CN1962254A - Multi-layer material - Google Patents

Multi-layer material Download PDF

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Publication number
CN1962254A
CN1962254A CN 200610136668 CN200610136668A CN1962254A CN 1962254 A CN1962254 A CN 1962254A CN 200610136668 CN200610136668 CN 200610136668 CN 200610136668 A CN200610136668 A CN 200610136668A CN 1962254 A CN1962254 A CN 1962254A
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China
Prior art keywords
layer
binder course
incorporated
foaming
polyethylene
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Pending
Application number
CN 200610136668
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Chinese (zh)
Inventor
叶宗殷
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Individual
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Individual
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Priority claimed from US11/270,492 external-priority patent/US20060134401A1/en
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Publication of CN1962254A publication Critical patent/CN1962254A/en
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Abstract

A multi-layer material mainly comprises an ionomer resin layer, a first bonding layer, a foam layer, a second bonding layer and a fabric layer. The first bonding layer is heat laminated to the ionomer resin layer. The foam layer made of an expanded polyethylene foam sheet or a blended foam sheet of polyethylene and ethylene vinyl acetate (EVA) is heat laminated to the first bonding layer. Additionally, the second bonding layer is laminated to the foam layer and the fabric layer is laminated to the second bonding layer. Furthermore, the first bonding layer is preferably a copolymer layer/agent and the second bonding layer is preferably an adhesive layer or a polyethylene layer.

Description

Multilayer material
Technical field
The present invention relates to a kind of field of composite, refer to a kind of manufacturing that is applied in casing especially, for example suitcase, luggage case, tool box, acoustic flat etc. also can be used as the material of making liner, mat, toy, sack or movement entertainment articles for use.
Background technology
For the manufactured materials demand of casings such as suitcase, luggage case, it mainly is to stress in light weight, structure toughness to reach low cost by force.Generally speaking, tank materials such as traditional suitcase, luggage case mostly are metallic composite, are characterized in firm in structure but weight is light and cost is high; The tank material that other is known is to make with the plastic material of multilayer, though such practice has reached light weight and advantages of cheap price, is not enough with regard to structural strength in fact with regard to metallic composite; For example a kind of acrylonitrile-butadiene-phenylethylene (acrylonitrilebutadiene styrene, ABS) material that is usually used in making suitcase or luggage case.This ABS material itself has antiwear characteristic, but its wear-resistant power is limited.Moreover the luggage case that utilizes the ABS material to make causes being out of shape or edge break because of being impacted easily in course of conveying.
On the other hand, multilayer material also is used in the manufacturing of sports equipment, such as the movement entertainment skin of plate, at United States Patent (USP) 5,211, to have the pattern of indentations crust promptly be an example to disclosed foam core structure in 593, and this crust is the surface that is used for being incorporated into this foamed core layer, and it has the plastic layer of multilayer.In addition, United States Patent (USP) 6,908,351 more disclose a kind of movement entertainment plate with combined type multilayer crust; Basically, its each crust is respectively to be formed by stacking by one deck polyolefine material, layer of polyethylene foaming material and one deck polystyrene and poly mixed foaming material.
Summary of the invention
The object of the present invention is to provide a kind of assembly light weight, the firm multilayer material cheaply that reaches.This multilayer material can not only be used as different casing manufacturings, as suitcase, luggage case or tool box etc.; Also can be used to manufacture liner, mat, toy, sack or sporting goods etc.
The object of the present invention is achieved like this, and a kind of multilayer material comprises:
One ionic bond polymer resin layer;
One first binder course is incorporated into this ionic bond polymer resin layer;
One foaming layer is incorporated into this first binder course;
One second binder course is incorporated into this foaming layer;
One layer of cloth is incorporated into this second binder course.
This foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
This foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
This foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
This foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
A kind of multilayer material comprises:
One thermoplastic elastomer layer;
One first binder course is incorporated into this thermoplastic elastomer layer;
One foaming layer is incorporated into this first binder course;
One second binder course is incorporated into this foaming layer;
One layer of cloth is incorporated into this second binder course.
This thermoplastic elastomer layer comprises a thermoplastic poly potassamide acid esters.
A kind of multilayer material comprises:
One ionic bond polymer resin layer;
One binder course is incorporated into this ionic bond polymer resin layer;
One visible pattern layer is incorporated into this binder course;
One foaming layer is incorporated into this visible pattern layer.
This visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil is incorporated into this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is a polyethylene foam layer, and this binder course is a copolymer layer.
This visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil is incorporated into this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this binder course is a copolymer layer.
More comprise a layer of cloth, be bonding on this foaming layer by a mucigel.
More comprise a layer of cloth, be incorporated into this foaming layer by a polyethylene layer.
A kind of multilayer material comprises:
One ionic bond polymer resin layer;
One visible pattern layer is incorporated into this ionic bond polymer resin layer;
One binder course is incorporated into this visible pattern layer;
One foaming layer is in conjunction with this binder course.
From the above mentioned, multilayer material of the present invention mainly has an ionic bond polymer resin layer, the transparent characteristic free from worldly cares of this ionic bond polymer resin layer tool antifriction scrape along, and the present invention more can utilize a kind of thermoplastic elastomer (thermoplastic rubber, TPR), a thermoplastic poly potassamide acid esters (thermoplastic polyurethane for example, TPU) layer, replace this ionic bond polymer resin layer, because of TPR have processing simple, easily with other multiple material allocate utilization, plasticity height, with and the returnable characteristic of waste material flash; And TPU material of the present invention has very high resistance to tearing, low temperature flexibility and rub resistance.Therefore, multilayer material of the present invention has light weight, the firm characteristics cheaply that reach.When multilayer material of the present invention was applied in the actual product, more can add one can be by the color layer or the patterned layer of outward appearance perspective, and it can be superimposed middle to improve the product aesthetic property in this foaming layer and this first binder course.
Description of drawings
Fig. 1: the multilayer material schematic diagram of the present invention's first most preferred embodiment.
Fig. 2: the multilayer material profile of the present invention's first most preferred embodiment.
Fig. 3: the multilayer material schematic diagram of the present invention's second most preferred embodiment shows that this multilayer material more comprises a visible pattern layer.
Fig. 4: the patterned layer schematic diagram of the present invention's second most preferred embodiment shows that this patterned layer comprises two plastic foils and is formed at pattern between this two plastic foil.
Fig. 5: the multilayer material schematic diagram of the present invention's second most preferred embodiment shows that this patterned layer is clipped between an ionic bond polymer resin layer and one first binder course.
Drawing reference numeral:
1,1a multilayer material
10,10a ionic bond polymer resin layer
11,11a first binder course
12,12a foaming layer
13,13a second binder course
14,14a layer of cloth
15 patterned layer
150 patterns
151 first plastic foils
152 second plastic foils
The specific embodiment
See also Fig. 1 and Fig. 2, one first preferred embodiment of the present invention, it shows that a kind of multilayer material 1 has an ionic bond polymer resin layer 10, one first binder course 11, a foaming layer 12, one second binder course 13 and a layer of cloth 14.As shown in Figure 1, these first binder course, 11 hot bindings are in the lower surface of this ionic bond polymer resin layer 10; Wherein, this ionic bond polymer resin layer 10 is made sarin (Surlyn) product of producing for E.I.Du Pont Company, and these ionic bond polymer resin layer 10 thickness are about 0.1~2 millimeter; In addition, 12 hot bindings of this foaming layer are in this first binder course 11, and foaming layer 12 of the present invention is a polyethylene foam material that expanded or a polyethylene and ethylene-vinyl acetate (ethylene vinyl acetate, EVA, be commonly called as rubber glue) the mixed foaming material, and foaming layer of the present invention 12 only is not limited to and can only uses above-mentioned material; Moreover the best of this foaming layer 12 foaming density is between 1.5~12PCF, and its optimum thickness is between 1~6 millimeter.In addition, preferably a kind of copolymer/medium of this first binder course 11 (copolymer/agent), be used for this ionic bond polymer resin layer 10 of thermal and this foaming layer 12, and this first binder course 11 pushes and coats this foaming layer 12 earlier in the hot pressing Cheng Qian.The thickness of this first binder course 11 is about 0.01~0.1 millimeter, and the preferred thickness condition is 0.03~0.05 millimeter.
In addition, 13 of this second binder courses are incorporated into this foaming layer 12, and this layer of cloth 14 is incorporated into this second binder course 13 more at last.Wherein, second binder course 13 of the present invention can be that a kind of mucigel or polyethylene layer are used for making this foaming layer 12 to cohere with these layer of cloth 14 rerum naturas.When using this polythene material to be used as second binder course 13, this polyethylene layer then thermal is bonded in this layer of cloth 14 in this foaming layer 12 and rerum natura.Further, about 0.03~0.3 millimeter of the thickness of this second binder course 13, and this layer of cloth 14 is a kind of elastomeric materials, as weave cotton cloth, knitted fabric, velvet or nylon weaves cotton cloth.
More particularly, the transparent characteristic free from worldly cares of these ionic bond polymer resin layer 10 tool antifriction scrape alongs in this multilayer material 1, and the present invention more can utilize a kind of thermoplastic elastomer (thermoplastic rubber, TPR), a thermoplastic poly potassamide acid esters (thermoplastic polyurethane for example, TPU) layer, replace this ionic bond polymer resin layer 10, because of TPR have processing simple, easily with other multiple material allocate utilization, plasticity height, with and the returnable characteristic of waste material flash or the like; And TPU material of the present invention has very high resistance to tearing, low temperature flexibility and rub resistance.Certainly, other material also can be used for the present invention, but above-mentioned ionic bond polymer resin layer 10 and TPR layer are applicable to multilayer material 1 of the present invention as the TPU layer.
See also Fig. 3 to Fig. 5, one second preferred embodiment of the present invention, it shows that a multilayer material 1a has an ionic bond polymer resin layer 10a, one first binder course 11a, a visible pattern layer 15, a foaming layer 12a, one second binder course 13a and a layer of cloth 14a.As shown in Figure 3, this first binder course 11a hot binding is in this ionic bond polymer resin layer 10a, that is the lower surface of sarin layer, this patterned layer 15 then thermal and can be seen the pattern of this patterned layer 15 from the outside of this ionic bond polymer resin layer 10a in this first binder course 11a.Moreover this foaming layer 12a hot binding is in this patterned layer 15, and this second binder course 13a then is incorporated into this foaming layer 12a, and last, this layer of cloth 14a is incorporated into this second binder course 13a.
Ionic bond polymer resin layer 10a in the second embodiment of the invention, the first binder course 11a, foaming layer 12a, the second binder course 13a and layer of cloth 14a ionic bond polymer resin layer 10, first binder course 11, foaming layer 12, second binder course 13 and the layer of cloth 14 in first embodiment.As Fig. 3 and shown in Figure 5, unique difference is more to comprise this visible pattern layer 15 at second embodiment.This patterned layer 15 can be assigned between this ionic bond polymer resin layer 10a and this first binder course 11a, or assigns between this foaming layer 12a and this first binder course 11a.In the present invention, preferable position is that this patterned layer 15 is dropped between this foaming layer 12a and this first binder course 11a, in addition, this patterned layer 15 is a color layer that has the individual layer of pattern 150 or have pattern 150, and the utilization of this patterned layer 15 is not limited to only in this.
See also Fig. 4, illustrate that this visible pattern layer 15 comprises one first plastic foil 151, one second plastic foil 152 and pattern 150.This pattern 150 is formed between this first plastic foil 151 and this second plastic foil 152.And this first plastic foil 151 and this second plastic foil 152 are preferably polyethylene film, as long as can be from the outside and see through this ionic bond polymer resin layer and see this pattern 150, no matter transparent, translucent or not even hyaline membrane all can select for use.In addition, this pattern 150 can utilize known printing technology to be formed on this first plastic foil 151 or this second plastic foil 152.In the second embodiment of the present invention, this pattern 150 preferably is printed on these first plastic foil, 151 surfaces, when these second plastic foil, 152 hot bindings behind first plastic foil 151,150 in this pattern is sandwiched between this first plastic foil 151 and this second plastic foil 151.Perhaps, this patterned layer 15 can only comprise a plastic foil and pattern, and this pattern directly is printed on this plastic foil.In addition, this first plastic foil 151 is respectively 0.01~0.15 millimeter with the optimum thickness of this second plastic foil 152.
In sum, the multilayer material 1 among the present invention, 1a can be applicable in the obducent manufacturing of Different Industries, and it has light weight, the firm advantage cheaply that reaches, and add the use of patterned layer 15 among this multilayer material 1a, more can enhance product appearance.

Claims (21)

1. multilayer material is characterized in that comprising:
One ionic bond polymer resin layer;
One first binder course is incorporated into this ionic bond polymer resin layer;
One foaming layer is incorporated into this first binder course;
One second binder course is incorporated into this foaming layer;
One layer of cloth is incorporated into this second binder course.
2. multilayer material as claimed in claim 1 is characterized in that: this foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
3. multilayer material as claimed in claim 1 is characterized in that: this foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
4. multilayer material as claimed in claim 1 is characterized in that: this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
5. multilayer material as claimed in claim 1 is characterized in that: this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
6. multilayer material is characterized in that comprising:
One thermoplastic elastomer layer;
One first binder course is incorporated into this thermoplastic elastomer layer;
One foaming layer is incorporated into this first binder course;
One second binder course is incorporated into this foaming layer;
One layer of cloth is incorporated into this second binder course.
7. multilayer material as claimed in claim 6 is characterized in that: this foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
8. multilayer material as claimed in claim 6 is characterized in that: this foaming layer is a polyethylene foam layer, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
9. multilayer material as claimed in claim 6 is characterized in that: this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a mucigel.
10. multilayer material as claimed in claim 6 is characterized in that: this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this first binder course is a copolymer layer, and this second binder course is a polyethylene layer.
11. multilayer material as claimed in claim 6 is characterized in that: this thermoplastic elastomer layer comprises a thermoplastic poly potassamide acid esters.
12. a multilayer material is characterized in that comprising:
One ionic bond polymer resin layer;
One binder course is incorporated into this ionic bond polymer resin layer;
One visible pattern layer is incorporated into this binder course;
One foaming layer is incorporated into this visible pattern layer.
13. multilayer material as claimed in claim 12 is characterized in that: this visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil is incorporated into this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is a polyethylene foam layer, and this binder course is a copolymer layer.
14. multilayer material as claimed in claim 12 is characterized in that: this visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil is incorporated into this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this binder course is a copolymer layer.
15. as claim 13 or 14 described multilayer materials, it is characterized in that: more comprise a layer of cloth, be bonding on this foaming layer by a mucigel.
16. as claim 13 or 14 described multilayer materials, it is characterized in that: more comprise a layer of cloth, be incorporated into this foaming layer by a polyethylene layer.
17. a multilayer material is characterized in that comprising:
One ionic bond polymer resin layer;
One visible pattern layer is incorporated into this ionic bond polymer resin layer;
One binder course is incorporated into this visible pattern layer;
One foaming layer is in conjunction with this binder course.
18. multilayer material as claimed in claim 17 is characterized in that: this visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil is incorporated into this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is a polyethylene foam layer, and this binder course is a copolymer layer.
19. multilayer material as claimed in claim 17 is characterized in that: this visible pattern layer comprises:
One first plastic foil;
Pattern is formed on the surface of this first plastic foil;
One second plastic foil in conjunction with this first plastic foil, has the surface of this pattern with covering;
Wherein, this foaming layer is the mixed foaming layer of a polyethylene and ethylene-vinyl acetate, and this binder course is a copolymer layer.
20. as claim 18 or 19 described multilayer materials, it is characterized in that: more comprise a layer of cloth, be bonding on this foaming layer by a mucigel.
21. as claim 18 or 19 described multilayer materials, it is characterized in that: more comprise a layer of cloth, be incorporated into this foaming layer by a polyethylene layer.
CN 200610136668 2005-11-10 2006-11-09 Multi-layer material Pending CN1962254A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/270,492 US20060134401A1 (en) 2004-12-20 2005-11-10 Multi-layer material
US11/270,492 2005-11-10

Publications (1)

Publication Number Publication Date
CN1962254A true CN1962254A (en) 2007-05-16

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Application Number Title Priority Date Filing Date
CN 200610136668 Pending CN1962254A (en) 2005-11-10 2006-11-09 Multi-layer material

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CN (1) CN1962254A (en)
TW (1) TWI270461B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102729530A (en) * 2012-06-14 2012-10-17 英特普制品有限公司 Protection pad and preparation method thereof
CN102950854A (en) * 2011-08-10 2013-03-06 叶宗殷 Multilayer foamed structure and application product thereof
WO2015161481A1 (en) * 2014-04-24 2015-10-29 The Procter & Gamble Company Bag made from a foamed film laminate

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102950854A (en) * 2011-08-10 2013-03-06 叶宗殷 Multilayer foamed structure and application product thereof
CN102950854B (en) * 2011-08-10 2015-11-18 叶宗殷 Multilayer foamed structure and application product thereof
CN102729530A (en) * 2012-06-14 2012-10-17 英特普制品有限公司 Protection pad and preparation method thereof
CN102729530B (en) * 2012-06-14 2015-06-24 英特普制品有限公司 Protection pad and preparation method thereof
WO2015161481A1 (en) * 2014-04-24 2015-10-29 The Procter & Gamble Company Bag made from a foamed film laminate

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Publication number Publication date
TWI270461B (en) 2007-01-11
TW200718557A (en) 2007-05-16

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Open date: 20070516