CN1909115A - Flame resisting wave-absorbing material and method for making same - Google Patents

Flame resisting wave-absorbing material and method for making same Download PDF

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Publication number
CN1909115A
CN1909115A CN 200610041349 CN200610041349A CN1909115A CN 1909115 A CN1909115 A CN 1909115A CN 200610041349 CN200610041349 CN 200610041349 CN 200610041349 A CN200610041349 A CN 200610041349A CN 1909115 A CN1909115 A CN 1909115A
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absorbing material
flame
coating
inorganic
resisting wave
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CN 200610041349
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CN100511487C (en
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汪洪
王相元
程其恒
黄忠明
刘维新
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Nanjing Aerospace Boping Electronic Technology Co ltd
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Nanjing Nanda Boping Electronics Information Co Ltd
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Abstract

The related preparation method for a new flame-resisting wave-absorbing material used on full/semi-anechoic chamber comprises: with non-woven fabrics as basal body, painting flame-retardant coat on both inner and outer surfaces of the fabric, drying; then painting conductive coat on former coat, drying; impressing and forming, and folding into the unit body. This invention improves product performance greatly.

Description

Flame resisting wave-absorbing material and preparation method thereof
Technical field
The present invention relates to a kind of novel wave-absorbing material and preparation method thereof, relate generally to a kind of important materials that is applied to fully anechoic chamber and semi-anechoic chamber, the test environment of no reflection events free space is provided.
Background technology
Absorbing material is as far back as the existing production seventies in last century, but both at home and abroad all with flexible polyurethane foams as matrix, cut into pyramidally, make by technologies such as chemical coating dipping, oven dry, be installed in the darkroom by the tackifier stickup then.
The isocyanurate foam absorbing material is owing to base material self aging action, and can only guarantee 5-8 tenure of use, produces dry linting, elbow, release toxic gas etc. owing to wear out simultaneously, not only darkroom electrical property decline, and test environment can't guarantee; Because isocyanurate foam itself is a macromolecular material, belong to inflammable thing on the other hand, self oxygen index LOI is about 17%-18%, though when the preparation absorbing material by adding fire retardant, final absorbing material oxygen index belongs to fire-fighting B2 level material about 26%; Especially producing highly higher absorbing material (height more than as 1000mm), the processing technology difficulty, the product uniformity consistency is relatively poor, unstable properties, oven dry cost costliness, so manufacturer generally seldom produces the above height of 1000mm isocyanurate foam absorbing material, but electromagnetic compatible dark chamber (mainly using frequency range to be 30MHz-1GHz), for satisfying low frequency performance, must use the absorbing material of height more than 1000mm.For addressing this problem, adopting another kind of absorbing material both at home and abroad usually---ferrite is used for satisfying the performance requirement of electromagnetic compatible dark chamber to test site with compound the making of isocyanurate foam absorbing material of height below 1000mm.But this compound substance exceeds 2-3 times of price than isocyanurate foam cost, and polyurethane wave-absorbing material on average bears power≤0.8kw/, can't satisfy the requirement of high-power emissive source test.In the 80-90 age in last century, because isocyanurate foam absorbing material fire resistance is relatively poor, domestic a lot of microwave dark room fire failures took place.
Previous Chinese patent application 200510038653.x discloses a kind of wave absorption base material, its technical scheme is: be matrix with the nonwoven fabrics, with being coated on the nonwoven fabrics after aluminum-magnesium compositing powder, water-soluble plasticizer, cementing agent, carbon black and the water mediation, be made into the cube-corner elements body.This Flame Retardancy can be higher, and oxygen index can reach more than 60%, bears power 2-15kw/m 2, solved the relatively poor situation of polyurethane pyramid absorbing material fire resistance substantially, also improved and born power.But still can not satisfy the requirement of more high-power emissive source test, therefore have better fire resistance and the higher absorbing material that bears power is anxious waits to develop.And, be matrix owing to adopt nonwoven fabrics, nonwoven fabrics has another name called adhesive-bonded fabric, mainly be to pass through impregnation or hot-forming by chemical fibre, the surface fiber burr is comparatively obvious, so relatively poor with this absorbing material any surface finish of making, stain resistance differences etc. have also had a strong impact on absorbing material appearance quality.
Summary of the invention
The purpose of this invention is to provide a kind of fire resistance better, bear the higher absorbing material of power, thoroughly solve the potential safety hazard of catching fire of microwave dark room, and satisfy the requirement of high-power emissive source test.
The technical solution adopted for the present invention to solve the technical problems is: a kind of flame resisting wave-absorbing material, be to be the cube-corner elements body of matrix with the nonwoven fabrics, it is characterized in that, be coated with flame retardant coating on the surfaces externally and internally of nonwoven fabrics, outside flame retardant coating, be coated with conductive coating.
Said flame retardant coating, its coating are formulated by inorganic composite flame retardants, organic adhesion agent, inorganic adhesive, defoamer and water.
Said conductive coating, its coating are formulated by inorganic absorbent, organic adhesion agent, defoamer, spreading agent and water.
Wherein said inorganic composite flame retardants is one or more in aluminium hydroxide, magnesium hydroxide or the aluminum-magnesium compositing powder.
The preferred acetylene carbon black of wherein said inorganic absorbent.
Wherein said inorganic adhesive, preferred silicasol.
Wherein said organic adhesion agent, preferably polyethylene alcohol glue.
Further, because the flame resisting wave-absorbing material structure is a hollow body, the different structure inner core is inserted in inside, and is not only useful to the absorbed performance, and material rectangular pyramid body is played a supporting role, and makes material have intensity preferably.
Another object of the present invention provides the preparation method of said flame resisting wave-absorbing material, specifically may further comprise the steps:
1) preparation anti-flaming dope: inorganic combustion inhibitor, organic adhesion agent, inorganic adhesive, defoamer and water are mixed, be mixed with anti-flaming dope;
2) brushing flame retardant coating: anti-flaming dope is coated in nonwoven fabrics matrix two surfaces goes up and oven dry;
3) preparation electrically-conducting paint: inorganic absorbent, organic adhesion agent, defoamer, spreading agent and water are mixed, be mixed with electrically-conducting paint;
4) brushing conductive coating: be coated on the flame retardant coating electrically-conducting paint and oven dry;
5) impression moulding: will on marking press, strike out pyramid absorbing material sheet material through matrix fire-retardant and that conductive coating applies;
6) folding forming is a cell cube.
For ease of in the darkroom, installing, can be with the cube-corner elements body (also claiming single awl) that makes, brush coating is pasted and is assembled into cell block.Also can be if necessary in cell block appearance spraying and decorating coating, as sky blue coating.
In order to make product of the present invention have preferable performance, the proportioning of anti-flaming dope is recommended following weight portion among the present invention:
Inorganic combustion inhibitor 35-45 part, organic adhesion agent 20-30 part, inorganic adhesive 6-10 part, defoamer 0.1-0.3 part, water 25-35 part.
The proportioning of electrically-conducting paint is recommended following weight portion:
Inorganic absorbent 2.5-3.4 part, organic adhesion agent 35-42 part, defoamer 0.1-0.3 part, spreading agent 0.8-1.2 part, water 50-60 part.
The present invention develops a kind of fire-retardant and electrically-conducting paint that is different from fully in first to file and is painted on successively on the nonwoven fabrics matrix, produce a kind of flame resisting wave-absorbing material, particularly mixing assembly by a kind of inorganic adhesive-silicasol and organic adhesion agent in flame retardant coating uses, on the one hand, effectively solved not smoothness of surface that nonwoven surface fiber burr causes, main is, on the other hand, mix assembly by having added inorganic silicon colloidal sol and organic adhesion agent, thoroughly solved the defective that adds single organic adhesion agent existence.Silicasol is the colloidal solution with the high-molecular-weight poly metasilicic acid of water dispersion medium, can form firm si-o key between its silicon dioxide granule, just forms continuous reticulate texture film.Because the rigidity of si-o key is stronger, after the mixed assembly of organic polymer emulsion, the organic polymer film forming matter is evenly distributed in the gap that si-o films, can improve the silicasol film forming so easily chaps, improved the organic adhesion agent coating property again, not only have organic polymer tackifier toughness, improved coating strength, adhesion, anti-soil, performance such as bright and clean, high temperature resistant simultaneously.Make to belong to fire-fighting B1 level material by flame resisting wave-absorbing material oxygen index of the present invention 〉=70%, thoroughly solve the potential safety hazard of catching fire, need not to be equipped with special fire fighting device in the darkroom simultaneously, saved a large amount of fire-fighting fund inputs for construction side.Simultaneously because coating strength, adhesion strengthen, and the coating brushing improved the anti-high power performance of matrix greatly at the surfaces externally and internally of matrix, this flame resisting wave-absorbing material on average bears the 5-20kw/m of anti-power 2, can satisfy in some high-power emissive source darkrooms and use; In addition, problems such as elbow, dry linting, environmental protection have also been solved.And because the flame resisting wave-absorbing material structure is a hollow body, the inner different structure inner core that inserts, not only useful to the absorbed performance, and material rectangular pyramid body played a supporting role, make material have intensity preferably, so there are not phenomenons such as elbow, can be made into highly is the 1600mm absorbing material.This material can have absorptive character preferably in low-frequency range, can directly be used in electromagnetic compatible dark chamber, need not to add that ferrite wave-absorbing material is compound can meet the demands, service band can be widened 30MHz-40GHz, and price only is half of isocyanurate foam pyramid absorbing material and ferrite Wave suction composite material.Because main raw material(s) has been selected dead matter for use, flame resisting wave-absorbing material can guarantee more than 10 years serviceable life.
Description of drawings
Fig. 1 is the cube-corner elements body stretch-out view that flame resisting wave-absorbing material of the present invention gets;
Fig. 2 is the cell block synoptic diagram that flame resisting wave-absorbing material makes; Wherein 1, single awl.
Fig. 3 is the cell block schematic bottom view of one embodiment of the invention.
Embodiment
The present invention is further described below in conjunction with drawings and Examples.
Employed in the present invention term unless other explanation is arranged, generally has the implication of those of ordinary skills' common sense.
In following embodiment, various processes of Xiang Ximiaoshuing and method are not conventional methods as known in the art.
Embodiment 1:
With impregnation moulding nonwoven fabrics is matrix; 40 parts of aluminum-magnesium compositing powders, 23 parts of organic adhesion agents (as polyvinyl alcohol glue), 7.5 parts of silicasol, 0.1 part of defoamer and water thrown in dispersion machine respectively for 29 parts stir, be uniformly dispersed and make anti-flaming dope; The anti-flaming dope for preparing is ground one time with three-roll grinder, make coating even, fine and smooth; Add anti-flaming dope in the fire-retardant mechanical brushing equipment slots of special use, will put in order the volume nonwoven fabrics and be immersed in the anti-flaming dope by pressure roller, open the long drying tunnel of 15m, the drying tunnel other end begins the rolling nonwoven fabrics, and anti-flaming dope evenly is coated on the nonwoven fabrics, and oven dry; 3 parts of carbon blacks, 38 parts of organic adhesion agents (as polyvinyl alcohol glue), 0.1 part of defoamer, 1 part of spreading agent, water are thrown in dispersion machine respectively for 57 parts and stirred, be uniformly dispersed and make electrically-conducting paint; The electrically-conducting paint for preparing is ground one time with three-roll grinder, make coating even, fine and smooth; In another special-purpose conductive mechanical brushing equipment slots, add electrically-conducting paint equally, the whole volume nonwoven fabrics that has applied flame-retardant layer is immersed in the electrically-conducting paint by pressure roller, opens the long drying tunnel of 15m, the drying tunnel other end begins the rolling nonwoven fabrics, electrically-conducting paint evenly is coated on the nonwoven fabrics, and oven dry; According to the different size material, the good semi-manufacture fire-retardant, conductive coating of brushing are cut into the corresponding size sheet material on request, will be installed on the indentation equipment with the laser plate-making cutting die in advance, then sheet material is placed on begin on the marking press die-cut; With die-cut good sheet material (as Fig. 1),, brush coating folding, paste single awl 1 by crease line.
Rice word core material is inserted in single awl 1, and single awl of using forming is in shaping frame, and brush coating is pasted the cell block that is assembled into as Fig. 2, and its bottom surface as shown in Figure 3.
Its performance is as shown in table 1 after tested for the flame resisting wave-absorbing material that the present invention makes
Table 1 flame resisting wave-absorbing material performance test of the present invention
Figure A20061004134900061
3 Fire-retardant rank B 2The level fire proofing B 2The level fire proofing B 1The level fire proofing
4 Anti-power ≤1KW/m 2 ≤1KW/m 2 ≥5KW/m 2
5 Environmental protection Non-environmental protection material Pay attention to environmental protection, carry out certain environmental protection treatment. Ep-type material
6 Weight (same specification relatively) 1 1 0.8
7 Cost (same specification relatively) 1 3 0.6
8 Mounting process If with the compound use mounting process of ferrite complexity, difficulty is higher. If with the compound use mounting process of ferrite complexity, difficulty is higher. Mount mode, convenient and swift.
9 With ferritic combination process Technical difficulty is higher, need carry out impedance matching, special transition processing. Technical difficulty is higher, need carry out impedance matching, special transition processing. Integrated material need not any transition section.
Embodiment 2:
Substantially the same manner as Example 1, difference is that anti-flaming dope is pressed following preparation: 35 parts of aluminium hydroxide, 20 parts of organic adhesion agents, 6 parts of silicasol, 0.1 part of defoamer, 25 parts in water.Electrically-conducting paint is pressed following preparation: 2.5 parts of acetylene carbon blacks, 35 parts of organic adhesion agents, 0.1 part of defoamer, 0.8 part of spreading agent, 50 parts in water.
Embodiment 3:
Substantially the same manner as Example 1, difference is that anti-flaming dope is pressed following preparation: 45 parts of magnesium hydroxides, 30 parts of organic adhesion agents, 10 parts of silicasol, 0.3 part of defoamer, 35 parts in water.Electrically-conducting paint is pressed following preparation: 3.4 parts of acetylene carbon blacks, 42 parts of organic adhesion agents, 0.3 part of defoamer, 1.2 parts of spreading agents, 60 parts in water.
The invention is not restricted to these disclosed embodiments, the present invention will cover the scope described in the patent book, and the various modification of claim scope and equivalence variation.

Claims (7)

1, a kind of flame resisting wave-absorbing material is to be the cube-corner elements body of matrix with the nonwoven fabrics, it is characterized in that, is coated with flame retardant coating on the surfaces externally and internally of nonwoven fabrics, is coated with conductive coating outside flame retardant coating.
2, flame resisting wave-absorbing material as claimed in claim 1 is characterized in that, said flame retardant coating, its coating are formulated by inorganic composite flame retardants, organic adhesion agent, inorganic adhesive, defoamer and water; Said conductive coating, its coating are formulated by inorganic absorbent, organic adhesion agent, defoamer, spreading agent and water.
3, flame resisting wave-absorbing material as claimed in claim 2 is characterized in that, wherein said inorganic composite flame retardants is one or more in aluminium hydroxide, magnesium hydroxide or the aluminum-magnesium compositing powder.
4, flame resisting wave-absorbing material as claimed in claim 2 is characterized in that, wherein said inorganic absorbent is an acetylene carbon black.
5, flame resisting wave-absorbing material as claimed in claim 2 is characterized in that, wherein said inorganic adhesive is a silicasol.
6, flame resisting wave-absorbing material as claimed in claim 2 is characterized in that, the cube-corner elements body is provided with one or more little cube-corner elements body in the bottom.
7, prepare the method for the described flame resisting wave-absorbing material of claim 1, it is characterized in that, may further comprise the steps:
1) preparation anti-flaming dope: inorganic combustion inhibitor, organic adhesion agent, inorganic adhesive, defoamer and water are mixed, be mixed with anti-flaming dope;
2) brushing flame retardant coating: anti-flaming dope is coated in nonwoven fabrics matrix two surfaces goes up and oven dry;
3) preparation electrically-conducting paint: inorganic absorbent, organic adhesion agent, defoamer, spreading agent and water are mixed, be mixed with electrically-conducting paint;
4) brushing conductive coating: be coated on the flame retardant coating electrically-conducting paint and oven dry;
5) impression moulding: will on marking press, strike out pyramid absorbing material sheet material through matrix fire-retardant and that conductive coating applies;
6) folding forming is single pyramid.
CNB2006100413495A 2006-08-16 2006-08-16 Flame resisting wave-absorbing material and method for making same Expired - Fee Related CN100511487C (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073961A (en) * 2013-01-24 2013-05-01 南京洛普电子工程研究所 Multi-element composite microwave absorbent, microwave absorbing coating, microwave absorbing base material and preparation method
CN103347379A (en) * 2013-07-10 2013-10-09 南京洛普电子工程研究所 Fire-retardant type wide-frequency-band high-power compound wave-absorbing material and preparing method thereof
CN103436220A (en) * 2013-09-17 2013-12-11 南京南大波平电子信息有限公司 Low-frequency stage microwave absorption material
CN103700410A (en) * 2013-12-31 2014-04-02 南京南大波平电子信息有限公司 Difficult-to-burn type wave-absorbing material for electromagnetic compatible anechoic chamber and preparation method thereof
CN103700950A (en) * 2013-12-03 2014-04-02 上海卫星装备研究所 Coating type wave-absorbing component used in high-vacuum condition
CN103889197A (en) * 2012-12-21 2014-06-25 财团法人工业技术研究院 Shielding composite membrane
CN105025695A (en) * 2015-07-28 2015-11-04 苏州驭奇材料科技有限公司 Broadband electromagnetic wave absorption complex with flame-retarding characteristics and manufacturing method of complex
CN106519471A (en) * 2016-10-26 2017-03-22 大连东信微波技术有限公司 Wave absorbing material and preparation method thereof
CN113394573A (en) * 2021-07-25 2021-09-14 西安安聚德纳米科技有限公司 Light-weight broadband wave-absorbing material for high-power microwave darkroom and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103889197A (en) * 2012-12-21 2014-06-25 财团法人工业技术研究院 Shielding composite membrane
CN103889197B (en) * 2012-12-21 2016-12-28 财团法人工业技术研究院 Shielding composite membrane
CN103073961B (en) * 2013-01-24 2015-06-03 南京洛普电子工程研究所 Multi-element composite microwave absorbent, microwave absorbing coating, microwave absorbing base material and preparation method
CN103073961A (en) * 2013-01-24 2013-05-01 南京洛普电子工程研究所 Multi-element composite microwave absorbent, microwave absorbing coating, microwave absorbing base material and preparation method
CN103347379B (en) * 2013-07-10 2016-03-23 南京洛普电子工程研究所 High power combined absorbing material of nonflammable wide-band and preparation method thereof
CN103347379A (en) * 2013-07-10 2013-10-09 南京洛普电子工程研究所 Fire-retardant type wide-frequency-band high-power compound wave-absorbing material and preparing method thereof
CN103436220A (en) * 2013-09-17 2013-12-11 南京南大波平电子信息有限公司 Low-frequency stage microwave absorption material
CN103700950A (en) * 2013-12-03 2014-04-02 上海卫星装备研究所 Coating type wave-absorbing component used in high-vacuum condition
CN103700950B (en) * 2013-12-03 2017-03-01 上海卫星装备研究所 For coating type wave absorbing assembly under high vacuum condition
CN103700410A (en) * 2013-12-31 2014-04-02 南京南大波平电子信息有限公司 Difficult-to-burn type wave-absorbing material for electromagnetic compatible anechoic chamber and preparation method thereof
CN105025695A (en) * 2015-07-28 2015-11-04 苏州驭奇材料科技有限公司 Broadband electromagnetic wave absorption complex with flame-retarding characteristics and manufacturing method of complex
CN106519471A (en) * 2016-10-26 2017-03-22 大连东信微波技术有限公司 Wave absorbing material and preparation method thereof
CN113394573A (en) * 2021-07-25 2021-09-14 西安安聚德纳米科技有限公司 Light-weight broadband wave-absorbing material for high-power microwave darkroom and preparation method thereof

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