CN1986903A - Electrolytic decontaminator for removing pollutant from metal surface - Google Patents

Electrolytic decontaminator for removing pollutant from metal surface Download PDF

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Publication number
CN1986903A
CN1986903A CN 200510135003 CN200510135003A CN1986903A CN 1986903 A CN1986903 A CN 1986903A CN 200510135003 CN200510135003 CN 200510135003 CN 200510135003 A CN200510135003 A CN 200510135003A CN 1986903 A CN1986903 A CN 1986903A
Authority
CN
China
Prior art keywords
electrolytic
inner chamber
exocoel
decontamination
negative electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200510135003
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Chinese (zh)
Inventor
董毅漫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Institute for Radiation Protection
Original Assignee
China Institute for Radiation Protection
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Institute for Radiation Protection filed Critical China Institute for Radiation Protection
Priority to CN 200510135003 priority Critical patent/CN1986903A/en
Publication of CN1986903A publication Critical patent/CN1986903A/en
Pending legal-status Critical Current

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Abstract

The electrolytic decontaminator for eliminating pollutant from metal surface includes one outer cavity with vacuumizing port for being vacuumized, and one inner cavity with water inlet and water outlet extending beyond the outer cavity and cathode inside the inner cavity and possessing end extending beyond the inner cavity for connection to the negative pole of the power source. The part to be decontaminated serves as the anode connected to the positive pole of the power source, and there are sealing pads set between the electrolytic decontaminator and the decontaminated part. The present invention can decontaminate large metal equipment partially in high efficiency, low cost and less waste producing amount, and the produced waste may be degraded for minimizing.

Description

Remove the electrolytic decontaminating device that pollute the metallic surface
Technical field
The present invention relates to remove the device of surface contamination, relate in particular to a kind of electrolytic decontaminating device that pollute the metallic surface of removing.
Background technology
Once the electrolytic decontaminating technology is used for radioactive decontamination abroad, and developed a lot of electrolytic decontaminating devices, but mostly be slot type, only be suitable for the electrolytic decontaminating of micro metal parts, then inapplicable for large-scale hardware, pipeline.There are many large-scale hardwares, pipeline after common decontamination, to leave over down during elimination of nuclear facilities decontamination and pollute focus, this pollution focus uses common decontamination method to remove, also can not realize whole hardware, pipeline electrolytic decontaminating, and secondary refuse generation is excessive, the decontamination expense is too high, and is very uneconomical; If not to polluting the focus decontamination, metal waste can't degradation, recirculation, utilize again, and the metal waste generation is big, and disposal costs is too high, and is also very uneconomical, and therefore the pollution focus of large-scale hardware, pipeline is the difficult point of retired decontamination.Develop and a kind ofly be used for the large-scale hardware of nuclear installation, pipe surface to pollute the electrolytic decontaminating device of focus decontamination significant.
Summary of the invention
The present invention is directed to insurmountable large-scale hardware in the prior art, pipeline focus decontamination problem, provide a kind of large-scale hardware, pipe surface of being applicable to pollute the electrolytic decontaminating device of removing.
The present invention removes the electrolytic decontaminating device that pollutes the metallic surface and comprises exocoel that can vacuumize and the inner chamber of placing electrolytic solution, exocoel is provided with vacuum orifice, inner chamber is provided with fluid inlet and liquid outlet, fluid inlet and liquid outlet all stretch out exocoel, negative electrode places inner chamber, the end of negative electrode is stretched out inner chamber and is linked to each other with the negative pole of power supply, treats that the decontamination parts link to each other with the positive pole of power supply as anode, is equipped with gasket on electrolytic decontaminating device and the surface for the treatment of the side that the decontamination parts contact.
Aforesaid electrolytic decontaminating device protrudes in exocoel with the inner chamber for the treatment of electrolytic decontaminating device one side that the decontamination parts contact, and to be applicable to that removing the metallic conduit internal surface pollutes, simultaneously, the negative electrode that places inner chamber is a circular arc type.
Aforesaid electrolytic decontaminating device, concordant with the inner chamber for the treatment of electrolytic decontaminating device one side that the decontamination parts contact with exocoel, remove the hardware surface contamination to be applicable to, simultaneously, the negative electrode that places inner chamber is plate.
Electrolytic decontaminating device of the present invention, adopt the mode of vacuum suck eradicator to be adsorbed on the surface of hardware, pipeline, eradicator is a double cavity structure, electrolytic solution can carry out electrolytic decontaminating in the inner chamber circulation, and exocoel is then kept the certain vacuum degree eradicator is fixed on the decontamination working face.Whole device volume is little, in light weight, and device is installed fast, easy during decontamination, can reduce a staff and be shone.This device is at large-scale hardware, the decontamination of pipeline focus, and do not need whole pipe equipment is carried out decontamination, thereby significantly reduced secondary refuse generation, improved working efficiency, reduced the decontamination expense, metal waste after the decontamination can pass through degradation, recirculation, utilize, reduces disposal costs, realizes waste minimization.
Description of drawings
Fig. 1 is electrolytic decontaminating device (being applicable to that removing the metallic conduit internal surface a pollutes) synoptic diagram;
Fig. 2 is electrolytic decontaminating device (be applicable to and remove a hardware surface contamination) synoptic diagram.
Among the figure: 1. exocoel; 2. treat the decontamination parts; 3. inner chamber; 4. gasket; 5. fluid inlet;
6. vacuum orifice; 7. negative electrode; 8. liquid outlet; 9. power supply.
Embodiment
Embodiment 1
Be described specifically below in conjunction with 1 pair of electrolytic decontaminating device of accompanying drawing (being applicable to that removing the metallic conduit internal surface pollutes):
The electrolytic decontaminating device comprises exocoel 1 and inner chamber 3, exocoel 1 is provided with vacuum orifice 6, inner chamber 3 is provided with fluid inlet 5 and liquid outlet 8, fluid inlet 5 and liquid outlet 8 all stretch out exocoel 1, negative electrode 7 places inner chamber 3 for circular arc type (being applicable to that removing the metallic conduit internal surface pollutes), the end of negative electrode 7 is stretched out inner chamber 3 and is linked to each other with the negative pole of power supply 9, treats that decontamination parts 2 link to each other as the positive pole of anode with power supply 9, is equipped with gasket 4 on electrolytic decontaminating device and the surface for the treatment of the side that decontamination parts 2 contact.
When carrying out decontamination, to treat that decontamination parts 2 (treating the decontamination pipeline) connect power supply 9 positive poles as anode, the negative electrode 7 that eradicator is provided with (being applicable to that removing the metallic conduit internal surface pollutes) connects power supply 9 negative poles, eradicator is placed on the Polluted area of metallic conduit internal surface, vacuumize by the vacuum orifice 6 that exocoel 1 is provided with vacuum pump, make the exocoel 1 of eradicator have the certain vacuum degree, thereby eradicator is fixed on the decontamination zone by vacuum suck, inner chamber 3 to eradicator adds electrolytic solution then, make electrolytic solution be full of inner chamber 3, at current density 0.1~0.6A/cm 2Following electrolysis for some time along with the electrolytic dissolution on anode metal surface, will enter in the electrolytic solution attached to the dissolving with the metallic surface of the radiocontamination of metallic surface, remove alpha-contamination purpose thereby reach.
After electrolysis finishes, discharge the electrolytic solution of 3 li of eradicator inner chambers, the electrolytic solution that 3 pairs of the inner chambers that rinsing liquid (water) is added eradicator remain in the metallic conduit internal surface carries out rinsing, exocoel 1 is still kept the certain vacuum degree in the time of rinsing, and eradicator still is fixed on the decontamination zone by vacuum suck;
Rinsing finishes, and discharges the rinsing liquid (water) of 3 li of eradicator inner chambers, removes eradicator and fixes air seasoning in the vacuum suck in decontamination zone.
Embodiment 2
Be described specifically below in conjunction with 2 pairs of electrolytic decontaminating devices of accompanying drawing (be applicable to and remove the hardware surface contamination):
The electrolytic decontaminating device comprises exocoel 1 and inner chamber 3, exocoel 1 is provided with vacuum orifice 6, inner chamber 3 is provided with fluid inlet 5 and liquid outlet 8, fluid inlet 5 and liquid outlet 8 all stretch out exocoel 1, negative electrode 7 places inner chamber 3 for plate (be applicable to and remove the hardware surface contamination), the end of negative electrode 7 is stretched out inner chamber 3 and is linked to each other with the negative pole of power supply 9, treats that decontamination parts 2 link to each other as the positive pole of anode with power supply 9, is equipped with gasket 4 on electrolytic decontaminating device and the surface for the treatment of the side that decontamination parts 2 contact.
When carrying out decontamination, to treat that decontamination parts 2 (treating washer) connect power supply 9 positive poles as anode, the negative electrode 7 that eradicator is provided with (be applicable to and remove the hardware surface contamination) connects power supply 9 negative poles, eradicator is placed on the Polluted area on hardware surface, vacuumize by the vacuum orifice 6 that exocoel 1 is provided with vacuum pump, make the exocoel 1 of eradicator have the certain vacuum degree, thereby eradicator is fixed on the decontamination zone by vacuum suck, inner chamber 3 to eradicator adds electrolytic solution then, make electrolytic solution be full of inner chamber 3, at current density 0.1~0.6A/cm 2Following electrolysis for some time along with the electrolytic dissolution on anode metal surface, will enter in the electrolytic solution attached to the dissolving with the metallic surface of the radiocontamination of metallic surface, remove alpha-contamination purpose thereby reach.
After electrolysis finishes, discharge the electrolytic solution of 3 li of eradicator inner chambers, the electrolytic solution that 3 pairs of the inner chambers that rinsing liquid (water) is added eradicator remain in the hardware surface carries out rinsing, exocoel 1 is still kept the certain vacuum degree in the time of rinsing, and eradicator still is fixed on the decontamination zone by vacuum suck;
Rinsing finishes, and discharges the rinsing liquid (water) of 3 li of eradicator inner chambers, removes eradicator and fixes air seasoning in the vacuum suck in decontamination zone.

Claims (3)

1. remove the electrolytic decontaminating device that pollute the metallic surface for one kind, it is characterized in that: this device comprises exocoel (1) that can vacuumize and the inner chamber (3) of placing electrolytic solution, exocoel (1) is provided with vacuum orifice (6), inner chamber (3) is provided with fluid inlet (5) and liquid outlet (8), fluid inlet (5) and liquid outlet (8) all stretch out exocoel (1), negative electrode (7) places inner chamber (3), the end of negative electrode (7) is stretched out inner chamber (3) and is linked to each other with the negative pole of power supply (9), treat that decontamination parts (2) link to each other as the positive pole of anode with power supply (9), be equipped with gasket (4) on electrolytic decontaminating device and the surface for the treatment of the side that decontamination parts (2) contact.
2. electrolytic decontaminating device according to claim 1, it is characterized in that: protrude in exocoel with the inner chamber for the treatment of electrolytic decontaminating device one side that decontamination parts (2) contact, to be applicable to that removing the metallic conduit internal surface pollutes, simultaneously, the negative electrode that places inner chamber is a circular arc type.
3. electrolytic decontaminating device according to claim 1, it is characterized in that: concordant with exocoel with the inner chamber for the treatment of electrolytic decontaminating device one side that decontamination parts (2) contact, remove the hardware surface contamination to be applicable to, simultaneously, the negative electrode that places inner chamber is plate.
CN 200510135003 2005-12-23 2005-12-23 Electrolytic decontaminator for removing pollutant from metal surface Pending CN1986903A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200510135003 CN1986903A (en) 2005-12-23 2005-12-23 Electrolytic decontaminator for removing pollutant from metal surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200510135003 CN1986903A (en) 2005-12-23 2005-12-23 Electrolytic decontaminator for removing pollutant from metal surface

Publications (1)

Publication Number Publication Date
CN1986903A true CN1986903A (en) 2007-06-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200510135003 Pending CN1986903A (en) 2005-12-23 2005-12-23 Electrolytic decontaminator for removing pollutant from metal surface

Country Status (1)

Country Link
CN (1) CN1986903A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110959183A (en) * 2018-05-11 2020-04-03 原子能股份公司 Device for electrochemical decontamination of metal radioactive wastes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110959183A (en) * 2018-05-11 2020-04-03 原子能股份公司 Device for electrochemical decontamination of metal radioactive wastes
CN110959183B (en) * 2018-05-11 2023-12-01 原子能股份公司 Electrochemical decontamination device for metal radioactive waste

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Open date: 20070627