance and migration of hydrophobicity performance under harsh environmental conditions.The preparation method of embodiment 2 described coating is identical with embodiment 1.
The fundamental property test result of embodiment 2 paint for preventing covering ice for insulator sees Table 3.
Table 3
| Test event | Test performance | Remarks |
| Hydrophobic nature | 1 grade, 100 °-110 ° | Water spray staging, Static Contact horn cupping |
| Migration of hydrophobicity (time of recovery) | 2 hours | Diatomite |
| 8 hours | Kaolin | |
| Volume specific resistance | 10 8MΩ·cm |
Figure 4 shows that a kind of insulator that is coated with paint for preventing covering ice for insulator of the present invention, comprise ceramic dielectic 1, metal electrode 2 and 3, cement 4, the anti-icing paint layer that is coated with good hydrophobicity performance and heating power performance at the internal surface and the outside surface of ceramic dielectic 1; Described anti-icing paint by weight, contains: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
The method of preventing covering ice for insulator provided by the present invention is the anti-icing paint that is coated with good hydrophobicity performance and heating power performance at insulator surface; When insulator moved on the line, the dielectric loss that leakage current flows through joule heating, field-effect heating and the insulator itself of coating generation will make insulator surface heat up, and formed at insulator surface thereby effectively stop to ice under cryogenic environment.
Its anti-icing paint can adopt the coating of the coating of the foregoing description 1 prescription or embodiment 2 prescriptions or adopt other to have the anti-icing paint of good hydrophobicity performance and heating power performance.
Applying anti-icing paint at insulator surface is a kind of novel ice control, through a large amount of laboratory icing simulating evidences, anti-icing paint has tangible anti-icing performance, significantly reduce the ice cover on the insulator and delay the formation of icing, and use simple to operately, and need not to carry out track remodelling, cheap, have great economic benefit, opened the breach for solving puzzlement power system icing problem for many years.
Claims (9)
1, a kind of paint for preventing covering ice for insulator, it is characterized in that: by weight, contain: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
2, paint for preventing covering ice for insulator according to claim 1 is characterized in that: described organic solvent is sherwood oil or industrial naptha.
3, paint for preventing covering ice for insulator according to claim 1 is characterized in that: described conductive filler material is the high electric conductivity carbon black, and its nitrogen adsorption specific surface area is 300m
2/ g.
4, paint for preventing covering ice for insulator according to claim 1 is characterized in that: to be the PAN-based carbon fiber continuous filament yarn be cut into the staple fibre of several millimeters long by cutting facility to described carbon fiber powder, grinds to form again.
5, paint for preventing covering ice for insulator according to claim 1 is characterized in that: described silicon-dioxide fineness is a nano level.
6, the preparation method of the described paint for preventing covering ice for insulator of claim 1 is characterized in that may further comprise the steps:
Dry the powdered material in the described component, standby by described each constituent materials of proportioning weighing;
Earlier polydimethylsiloxane and solvent were put into the dispersion machine dispersed with stirring 0.2-0.8 hour, solvent and polydimethylsiloxane are fully merged; Again load weighted carbon black, carbon fiber powder, aluminium hydroxide, silicon-dioxide and zinc oxide are added and stirring in the dispersion machine of sizing material, continue to disperse 0.2-0.8 hour after adding all fillers; Sizing material after will disperseing is then put into basket dispersion mill and was ground 1-2 hour, cooling;
Ground coating is added in the vacuum stirring reactor, stirred 0.2-0.5 hour, reacting kettle inner pressure is remained to-0.7MPa, stirred autoclave is also put into silane coupling agent, stops to stir, and restarts stirrer when reactor temperature is risen to 70 ℃, after being warmed up to 80 ℃, kept 8 hours;
Be cooled to room temperature then, annotate the nitrogen discharge, the coating sealed storage.
7, a kind of insulator that is coated with the described coating of claim 1 is characterized in that: insulator surface is coated with the anti-icing paint layer of good hydrophobicity performance and heating power performance; Described anti-icing paint by weight, contains: 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
8, a kind of method of preventing covering ice for insulator is characterized in that: the anti-icing paint that is coated with good hydrophobicity performance and heating power performance at insulator surface; When insulator moved on the line, the dielectric loss that leakage current flows through joule heating, field-effect heating and the insulator itself of coating generation will make insulator surface heat up, and formed at insulator surface thereby effectively stop to ice under cryogenic environment.
9, the method for preventing covering ice for insulator according to claim 8, it is characterized in that: described anti-icing paint adopts the described anti-icing paint of claim 1, by weight, this coating contains 100 parts of polydimethylsiloxanes, 100～150 parts of organic solvents, 12～15 parts of conductive filler materials, 10 parts of carbon fiber powders, 15～30 parts in aluminium hydroxide, 3 parts of silicon-dioxide, 3 parts of zinc oxide or weisspiessglanzs, 7 parts of silane coupling agents.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610064503A CN100595248C (en) | 2006-12-27 | 2006-12-27 | Paint for preventing covering ice for insulator and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610064503A CN100595248C (en) | 2006-12-27 | 2006-12-27 | Paint for preventing covering ice for insulator and its preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN1995251A true CN1995251A (en) | 2007-07-11 |
| CN100595248C CN100595248C (en) | 2010-03-24 |
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|---|---|---|---|
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Cited By (12)
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|---|---|---|---|---|
| WO2010078745A1 (en) * | 2008-12-29 | 2010-07-15 | Wang Wei | Hollow supporting composite insulator whose inner wall has creepage joints |
| CN101787244A (en) * | 2010-03-26 | 2010-07-28 | 陈俊光 | Antifouling flash insulator coating and preparation method thereof |
| CN102511065A (en) * | 2011-10-08 | 2012-06-20 | 清华大学深圳研究生院 | Insulator and power transmission line equipment |
| CN103328590A (en) * | 2011-04-22 | 2013-09-25 | 松下电器产业株式会社 | Antifouling film, air blower blade provided with same, air blower, and antifouling coating material |
| CN104098960A (en) * | 2014-06-18 | 2014-10-15 | 国家电网公司 | Anti-icing coating slurry for transmission lines |
| CN105315870A (en) * | 2015-07-02 | 2016-02-10 | 江苏足迹涂料有限公司 | Ice-coating-resistant coating and preparation method and application thereof |
| CN105989934A (en) * | 2015-02-11 | 2016-10-05 | 国家电网公司 | Insulator possessing super-hydrophobic surface |
| CN106398518A (en) * | 2016-08-31 | 2017-02-15 | 南方电网科学研究院有限责任公司 | Dry-type air-core reactor protective coating and preparation method and use method thereof |
| WO2019023838A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | Ice-phobic coatings |
| CN109633306A (en) * | 2018-12-13 | 2019-04-16 | 国网湖南省电力有限公司 | The temperature rise calculation method of anti-ice-flashing composite insulator |
| US11326059B2 (en) | 2017-09-07 | 2022-05-10 | Dow Global Technologies Llc | Thermally conductive ice-phobic coatings |
| CN118325383A (en) * | 2024-02-27 | 2024-07-12 | 可慧(河南)新材料科技有限公司 | Silicone resin anti-icing coating material and preparation method thereof |
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- 2006-12-27 CN CN200610064503A patent/CN100595248C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010078745A1 (en) * | 2008-12-29 | 2010-07-15 | Wang Wei | Hollow supporting composite insulator whose inner wall has creepage joints |
| CN101787244A (en) * | 2010-03-26 | 2010-07-28 | 陈俊光 | Antifouling flash insulator coating and preparation method thereof |
| CN101787244B (en) * | 2010-03-26 | 2013-04-10 | 陈俊光 | Antifouling flash insulator coating and preparation method thereof |
| CN103328590A (en) * | 2011-04-22 | 2013-09-25 | 松下电器产业株式会社 | Antifouling film, air blower blade provided with same, air blower, and antifouling coating material |
| CN103328590B (en) * | 2011-04-22 | 2016-09-28 | 松下知识产权经营株式会社 | Anti-soil film and the formation airblast blade of this anti-soil film, air-blast device and antifouling paint |
| CN102511065A (en) * | 2011-10-08 | 2012-06-20 | 清华大学深圳研究生院 | Insulator and power transmission line equipment |
| WO2013049968A1 (en) * | 2011-10-08 | 2013-04-11 | 清华大学深圳研究生院 | Insulator and power transmission line device |
| US9196396B2 (en) | 2011-10-08 | 2015-11-24 | Graduate School At Shenzhen, Tsinghua University | Insulator and power transmission line apparatus |
| CN104098960A (en) * | 2014-06-18 | 2014-10-15 | 国家电网公司 | Anti-icing coating slurry for transmission lines |
| CN105989934A (en) * | 2015-02-11 | 2016-10-05 | 国家电网公司 | Insulator possessing super-hydrophobic surface |
| CN105315870A (en) * | 2015-07-02 | 2016-02-10 | 江苏足迹涂料有限公司 | Ice-coating-resistant coating and preparation method and application thereof |
| CN105315870B (en) * | 2015-07-02 | 2019-02-15 | 江苏足迹涂料有限公司 | A kind of anti-icing paint, preparation method and application |
| CN106398518A (en) * | 2016-08-31 | 2017-02-15 | 南方电网科学研究院有限责任公司 | Dry-type air-core reactor protective coating and preparation method and use method thereof |
| WO2019023838A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | Ice-phobic coatings |
| US11326059B2 (en) | 2017-09-07 | 2022-05-10 | Dow Global Technologies Llc | Thermally conductive ice-phobic coatings |
| CN109633306A (en) * | 2018-12-13 | 2019-04-16 | 国网湖南省电力有限公司 | The temperature rise calculation method of anti-ice-flashing composite insulator |
| CN118325383A (en) * | 2024-02-27 | 2024-07-12 | 可慧(河南)新材料科技有限公司 | Silicone resin anti-icing coating material and preparation method thereof |
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| CN100595248C (en) | 2010-03-24 |
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