CN1982227A - Ionic rod water treater in water pool - Google Patents
Ionic rod water treater in water pool Download PDFInfo
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- CN1982227A CN1982227A CN 200510111556 CN200510111556A CN1982227A CN 1982227 A CN1982227 A CN 1982227A CN 200510111556 CN200510111556 CN 200510111556 CN 200510111556 A CN200510111556 A CN 200510111556A CN 1982227 A CN1982227 A CN 1982227A
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Abstract
An ion-bar water treater in water pool has cleaning, sterilizing, algae-killing and slow-releasing functions. A circular hole is opened at connecting-pipe sided wall to connect with water inlet and outlet, positioning ring is arranged at top of connecting pipe, sliding pipe and cathode are set on positioning ring, anode is set at center of cathode, leading boards of cathode and anode are grounded separately to cathode and anode of power supply, circular hole of water treater is aligned to water inlet and outlet and is installed in water pool. It has good effect, reliability and no pollution and saves resources.
Description
Technical field
The present invention relates to Treatment of Industrial Water technology and a kind of mechanical water treater, particularly a kind of pond intermediate ion rod water treater.
Background technology
Contain scale forming matters such as calcium, magnesium in the industrial circulating cooling water, the heat exchanging apparatus of long-time running increases energy consumption because of the fouling meeting, can be forced to stop production and damage equipment when fouling is serious.Therefore, water treatment is an important ring in the industrial production.Water treatment method commonly used is a chemical method.Because of chemical method needs sizable construction cost, take certain place, consume certain electric energy, consume various chemical agents, the more important thing is chemical method will discharge certain environmental protection influence to environment waste water, cleaning waste liquid also has bigger pollution to environment.Therefore, people are just seeking not antiscale, the descalling technique of with medicament for a long time.Since nearly half a century, the domestic and international water treating device that physical principles such as electronics, high frequency, high pressure static electricity, ultrasonic wave, magnetic field are arranged that has used.The electronic hydrotreater of the triumphant electronics worker of Beijing moral Water Management Equipment Ltd. for example, but it is not mounted in the pond, but (1) must be installed near on the inlet channel of equipment, the incision pipeline that must stop production is installed; (2) low-tension current is at several amperes, and too high meeting produces electrolytic corrosion, and inconvenient clean and maintenance; (3) electrostatic high-pressure is less than 10000 volts, and it is difficult to handle the above hard water of 700mg/L; (4) handle the above large vol water treatment device of 3000M3/h and be difficult to make, and occupation of land face takes up space the treatment effect instability.
Summary of the invention
The object of the present invention is to provide a kind of pond intermediate ion rod water treater that is installed in.
Purpose of the present invention is finished by following technical solution: support the communicating pipe sidewall at drum shape steel overcoat and have the circular port that is connected with water return outlet or water outlet in the pond, communicating pipe nearly upper inner be fixed with retaining ring.Be equipped with slip pipe on retaining ring top, be welded in the communicating pipe inwall by the solder joint slip pipe.Stainless steel treater shell as negative electrode places the slip pipe inner chamber and is shelved on retaining ring top, and two titaniums contain the au cathode pole plate and are welded in the shell top, and cathode plate links to each other with the output negative pole of power-supply controller of electric.Outer shroud is connected with annulus at the slip pipe top.In shell central authorities cylindrical plated film titanium anode bar is set, is welded with positive plate in the anode bar upper end, plate is connected with the output cathode of power-supply controller of electric.
Ionic rod water treater is directly installed in the pond, and a kind of installation method is a water outlet of the circular port of ionic rod water treater being aimed at the pond, and Chi Zhongshui is gone into by the top Chung of ionic rod water treater, handles the back and causes watering equipment by water outlet.Another kind of installation method is a water return outlet of the circular port of ionic rod water treater being aimed at the pond, be that the water that watering equipment row comes enters the pond by water return outlet, at this moment water enters water treating device by the circular port of ionic rod water treater, handles the back and goes out to the pond from head tube.
Beneficial effect of the present invention is:
1, compares with the water treating devices such as electronics on the pipeline, high frequency, high pressure static electricity, ultrasonic wave that are installed on that need ground, space, gate, flange, elbow, pipeline and sealing member, it is a new Treatment of Industrial Water practical technique, its treatment effect is stable, and the long-time running effect is good.Be directly installed in the pond, installation needn't stop production.
2, replace pharmaceutical chemicalss such as Scale inhibitors, scale remover, biocide, inhibiter, can reach the water conditioning index of antiscale, scale removal, sterilization, algae removal, inhibition in the lump.
3, practical, reliable, pollution-free, energy-conservation.
Description of drawings
Fig. 1 is the structural representation of pond of the present invention intermediate ion rod water treater.There is shown shell (negative electrode) 1, communicating pipe 2, slip pipe 3, cathode plate 4, solder joint 5, retaining ring 6, circular port 7, annulus 8, anode 9 and the plate 10 of connection slip pipe.
Fig. 2 is installed on synoptic diagram in the pond for this ionic rod water treater.
Fig. 3 is the electrical schematic diagram of the power-supply controller of electric of this ionic rod water treater.
Embodiment
The invention will be further described below in conjunction with accompanying drawing.On principle and experimentally, illustrate earlier.
(1) intermediate ion rod water treater in pond is the producer of single water molecules, line attitude oxygen.The treater of electric field water as a result of trying out in the laboratory, for many years according to ionic rod water treater has the multinomial function of antiscale, scale removal, sterilization, algae removal, inhibition based on following factors.
1, crack the associated water molecule: because water molecules is a polar molecule, according to thermodynamic principles, water molecules does not trend towards showing polarity, and trends towards the minimum stable existence state of energy.Therefore, the different mutual sorption of dipole of polarity forms the associated molecule of putting upside down each other, also can be the sorptions end to end each other of three water moleculess, can also form longer moisture subchain.Under no external force effect, water molecules is many to be existed in these association modes.A little less than its suction, when external force is applied on the associated water molecule, be easy to make the associated water molecule to crack into single water molecules.After leaving electric field, single water molecules can return to the association state again the partition time.Be called working lipe during this period of time.Single water molecules flows to the there just and right over there brings into play its function in working lipe.
It is relevant to crack associated water molecule same electric field intensity.Water is applied electrical forces, as long as this power is enough powerful, the associated molecule structure of water is cracked, discerp original association existing way, and form single polar water molecules, polar water molecules is just being pressed in electric field, negative pole aligns in proper order, produce the intensive wall that becomes, when containing dissolved salts in the water, the negative ions of these salts also will be surrounded by the water dipole, form the atmosphere (or group) of hydrate molecule, and by positive and negative series arrangement in the dipole subgroup, can not free movement, water molecules always arrives wall earlier under the effect of electrical forces, other ion and silt particulate are difficult for depositing near wall, thereby have prevented the incrustation scale generation.
Strength of electric field can be calculated: in the reality trial run, in the water treatment preferably always of effects such as antiscale, the product working current is 18 amperes, and current density is 1.0-1.4mA/cm
2, such strength of current and current density are moved and can be kept water conditioning, and the electrical forces that this strength of current produced is the optimum value that cracks the associated water molecule, produces single water molecules.
Above calculation result draws in practice, if change strength of current, 18A is become 12A, approximately about two weeks, finds that at first moss manifests, and sampling analysis finds that total plate count raises.
2, water excites down at electric field, a large amount of unbound electrons can occur in the water, and these unbound electrons are absorbed the back by oxygen and easily generate O
2 -, H
2O
2Etc. attitude oxygen.Line attitude oxygen not only has the function of sterilization, algae removal, and porous makes in the dirt layer it loose gradually and come off, thereby also has the function of scale removal.
O
2+ e
-→ 2O+e
-Reversible reaction
3O → O
3The oxidable one-tenth ozone of Sauerstoffatom, ozone is instability oxygen again extremely
Change into oxygen molecule: O
3+ O → 2O
2
O
2+e
-→O
2 - O
2 -+e
-→O
2 2-
O
2 2-+ H
++ e
-→ HO
2Reversible
O
2+ 2H
++ 2e
-→ H
2O
2Reversible
Above-listed O
2 2-, H
2O
2, OH, O
3, HO
2Deng being called line attitude oxygen.According to biology department of Nanjing University experimental result, materials such as line attitude oxygen break microorganism wall, and protoplasma flows out and death.To the kill rate of oblique living scenedemine, can reach 100% in 14 days; To the colibacillary sterilizing rate of dust Xi Shi, behind 6.5h, reach 92.9%.
In the water treatment of production project, done strength of electric field with the test of handling effect relation, measurement result to dissolved oxygen in experiment shows, strength of electric field is big, dissolved oxygen decline (being ionized to line attitude oxygen) gets soon, and can observe ion-bar water and handle the bubble of emerging on the water surface of top, if in breadboard stationary water, can find out that more the image of bubble " smog " on the anode bar is the same.Electric current is big, and " smog " is dense and close.The people is also arranged having or not the water treatment effect to link up.By above-mentioned, can treat as the ion-bar water processing is single water molecules and line attitude oxygengenerator.
(2), in the ionic rod water treater DC electric field, redox reaction takes place, can reduce water hardness: in the DC electric field of treater, the charge movement direction is by just to negative.After recirculated water flowed into electric field, the negative ions in the water moved to the direction of opposite charge separately, and positive ions such as calcium, magnesium are adsorbed by negative electrode and become precipitate with near negative ion formation salts such as carbonate.The quality m of precipitate with conduction time t and electric current I be directly proportional:
m＝Kit＝Kq
K is a proportionality constant in the formula, is called electrochemical equivalent, and its numerical value is along with being separated out substance classes and difference.In actual motion, once the precipitate to several water treatment projects carried out moisture weighing.
Example 1: quantity of circulating water 600m
3/ h, total hardness 60mg/L tried out 3 months, and an ion bar treater is separated out substance weight (moisture) and is: 84Kg.Three treater eutectoid go out: 252Kg.
Example 2:5600m
3/ h quantity of circulating water, total hardness 160mg/L moves 3 months, and it is 185Kg that an ionic rod water treater is separated out substance weight (moisture).Two ion bar eutectoid go out 370Kg.
(3) electrostatic repulsion effect: negativity increases between the particulate of saline crystallization because electric field action makes, electrical repulsion between particulate increases, thereby be agglomerated into dirty face deposition between the obstruction particulate, the polar water sorption is in lime carbonate crystallite surface, form the micelle or the crystallite of the polar water molecules encirclement of band same-sign, make each other and refuse, thereby the dissemination of playing prevents the combination of hardness salt and the growth of incrustation scale crystallite.
(4) crystal distortion: after the electric field treatment, the crystal angle face changes, and the crystal that forms salt crust distorts.Electron microscopy observation lime carbonate and calcium sulphate crystal pattern are found, without electric field treatment, amplify 1000 times, and as seen the crystalline structure form is clear locates the crystal rule; Dirty shape is amplified 2000 times after electric field treatment, forms loose, random bulk.Explanation hinders and has destroyed the crystalline normal growth after electric field treatment, has suppressed crystalline growth velocity, thereby reduces and prevent the deposition of dirt.
Simultaneously, water is at a large amount of unbound electron of generation under the effect that intensifies of electric field, and these unbound electrons are by O
2Absorb the back and easily generate O
2 -And H
2O
2Deng material microorganism wall is broken, protoplasma flows out and death.Thereby electric field treatment also has sterilization, algae removal effect.Someone is through experiment, and electric field can reach 100% in 14 days to the kill rate of oblique living scenedemine; To the colibacillary kill rate of dust Xi Shi, reach 92.9% after 6.5 hours.Because of dissolved oxygen reduces, slowed down oxidation corrosion again; Because of the bacterium algae is killed, suppressed biological corrosion again.See also Fig. 1, this pond intermediate ion rod water treater is drum shape steel overcoat to be supported communicating pipe 2 sidewalls have the circular port 7 that is connected with water return outlet or water outlet in the pond, the wall thickness 8mm of communicating pipe 2, communicating pipe 2 nearly upper inner be fixed with retaining ring 6, location ring width 70mm, thick 8mm.Be equipped with slip pipe 3 on retaining ring 6 tops, slip pipe 3 be welded in the inwall of communicating pipe 2, totally 5 of solder joints by solder joint 5.Stainless steel treater shell 1 as negative electrode places slip pipe 3 inner chambers and is shelved on retaining ring 6 tops, and shell is to roll diameter phi 100-1500mm with the 5mm stainless steel.Two titanium alloy cathode plates 4 are welded in shell 1 top, and cathode plate 4 is electrically connected with the output negative pole of power-supply controller of electric.Also be equipped with the annulus 8 that connects slip pipe at slip pipe 3 top outer shrouds.In shell central authorities cylindrical titanizing anode bar 9 is set, diameter phi 200-300mm, its outer passive film that is coated with.Be welded with plate 10 in anode bar 9 upper ends.Plate 10 is electrically connected mutually with the output cathode of power-supply controller of electric.Sun negative electrode diameter ratio is 1: 5, working current 18-22 ampere, current density 1.0-1.4mA/cm
2
This ionic rod water treater is directly installed in the pond, water outlet or the water-in of the round mouth of water treating device being aimed at the pond as Fig. 2 signal are connected, for adapting to pond water return outlet or water outlet height and environment, the round mouth height of communicating pipe of this treater can be adjusted accordingly, or the shape of changing communicating pipe is to adapt to the pond environment.
Said power-supply controller of electric adopts the single-phase rectifier circuit, with the pressure regulation of single-phase voltage regulating device.Single unit system is box sealing inside plant, and pilot lamp, switch and instrument all are loaded on panel, and transformer, voltate regulator, silicon cell, contactor and resistance-capacitance protection all are loaded in the case.The steel plate sealing is arranged all around, all can open or pull down easy access.Its electrical schematic diagram is illustrated in Fig. 3.Select suitable electronic devices and components for use according to the needs of output voltage electric current, this power-supply controller of electric maximum output current is 22 amperes.And this power-supply controller of electric has anti-automatically swash function, i.e. positive and negative electrode negative function.
The inventor recommends following embodiment:
Embodiment 2, the high 4500mm of trimmed size * diameter 250mm, the high 2200mm of anode * diameter 250mm, the high 2600mm of negative electrode * diameter 1250mm, positive negative electrode diameter be than 1: 5,20 amperes of working currents, and electric current is spended 1.2mA/cm in comfort
2
Embodiment 3, the high 6200mm of trimmed size * diameter 300mm, the high 2400mm of anode * diameter 300mm, the high 2800mm of negative electrode * diameter 1500mm, positive negative electrode diameter be than 1: 5,22 amperes of working currents, current density 1.0mA/cm
2
Claims (1)
1. pond intermediate ion rod water treater, comprise negative electrode and anode, it is characterized in that drum shape steel overcoat supports communicating pipe (2) sidewall and has the circular port (7) that is connected with water return outlet or water outlet in the pond, communicating pipe (2) closely upper inner be fixed with retaining ring (6); Be equipped with slip pipe (3) on retaining ring (6) top, be welded in communicating pipe (2) inwall by solder joint (5) slip pipe (3); Stainless steel treater shell (1) as negative electrode places slip pipe (3) inner chamber and is shelved on retaining ring (6) top, and two titanium alloy cathode plates (4) are welded in shell (1) top, and cathode plate (4) is electrically connected with the output negative pole of power-supply controller of electric; Outer shroud also is equipped with annulus (8) at slip pipe (3) top; Central authorities are provided with cylindrical titanizing anode bar (9) at shell (1), are welded with plate (10) in anode bar (9) upper end, and plate (10) is electrically connected with the output cathode of power-supply controller of electric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101115569A CN100564272C (en) | 2005-12-15 | 2005-12-15 | Pond intermediate ion rod water treater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101115569A CN100564272C (en) | 2005-12-15 | 2005-12-15 | Pond intermediate ion rod water treater |
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| Publication Number | Publication Date |
|---|---|
| CN1982227A true CN1982227A (en) | 2007-06-20 |
| CN100564272C CN100564272C (en) | 2009-12-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101115569A Expired - Fee Related CN100564272C (en) | 2005-12-15 | 2005-12-15 | Pond intermediate ion rod water treater |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070228A (en) * | 2010-09-20 | 2011-05-25 | 宝钢工程技术集团有限公司 | Electrochemical processing system for stabilizing water quality of cooling circulating water |
| CN101514324B (en) * | 2009-03-30 | 2011-08-31 | 新奥科技发展有限公司 | Method and device for collecting micro-algae |
| CN102807270A (en) * | 2011-06-01 | 2012-12-05 | 山东海吉雅环保设备有限公司 | Method for removing dissolved oxygen from water by adding electrons |
| US9079788B2 (en) | 2007-07-12 | 2015-07-14 | Bio Concept, LLC | Reducing waterborne bacteria and viruses by a controlled electric field |
| CN106186504A (en) * | 2016-07-28 | 2016-12-07 | 大庆凯浮化工产品销售有限公司 | The method of compound physical formula sewage sterilization |
| CN106477735A (en) * | 2015-08-24 | 2017-03-08 | 武汉市嘉扬电气有限责任公司 | Water body descaling and antiscaling device and its application |
-
2005
- 2005-12-15 CN CNB2005101115569A patent/CN100564272C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9079788B2 (en) | 2007-07-12 | 2015-07-14 | Bio Concept, LLC | Reducing waterborne bacteria and viruses by a controlled electric field |
| CN101514324B (en) * | 2009-03-30 | 2011-08-31 | 新奥科技发展有限公司 | Method and device for collecting micro-algae |
| CN102070228A (en) * | 2010-09-20 | 2011-05-25 | 宝钢工程技术集团有限公司 | Electrochemical processing system for stabilizing water quality of cooling circulating water |
| CN102807270A (en) * | 2011-06-01 | 2012-12-05 | 山东海吉雅环保设备有限公司 | Method for removing dissolved oxygen from water by adding electrons |
| CN106477735A (en) * | 2015-08-24 | 2017-03-08 | 武汉市嘉扬电气有限责任公司 | Water body descaling and antiscaling device and its application |
| CN106186504A (en) * | 2016-07-28 | 2016-12-07 | 大庆凯浮化工产品销售有限公司 | The method of compound physical formula sewage sterilization |
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| Publication number | Publication date |
|---|---|
| CN100564272C (en) | 2009-12-02 |
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Owner name: SHANGHAI QIANGYUAN WATER TREATMENT TECHNOLOGY CO., Free format text: FORMER OWNER: XIE DOUDOU Effective date: 20110818 Free format text: FORMER OWNER: XIE FENG |
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Effective date of registration: 20110818 Address after: 1301 room 25, No. 258, Lane 200237, waiting Road, Shanghai Patentee after: Shanghai Qiangyuan Water Treatment Technology Co., Ltd. Address before: 338013, a happy village, Liang Shan town, Xinyu, Jiangxi, 402 Co-patentee before: Xie Feng Patentee before: Xie Doudou |
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