CN1923436A - Pile-up welding flux-cored wire for restoring cold rolling intermediate roller buffer layer and method for manufacturing same - Google Patents

Pile-up welding flux-cored wire for restoring cold rolling intermediate roller buffer layer and method for manufacturing same Download PDF

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Publication number
CN1923436A
CN1923436A CN 200610021799 CN200610021799A CN1923436A CN 1923436 A CN1923436 A CN 1923436A CN 200610021799 CN200610021799 CN 200610021799 CN 200610021799 A CN200610021799 A CN 200610021799A CN 1923436 A CN1923436 A CN 1923436A
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China
Prior art keywords
cored wire
cold
flux
rolling intermediate
iron
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Pending
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CN 200610021799
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Chinese (zh)
Inventor
林剑东
何藩
周三保
熊旭
姜庆波
李坚
杨建民
胡相东
邹宏军
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GANGCHENG ENTERPRISE GENERAL CO PANGANG GROUP
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Panzhihua New Steel and Vanadium Co Ltd
Original Assignee
GANGCHENG ENTERPRISE GENERAL CO PANGANG GROUP
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Panzhihua New Steel and Vanadium Co Ltd
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Application filed by GANGCHENG ENTERPRISE GENERAL CO PANGANG GROUP, Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd, Panzhihua New Steel and Vanadium Co Ltd filed Critical GANGCHENG ENTERPRISE GENERAL CO PANGANG GROUP
Priority to CN 200610021799 priority Critical patent/CN1923436A/en
Publication of CN1923436A publication Critical patent/CN1923436A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a welding drug core welding wire used to repair the working layer of cold rolling middle roller. Wherein, said welding wire comprises coat and drug core; said drug core comprises medium-carbon ferromanganese at 0.8-1.4%, medium-low carbon ferrochrome at 6.0-9.0%, ferro-molybdenum at 1.0-3.0%, ferro-vanadium at 0.7-1.5%, ferrocolumbium at 0.06-0.16%, nickel at 0.5-1.2%, silicon iron at 0.60-1.2%, rare-earth at 1.0-5.0%, derbyshire spar at 4.5-10.5%, and the left is iron powder. The invention has simple process, and the rigidity is HRC25-35, without crack.

Description

Repair cold-rolling intermediate calender rolls transition zone flux-cored wire and manufacture method thereof
Technical field
The invention belongs to welding material and manufacture method thereof, particularly relate to a kind of repair cold-rolling intermediate calender rolls transition zone flux-cored wire and manufacture method thereof.
Background technology
Cold rolling intermediate calender rolls is the critical component that cold-rolled steel sheet is produced required parts, bear bigger alternate stress during work, hardness of roll body reaches HRC56~59, also require to have the ability of anti-strip preferably simultaneously, present for this reason manufacturer generally adopts high-carbon low-alloy steel such as 9Cr3Mo through forging and the manufacturing of complicated heat treatment process forms, and costs an arm and a leg.The consumption of the annual cold rolling intermediate calender rolls in the whole nation is very big, just scraps because of repairing very big the reparation hardly of difficulty again, causes enormous economic loss.
Technique for overlaying is mainly adopted in reparation to cold rolling intermediate calender rolls, and it comprises weld preheating, built-up welding and the post weld heat treatment process of roller.Built-up welding comprises the built-up welding of transition zone and working lining, and the resurfacing welding material that uses in this operation is the key factor in decision surfacing layer metal performance and cold rolling intermediate calender rolls service life.Also there is not at present special cold rolling intermediate calender rolls reparation transition zone welding wire.
Summary of the invention
Technical problem to be solved by this invention provides a kind of repair cold-rolling intermediate calender rolls transition zone flux-cored wire, and this welding wire built-up welding metal hardness reaches HRC25~35, has good cracking resistance.
The present invention also will provide a kind of manufacture method of above-mentioned welding wire.
The technical scheme that technical solution problem of the present invention is adopted is: repair cold-rolling intermediate calender rolls transition zone flux-cored wire, comprise crust and medicine core, the component of described medicine core content by weight percentage comprises: mid-carbon fe-mn: 0.8~1.4%, medium carbon ferrochrome: 6.0~9.0%, molybdenum-iron: 1.0~3.0%, vanadium iron: 0.7~1.5%, ferro-niobium 0.06~0.16%, metallic nickel: 0.5~1.2%, ferrosilicon: 0.60~1.2%, rare earth: 1.0~5.0%, fluorite: 4.5~10.5%, all the other are iron powders.
Further, the granularity (order) of described medicine core component is respectively: mid-carbon fe-mn: 80~120, medium carbon ferrochrome: 80~120, molybdenum-iron: 80~120, vanadium iron: 60~120, ferro-niobium: 80~120, metallic nickel: 80~120, ferrosilicon: 60~120, rare earth: 80~120, fluorite: 60~120, iron powder: 80~120.
Above-mentioned repair cold-rolling intermediate calender rolls transition zone may further comprise the steps: be rolled into " U " type after the oven dry of 1) cold-rolled strip being with, being deoiled through cutting out with the manufacture method of flux-cored wire; 2) preparation medicine core batching and oven dry; 3) with being rolled into " O " type behind the filling medicine core in steel band " U " the type groove, be drawn into flux-cored wire then.
Further, the described cold-rolled strip of step 1 is that thickness is that 0.3~0.8mm, width are the cold-rolled strip of 8.0~16.0mm.
Further, described cold-rolled strip adopts the HO8A cold-rolled strip.
Further, the described flux-cored wire of step 3 is that diameter is the flux-cored wire of 2.0~5.0mm.
The invention has the beneficial effects as follows: manufacture method is simple, and the deposited metal hardness of welding wire is HRC25~35, and cracking resistance is good in the weld deposit process, is difficult for cracking, when reaching cold rolling intermediate calender rolls built-up welding fully and repairing to the specification requirement of transition zone built-up welding.
The specific embodiment
Because the carbon content of cold rolling intermediate calender rolls mother metal is higher, and the carbon content of transition zone welding wire is lower, on cold rolling intermediate calender rolls mother metal during built-up welding, the carbon content of surfacing layer metal just can reduce a lot, thereby is not prone to crackle in the weld deposit process like this.
V and Nb element all have stronger crystal grain thinning and solution strengthening ability, V and Nb element also have stronger precipitation strength ability, they and Mo element all are the strong carbide forming elements, add that these alloying elements make the crystallite dimension of deposited metal little, hardness is high, toughness is better, preferred 0.06~0.16%, the molybdenum-iron preferred 1.0~3.0% of preferred 0.7~1.5% (weight percent content, as follows) of vanadium iron of the present invention, ferro-niobium.
Adding Ni element can improve the intensity and the toughness of alloy, contains at the same time under the situation of Ni and Cr element, and the Ni element can also improve the temper resistance of hardfacing alloy layer greatly, metallic nickel of the present invention preferred 0.5~1.2%.
Add more Cr and improve the Cr/C ratio, easily generate the high rigidity M of isolated strip form 7C 3The type carbide, than the M of net distribution 3C type carbide can strengthen the continuity of matrix, thereby improves the toughness of integral material, medium carbon ferrochrome of the present invention preferred 6.0~9.0%.
The Mn element can promote the dissolving of strong carbide in austenite, and the content of alloying element in balance carbide and the austenite is given full play to the precipitation strength and the solution strengthening ability of V, Nb and Mo element; In addition, improve Mn/C, thereby improve the toughness of overlay cladding to a certain extent, but Mn content is unsuitable too high, otherwise can increase the temper brittleness of overlay cladding, mid-carbon fe-mn of the present invention preferred 0.8~1.4% than the effect that can also play the formation that reduces grain boundary carbide.
The adding of rare earth has hardfacing alloy to suppress preferably hydrogen embrittlement, reduce temper brittleness and suppress P poly-partially ability on crystal boundary in heat treatment process, thereby can reach the purpose of the toughness of raising hardfacing alloy.In addition, because rare earth has the effect that makes inclusion modification, purifies crystal boundary and stronger crystal grain thinning, join in the resurfacing welding material and can play the effect of improving the overlay cladding performance, rare earth of the present invention preferred 1.0~5.0%.
Si deoxidizing capacity in the ferrosilicon is very strong, can form SiO with the FeO effect 2, enter slag then and be excluded; Si can improve the quenching degree and the intensity of surfacing layer metal, and improves its temper resistance, but Si can not be too high, thereby otherwise easily produces grain boundary carbide and be prone to crackle.Ferrosilicon of the present invention preferred 0.60~1.2%.
The main component of fluorite is CaF 2, it can reduce the fusing point and the viscosity of slag, increases flowability, is beneficial to slag making; It can reduce the hydrogen dividing potential drop in the arc atmosphere, causes hydrogen content minimizing in the weld metal, improves the toughness and the anti-crack ability of weld metal.Fluorite of the present invention preferred 4.5~10.5%.
Embodiment 1:
Medicine core component content by weight percentage comprises: mid-carbon fe-mn: medium carbon ferrochrome 0.8%: molybdenum-iron 6.0%: vanadium iron 1.0%: 0.7%, ferro-niobium 0.06%, metallic nickel: ferrosilicon 0.5%: rare earth 0.60%: fluorite 1.0%: 4.5%, all the other are iron powders.
The hardness of produced welding wire built-up welding layer metal is greater than HRC25.
Embodiment 2:
Medicine core component content by weight percentage comprises: mid-carbon fe-mn: medium carbon ferrochrome 1.4%: molybdenum-iron 9.0%: vanadium iron 3.0%: 1.5%, ferro-niobium 0.16%, metallic nickel: ferrosilicon 1.2%: rare earth 1.2%: fluorite 5.0%: 10.5%, all the other are iron powders.
Produced welding wire built-up welding layer metal hardness is HRC35.
Embodiment 3:
Medicine core component content by weight percentage comprises: mid-carbon fe-mn: medium carbon ferrochrome 1.2%: molybdenum-iron 8.0%: vanadium iron 2.5%: 1.2%, ferro-niobium 0.16%, metallic nickel: ferrosilicon 0.8%: rare earth 1.1%: fluorite 4.0%: 8.5%, all the other are iron powders.
Produced welding wire built-up welding layer metal hardness is HRC32.
Embodiment 4:
Medicine core component content by weight percentage comprises: mid-carbon fe-mn: medium carbon ferrochrome 1.2%: molybdenum-iron 9.0%: vanadium iron 2.8%: 1.4%, ferro-niobium 0.16%, metallic nickel: ferrosilicon 0.8%: rare earth 1.2%: fluorite 4.0%: 8.5%, all the other are iron powders.
The hardness of produced welding wire built-up welding layer metal is HRC33.

Claims (6)

1, repair cold-rolling intermediate calender rolls transition zone flux-cored wire, comprise crust and medicine core, it is characterized in that: the component of described medicine core content by weight percentage comprises: mid-carbon fe-mn: 0.8~1.4%, medium carbon ferrochrome: 6.0~9.0%, molybdenum-iron: 1.0~3.0%, vanadium iron: 0.7~1.5%, ferro-niobium 0.06~0.16%, metallic nickel: 0.5~1.2%, ferrosilicon: 0.60~1.2%, rare earth: 1.0~5.0%, fluorite: 4.5~10.5%, all the other are iron powders.
2, repair cold-rolling intermediate calender rolls transition zone flux-cored wire as claimed in claim 1, it is characterized in that: the granularity (order) of described medicine core component is respectively: mid-carbon fe-mn: 80~120, medium carbon ferrochrome: 80~120, molybdenum-iron: 80~120, vanadium iron: 60~120, ferro-niobium: 80~120, metallic nickel: 80~120, ferrosilicon: 60~120, rare earth: 80~120, fluorite: 60~120, iron powder: 80~120.
3, the described repair cold-rolling intermediate calender rolls of claim 1 transition zone is characterized in that: may further comprise the steps: be rolled into " U " type after the oven dry of 1) cold-rolled strip being with, being deoiled through cutting out with the manufacture method of flux-cored wire; 2) preparation medicine core batching and oven dry; 3) with being rolled into " O " type behind the filling medicine core in steel band " U " the type groove, be drawn into flux-cored wire then.
4, the repair cold-rolling intermediate calender rolls transition zone as claimed in claim 3 manufacture method of flux-cored wire, it is characterized in that: the described cold-rolled strip of step 1 is that thickness is that 0.3~0.8mm, width are the cold-rolled strip of 8.0~16.0mm.
5, repair cold-rolling intermediate calender rolls transition zone as claimed in claim 4 is characterized in that: described cold-rolled strip employing H08A cold-rolled strip with the manufacture method of flux-cored wire.
6, the repair cold-rolling intermediate calender rolls transition zone as claimed in claim 3 manufacture method of flux-cored wire, it is characterized in that: the described flux-cored wire of step 3 is that diameter is the flux-cored wire of 2.0~5.0mm.
CN 200610021799 2006-09-08 2006-09-08 Pile-up welding flux-cored wire for restoring cold rolling intermediate roller buffer layer and method for manufacturing same Pending CN1923436A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434017B (en) * 2007-11-14 2010-11-03 中冶集团建筑研究总院 Welding wire for welding cold-rolled steel strip strain roll
CN101386115B (en) * 2008-10-13 2011-03-16 攀钢集团研究院有限公司 Flux-cored wire for cold rolling middle roller transient layer built-up welding and preparation method thereof
CN101780609B (en) * 2009-01-15 2012-03-07 山东聚力焊接材料有限公司 Slag-free flux-cored wire process
CN102441748A (en) * 2011-11-16 2012-05-09 燕山大学 Special welding rod for surfacing and repairing broken teeth of heavy-duty high-speed gear
CN107225339A (en) * 2017-06-02 2017-10-03 重庆大学 A kind of self-shield flux-cored wire for having sandwich of layers for heavy-duty forging die and preparation method thereof
CN107350661A (en) * 2017-08-19 2017-11-17 安徽鼎恒再制造产业技术研究院有限公司 The transition zone of built-up welding submerged-arc welding flux cored wire and its welding procedure
CN109249152A (en) * 2018-09-06 2019-01-22 四川大西洋焊接材料股份有限公司 The dedicated hard-face overlaying welding welding wire of core bar for rolling seamless and preparation method
CN110170768A (en) * 2019-06-19 2019-08-27 鞍钢未来钢铁研究院有限公司 A kind of Ni-based electric arc spraying flux-cored wire and preparation method
CN110216399A (en) * 2019-06-19 2019-09-10 鞍钢未来钢铁研究院有限公司 A kind of flux-cored wire and preparation method for laminar flow roller electric arc spraying
CN110253174A (en) * 2019-06-19 2019-09-20 鞍钢未来钢铁研究院有限公司 A kind of continuous cast roller flux-cored welding wire for overlaying welding and preparation method
CN114571132A (en) * 2021-12-14 2022-06-03 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for extrusion roller transition layer
CN114589431A (en) * 2021-12-20 2022-06-07 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for cover layer of extrusion roll

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434017B (en) * 2007-11-14 2010-11-03 中冶集团建筑研究总院 Welding wire for welding cold-rolled steel strip strain roll
CN101386115B (en) * 2008-10-13 2011-03-16 攀钢集团研究院有限公司 Flux-cored wire for cold rolling middle roller transient layer built-up welding and preparation method thereof
CN101780609B (en) * 2009-01-15 2012-03-07 山东聚力焊接材料有限公司 Slag-free flux-cored wire process
CN102441748A (en) * 2011-11-16 2012-05-09 燕山大学 Special welding rod for surfacing and repairing broken teeth of heavy-duty high-speed gear
CN107225339A (en) * 2017-06-02 2017-10-03 重庆大学 A kind of self-shield flux-cored wire for having sandwich of layers for heavy-duty forging die and preparation method thereof
CN107225339B (en) * 2017-06-02 2019-04-05 重庆大学 A kind of self-shield flux-cored wire and preparation method thereof for heavy-duty forging die tool sandwich of layers
CN107350661A (en) * 2017-08-19 2017-11-17 安徽鼎恒再制造产业技术研究院有限公司 The transition zone of built-up welding submerged-arc welding flux cored wire and its welding procedure
CN109249152B (en) * 2018-09-06 2021-04-30 四川大西洋焊接材料股份有限公司 Special hard surfacing welding wire for mandrel for rolling seamless steel tube and preparation method
CN109249152A (en) * 2018-09-06 2019-01-22 四川大西洋焊接材料股份有限公司 The dedicated hard-face overlaying welding welding wire of core bar for rolling seamless and preparation method
CN110170768A (en) * 2019-06-19 2019-08-27 鞍钢未来钢铁研究院有限公司 A kind of Ni-based electric arc spraying flux-cored wire and preparation method
CN110253174A (en) * 2019-06-19 2019-09-20 鞍钢未来钢铁研究院有限公司 A kind of continuous cast roller flux-cored welding wire for overlaying welding and preparation method
CN110216399A (en) * 2019-06-19 2019-09-10 鞍钢未来钢铁研究院有限公司 A kind of flux-cored wire and preparation method for laminar flow roller electric arc spraying
CN110216399B (en) * 2019-06-19 2021-08-03 鞍钢未来钢铁研究院有限公司 Flux-cored wire for laminar flow roller arc spraying and preparation method
CN110170768B (en) * 2019-06-19 2022-03-15 鞍钢未来钢铁研究院有限公司 Flux-cored wire for nickel-based arc spraying and preparation method thereof
CN114571132A (en) * 2021-12-14 2022-06-03 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for extrusion roller transition layer
CN114571132B (en) * 2021-12-14 2023-07-18 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for transition layer of squeeze roller
CN114589431A (en) * 2021-12-20 2022-06-07 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for cover layer of extrusion roll
CN114589431B (en) * 2021-12-20 2023-07-18 鞍山冶金集团工业有限公司鞍山三炼钢分公司 Self-protection flux-cored wire for extrusion roller cover layer

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