CN1928540A - Portable smart water quality conductive detection device - Google Patents

Portable smart water quality conductive detection device Download PDF

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Publication number
CN1928540A
CN1928540A CN 200610053633 CN200610053633A CN1928540A CN 1928540 A CN1928540 A CN 1928540A CN 200610053633 CN200610053633 CN 200610053633 CN 200610053633 A CN200610053633 A CN 200610053633A CN 1928540 A CN1928540 A CN 1928540A
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pins
link
water quality
detection device
converter
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CN 200610053633
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CN100485375C (en
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安庆敏
吴明光
吴巍
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The disclosed portable intelligent conductance detector for water quality comprises a SCM connected with a keyboard and a display; a square wave generator connects with a voltage follower, a conductance cell, and an operational amplifier bridge; and a temperature sensor connects with a conductance cell, a signal amplifier, and a capacitor filter. Wherein, every of former members also connect with a multiplex selection switch and an ADC. This invention integrates different technologies, and is convenient and high precise for wide application.

Description

A kind of portable smart water quality conductive detection device
Technical field
The present invention relates to a kind of portable smart water quality conductive device, belong to water quality measurement technology of instrument and meter field.
Background technology
Along with the aggravation of environmental pollution and the development of sewage disposal technology, water quality detection is increasingly important in the status of modern industrial and agricultural production.The water quality conductive instrument of producing adopts ac power supply usually at present, and volume weight is bigger than normal, and inconvenience is carried.The conductivity sensor of conventional electrodes class conductivity meter, its conductance electrode are embedded in two parallel platinized platinums on glass usually, draw two leads from platinized platinum and link to each other with the data processing unit of instrument.This type of conductance electrode is in a single day contaminated, burn into or fouling, and its measuring accuracy will reduce greatly.Based on the conductivity sensor of electromagnetic induction principle, 20 microns Teflons of its external spray (teflon) dispersion coating encapsulation can not only be used for the conductivity measurement of common water quality, and strong for corrosivity, high pollution water quality is particularly effective.Instrument adopts technology such as automatic zero adjustment technology, temperature compensation, has improved the precision of instrument, makes operation more simple, and instrument adopts dc inversion to exchange technology, has overcome the polarization phenomena that produce when direct current is measured electrical conductivity of solution.
Summary of the invention
The purpose of this invention is to provide a kind of portable smart water quality conductive detection device.
It has single-chip microcomputer, single-chip microcomputer links to each other with squarer, temperature sensor, keyboard, display, multidiameter option switch, A/D converter respectively, squarer links to each other with voltage follower, conductance cell, amplifier electric bridge, multidiameter option switch, A/D converter successively, and temperature sensor links to each other with conductance cell, signal amplifier, capacitor filter, multidiameter option switch, A/D converter successively.
Described interchange generating means is battery-powered, and the multivibrator that constitutes by the LM555 chip produces the ac square wave of frequency f=250HZ, generates the 250HZ alternating current through Hi-pass filter.
Conductance cell adopts the conductivity sensor based on electromagnetic induction, and the electromagnetic induction conductivity sensor is made up of two transformer modules, and magnetic core of transformer adopts the soft magnetic ferrite high permeability material, 20 microns polytetrafluoroethyldispersions dispersions coating encapsulation of its external spray.The temperature sensor of temperature compensation unit is thermistor NTC, and thermistor NTC and electromagnetic induction conductivity sensor integrate.
The circuit of A/D translation data processing unit is: 22 pins of A/D converter ICL7135 link to each other with 15 pins of pulse generator 74LS163D, 3 of pulse generator 74LS163D, 4,6,8 pins link to each other with ground, 1 of pulse generator 74LS163D, 5,7,10 pins link to each other with power supply VCC, 3 of A/D converter ICL7135,24 pin ground connection, 7 pins link to each other with 8 pins through electric capacity, 9 pins are through ground wire, electric capacity converges mutually with 10 pins to be exported via resistance, 6 pins link to each other with 5 pins via two resistance, 6 pins are through resistance, electric capacity, resistance links to each other with 5 pins, 4 pins oppositely connect diode via resistance eutral grounding, 8 of digital multi-channel switch 74LS157,15 pin ground connection, digital multi-channel switch 1,2,3,5,11,14 pins respectively with 12 of A/D converter ICL7135,13,14,15,16 pins link to each other.
The circuit of led display unit is: the interface P3.0 of single-chip microcomputer and the interface P3.1 of single-chip microcomputer link to each other with the interface of led display unit, the remaining five I/O lines of the P3 interface of single-chip microcomputer link to each other with five position route selection D1-D5 of A/D converter ICL7135, and the B1 of A/D converter ICL7135, B2, B4, B8, R/H and BUSY pin link to each other with the P1 interface of single-chip microcomputer.
Integrated application of the present invention based on the conductivity sensor technology of electromagnetic induction principle, eliminate the alternating current technology of electrolytic reaction polarization phenomena, instrument automatic zero adjustment technology, technique for temperature compensation, and technology such as microprocessor and digital demonstration.This apparatus structure compactness is easy to carry, and is easy to operate, and the measuring accuracy height can be widely used in fields such as chemical industry, medicine, metallurgy, environmental protection,, high pollution water-quality test strong for corrosivity, and its advantage is particularly evident.
Description of drawings
The present invention is described further below in conjunction with accompanying drawing
Fig. 1 is the portable smart water quality conductive detection device structural representation;
Fig. 2 is based on the conductivity sensor schematic diagram of electromagnetic induction;
Fig. 3 is alternating current generating means circuit theory diagrams;
Fig. 4 is a conductivity measurement partial circuit schematic diagram;
Fig. 5 is that ICL7135 realizes A/D change-over circuit schematic diagram;
Fig. 6 is AT89C2051 single-chip microcomputer and ICL7135 and LED interface circuit schematic diagram;
Fig. 7 is the software flow pattern of electric conductivity detector.
Embodiment
As shown in Figure 1, portable smart water quality conductive detection device has single-chip microcomputer, single-chip microcomputer links to each other with squarer, temperature sensor, keyboard, display, multidiameter option switch, A/D converter respectively, squarer links to each other with voltage follower, conductance cell, amplifier electric bridge, multidiameter option switch, A/D converter successively, and temperature sensor links to each other with conductance cell, signal amplifier, capacitor filter, multidiameter option switch, A/D converter successively.Details are as follows for its each several part circuit:
The LM555 chip connects into multivibrator, produces the ac square wave of frequency f=250Hz.Voltage follower (LM258) reduces input impedance, the raising signal stabilization of conductance cell.Capacitor filtering is eliminated the influence of multiple harmonic.The temperature compensation link is used thermistor NTC and amplifier electric bridge, and NTC and electromagnetic induction conductivity sensor integrate.The ICL7135 chip is adopted in the A/D conversion, and it is a kind of 4 half double integration A/D converters, is input as differential signal, is output as binary-coded decimal, five (only once) ST negative pulses of output after each conversion finishes.Because ICL7135 chip and AT89C2051 single-chip microcomputer all are time-sharing operations, be provided with multidiameter option switch CD4051, the two can only selected the sending in the single-chip microcomputer of data to realize same time conductivity sense channel and temperature survey passage.
As shown in Figure 2, the electromagnetic induction conductivity sensor is by the parallel T1 that stacks, and the T2 transformer constitutes, and magnetic core of transformer adopts soft magnet oxygen high permeability material, the encapsulation of 20 microns Teflons of its external spray (teflon) dispersion coating.Sensor immerses the conductance cell sample liquid, and main coil L1 feeds the 250HZ alternating current, then produces corresponding alternating flux in T1, and the conductance cell sample liquid produces induction current i under the alternating flux effect, form an electric current loop that intersects at T1, T2; This electric current loop generates alternating flux in T2, and generates induced potential e at secondary coil L2 two ends.Because the conductivity of induced electricity flow valuve and conductance cell sample solution is proportional, so the conductivity of conductance cell sample solution can be obtained by the induced potential e that measures secondary coil L2 two ends.
As shown in Figure 3, the LM555 chip connects into multivibrator, produces the ac square wave of frequency f=250Hz.Voltage follower (LM258) reduces the input impedance of conductance cell, improves signal stabilization.
As shown in Figure 4, D1, D2 are the diodes of two reverse parallel connections, its effect be voltage signal values is limited to+0.7V~-0.7V between.A1 is a voltage follower.Ga is a conductance cell, adopts the conductivity sensor of electromagnetic induction, and main coil feeds exchange current, according to electromagnetic induction principle, obtains the induction electromotive force that is directly proportional with electrical conductivity of solution in secondary coil.Voltage signal with conductivity variations enters among the integrated operational amplifier A2, and enlargement factor satisfies formula by feedback resistance Rf decision:
K = 1 Ra = V 0 RfVi
In the formula: Ra is the equivalent resistance of Ga; Vo is an output voltage, and Vi is input voltage (set-point 50mV).
As shown in Figure 5, the circuit of A/D translation data processing unit is: 22 pins of A/D converter ICL7135 link to each other with 15 pins of pulse generator 74LS163D, 3 of pulse generator 74LS163D, 4,6,8 pins link to each other with ground, 1 of pulse generator 74LS163D, 5,7,10 pins link to each other with power supply VCC, 3 of A/D converter ICL7135,24 pin ground connection, 7 pins link to each other with 8 pins through electric capacity, 9 pins are through ground wire, electric capacity converges mutually with 10 pins to be exported via resistance, 6 pins link to each other with 5 pins via two resistance, 6 pins are through resistance, electric capacity, resistance links to each other with 5 pins, 4 pins oppositely connect diode via resistance eutral grounding, 8 of digital multi-channel switch 74LS157,15 pin ground connection, digital multi-channel switch 1,2,3,5,11,14 pins respectively with 12 of A/D converter ICL7135,13,14,15,16 pins link to each other.
The output of ICL7135 is not three condition, not directly links to each other with bus.Because of its inner no clock circuit, must external clock generation circuit and reference voltage.Use 74LS163D to produce time clock, obtain the circuit of 12 frequency divisions.Transformation result selects 1 digital multi-channel switch 74LS157 to read in single-chip microcomputer by 42.Single-chip microcomputer is controlled and is detected by R/H signal and BUSY signal to ICL7135, and control ICL7135 finishes the A/D convert task.
As shown in Figure 6, the circuit of led display unit is: the interface P3.0 of single-chip microcomputer and the interface P3.1 of single-chip microcomputer link to each other with the interface of led display unit, the remaining five I/O lines of the P3 interface of single-chip microcomputer link to each other with five position route selection D1-D5 of A/D converter ICL7135, and the B1 of A/D converter ICL7135, B2, B4, B8, R/H and BUSY pin link to each other with the P1 interface of single-chip microcomputer.
The P1 mouth of AT89C2051 is as the input of binary-coded decimal and control signal.P3.0 and P3.1 work in the serial port state as the interface of single-chip microcomputer and LED.The remaining I/O line of P3 mouth is as the position route selection of reading the A/D translation data.Startup and the reading changed with P3.2 and P3.4 control A/D among the figure.The LED interface circuit adopts the static display mode of serial port.Serial data is from P3.0 (RXD) output, and P3.1 (TXD) exports the synchronizing pulse driving LED.The temperature survey passage uses thermistor NTC, differential amplifier electric bridge and software compensation algorithm.
As shown in Figure 7, the software platform of system is based on C51 series monolithic and ICES series monolithic artificial debugging software systems, major function is to use interrupt control multidiameter option switch, A/D conversion and driving LED to show, and accounting temperature compensation and conductivity value, and the instrument automatic zero adjustment.
Conductive detection device be zero demonstration when zero imports, but the instrument demonstration is non-vanishing in actual the use, and the main source of tracing it to its cause is by the drift of amplifier and the distributed capacitance of conductance cell cable.Existing electricity is led device and is adopted capacitor compensating circuit and low drift circuit engineering, but actual effect is unsatisfactory.The present invention makes full use of the characteristics of microprocessor digitizing technique, adopts instrument to power on after the abundant preheating, reads in the zero error (the non-zero output error during zero input) of instrument, deposits among the EEPROM.During the conductive detection device real time execution, single-chip microcomputer deducts after the zero error among the EEPROM real-time measurement values as real measured value, finishes the software compensation of zero error.

Claims (6)

1. portable smart water quality conductive detection device, it is characterized in that single-chip microcomputer links to each other with squarer, temperature sensor, keyboard, display, multidiameter option switch, A/D converter respectively, squarer links to each other with voltage follower, conductance cell, amplifier electric bridge, multidiameter option switch, A/D converter successively, and temperature sensor links to each other with conductance cell, signal amplifier, capacitor filter, multidiameter option switch, A/D converter successively.
2. a kind of portable smart water quality conductive detection device according to claim 1, it is characterized in that described interchange generating means is battery-powered, the multivibrator that constitutes by the LM555 chip produces the ac square wave of frequency f=250HZ, generates the 250HZ alternating current through Hi-pass filter.
3. a kind of portable smart water quality conductive detection device according to claim 1, it is characterized in that described conductance cell adopts the conductivity sensor based on electromagnetic induction, the electromagnetic induction conductivity sensor is made up of two transformer modules, magnetic core of transformer adopts the soft magnetic ferrite high permeability material, 20 microns polytetrafluoroethyldispersions dispersions coating encapsulation of its external spray.
4. a kind of portable smart water quality conductive detection device according to claim 1, the temperature sensor that it is characterized in that described temperature compensation unit is thermistor NTC, thermistor NTC and electromagnetic induction conductivity sensor integrate.
5. a kind of portable smart water quality conductive detection device according to claim 1, the circuit that it is characterized in that described A/D translation data processing unit is: 22 pins of A/D converter ICL7135 link to each other with 15 pins of pulse generator 74LS163D, 3 of pulse generator 74LS163D, 4,6,8 pins link to each other with ground, 1 of pulse generator 74LS163D, 5,7,10 pins link to each other with power supply VCC, 3 of A/D converter ICL7135,24 pin ground connection, 7 pins link to each other with 8 pins through electric capacity, 9 pins are through ground wire, electric capacity converges mutually with 10 pins to be exported via resistance, 6 pins link to each other with 5 pins via two resistance, 6 pins are through resistance, electric capacity, resistance links to each other with 5 pins, 4 pins oppositely connect diode via resistance eutral grounding, 8 of digital multi-channel switch 74LS157,15 pin ground connection, digital multi-channel switch 1,2,3,5,11,14 pins respectively with 12 of A/D converter ICL7135,13,14,15,16 pins link to each other.
6. a kind of portable smart water quality conductive detection device according to claim 1, the circuit that it is characterized in that described led display unit is: the interface P3.0 of single-chip microcomputer and the interface P3.1 of single-chip microcomputer link to each other with the interface of led display unit, the remaining five I/O lines of the P3 interface of single-chip microcomputer link to each other with five position route selection D1-D5 of A/D converter ICL7135, and the B1 of A/D converter ICL7135, B2, B4, B8, R/H and BUSY pin link to each other with the P1 interface of single-chip microcomputer.
CNB2006100536334A 2006-09-27 2006-09-27 Portable smart water quality conductive detection device Expired - Fee Related CN100485375C (en)

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CN101986162A (en) * 2010-08-26 2011-03-16 东北大学 Device and method for measuring conductivity of industrial aluminum electrolyte on line
CN102426184A (en) * 2011-11-14 2012-04-25 中国海洋石油总公司 Conductivity sensor
CN101629925B (en) * 2008-06-23 2013-12-04 Emd密理博公司 Method and device for measuring the conductivity of a pure or ultrarapture liquid
CN103675023A (en) * 2012-09-12 2014-03-26 珠海格力电器股份有限公司 Detection circuit and detection method of TDS
CN104535630A (en) * 2014-12-31 2015-04-22 沁园集团股份有限公司 Water quality measuring system of water drinking equipment
CN104995503A (en) * 2013-02-12 2015-10-21 株式会社堀场先进技术 Resistivity-measuring circuit, cell for measuring liquid sample, resistivity-measuring apparatus, liquid sample control method and liquid sample control system
CN105074443A (en) * 2012-12-27 2015-11-18 通用电气公司 Wide dynamic range conductivity measurements in water
CN105588983A (en) * 2014-11-14 2016-05-18 佛山市顺德区美的电热电器制造有限公司 Test device for conductivity and electric equipment
CN105652092A (en) * 2014-11-14 2016-06-08 佛山市顺德区美的电热电器制造有限公司 Testing apparatus of conductivity and electrical equipment
CN105652096A (en) * 2014-11-14 2016-06-08 佛山市顺德区美的电热电器制造有限公司 Testing apparatus of conductivity and electrical equipment
CN105954485A (en) * 2016-04-29 2016-09-21 上海海纳通物联网科技有限公司 Method for monitoring TDS water quality power circuit
CN106199204A (en) * 2016-07-27 2016-12-07 武汉诚迈科技有限公司 A kind of electrical conductivity of solution measuring instruments based on microcontroller
CN106525909A (en) * 2016-12-31 2017-03-22 郑州贯奥仪器仪表有限公司 Intelligent water quality detector
CN106990145A (en) * 2017-04-11 2017-07-28 北京农业智能装备技术研究中心 A kind of portable soil available nutrient detection means
WO2022021471A1 (en) * 2020-07-30 2022-02-03 海德星科技南京有限公司 Agricultural irrigation water quality testing system based on wireless sensing, and testing method therefor
CN114397511A (en) * 2021-12-28 2022-04-26 杭州春来科技有限公司 High-precision conductivity detection circuit for preventing polarization

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CN101629925B (en) * 2008-06-23 2013-12-04 Emd密理博公司 Method and device for measuring the conductivity of a pure or ultrarapture liquid
CN101986162B (en) * 2010-08-26 2013-01-02 东北大学 Device and method for measuring conductivity of industrial aluminum electrolyte on line
CN101986162A (en) * 2010-08-26 2011-03-16 东北大学 Device and method for measuring conductivity of industrial aluminum electrolyte on line
CN102426184A (en) * 2011-11-14 2012-04-25 中国海洋石油总公司 Conductivity sensor
CN103675023B (en) * 2012-09-12 2017-03-22 珠海格力电器股份有限公司 Detection circuit and detection method of TDS
CN103675023A (en) * 2012-09-12 2014-03-26 珠海格力电器股份有限公司 Detection circuit and detection method of TDS
CN105074443B (en) * 2012-12-27 2017-03-22 通用电气公司 Wide dynamic range conductivity measurements in water
CN105074443A (en) * 2012-12-27 2015-11-18 通用电气公司 Wide dynamic range conductivity measurements in water
CN104995503A (en) * 2013-02-12 2015-10-21 株式会社堀场先进技术 Resistivity-measuring circuit, cell for measuring liquid sample, resistivity-measuring apparatus, liquid sample control method and liquid sample control system
US10082477B2 (en) 2013-02-12 2018-09-25 Horiba Advanced Techno, Co., Ltd. Resistivity-measuring circuit, cell for measuring liquid sample, resistivity-measuring apparatus, liquid sample control method, and liquid sample control system
CN105652092A (en) * 2014-11-14 2016-06-08 佛山市顺德区美的电热电器制造有限公司 Testing apparatus of conductivity and electrical equipment
CN105652096A (en) * 2014-11-14 2016-06-08 佛山市顺德区美的电热电器制造有限公司 Testing apparatus of conductivity and electrical equipment
CN105588983A (en) * 2014-11-14 2016-05-18 佛山市顺德区美的电热电器制造有限公司 Test device for conductivity and electric equipment
CN104535630A (en) * 2014-12-31 2015-04-22 沁园集团股份有限公司 Water quality measuring system of water drinking equipment
CN105954485B (en) * 2016-04-29 2017-12-26 上海海纳通物联网科技有限公司 A kind of circuit with monitoring TDS water quality functions
CN105954485A (en) * 2016-04-29 2016-09-21 上海海纳通物联网科技有限公司 Method for monitoring TDS water quality power circuit
CN106199204A (en) * 2016-07-27 2016-12-07 武汉诚迈科技有限公司 A kind of electrical conductivity of solution measuring instruments based on microcontroller
CN106525909A (en) * 2016-12-31 2017-03-22 郑州贯奥仪器仪表有限公司 Intelligent water quality detector
CN106990145A (en) * 2017-04-11 2017-07-28 北京农业智能装备技术研究中心 A kind of portable soil available nutrient detection means
WO2022021471A1 (en) * 2020-07-30 2022-02-03 海德星科技南京有限公司 Agricultural irrigation water quality testing system based on wireless sensing, and testing method therefor
CN114397511A (en) * 2021-12-28 2022-04-26 杭州春来科技有限公司 High-precision conductivity detection circuit for preventing polarization

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