CN1931980A - Process of preparing lubricant for hardware production - Google Patents
Process of preparing lubricant for hardware production Download PDFInfo
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- CN1931980A CN1931980A CN 200610062965 CN200610062965A CN1931980A CN 1931980 A CN1931980 A CN 1931980A CN 200610062965 CN200610062965 CN 200610062965 CN 200610062965 A CN200610062965 A CN 200610062965A CN 1931980 A CN1931980 A CN 1931980A
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Abstract
The present invention relates to environment protection and vegetable oil extracting technology, and is especially the process of esterifying vegetable oil in a microwave synthesizer to produce fatty alcohol amine ester used as lubricant. The microwave synthesis process is performed at normal temperature and normal pressure, uses no catalyst, produces no pollutant and has conversion rate as high as 95.5 %.
Description
Technical field
The present invention relates to environment protection, vegetables oil refinement technique field, refer in particular to a kind of vegetables oil that utilizes and in microwave synthesizer, carry out the method for esterification reaction production lipid acid hydramine fat as lubricant.
Background technology
Modern mechanical processing at a high speed, powerful, accurate direction develops, the development of difficult-to-machine materials such as superhard, super-strength also makes the difficulty of machining increase day by day.The reason of this two aspect causes frictional force, the heat of friction in the cutting process to increase substantially, and this just requires metal working fluid to have better lubricated, cooling, cleaning, rustless property, so that obtain the ideal finished surface.Mineral lubricating oils lubricated, rustless property is superior, but cooling, cleaning performance are poor; Cooling, the cleaning performance of emulsion and water-base cutting fluid are good, but lubricated, rustless property is poor.Water-base cutting fluid is except that all properties with emulsion, and it is lubricated, cooling, rustless property also reached and surpass outside all properties of emulsion, the standard-required that it is lubricated, cooling, rustless property also meet or exceed emulsion.Thereby water-base cutting fluid has become the developing direction that improves processing characteristics in the domestic and international mechanical workout.The present water-base cutting fluid that adopts, mainly be to adopt chemical synthesis, produce band hydrophilic radical hydrocarbon alkane thing, the lubricant of water is dissolved in formation, but the production one of this compounds is that material cost is higher, the 2nd, need conditions such as catalyzer, temperature, pressure and rare gas element in the chemical combination process, cause that cost is excessive, contaminate environment, the low inferior major defect of yield rate.
Summary of the invention
Purpose of the present invention is exactly to propose a kind of by the method for vegetable oil production lipid acid hydramine fat as lubricant at above-mentioned situation.
For achieving the above object, the present invention is reactant, adds oleic acid as conditioning agent with vegetables oil and hydramine, carries out esterification reaction in microwave synthesizer, i.e. lipid acid hydramine fat; Hydramine mole number wherein: the vegetables oil average mol is 0.3-4.5: 1, the oleic acid of 1-3.9 part carries out the raw materials of compound formulation ratio as conditioning agent by weight, through sent out in 1-30 minute should after, promptly obtain the pure amine fat of lipid acid, separate desired product and purifying subsequently, its production process and processing condition are:
A) above-mentioned formulation ratio is finished after, the stirrer that utilizes rotating speed 300-3200 rev/min was with raw material stirring 15-90 minute;
B) stirring the raw material finish enters and reacted at normal temperatures and pressures in the 600W-1800W microwave synthesizer 1-30 minute;
C) react the goods of finishing and be cooled to room temperature;
D) deionized water of the 50%-500% of product weight stirs at a slow speed and adds above-mentioned finished product, and add the defoamer of 0.3-5%, the oxidation inhibitor of 0.1-10% stirs more than 15 minutes, separate the milky white color fat in upper strata and separate as lubricating grease, all the other are the finished product.
Do not need any catalyzer in the reaction process.
Described vegetables oil is one or more the mixture in rapeseed oil, Semen Maydis oil, peanut oil, sweet oil, Thistle oil, soybean oil, Trisun Oil R 80, plam oil, the tip water oil.
Described hydramine is to have list, two, three and the hydramine of many thanomins functional group.
Adopt of the present invention method, directly adopt vegetables oil as raw material, building-up process is used microwave method, carries out under the normal temperature and pressure atmospheric condition, does not use catalyzer, does not produce pollutent, and finished product transformation efficiency high energy arrives 95.5%.Overcome in the existing chemical combination process need that catalyzer, cost are big, contaminate environment, defective that yield rate is low.Because the plant main body of oil is fatty acid ester (comprising saturated and unsaturated composition).The molecular formula of fatty acid ester can be expressed as follows:
R wherein
1, R
2, R
3Be identical or different fatty acid chains.In vegetables oil, saturated fatty acid contains 22 carbon atoms, the carbon atom number from 10 to 22 of single unsaturated link(age) lipid acid, and two carbon atom numbers unsaturated and three unsaturated fatty acidss are generally 18.Bandit's acid and different linolic acid and linolenic acid etc. of in vegetable fatty acids, containing lauric acid, the 0.3-0.7% of 0.1-0.8%.Method of the present invention is utilized lipid acid (mainly being unsaturated fatty acids) and hydramine esterification reaction, forms water miscible group on the lipid acid segment; Utilize lauric acid, bandit acid and hydramine reaction to produce nonionogenic tenside, thereby very easily finish water-solubleization of vegetables oil, and reduced the second-order transition temperature of lipid acid, make the new system of formation satisfy functional requirements such as lubricated, cooling, anti-embroidery.
1) product lubricity of the present invention is good: in metal cutting processing, the great majority friction belongs to the boundary lubrication friction.In boundary lubrication, owing to there is not oil film completely, its supporting capacity is irrelevant with oil viscosity, and depends on the oiliness of lubricating fluid, and whether promptly lubricated composition is comprising the atomic group that metal is existed strong adsorption, can form the physical adsorption film at the cutting interface.In the present invention was synthetic, lauric acid, bandit's acid etc. formed nonionogenic tenside, and the polar group in its nonionogenic tenside has bigger affinity ability to metal, were easy to be adsorbed on the metallic surface, formed adsorbed lubricating film.Because of its hydrophobic grouping is bigger, has the effect of oiliness improver.Can prevent or reduce the direct contact between workpiece, cutting, the cutter, reach reduce the friction and the agglutinating purpose, play fabulous lubrication.
The lipid acid hydramine is a kind of cats product, is added in the cutting fluid as oiliness improver, easily forms the physical adsorption film between sword and cutting workpiece, thus the lubrication of playing.In addition, fatty acid ethanolamide amine and extreme pressure anti-wear additives also have good collaborative wear-resistant effect, and lubricity is significantly improved.
2) cleaning performance is good: the quality of cutting fluid cleaning performance, be closely related with cutting fluid penetration and flowability, and surface tension is low, the cutting fluid of perviousness and good fluidity, and cleaning performance is all right.
In the novel water-based cutting fluid because the existence of not low nonionogenic tenside of content and cats product lipid acid hydramine is arranged, the two coordinative role, greatly reduce the surface tension of cutting fluid, strengthened the perviousness and the flowability of cutting fluid significantly.Thereby has a good cleaning performance.
3) cooling performance is good: the cooling effect of cutting fluid, depend on its thermal conductivity, specific heat, vaporization heat and vaporization rate etc.The thermal conductivity of water is 3~5 times of oil, and specific heat is 2~2.5 times of oil, and the cooling performance of Gu Shui is superior more a lot of than oil.Contain the moisture more than 90% in the novel water-based cutting fluid, so cooling performance is outstanding.
4) good antirust property: nonionogenic tenside itself has anti-the embroidery and preservative activity; produce the composite synergistic effect with the lipid acid hydramine; form the absorption protective film in the metallic surface; passivation film; thereby blocked the cathode and anode corrosion process; because fine and close mulch film is arranged, and the infiltration that can resist water molecules, oxygen and other corrosivess in the medium effectively has good anticorrosion, rustless property.
Embodiment
The present invention is a kind of by the method for vegetable oil production lipid acid hydramine fat as lubricant.It is reactant, adds oleic acid as conditioning agent with vegetables oil and hydramine, carries out esterification reaction in microwave synthesizer, i.e. the pure amine fat of lipid acid; Hydramine mole number wherein: the unsaturated fatty acids average mol is 0.3-4.5 in the vegetables oil: 1, the oleic acid of 1-3.9 part carries out the raw materials of compound formulation ratio as conditioning agent by weight, through sent out in 1-30 minute should after, promptly obtain the pure amine fat of lipid acid, separate desired product and purifying subsequently, its production process and processing condition are:
A) above-mentioned formulation ratio is finished after, the stirrer that utilizes rotating speed 300-3200 rev/min was with raw material stirring 15-90 minute;
B) mixing the raw material of finishing enters and reacted at normal temperatures and pressures in the 600W-1800W microwave synthesizer 1-30 minute;
C) send out the goods that to finish and be cooled to room temperature;
D) stir at a slow speed with the deionized water of the 50%-500% of product weight and add above-mentioned finished product, and add the defoamer of 0.3-5%, the oxidation inhibitor of 0.1-10% stirs more than 15 minutes, separate the milky white color fat in upper strata and separate as lubricating grease, all the other are the finished product.
E) get final product the finished product.
Do not need any catalyzer in the reaction process.
Described vegetables oil is one or more the mixture in rapeseed oil, Semen Maydis oil, peanut oil, sweet oil, Thistle oil, soybean oil, Trisun Oil R 80, plam oil, the tip water oil.
Described hydramine is to have list, two, three and the hydramine of many thanomins functional group.
Following structure embodiment is described in further details the present invention: embodiment one.Take by weighing plam oil 50 grams, analyzing its monounsaturated fatty acids is 19.5 grams, polyunsaturated fatty acid 5 grams, add 49.2 gram trolamines, add 5 gram oleic acid, it is blended in the beaker, with Building 300/minute agitator stirred 15 minutes, insert in the household microwave oven and reacted 10 minutes, be cooled to 50 ℃, add antioxidant BHT 0.8 gram, deionized water 105 grams, FOAM BANMS-293 defoamer 0.6 gram, 300 rev/mins were stirred 15 minutes, and left standstill and be cooled to room temperature, after top layer smectic thing separated, weighing obtained finished product 176 grams.Detect through INFRARED SPECTRUM, isolating smectic thing does not contain unsaturated fatty acids, yet can transform yield rate and has reached more than 95.5% by calculating in the plam oil unsaturated fatty acids.The transparent no floss of the said products, sediment-free produce, and detect after water dilutes 20 times, meet the standard-required of GB3392/T, leading indicator:
Test event | Standard-required | Measured result | |
Diluent: concentrated solution+distilled water=1+20 (V/V) | |||
Transparency | Transparent or semitransparent | Transparent | |
PH value | 8-10.0 | 8.0 | |
Corrosion test h | The one-level grey cast iron | 24h | The A level |
Red copper | 8h | The B level | |
LY12 aluminium | 8h | The A level | |
Rust prevention test h | Monolithic | 24 | The A level |
Lamination | 8 | The A level | |
Last non seizure load Ps, Kg | ≥40 | 78 |
Embodiment two.Take by weighing Canola Oil 50 grams, analyzing its monounsaturated fatty acids is 31 grams, polyunsaturated fatty acid 16 grams, add 99 gram trolamines, add 5 gram oleic acid, it is blended in the beaker, with Building 300/minute agitator stirred 15 minutes, insert in the household microwave oven and reacted 10 minutes, be cooled to 50 ℃, add antioxidant BHT 1.5 grams, deionized water 225 grams, FOAM BAN MS-293 defoamer 1.2 grams, 300 rev/mins were stirred 15 minutes, and left standstill and be cooled to room temperature, after top layer smectic thing separated, weighing obtained finished product 377 grams.Detect through INFRARED SPECTRUM, isolating smectic thing does not contain unsaturated fatty acids, yet can transform yield rate and has reached more than 95.5% by calculating in the plam oil unsaturated fatty acids.
Water detects after diluting 20 times, meets the standard-required of GB3392/T.Leading indicator is as follows:
Test event | Standard-required | Measured result | |
Diluent: concentrated solution+distilled water=1+20 (V/V) | |||
Transparency | Transparent or semitransparent | Transparent | |
PH value | 8-10.0 | 8.0 | |
Corrosion test h | The one-level grey cast iron | 24h | The A level |
Red copper | 8h | The A level | |
LY12 aluminium | 8h | The A level | |
Rust prevention test h | Monolithic | 24 | The A level |
Lamination | 8 | The A level | |
Last non seizure load Ps, Kg | ≥40 | 80 |
Embodiment three.Take by weighing hogwash fat 50 grams, detecting its monounsaturated fatty acids is 31 grams, polyunsaturated fatty acid 16 grams, add 33 gram trolamines, diethanolamine 19 grams, add 5 gram oleic acid, it is blended in the beaker, with Building 300/minute agitator stirred 15 minutes, insert in the household microwave oven and reacted 10 minutes, be cooled to 50 ℃, add antioxidant BHT 1.5 grams, deionized water 225 grams, FOAM BAN MS-293 defoamer 1.2 grams, 300 rev/mins were stirred 15 minutes, leave standstill and be cooled to room temperature, after top layer smectic thing was separated, weighing obtained finished product 315 grams.Detect through INFRARED SPECTRUM, isolating smectic thing does not contain unsaturated fatty acids, yet can transform yield rate and has reached more than 95.5% by calculating in the plam oil unsaturated fatty acids.
Water detects after diluting 20 times, meets the standard-required of GB3392/T.Leading indicator is as follows:
Test event | Standard-required | Measured result | |
Diluent: concentrated solution+distilled water=1+20 (V/V) | |||
Transparency | Transparent or semitransparent | Transparent | |
PH value | 8-10.0 | 8.0 | |
Corrosion test h | The one-level grey cast iron | 24h | The A level |
Red copper | 8h | The B level | |
LY12 aluminium | 8h | The A level | |
Rust prevention test h | Monolithic | 24 | The A level |
Lamination | 8 | The A level | |
Last non seizure load Ps, Kg | ≥40 | 69 |
By the foregoing description as can be known, according to the product that the inventive method obtains, its lubricity, cleaning performance, cooling performance and rustless property are significantly improved than other lubricants when using in five metals processing.
Claims (4)
1, a kind of method for preparing lubricant for hardware production is characterized in that: be reactant, add oleic acid as conditioning agent with vegetables oil and hydramine, carry out esterification reaction in microwave synthesizer, i.e. lipid acid hydramine fat; Hydramine mole number wherein: the unsaturated fatty acids average mol is 0.3-4.5 in the vegetables oil: 1, the oleic acid of 1-3.9 part carries out the raw materials of compound formulation ratio as conditioning agent by weight, after reaction in 1-30 minute, promptly obtain lipid acid hydramine fat, separate desired product and purifying subsequently, its production process and processing condition are:
A) above-mentioned formulation ratio is finished after, the stirrer that utilizes rotating speed 300-3200 rev/min was with raw material stirring 15-90 minute;
B) stirring the raw material finish enters and reacted at normal temperatures and pressures in the 600W-1800W microwave synthesizer 1-30 minute;
C) goods that reaction is finished are cooled to room temperature;
D) stir at a slow speed with the deionized water of the 50%-500% of product weight and add above-mentioned finished product, and add the defoamer of 0.3-5%, the oxidation inhibitor of 0.1-10% stirs more than 15 minutes, left standstill 30 minutes, the milky white color fat in upper strata is separated as lubricating grease, and the transparent liquid of remaining yellow or red-brown is the finished product.
2, a kind of method for preparing lubricant for hardware production according to claim 1 is characterized in that: do not need any catalyzer in the reaction process.
3, a kind of method for preparing lubricant for hardware production according to claim 1 is characterized in that: described vegetables oil is rapeseed oil, Semen Maydis oil, peanut oil, sweet oil, Thistle oil, soybean oil, Trisun Oil R 80, plam oil, the mixture of one or more in the water oil slightly.
4, a kind of method for preparing lubricant for hardware production according to claim 1 is characterized in that: described hydramine is to have list, two, three and the hydramine of many thanomins functional group.
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CN 200610062965 CN1931980A (en) | 2006-09-29 | 2006-09-29 | Process of preparing lubricant for hardware production |
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Cited By (14)
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US20110083956A1 (en) * | 2008-04-04 | 2011-04-14 | Clariant Finance (Bvi) Limited | Continuous Method For Producing Fatty Acid Alkanol Amides |
CN102260170A (en) * | 2011-06-02 | 2011-11-30 | 浙江大学 | Method for microwave pipeline production of butyl acetate |
CN102337177A (en) * | 2011-08-24 | 2012-02-01 | 中国林业科学研究院木材工业研究所 | Environmentally-friendly type antisticking cooling liquid for wood sawing processing and preparation method thereof |
CN101407747B (en) * | 2007-10-11 | 2012-02-22 | 中国石油化工股份有限公司 | Microwave modified vegetable oil |
CN101628876B (en) * | 2008-07-15 | 2012-07-04 | 南京理工大学 | Method for synthesizing ionic liquid of ethanolamine lactate |
CN101679895B (en) * | 2007-04-25 | 2013-10-02 | 陶氏环球技术有限责任公司 | Lubricant blend composition |
CN104031718A (en) * | 2014-06-19 | 2014-09-10 | 天津舜能化学品有限公司 | Aliphatic amine ester boride lubricating oil additive and preparation method thereof |
US8884040B2 (en) | 2008-04-04 | 2014-11-11 | Clariant Finance (Bvi) Limited | Continuous method for producing fatty acid amides |
US8974743B2 (en) | 2009-06-30 | 2015-03-10 | Clariant Finance (Bvi) Limited | Device for continuously carrying out chemical reactions at high temperatures |
US9000197B2 (en) | 2009-09-22 | 2015-04-07 | Clariant Finance (Bvi) Limited | Continuous transesterification method |
US9039870B2 (en) | 2006-10-09 | 2015-05-26 | Clariant Finance (Bvi) Limited | Method for producing alkaline (meth)acrylamides |
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US9243116B2 (en) | 2010-12-30 | 2016-01-26 | Clariant International Ltd. | Method for modifying polymers comprising hydroxyl groups |
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Cited By (17)
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US9039870B2 (en) | 2006-10-09 | 2015-05-26 | Clariant Finance (Bvi) Limited | Method for producing alkaline (meth)acrylamides |
CN101679895B (en) * | 2007-04-25 | 2013-10-02 | 陶氏环球技术有限责任公司 | Lubricant blend composition |
CN101407747B (en) * | 2007-10-11 | 2012-02-22 | 中国石油化工股份有限公司 | Microwave modified vegetable oil |
US8884040B2 (en) | 2008-04-04 | 2014-11-11 | Clariant Finance (Bvi) Limited | Continuous method for producing fatty acid amides |
US20110083956A1 (en) * | 2008-04-04 | 2011-04-14 | Clariant Finance (Bvi) Limited | Continuous Method For Producing Fatty Acid Alkanol Amides |
CN101628876B (en) * | 2008-07-15 | 2012-07-04 | 南京理工大学 | Method for synthesizing ionic liquid of ethanolamine lactate |
US8974743B2 (en) | 2009-06-30 | 2015-03-10 | Clariant Finance (Bvi) Limited | Device for continuously carrying out chemical reactions at high temperatures |
US9000197B2 (en) | 2009-09-22 | 2015-04-07 | Clariant Finance (Bvi) Limited | Continuous transesterification method |
US9302245B2 (en) | 2009-09-22 | 2016-04-05 | Clariant International Ltd. | Apparatus for continuously carrying out heterogeneously catalyzed chemical reactions at elevated temperatures |
US9221938B2 (en) | 2010-12-30 | 2015-12-29 | Clariant Finance (Bvi) Limited | Polymers carrying hydroxyl groups and ester groups and method for the production thereof |
US9243116B2 (en) | 2010-12-30 | 2016-01-26 | Clariant International Ltd. | Method for modifying polymers comprising hydroxyl groups |
CN102260170B (en) * | 2011-06-02 | 2014-10-15 | 浙江大学 | Method for microwave pipeline production of butyl acetate |
CN102260170A (en) * | 2011-06-02 | 2011-11-30 | 浙江大学 | Method for microwave pipeline production of butyl acetate |
CN102337177B (en) * | 2011-08-24 | 2013-12-04 | 中国林业科学研究院木材工业研究所 | Environmentally-friendly type antisticking cooling liquid for wood sawing processing and preparation method thereof |
CN102337177A (en) * | 2011-08-24 | 2012-02-01 | 中国林业科学研究院木材工业研究所 | Environmentally-friendly type antisticking cooling liquid for wood sawing processing and preparation method thereof |
CN104031718A (en) * | 2014-06-19 | 2014-09-10 | 天津舜能化学品有限公司 | Aliphatic amine ester boride lubricating oil additive and preparation method thereof |
CN104031718B (en) * | 2014-06-19 | 2016-02-03 | 天津舜能化学品有限公司 | A kind of boronation aliphatic amide ester lubricating additive and preparation method thereof |
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