CN1919761A - Manufacture method of glass-ceramic with jade veins - Google Patents
Manufacture method of glass-ceramic with jade veins Download PDFInfo
- Publication number
- CN1919761A CN1919761A CNA2006101407472A CN200610140747A CN1919761A CN 1919761 A CN1919761 A CN 1919761A CN A2006101407472 A CNA2006101407472 A CN A2006101407472A CN 200610140747 A CN200610140747 A CN 200610140747A CN 1919761 A CN1919761 A CN 1919761A
- Authority
- CN
- China
- Prior art keywords
- glass
- parts
- jade
- veins
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
Abstract
The invention discloses a preparing method of jade pin microcrystal glass, which comprises the following steps: blending raw material completely; fusing in the furnace; adopting punching method to grain the fused liquid into glass particle with grain size at 10-50mm; putting the glass particle in the cool water to crack; loading glass particle on the mould to crystallize; finishing crystallizing; grinding; polishing; cutting into micro-crystal glass product.
Description
Technical field
The present invention relates to building material technical field, relate in particular to a kind of manufacture method of glass-ceramic with jade veins.
Background technology
The sintered glass-ceramics decorative sheet more and more has been subjected to domestic and international architect and user's favor as a kind of building and ornament materials of novel high-grade.The devitrified glass of prior art mainly adopts the sintering process preparation, be after raw material is evenly mixed by prescription, drop in the glass melter and melt, the glass slag of 1~4 mm particle size is made in shrend, then the glass slag is put into mould, sintering and crystallization in crystallization kiln, at last that crystallization is good microcrystal glass plate grind, throw, cut and be processed as product.The devitrified glass of this method manufacturing can only produce machine-made small-particle decorative pattern, and the assortment of crystallizing glass decoration board are few, can not satisfy the diversified market requirement of finishing material.
Summary of the invention
The object of the present invention is to provide a kind of manufacture method of glass-ceramic with jade veins, the devitrified glass of this method manufacturing is as natural jade, and lines is true to nature naturally, color is soft, clear attractive in appearance, well arranged.
Manufacture method of glass-ceramic with jade veins of the present invention, be after starting material are mixed, put in the smelting furnace and melt, manufacture glass particle, glass particle is contained in enters the crystallization kiln crystallization on the template, kiln discharge after crystallization is finished, through grinding, polish and cut into the devitrified glass finished product, it is characterized in that: with glass melt under 900~950 ℃ temperature, applying the coercive method and making particle diameter is the glass particle of 10~50mm, and glass particle cools to 800~900 ℃ and puts in the cold water tempering and form crackle.
Described glass particle can be spheroidal, oblateness, cubes and other shape.
Make glass-ceramic with jade veins and generally adopt CaO-Al
2O
3-SiO
2It is more that β-wollastonite is, its prescription is preferably pressed row weight part ratio preparation: SiO
255~61 parts, Al
2O
33~9 parts, 2~7 parts of 5~15 parts of CaO, ZnO, 1~6 part of BaO, Na
2O+K
23~8 parts of O, B
2O
30~5 part, 0~5 part of MgO, SO
30~1 part, Sb
2O
30~5 part of 0~1 part, tinting material.
Major advantage of the present invention is: 1, the devitrified glass of this method manufacturing is as natural jade, and lines is true to nature naturally, color is soft, clear attractive in appearance, well arranged.2, the devitrified glass smooth surface is smooth, no sintering bubble, and the section structure densification, mechanical-physical intensity height, wear resistance, erosion resistance, fastness to efflorescence are good.3, manufacture method is simple, with low cost, can be widely used in the devitrified glass manufacturing, for building material market has increased new assortment.
Embodiment
Below by specific embodiments the present invention is further described.
Embodiment 1: press row weight part ratio preparation starting material: SiO
258 parts, Al
2O
38 parts, 2.7 parts of 11.5 parts of CaO, ZnO, 4.4 parts of BaO, Na
23.5 parts of O, K
23 parts of O, B
2O
32 parts, SO
30.5 part, Sb
2O
30.4 part, tinting material (TiO
2+ CeO
2) TiO
23.5 part, CeO
22.5 part.Starting material are prepared the back thorough mixing, put in the melting furnaces, found into glass melt at 1470 ℃, under 930 ℃ of temperature, the fused glass melt is pressed into particle diameter and is the ball shape about 30mm, then glass sphere is cooled to 850 ℃ and put in the cold water tempering and form crackle.Pack into after the drying in the mould, enter crystallization in the shuttle kiln, crystallization is finished through grinding, cut, polishing and is obtained yellow glass-ceramic with jade veins product.
Embodiment 2: press row weight part ratio preparation starting material: SiO
254 parts, Al
2O
35 parts, 6 parts of 10 parts of CaO, ZnO, 3 parts of BaO, Na
23 parts of O, K
24 parts of O, B
2O
33 parts, 2 parts of MgO, SO
30.2 part, Sb
2O
30.3 part, 0.05 part of blue colorant (CoO+CuO) CoO, 0.15 part of CuO.Starting material are prepared the back thorough mixing, put in the melting furnaces, found into glass melt at 1470 ℃, under 910 ℃ of temperature, the fused glass melt is pressed into particle diameter and is the oblate shape about 40mm, then oblate glass particle is cooled to 860 ℃ and put in the cold water tempering and form crackle.Pack into after the drying in the mould, enter crystallization in the shuttle kiln, crystallization is finished through grinding, cut, polishing and is obtained blue glass-ceramic with jade veins product.
Embodiment 3: press row weight part ratio preparation starting material: SiO
260 parts, Al
2O
36 parts, 5 parts of 12 parts of CaO, ZnO, 5 parts of BaO, Na
24 parts of O, K
23 parts of O, B
2O
34 parts, 3 parts of MgO, SO
30.5 part, Sb
2O
30.2 0.025 part of part, cream-coloured tinting material NiO.Starting material are prepared the back thorough mixing, put in the melting furnaces, found into glass melt at 1470 ℃, under 945 ℃ of temperature, the fused glass melt is pressed into particle diameter and is the square shape about 20mm, then the glass particle of square shape is cooled to 880 ℃ and put in the cold water tempering and form crackle.Pack into after the drying in the mould, enter crystallization in the shuttle kiln, crystallization is finished through grinding, cut, polishing and is obtained cream-coloured glass-ceramic with jade veins product.
Claims (2)
1, a kind of manufacture method of glass-ceramic with jade veins, be after starting material are mixed, put in the smelting furnace and melt, manufacture glass particle, glass particle is contained in enters the crystallization kiln crystallization on the template, kiln discharge after crystallization is finished, through grinding, polish and cut into the devitrified glass finished product, it is characterized in that: with glass melt under 900~950 ℃ temperature, applying the coercive method and making particle diameter is the glass particle of 10~50mm, and glass particle cools to 800~900 ℃ and puts in the cold water tempering and form crackle.
2, by the described manufacture method of glass-ceramic with jade veins of claim 1, it is characterized in that: the prescription of making glass-ceramic with jade veins is pressed row weight part ratio preparation: SiO
255~61 parts, Al
2O
33~9 parts, 2~7 parts of 5~15 parts of CaO, ZnO, 1~6 part of BaO, Na
2O+K
23~8 parts of O, B
2O
30~5 part, 0~5 part of MgO, SO
30~1 part, Sb
2O
30~5 part of 0~1 part, tinting material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101407472A CN100551854C (en) | 2006-10-09 | 2006-10-09 | A kind of manufacture method of glass-ceramic with jade veins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101407472A CN100551854C (en) | 2006-10-09 | 2006-10-09 | A kind of manufacture method of glass-ceramic with jade veins |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1919761A true CN1919761A (en) | 2007-02-28 |
CN100551854C CN100551854C (en) | 2009-10-21 |
Family
ID=37777641
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2006101407472A Expired - Fee Related CN100551854C (en) | 2006-10-09 | 2006-10-09 | A kind of manufacture method of glass-ceramic with jade veins |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100551854C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103641316A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Bowlder-like microcrystalline glass |
CN103641318A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Bowlder-like microcrystalline glass |
-
2006
- 2006-10-09 CN CNB2006101407472A patent/CN100551854C/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103641316A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Bowlder-like microcrystalline glass |
CN103641318A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Bowlder-like microcrystalline glass |
CN103641316B (en) * | 2013-12-06 | 2015-09-23 | 辽宁红山玉科技有限公司 | A kind of bowlder-like devitrified glass |
CN103641318B (en) * | 2013-12-06 | 2015-09-23 | 辽宁红山玉科技有限公司 | A kind of bowlder-like devitrified glass |
Also Published As
Publication number | Publication date |
---|---|
CN100551854C (en) | 2009-10-21 |
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C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091021 Termination date: 20151009 |
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EXPY | Termination of patent right or utility model |