CN1994517A - Filter core for removing fluorine from drinking water and preparation method thereof - Google Patents
Filter core for removing fluorine from drinking water and preparation method thereof Download PDFInfo
- Publication number
- CN1994517A CN1994517A CN 200610168010 CN200610168010A CN1994517A CN 1994517 A CN1994517 A CN 1994517A CN 200610168010 CN200610168010 CN 200610168010 CN 200610168010 A CN200610168010 A CN 200610168010A CN 1994517 A CN1994517 A CN 1994517A
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- Prior art keywords
- filter core
- powder
- drinking water
- fluorine
- activated
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011737 fluorine Substances 0.000 title claims abstract description 44
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 44
- 239000003651 drinking water Substances 0.000 title claims abstract description 29
- 235000020188 drinking water Nutrition 0.000 title claims abstract description 29
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title claims abstract 11
- 238000002360 preparation method Methods 0.000 title claims description 12
- 238000005245 sintering Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical class [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 230000000694 effects Effects 0.000 description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000036541 health Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 208000005374 Poisoning Diseases 0.000 description 3
- 210000000988 bone and bone Anatomy 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 206010016818 Fluorosis Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000006115 defluorination reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 208000004042 dental fluorosis Diseases 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
Abstract
The invention relates to a filter element which can remove the fluorine in drinking water and relative production, wherein its production comprises that: preparing materials via formula, mixing and putting into mould; sintering at high temperature, drying to normal temperature, removing mould, to obtain the porous filter element. The invention can effectively remove fluorine at 70-90%.
Description
Technical field
The present invention relates to a kind of filter core, particularly relate to a kind of filter core of removing fluorine in the drinking water and preparation method thereof.
Background technology
Along with developing rapidly of industry and agricultural, the water resource of China has been suffered heavy damage.Increasing industrial wastewater discharge has destroyed our ecological environment in rivers, lake.The discharging wantonly of the extensive application of agricultural chemicals, pesticide and house refuse causes the quality of groundwater variation, and causes producing in the water a lot of harmful materials.Water pollutes more and more becomes the severe problem that influences people's life.
Fluorine is one of human life activity's trace elements necessary, needs the fluorine of 1.0~1.5mg everyone every day approximately.The source of fluorine mainly contains nature and two kinds of artificial modes.A spot of fluorine has certain effect to health especially tooth is firm.Over nearly 60 years, the industrial production activity becomes the main artificial source of fluoride in the underground water.Produce phosphate chemical fertilizer, dissolved aluminum, glassware and bake bricks, industrial process such as steel-making all can discharge fluoride, thereby cause a lot of local underground water fluorinated volumes to exceed standard.The drinking water fluorinated volume is greater than 1,000,000/time, and tooth enamel can be destroyed, and gloss disappears, and ash or yellow spotting occur, i.e. glaze tooth or mottling of teeth; Reach at 8/1000000ths o'clock, will make bone and kidney suffer infringement; Reach at 10/1000000ths o'clock, can cause bone malformation, simultaneously with nervous symptoms, maimed type fluorosis of bone that Here it is.Drinking-water is the main source of fluorine, and in high fluorine geographical environment, human body is because of the fluorine of long-term excess intake, body accumulation and cause fluorine poisoning.In China, some areas such as capital, Tianjin, Ji, Henan, Shandong, Shanxi, Shan, sweet, peaceful, three provinces in the northeast of China and Inner Mongol are exactly high fluoride area (fluorinated volume is above 1.5 milligrams in every premium on currency).Often drink these local underground water, can be detrimental to health, cause various fluorine poisonings.
Present stage, along with growth in the living standard, people's health care consciousness is also more and more stronger.Only the water through the waterworks sterilization does not have removal effect to fluorine.Though the various water quality treaters that occur on the market have the improvement effect to the overall purification of water quality, but still can not solve the fluorine-containing pollution problem in high fluorine area well.Fluoride pollution remains our water treatment difficult problem of puzzlement.
Traditional defluorination method mainly contains the precipitation method, absorption method and hyperfiltration etc.The precipitation ratio juris is to add medicament in former water, formation fluoride precipitation, separate through solid then and reach the purpose of removing fluorine ion, the general medicament that adopts has lime, carbide slag, dolomite or alum etc., this method treated water generally can not reach guidelines for drinking water quality, also need to carry out advanced treating, and the water that some chemicals treatment is crossed also needs to carry out pH value adjusting etc., process more complicated again.Absorption method is to utilize fluorine to select sorbing material to remove by filter fluoride, and its basic mechanism is a kind of ion-exchange or adsorption reaction.This method operation and maintenance technology are higher, and expense is bigger, only are applicable to the advanced treating regional or fluorinated water after preliminary treatment fluorine content drops to 1.5mg/L~3.0mg/L that fluorinated volume is low.Reverse osmosis technology is a kind of membrane separation technique, its principle is under the pressure effect that is higher than the solution infiltration, the selection of the pellicle by other material effect of damming does not separate harmful substance by only allowing water to see through, this method depends on the pH value of former water to a great extent, apparatus expensive is made water cost height, and the water rate of recovery is low, power consumption is bigger, is generally used for industry and makes pure water.
Summary of the invention
The present invention is in order to address the above problem, a kind of filter core that is used to purify water is provided, it not only can remove other harmful substance in the water, improve water quality, be particularly useful for fluorine-containing higher water source, can play good clean-up effect, effectively improve the water quality in the high area of fluorinated volume fluorine, reduce the fluorine poisoning phenomenon, improve high fluorine area people's health.
An object of the present invention is to provide a kind of filter core of removing fluorine in the drinking water.
Another object of the present invention provides the preparation method of the filter core of fluorine in the described removal drinking water.
The objective of the invention is to be achieved through the following technical solutions:
A kind of filter core of removing fluorine in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 30-100 activated carbon powder 5-30
The polyethylene powder 150-300 activated aluminum powder 5-50 of 1,500,000-7,000,000 molecular weight
Preferably, a kind of filter core of removing fluorine in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 50-80 activated carbon powder 15-25
The polyethylene powder 200-250 activated aluminum powder 15-35 of 1,500,000-7,000,000 molecular weight
More preferably, a kind of filter core of removing fluorine in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 80 activated carbon powders 20
Polyethylene powder 200 activated aluminum powders 25 of 1,500,000-7,000,000 molecular weight
Activated carbon powder described in the present invention is the medicinal active powdered carbon, has the effect of efficient absorption chemical fertilizer, residues of pesticides, heterochromatic peculiar smell and heavy metal, and its order number is the 40-200 order.
Polyethylene powder described in the present invention has powerful static dynamic absorption effect, can capture trickle, superfine particle that microfiltration can not filtration resistance, and its order number is the 20-160 order, and molecular weight is 1,500,000-7,000,000, and preferred, molecular weight is 2,500,000-4,000,000.
Activated magnesia powder described in the present invention and activated aluminum powder can effectively be removed the fluorine that exceeds standard in the drinking water by displacement and absorption, and wherein activated magnesia powder order number is the 200-325 order, and activated aluminum powder order number is the 100-300 order.
A kind of preparation method who removes the filter core of fluorine in the drinking water of the present invention, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through the sintering aftershaping, the demoulding to the normal temperature of drying in the air.Promptly become the tubular structure filter core with regulation wall thickness, height of porous.In use, this naked filter core liner two-layer nonwoven, the outsourcing two-layer nonwoven wraps polypropylene porous net at skin again, and bonding the going up in filter core two ends connects end cap, is positioned over stainless steel or plastic casing, gets final product.
The present invention is a kind of to remove that sintering temperature is at 200-300 ℃ among the preparation method of the filter core of fluorine in the drinking water, and sintering time is 120-160 minute, dries in the air behind the sintering to take off to 40-60 ℃ to touch.
The present invention is a kind of to remove that the filter core of fluorine has in purifying drinking water in the drinking water, effectively removes the effect of fluorine, has certain mechanical strength and crushing resistance, and permeability is good, and is easy to use, is fit to very much the home terminal drinking water treatment.After testing, this filter core to the clearance of fluorine in the drinking water at 70%-90%.
The specific embodiment
Following examples are in order further to describe the present invention for example, rather than limit the present invention by any way.
Embodiment 1
Activated magnesia powder (200 order) 80g medicinal active powdered carbon (60 order) 20g
The polyethylene powder of 4,000,000 molecular weight (150 order) 200g activated aluminum powder (200 order) 25g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 240 ℃ of following sintering after 150 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 2
Activated magnesia powder (280 order) 40g medicinal active powdered carbon (100 order) 30g
The polyethylene powder of 3,000,000 molecular weight (80 order) 280g activated aluminum powder (100 order) 15g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 260 ℃ of following sintering after 130 minutes, the demoulding after 45 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 3
Activated magnesia powder (300 order) 30g medicinal active powdered carbon (150 order) 10g
The polyethylene powder of 5,000,000 molecular weight (160 order) 250g activated aluminum powder (280 order) 20g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 230 ℃ of following sintering after 160 minutes, the demoulding after 50 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 4
Activated magnesia powder (230 order) 90g medicinal active powdered carbon (160 order) 15g
The polyethylene powder of 4,000,000 molecular weight (40 order) 160g activated aluminum powder (200 order) 50g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 220 ℃ of following sintering after 120 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Below a kind of effect of removing the filter core of fluorine in the drinking-water by the survey report explanation embodiment of the invention 1;
Examining report
Test sample: a kind of filter core of removing fluorine in the drinking-water of inventive embodiments 1
Testing goal: the effect of absorption fluoride
Testing result:
1.0mg/L filter back 0.31mg/L before the filter
Detect unit: HSPH of Beijing Medical University
Testing staff: Zhao Jinghui
Detect the date: on January 19th, 2005
Claims (8)
1. filter core of removing fluorine in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 30-100 activated carbon powder 5-30
The polyethylene powder 150-300 activated aluminum powder 5-50 of 1,500,000-7,000,000 molecular weight
2. a kind of filter core of removing fluorine in the drinking water according to claim 1, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 50-80 activated carbon powder 15-25
The polyethylene powder 200-250 activated aluminum powder 15-35 of 1,500,000-7,000,000 molecular weight
3. a kind of filter core of removing fluorine in the drinking water according to claim 2, it is formed by the feedstock production that comprises following parts by weight;
Activated magnesia powder 80 activated carbon powders 20
Polyethylene powder 200 activated aluminum powders 25 of 1,500,000-7,000,000 molecular weight
4. a kind of filter core of removing fluorine in the drinking water according to claim 1, wherein said activated carbon powder is the medicinal active powdered carbon, its order number is the 40-200 order.
5. a kind of filter core of removing fluorine in the drinking water according to claim 4, the polyethylene powder of wherein said 1,500,000-7,000,000 molecular weight, molecular weight are 2,500,000-4,000,000, its order number is the 20-160 order.
6. a kind of filter core of removing fluorine in the drinking water according to claim 5, wherein said activated magnesia powder order number is the 200-325 order, activated aluminum powder order number is the 100-300 order.
7. a kind of preparation method who removes the filter core of fluorine in the drinking water according to claim 1, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through the sintering aftershaping, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness and height of porous.
8. a kind of preparation method who removes the filter core of fluorine in the drinking water according to claim 7, wherein said sintering temperature is at 200-300 ℃, and sintering time is 120-160 minute, dries in the air behind the sintering to take off to 40-60 ℃ to touch.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006101680101A CN100444925C (en) | 2006-12-22 | 2006-12-22 | Filter core for removing fluorine from drinking water and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006101680101A CN100444925C (en) | 2006-12-22 | 2006-12-22 | Filter core for removing fluorine from drinking water and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN1994517A true CN1994517A (en) | 2007-07-11 |
CN100444925C CN100444925C (en) | 2008-12-24 |
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CNB2006101680101A Active CN100444925C (en) | 2006-12-22 | 2006-12-22 | Filter core for removing fluorine from drinking water and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102350129A (en) * | 2011-06-21 | 2012-02-15 | 黄光智 | Integrated water purifying filter core for removing fluorine and filtering |
CN108745270A (en) * | 2018-06-12 | 2018-11-06 | 天津医科大学 | A kind of removing fluorine from water magnesium oxide composite material and the preparation method and application thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6550622B2 (en) * | 1998-08-27 | 2003-04-22 | Koslow Technologies Corporation | Composite filter medium and fluid filters containing same |
CN1140344C (en) * | 2001-10-08 | 2004-03-03 | 穆柏春 | High-strength refractory catalytic cleaning ceramic filter and its preparing process |
CN1765468A (en) * | 2004-10-27 | 2006-05-03 | 核工业第八研究所 | Microporous nano silver active filter core and its production method |
-
2006
- 2006-12-22 CN CNB2006101680101A patent/CN100444925C/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102350129A (en) * | 2011-06-21 | 2012-02-15 | 黄光智 | Integrated water purifying filter core for removing fluorine and filtering |
CN108745270A (en) * | 2018-06-12 | 2018-11-06 | 天津医科大学 | A kind of removing fluorine from water magnesium oxide composite material and the preparation method and application thereof |
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Publication number | Publication date |
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CN100444925C (en) | 2008-12-24 |
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Address after: 100032, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District Patentee after: Beijing Zhongke Green Hydrogen Technology Co.,Ltd. Country or region after: China Address before: 100032, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District Patentee before: Beijing Genecare Water Treatment Technology Co.,Ltd. Country or region before: China |
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