CN1908277A - Nonwoven fabrics and methods for making the same - Google Patents

Nonwoven fabrics and methods for making the same Download PDF

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Publication number
CN1908277A
CN1908277A CN 200610108355 CN200610108355A CN1908277A CN 1908277 A CN1908277 A CN 1908277A CN 200610108355 CN200610108355 CN 200610108355 CN 200610108355 A CN200610108355 A CN 200610108355A CN 1908277 A CN1908277 A CN 1908277A
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long filament
monofilament
bondedfibre fabric
fabric
lay
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R·格罗滕
C·约瑟菲亚克
G·里布莱
P·登格尔
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Carl Freudenberg KG
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Carl Freudenberg KG
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Publication of CN1908277A publication Critical patent/CN1908277A/en
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Abstract

The present invention relates to a filamentary nonwoven fabrics made of the materials-the fiber created by the non-fusion spin not fabricated in the spin stick type non-weaving process. The neotype nonwoven fabrics with novel performance combination are made through the filament combined sometime in the nonwoven process. The manufacture can be performed on the ordinary stick type non-weaving device, wherein one part of the tension device acts on the filamentary conveyor not made in the spin stick type non-weaving process.

Description

Bondedfibre fabric and manufacture method thereof
Technical field
The present invention relates to a kind of novel bondedfibre fabric, be used for making the new method and the application in weaving and industrial application thereof of bondedfibre fabric.
Background technology
The plane configuration thing of weaving is exactly known for a long time.The technology that is used for making this plane configuration thing constantly is improved.
Though for example loom belongs to the most ancient in the world machine, also updating up to today.Even because the raising of filling speed mainly is to improve constantly weaving speed, but the basis of processing procedure is before weft yarn can move again round about, to make weft yarn drop to 0 in the speed of two edges of fabric.
Knitting also is a kind of very ancient plane configuration thing manufacturing technique that can utilize machine to carry out.Knitting be one to each independent long filament, the perhaps process that in modern circular loom, also has guiding ground to arrange with the form of tow.
The common ground of above-mentioned two kinds of methods is to adopt continuous long filament as semi-finished product.
Felt and long wool tweed (Loden) are another kind of spinning plane configuration things.Felt is undertaken by the layer to a plurality of particularly wool fibres that stack mutually that fulling milling or acupuncture obtains.Therefore felt also can be regarded the fiber matting that wool is made as.The long wool tweed at first is made into by knitting wool, and the woolen knitwear that will obtain like this becomes so-called long wool tweed by fulling milling felting then.Here it is because the hair unicorn sheet of holding up relates to (also being undesirable usually) hook company of wool fibre.
Nonwoven fabric constitutes another group spinning plane configuration thing.They can pass through dry type or wet method manufacturing.
When making bondedfibre fabric with damp process staple fibre in water, stir very rarely and by separating screen (Ablagesieb) and moisture from, then chemistry or thermally be combined into nonwoven fabric mutually.Dilution factor high in water is guaranteed from the extremely fiber hook company and the inter coagulation mutually mutually of separate sources with the fibre length of lacking.Can realize the very high uniformity that fiber distributes on the whole like this.But the plane configuration thing that obtains can not bear big mechanical load.
The finite length fiber of the fibre bag for preparing from the manufacturing preliminary stage when making bondedfibre fabric with dry process is by shredding, in case of necessity with the mixed with fibers of other type, in combing equipment, it is carried out " combing ", at this moment form fiber web/fiber pile (Faserflor) along preferred orientations.A plurality of this fibroreticulate layers stack (" piling up ") mutually, at this moment can adjust the preferred orientations of fiber by the motion of the lay in the border, and these layers are transformed into nonwoven fabric perpendicular to the nonwoven fabric plane earth by reinforcement means arbitrarily then.This technology allows high productivity ratio simultaneously in that high fiber placement is inhomogeneity.The mixing of fiber allows in very large range to be complementary with desirable flat fabric performance.In order to improve mechanically stable, for example pill resistance or washability must contact major part the crosspoint chemistry or thermally reinforce into so-called binding site.At this moment improved bending stiffness, and flat fabric has lost drapability (Drapierf  higkeit).
When making spunbonded nonwoven, one or more meltings of fusing spin the polymer beads of making in extruder, it are extruded machinery or pneumatically it is stretched and be laid on the lay band by spinning-nozzle.Then with the above-mentioned bondedfibre fabric autofrettage unguyed bondedfibre fabric of mechanical consolidation similarly.
Before several years, also adopting the manufacture method of this plane configuration thing, this plane configuration thing for example is used as the matrix of roof cloth matrix or carpet fiber, they are not had the requirement of textiles drapability usually, and the feature of spunbonded nonwoven is to compare relatively poor uniformity and higher mechanical bearing capacity with the bondedfibre fabric of other type.
Compare with other weaving bondedfibre fabric manufacturing technique, the feature of spunbonded nonwoven equipment is high productivity ratio.This can bring high investment cost, and needs very high repacking time and expense when changing polymer.These factors cause such equipment flexibility to move relatively poorly, and must remain operation.
The common basis of all bondedfibre fabric types is, makes their fiber and piles up mutually by a plurality of (lay in the x-y plane) layer, also must carry out fixed to the bondedfibre fabric of formed mechanical instability in the z direction then.The associated methods of described chemistry or heat causes the decline of drapability.
Compare with other spinning plane configuration thing, bondedfibre fabric has such advantage, and promptly for the bondedfibre fabric plastics, a material or fiber directly are transformed into finished product plane configuration thing.And weaving or when knitting yarn at first must just can be transformed into the spinning plane fabric through plane (configuration piece) forming process of complexity.
Advise that in the prior art monofilament is reeled earlier, then these products is used in the plane configuration thing forming process after it is made.
US-A-3,921,265 and US-A-3,885,279 have illustrated a kind of device that is used for making the method for spinning plane configuration thing and is suitable for this method, wherein yarn is by a plurality of laying device laies.The oriented-laying of yarn has been described here, but the bondedfibre fabric forming process has not been described, it is characterized in that lay to a certain extent by statistical law.In addition not about the explanation of the performance of the yarn of lay.
A kind of device of being made mat or belt by glass fibre or like fibrous has been described in Deutsche Bundespatent 816,215.Wherein in a mechanical conveyor, merge a plurality of long filaments, and become pad as strand twisted back lay on a plane.The lay of thigh is undertaken by the conveying by means of air blast.Difference according to its adjustment can change lay.Do not disclose other details in this part data, particularly thigh is pressed the lay of statistical law.Described strand is retained in the plane configuration thing.
At DE-A-3, a kind of knotted rug that has the second layer base fabric of being made by the endless filament yarn bondedfibre fabric of being made up of the polyester yarn of the mixed and disorderly lay of multilayer has been described in 012,806, yarn is arranged by the parallel construction that intersects.Nonwoven fabric can spin to make or form to have by common traction or unwinding polyester filament and with its common lay and intersect the nonwoven fabric of parallel construction and make by packet type.Do not illustrate that in this part file non-melt spins the use of the fiber of making.
At DE-A-3, illustrated in 630,392 a kind of be used for making be used for depositing water and/or have oleophylic and/or the method for the reinforcing nonwoven fabric of the material of lipophilic characteristic.The formation of nonwoven fabric is spun by direct air blowing and is made (Blasverspinnen) and carry out to a receiving system.
By EP-A-281,865 is known to inorfil, as waterglass fiber or silicate fiber, and the plane configuration thing of the combination of composition.Form nonwoven fabric by directly handle spun fiber with dried lay or wet lay technology.Fiber is by the mutual combination of heat treatment under the temperature more than 50 ℃.Because lower bonding temp must carry out subsequent treatment to spun fiber immediately.
By US-A-5,660,910 known a kind of bondedfibre fabrics with better fracture strength.This bondedfibre fabric also has the reinforcement monofilament of big fiber number except the matrix monofilament.Except the manufacturing of spunbonded nonwoven, also illustrated before to have spun and the monofilament of intermediate storage is processed into bondedfibre fabric.Described monofilament directly is laid on the conveyer belt by an aspirator.The statistics lay of the monofilament of intermediate storage is not disclosed.Owing to adopt the uniformity of the bondedfibre fabric of thick monofilament production also to be restricted.
At DE-A-4, the nonwoven fabric of being made up of monofilament is disclosed in 115,190, described nonwoven fabric has 250g/m 2Big surface density the time have a Mass Distribution very uniformly.In order to make this nonwoven fabric, will resolve into single monofilament by the monofilament (bundle) that various different materials are made by air nozzle, extremely equably it is laid on the face of a motion, then reinforce with known method own.Unexposed bonded fabric with little surface density and homogeneous quality distribution.This just bondedfibre fabric is difficult to make, because on average fall for the easier quilt of the formed inhomogeneities of nonwoven fabric with big surface density and corresponding high unit space fiber number.But only disclose thermoplasticity as fibrous material and spun the material of making.
Summary of the invention
The objective of the invention is from prior art, provide to have the very bondedfibre fabric of high uniformity.
Here novel bondedfibre fabric grouping relates to such product, this endless filament yarn that can not be processed into bondedfibre fabric up to now that comprises.Can expand kind and the performance characteristic and the Application Areas of possible bondedfibre fabric like this.
The present invention relates to have surface density can be up to 250g/m 2With the bondedfibre fabric of the high uniformity that shows as the variation coefficient CV that distributes less than 10% surface density, described bondedfibre fabric comprise by be not form with the long filament of spunbonded nonwoven manufactured, by the long filament of statistical law lay.
In another kind of scheme, the present invention relates to comprise by non-melt spin that the material made is formed, by the bondedfibre fabric of the long filament of statistical law lay.
" long filament " and " plurality of threads " is construed as the configuration piece that is made of fiber or monofilament in this specification scope, the size that wherein is called " length " surpasses all the other two size several magnitude of describing filament cross, and its fiber number changes in the scope of 0.1dtex to 100tex.Common filament length changes in several meters to several thousand kilometers scope.
" fiber " or " plurality of fibers " is construed as time-limited configuration piece in this specification scope, the size that wherein is called " length " surpasses all the other two size several magnitude of describing fiber cross section, and its fiber number changes in 0.1dtex to 100tex scope.Common fibre length changes in 1 millimeter to several centimetres scope.
" monofilament " or " multifilament " is construed as such configuration piece in this specification scope, the size that wherein is called " length " surpasses the several magnitude of all the other two sizes of describing the monofilament cross section, and its fiber number changes in 0.1dtex to 100tex scope.Common filament length changes in several meters to several thousand kilometers scope.
Long filament can be multifilament textile (Filamentgarn) on the meaning of this specification, spun yarn (Fasergarn), monofilament (wire) and twist thread (Zwirn).
Manufacturing is not subjected to any restriction by the material of the formation fiber of long filament of the present invention.Can adopt various material or material blends.Its example comprises by long filament synthetic and/or that the natural material that constitutes fiber is formed, as by thermoplastic polymer, by natural material, as cellulose, modified cellulose or protein, or by inorganic material, the long filament of making as carbon, metal or glass, the long filament that can obtain by peeling process (Sch  lprozess) maybe is as the polytetrafluoroethylene (PTFE) long filament.Except that one pack system silk or fiber, also can adopt multicomponent silk or fiber.
" by the bondedfibre fabric of forming by the long filament of statistical law lay " is interpreted as in this specification scope by long filament being laid in the bondedfibre fabric that produces on the conveyer of motion, wherein carry out the lay of long filament on conveyer by multilayer, long filament be not lay to the lay point of prior appointment, so long filament distributes in each layer independently of each other.The long filament lay can have or not have to carry out towards the ground, preset bearing of assigned position, wherein because this lay process is not accurately to determine accurate lay position.
Bondedfibre fabric of the present invention is made up of multiple extremely different material or combination of materials.
The feature of bondedfibre fabric of the present invention is that at least a portion long filament is not made in adhesive formed non-woven fabrics technology.Different with the generation of monofilament with the common adhesive formed non-woven fabrics autofrettage that the formation of spinning plane thing directly combines, here at least a portion long filament produces in one or several is provided with the step of front, it is carried out intermediate storage, perhaps be not in adhesive nonwoven equipment, produce but be connected in other spinning equipment of its front, use it in nonwoven production then one.Promptly adopting is not the long filament that produces in the nonwoven fabric forming device.One group of this long filament can have fiber or the monofilament of being made up of the material that can not produce in common adhesive nonwoven process.This method allows to make the bondedfibre fabric of being made by new material (combination).Second group of this long filament can have by melting and spin fiber or the monofilament that the material made is formed, in adhesive formed non-woven fabrics technology, can not or can only make described fiber or monofilament, so they are suitable for making in the equipment that is arranged on nonwoven fabric forming device front with higher expense.
First group of examples of material spun the long filament that the material made is formed by non-melt, as cellulosic filaments.
Second group example is to comprise the fiber of POY type (partially oriented yarn) or the long filament of monofilament, perhaps comprise the fiber of FOY type (fully oriented filament) or the long filament of monofilament, perhaps comprise have additive, in the adhesive nonwoven process, can not or be difficult to spin the fiber made or the long filament of monofilament, perhaps be included in to spin and make the back by the high strength fibre of big stretching generation or the long filament of monofilament.
The long filament that can not make with the adhesive nonwoven method that adopts by the present invention can spin the material of making by non-melt fully and form; But described long filament also can spin other fiber that the material made makes or the combination of monofilament is made by these fibers or monofilament and by thermoplasticity; And/or but described long filament spins the material of making and comprise additive by thermoplasticity and forms; And/or described long filament by thermoplasticity can spin make, spin make after the material of post processing in such a way make, this mode can not be carried out in adhesive nonwoven equipment usually, for example repeatedly stretch with very high extensibility, step in case of necessity then bounces back.
But when can not thermoplasticity spinning the material made or thermoplasticity and spin the material of making and make long filament, the technology type that forms long filament is unimportant.Can adopt the monofilament for no reason that obtains by wet type spin processes, dry spinning method, wet-the dry spinning method, gel spinning, decortication method or matrix spin processes (Matrixspinnverfahren), this monofilament can not or be difficult to perhaps can adopt by secondary and spin the spun yarn that the method for making is produced with the manufacturing of adhesive nonwoven process.
Supatex fabric of the present invention be characterized as very high uniformity, this shows less than 10%, especially the changes in weight coefficient CV that distributes less than 7% surface density.
Here determine the changes in weight coefficient that surface density distributes by the following method:
Each goes out two row, 5 * 5cm on the width of flat fabric band 2à 19 samples, wherein second row is with respect to the first row sample that staggers half.
Order is gone out 60 5 * 5cm that are in line before and after the direct of travel of the length upper edge of flat fabric band 2Sample.
The surface density x of each sample i iBe converted into g/m 2, because each sample has 0.0025m 2Area, its surface density must multiply by 400, to obtain with respect to 1m 2Surface density g/m 2
Variation coefficient is obtained by following formula:
CV=(Et*100)/X(%)
Wherein
Et=(∑(x i-X) 2/n) 1/2 X=(∑x i*400)/n
Centre plane density (the g/m of X=bondedfibre fabric 2)
x i=with g/0.0025m 2The weight of the sample i of expression
The n=sample quantities
The shape sample that is used for making the long filament of bondedfibre fabric of the present invention can be selected arbitrarily.Except that monofilament and multifilament, can also adopt short fibre yarn or twist thread.
Bondedfibre fabric is preferred to be formed by comprising by can not thermoplasticity spinning the fiber that the material made, form fiber makes or the long filament of monofilament fully.
Other preferred bondedfibre fabric is except that spinning the long filament that fiber that the material made, form fiber makes or monofilament are formed by can not thermoplasticity spinning also additionally to comprise fiber that the fiber constituent material made forms or the monofilament by melting, or is made up of these two kinds of fibers or monofilament.
Other preferred bondedfibre fabric comprises by POY fiber or POY monofilament or the long filament be made up of FOY fiber or FOY monofilament.Described POY fiber or POY monofilament or FOY fiber or FOY monofilament produce with very high hauling speed on device for spinning, next stretch in case of necessity.Form fiber or the monofilament with very high strength thus, this fiber or monofilament are difficult to create on adhesive nonwoven equipment now.
Another kind of preferred bondedfibre fabric comprises by highstrenghtpiston's fiber or highstrenghtpiston's monofilament, the particularly long filament of being made up of polyester.These fibers or monofilament spin by fusion or dissolving and make generation, then it are stretched strongly.Form fiber or the monofilament with very high strength thus, this fiber or monofilament are very difficult to create on adhesive nonwoven equipment now equally.
Another kind of preferred bondedfibre fabric comprises the long filament of being made by metal or metal alloy.
Another kind of preferred bondedfibre fabric comprises by the plastics that added additive, particularly makes the long filament that dyeing and/or fireproof plastics are formed by spinning.These fibers or monofilament are made or the melt-spinning generation by the spinning material that has added additive being dissolved spin, and then it are stretched.Form fiber or the monofilament that contains additive thus, they can not be made on common adhesive nonwoven equipment.
The preferred example that non-melt spins the material of the formation fiber of making is cotton, wool, cellulose and cellulose derivative (as viscose glue, Modal fibre (Modal), ammonia copper wire, cellulose acetate, half cellulose acetate, Triafol T), polyacrylonitrile, aromatic polyamide (Aramide), and non-thermal plasticity polyurethane, non-melt spin the halogenated polyolefin made, as polytetrafluoroethylene (PTFE), polyvinyl chloride or Vingon and natural rubber, polyvinyl alcohol or carbon.
Cellulose fibre or monofilament especially are interpreted as viscose or the monofilament that obtains by viscose process.Next can be to spin fiber or the monofilament that the method for making obtains by dissolving, for example Lyocell  fiber or Lyocell  monofilament.
Cellulose derivative fibres or monofilament are interpreted as fiber or the monofilament that is derived from by the chemically modified fibre element, for example cellulose acetate or half cellulose acetate.
The preferred example that melting spins the material of the formation fiber of making is that melting spins the thermoplastic condensed polymer who makes, polyester for example, as polyethylene terephthalate, polybutylene terephthalate (PBT) or PLA, aliphatic or aliphatic aromatic polyamide, as polyamide 6, polyamide 6,6 or polyether-ketone, polyarylene sulfide, poly (arylene ether) sulfone (Polyarylenethersulfone), Merlon or protein and protein derivatives, as gelatin, chitin or alginates (Alginate), polypropylene particularly, polyethylene or its copolymer, or thermoplastic polyurethane, comprise Polyurethane Thermoplastic Elastomer, and other melting spins the material of making, and comprises metal alloy as glass or metal.
Thermoplastic condensed polymer who especially preferably adopts melting to spin to make or melting spin the thermoplastic polymer of making and spin the material of making, form fiber as melting.
In the another kind of preferred implementing form of the present invention bondedfibre fabric additionally comprise by the statistical law lay with the monofilament of in the adhesive nonwoven process, making, particularly have mostly two kinds mutually mutual exclusive, can ftracture, multicomponent monofilament, especially the ftractureed monofilament of forming by polyester/polyamide, polyester/polyolefin, polyamide/polyolefine, polyolefin/polyolefin, polyester/polyurethane, polyamide/polyurethane, polyolefin/polyurethane (Spaltfilamente) of fibrillation monofilament form that melting spins the polymer of making and construct fiber.
This monofilament that ftractures and the bondedfibre fabric made by it are for example by US-A-5, and 970,583 as can be known.
Especially preferably adopt its long filament only by spin the bondedfibre fabric that monofilament that the material made, form fiber makes and/or filament are formed with non-melt.
By a kind of flexible program of bondedfibre fabric of the present invention have arbitrarily and can with the surface density of application corresponding purpose coupling.Surface density for example is 15 to 1000g/m 2, especially 50 to 600g/m 2, particularly 50 to 250g/m 2
Another kind of flexible program by bondedfibre fabric of the present invention has maximum 250g/m 2, especially 15 to 250g/m 2, particularly 20 to 150g/m 2Surface density.
Be used in that monofilament in the bondedfibre fabric of the present invention and/or filament can have arbitrarily and and the fiber number that is complementary of corresponding application target.Fiber number for example is 0.05 to 200dtex, and especially 0.15 to 150dtex.
Except adopting monofilament and/or filament by the mixture that can also adopt hetero fibre-for example the monofilament of homofil and/or the staple-form by bicomponent fiber Texturized or not Texturized form or various dissimilar fiber.
By in the bondedfibre fabric of the present invention, long filament does not have isotropically lay of preferred orientations ground-promptly usually.Bondedfibre fabric can be made up of the long filament of the same race of identical or different fiber number.The long filament that constitutes bondedfibre fabric can be made of various very different monofilament and/or fiber, for example constitute by homofil or one pack system monofilament, but also can constitute, or constitute by the admixture of bicomponent fiber or monofilament and homofil or monofilament by 100% bicomponent fiber or monofilament.Also can adopt the long filament made by synthetic fiber or monofilament and the mixture of natural fabric.
By adopting the filamentary material that in spunbonded nonwoven, do not adopt up to now-combine with the filamentary material that in common spunbonded nonwoven, adopts in case of necessity, can make novel bondedfibre fabric with new performance combination.The bondedfibre fabric that for example can have conduction and heat conductivility by the production of lay wire, or by being laid in the long filament that correspondingly adds additive in the spinning material, can produce to be equipped with and spin the bondedfibre fabric of making dyeing or fire resistance, or can produce by the lay high strength filaments and to have high-intensity especially bondedfibre fabric.
Can produce such spinning plane configuration thing with described method, described plane configuration thing is equivalent to fabric on its changes of properties scope, but the different long filament that has by the statistical law lay with fabric.Can also produce such spinning plane configuration thing, wherein can equally with staple fiber nonwoven fabric carry out mixed with fibers, but have much much higher and lasting durability degree,, long filament is embedded in the structure of flat fabric because the situation with fabric is similar in bondedfibre fabric of the present invention.For a series of performance, as maximum pull, lauderability, tearing toughness (WRK) and pilling property (wearing and tearing), this can make and reach obvious improved value.
Can mechanically finalize the design and further processing with known method itself after being laid on the conveyer by bondedfibre fabric of the present invention.
After just lay becomes multilayer, formed mechanically unsettled and that can not operate, unconjugated nonwoven fabric, described nonwoven fabric must be finalized the design by each layer knitted.This by adopt machinery, hydraulic machine, pneumatic and/or hot method carries out and/or undertaken by chemical bond.
Preferred especially by adopting the method for machinery, hydraulic machine and/or heating power, particularly by adopting acupuncture or water-jet to carry out the reinforcing of bondedfibre fabric.
Bondedfibre fabric of the present invention can be included in normally used other additive in the bondedfibre fabric.The example of these additives comprises finishing agent (Appretur), flexibilizing agent (Avivage), antistatic auxiliary agent (Antistatika), bactericide (Biotide), antioxidant (Antioxidantien), gives additive, adsorbent or the filler of conductive capability.
By the invention provides a kind of method new and that simply be used for making bondedfibre fabric, it is characterized in that high productivity ratio and flexibility.The method allows by the material manufacturing bondedfibre fabric that can not or be difficult to be processed into the bondedfibre fabric that comprises endless filament yarn up to now in addition.
The invention still further relates to a kind of method that is used for making bondedfibre fabric, it comprises following steps:
I) to a plurality of storage device A input long filaments, particularly comprise by non-melt and spin the fiber that the material made forms or the long filament of monofilament,
The long filament that ii) is different from the long filament that is arranged in storage device A in case of necessity to other storage device B input,
Iii), especially from storage device A, extract long filament out by a plurality of transports by at least one transport,
Iv) will be laid on the conveyer by statistical law with the form of unconjugated nonwoven fabric and by a plurality of layers at the long filament that step I is extracted out in ii),
V), especially from storage device B, extract long filament out by a plurality of transports in case of necessity by at least one transport,
Vi) the long filament that will extract out in v) in step where necessary is laid in by statistical law on the conveyer with the form branch multilayer of unconjugated nonwoven fabric,
Vii) by known machinery itself, hydraulic machine, pneumatic and/or hot method and/or by adopting chemical bond that resulting unguyed nonwoven fabric is reinforced.
In another kind of flexible program, the present invention relates to a kind of method that is used for making bondedfibre fabric, wherein at least a portion long filament is directly imported from the other manufacturing equipment of nonwoven fabric forming device.This method may further comprise the steps:
Viii) input comprise by non-melt spin fiber that the producing material material forms or monofilament, from the long filament of the manufacturing equipment A ' of these long filaments, and draw these long filaments by at least one transport,
I) in case of necessity to a plurality of storage device A input long filaments, particularly comprise by non-melt and spin the fiber that the material made forms or the long filament of monofilament,
The long filament that ii) is different from the long filament that is arranged in storage device A in case of necessity to other storage device B input,
Iii) from storage device A, extract long filament by at least one transport out in case of necessity,
Ix) will be in step I) in the long filament extracted out be laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric,
Iv) the long filament that will extract out in ii) in step I is laid in by statistical law on the conveyer with the form and the branch multilayer of unconjugated nonwoven fabric,
V) from storage device B, extract long filament by at least one transport out in case of necessity,
Vi) will be laid in by statistical law on the conveyer with unconjugated nonwoven fabric form and branch multilayer at the long filament that step is extracted out in v) in case of necessity,
Vii) by known machinery itself, hydraulic machine, pneumatic and/or hot method and/or by adopting chemical bond that resulting unguyed nonwoven fabric is reinforced.
The enforcement of described method can be carried out on a common adhesive nonwoven equipment.Here existing stretching device is at least in part with the transport or the draw-gear that act on from the long filament of storage device.In one or more steps that are arranged on the front, make described long filament and put it into storage device or directly from manufacturing equipment input nonwoven fabric forming device.Described long filament is with acting on the further long filament of processing input in adhesive nonwoven equipment.
Above-mentioned except making by the bondedfibre fabric of the present invention, can also make common spunbonded nonwoven with method of the present invention.In a kind of method flexible program in back, in storage device, store the long filament of forming by the fiber that can in the adhesive nonwoven process, make or monofilament.Wherein the nonwoven fabric forming process is carried out like this, promptly obtains having the bondedfibre fabric of the changes in weight coefficient CV that the surface density of hope distributes.Wish the layer that lay is as much as possible, surface density is as far as possible little in principle.Preferably press bondedfibre fabric of the present invention with method manufacturing of the present invention.
Can adopt known devices as storage device, for example reel or bar tube.Each storage device A and B can comprise identical or different long filament.
The equipment that can adopt wet type or dry spinning equipment or be used for the secondary spinning is as other manufacturing equipment A '.
Can adopt known devices as transport, the device of air force work particularly is as pneumatic conveyor.
The long filament of storage device A and/or B or other manufacturing equipment preferably guides by the thread guide that is arranged on the transport porch before entering transport.This method flexible program allows to produce the bonded fabric of the mass change coefficient CV with especially little surface density distribution.
Come self-storing mechanism A and in case of necessity long filament A, the A ' of B or other manufacturing equipment and B and in case of necessity by the lay of spun other monofilament of adhesive nonwoven equipment C by known method by statistical law ground rather than to the lay point ground of predesignating, especially carrying out on the lay band on the one advancing conveyer, the lay band can have opening in case of necessity, by the overlapped distribution of multilayer.
In order to carry out lay by statistical law, can the known lay unit of employing itself.Its example comprises arrangement for deflecting, and described arrangement for deflecting makes endless tow leave the mechanical conveyor post deflection, and changes advancing of one filament with statistical.The example of arrangement for deflecting comprises deflector, the device of air force work or the gatherer of tubulose that deflection plate or other are mechanically worked, they along and/or transverse to the reciprocating motion of moving of conveyer.The purpose of these devices is to guarantee that long filament is laid on the conveyer brokenly.
In order to realize that high uniformity, long filament branch multilayer are laid on the conveyer.Adjust the number of plies like this according to desirable productivity ratio (speed of=conveyer), promptly obtain the uniformity of wishing.
By under the situation of each layer of arrangement for deflecting lay, adopt ten usually at least, at least ten two arrangements for deflecting especially are with the quantity of the single layer realizing requiring.
Under the situation that adopts curtain falling type spinning equipment (Vorhangspinnanlage), adopt two as far as possible, four equipment that front and back are linked in sequence especially are with the quantity of the single layer realizing requiring.
Promptly introduce the method for continuous production of a kind of like this spinning plane configuration thing (being also referred to as bondedfibre fabric here), promptly mechanically, hydraulic machine ground or pneumatically with any source, as metal, mineral, natural or synthetic can not be by melt-spinning, in case of necessity with can be combined by the long filament that melt-spinning is made, continuous promptly for no reason long filament shape solid by statistical law ground promptly to the lay point of prior regulation the overlapped distribution shakedown of minute multilayer be not put on the conveyer, for example on the lay band in the forward travel, then make long filament shape solid and the interior long filament shape solid machinery of layer on the described layer, hydraulic machine, pneumatic, heating power or chemically mutually combine.
When making bondedfibre fabric of the present invention, can utilize the equipment and technology of adhesive nonwoven equipment.
This can be such equipment, and wherein the fabric width of spinning and draw unit is equivalent to total product fabric width (so-called curtain falling type spinning equipment).
Also can be such equipment, wherein spinning and draw unit are independent circular spinning packs, they at first make the monofilament that stretches and finish, and with induction system described monofilament are flowed to the lay band then, and can adjust the product fabric width by this induction system in described equipment.
But do not use in the method for the invention or only the part use adhesive nonwoven equipment to be used for the part of melt-spinning and stretched thermoplastic polymer.The long filament that at least a portion that is arranged on the stretching device in the adhesive nonwoven equipment is used for having produced is imported and is transported on the conveyer from storage device and/or other manufacturing equipment.
In a kind of preferred form of implementation, adhesive nonwoven equipment is arranged by a kind of pipe of similar pipe organ sound pipe and is formed, described pipe guarantees respectively at least one endless filament yarn (bundle) pneumatic conveying to the lay band that advances continuously, and from its pipe outlet by the edge and transverse to lay band direct of travel by the induction system of statistical law vibration, the lay system of vibrating by statistical law by the edge with transverse to lay band direct of travel or by making air between pipe end and lay band, realize the distribution of long filament by statistical law by moving of statistical law.
In a kind of preferred variant of method of the present invention, the motion of pressing statistical law by the lay unit, by the motion of pressing statistical law of lay band, carry out the lay of long filament by the motion of statistical law or by two or three combination in the described measure by statistical law by the air between lay unit and lay.
In the another kind of modification preferred version of method of the present invention, the long filament that is laid on the conveyer fixedly remains on the conveyer by air negative pressure (suction).
The such method of preferred especially employing, in the method except that long filament A and/or A ' with go back lay monofilament C the long filament B in case of necessity, described monofilament produces by the material that forms long filament is carried out melt-spinning in identical equipment, and after through a stretching device with long filament A and/or A ' and in case of necessity in addition long filament B be laid on the conveyer.
A kind of particularly preferred flexible program of method of the present invention is included in and makes monofilament C in the adhesive nonwoven equipment, described monofilament by at least two kinds inconsistent, can ftracture, melting spins the multicomponent monofilament that the polymer with forming fiber made is made, and divides described multicomponent monofilament by water bundle inject process in step in vii).
After long filament is laid on the conveyer, it is flowed to the reinforcing step that one or several is connected in proper order.
The reinforcing of resulting unguyed nonwoven fabric is carried out by known machinery itself, hydraulic machine, pneumatic and/or hot method and/or by chemical bond.
Its example is to adopt needing machine, liquid or air beam, calender or heat cross-linking bond or binding fiber and self-crosslinking bond.Also can adopt the combination of these methods.
Preferred reinforcement process is to reinforce by adopting the water bundle to spray when making bondedfibre fabric of the present invention.
Bondedfibre fabric of the present invention can be used for very different fields.Its example is included in weaving and particularly technical application, and bondedfibre fabric of the present invention can be used in the application scenario of having only fabric or other plane configuration thing to be competent at present.For example as textiles such as dress material, household textiles or industrial textiles, or as technical fabric, in particular as the high-strength material of the spinning plane configuration thing that is used for building field, or as applying or the matrix of the bondedfibre fabric of dipping, or be used for the filtration of fluid stream or liquid.
These application also are contents of the present invention.
The energy carrier that bondedfibre fabric described here can be used in by chemistry produces in the fuel cell of electric energy.For example by the known hydrogen oxygen cell of reference.Be provided with film in fuel cell between electrode, these films can set so-called gas diffusion layers, and described gas diffusion layers should not damage film as far as possible.Bondedfibre fabric described here is particularly suitable for the part as gas diffusion layers or gas diffusion layers, because exist hardly because the fiber end of bondedfibre fabric damages the danger of film.This is relevant with the structure of bondedfibre fabric structure, they by long filament or for no reason fiber constitute.This structure also shows to have to have only the seldom surface texture of fiber end except high steadiness.
The specific embodiment
Following Example illustrates the present invention and does not limit the present invention.
Example 1
The not twisted single monofilament fiber number of 84f31 type of 10 cops (spinning reel) ENKA factory is that the continuous filament rayon yarn yarn of 2.7dtex is suspended on one and is provided with on the panel of keeper, the narrow end by conical cop (Cops) of setting out therefrom imports one with monofilament lines and be used as nozzle in the venturi of draw unit of firm spun monofilament usually in adhesive nonwoven equipment, and with its pneumatic extraction from cop.Yarn is introduced in the pipe-line system, pipe-line system converts a so-called steel traveler system (Traveller-System) to, described steel traveler system is made up of the pipe that stretchably moves into mutually, along machine direction with perpendicular to the head of machine direction vibration the monofilament of ejection is distributed on the lay band of advancing along machine direction by statistical law simultaneously at the place, end one of pipe.
Under a pressure for the stretching of firm spun monofilament polyester 3.2bar commonly used, can be near 3000m/min, one uniform, but in the about 500mm of asymmetrical diameter regional the viscose glue monofilament lines is laid on the lay band under the situation of about 200g/min.
Wood glue (Ponal with water dilution in 1: 30, Henkel factory) dashes the fiber web that drenches pine, evaporation water in a calendering step, now, in first step the pre-slightly nonwoven fabric of reinforcing is carried out durability by means of needing machine and reinforce (wherein spraying the glue position overwhelming majority unclamps), the sparge pipe à with 4 230bar and about 10m/min in second step finally reinforces into viscose glue monofilament bondedfibre fabric for no reason with it.Obtain changes in weight coefficient CV and be 7.6 122g/m 2Surface density.
Example 2
Be similar to 84f60 type that example 1 produces 10Cops ENKA factory not twisted, the single monofilament fiber number is in the draw unit of the adhesive nonwoven testing equipment described in the continuous filament rayon yarn yarn input example 1 of 1.4dtex.Be about under the quantum of output of 220g/min and at a spinning part, the zone of lay one about 55cm diameter.Open now the steel traveler system, adjust the lay fabric width like this, make circuitously transverse to the zone of institute's lay of the lay band motion of advancing most of overlapped with respect to the lay tape speed.
As chemical bond, common wood glue on the dilution market, 1: 30 ground of water is sprayed at it equably on the fiber web that slowly advances with a hand-held water jet (shower nozzle of watering flowers), and in the calender of heating solvent (water) is evaporated.The bonding viscose glue monofilament lines long filament slightly mutually that obtains is in this way flowed to a needing machine, and with every cm 2About 60 pins are reinforced so in advance, even fabric warrping gets up.
Fabric is launched before a water bundle sprays ruggedized equipment, import this equipment, spray with 4 * 230bar water bundle under the speed of about 10m/min there and reinforce, then dry in a float drier.Obtain an about 40cm wide, surface density is 115g/m 2, changes in weight coefficient CV is 6.1% non-thermal plasticity bondedfibre fabric.
Example 3
Be similar to the not twisted single monofilament fiber number of 147f42 type that example 1 produces 10Cops ENKA factory and be in the draw unit of the adhesive nonwoven testing equipment described in the continuous filament rayon yarn yarn input example 1 of 3.9dtex.Under the transporting velocity of about 2400m/min, can obtain the quantum of output of 330g/min and the zone of an about 45cm.Obtain changes in weight coefficient CV and be 8.2% 152g/m 2Surface density.
Example 4
Being similar to example 3 feeds the not twisted continuous filament rayon yarn yarn of 84f60 type that 10Cops ENKA factory produces in the draw unit of the adhesive nonwoven testing equipment described in the example 1.Obtaining one, to have changes in weight coefficient CV be that 9.8% surface density is 234g/m 2The zone.
Example 5
At an EP-A-814, described in 188, be used for making in the adhesive nonwoven equipment of little monofilament spunbonded nonwoven, during the spinning speed with about 4500m/min is used for the process that just polyester-polyamide bicomponent monofilament spun, that be in stretching step stretches, respectively to draw unit, it is the continuous filament rayon yarn yarn in the nozzle input example 3 in the venturi, carry out lay simultaneously, and the water bundle spray to reinforce combination, make the bicomponent monofilament cracking simultaneously and it is reinforced.
Here unexpectedly under the much higher bicomponent monofilament spinning speed of the continuous filament rayon yarn yarn speed of the stretching air pressure of about 3.5bar and the 1500m/min described in the ratio 1, do not break down.Do not occur stopping up in the long steel traveler system (pipe of stretchably work) of about 7-10m, when lay, do not have knot yet.Therefore can realize the unit tearing strength of much better little monofilament bondedfibre fabric.
Example 6
Be similar in the test of carrying out in the example 5 at another, the FOY-PET multicomponent monofilament lines of the 100f88 type monofilament of SETILA factory is added in the just spun bicomponent monofilament that is in draw stage, and select the reinforcing condition like this, make and also realize good anti-pilling.Owing to added the tearing strength that multifilament textile can improve resulting flat fabric greatly.Although bicomponent monofilament moves in pipe-line system with processing procedure speed 4500m/min commonly used, withdrawal speed only reaches 1500m/min in contrast to this simultaneously, does not break down in processing procedure.Simultaneously can realize extraordinary surface density uniformity.
The bondedfibre fabric that is produced has following characteristic value:
Surface density 100 is to 107g/m 2CV value 5.2-7.2%
Surface density 127 is to 133g/m 2CV value 5.2-6.4%
Surface density 164 is to 168g/m 2CV value 4.8-5.4%
Example 7
Repeat the method for example 5.Because viscose glue allows to have the color that is different from polyester and polyamide, the test polyester mutifilament yarn (polyethylene terephthalate of forming by high strength (POY) polyester=PET) repeat.For this reason, in the continuous process that the spinning speed with about 4500m/min stretches to the new spun polyester-polyamide bicomponent monofilament that is in the stretching step, in the adhesive nonwoven equipment described in the example 5 to draw unit, promptly the article number that nozzle is imported EETILA factory respectively in venturi is 12058 to have the 100f88 type POY-PET-multifilament of single monofilament fiber number 1.14dtex, carry out lay together, and the water bundle spray to reinforce and to carry out combination, at this moment makes the bicomponent monofilament cracking and reinforces.
Example 8
One have rectangular configuration hold court from behind a screen or adhesive nonwoven equipment in the melt spinning part of (spinning pack on the whole width of equipment) inoperative equipment.
By means of second reel stand that is used for each 20 long filament reel, with the ElastallanIREL 22dtex type polyurethane multifilament of 40 bursts of Elastogran factories that on the width of 80cm, keep proportional spacing by a device that is similar to comb leniently side set out the importing rectangle the 3rd air duct (Terti  rluftkanal) and flow to the lay band.
Obtain having changes in weight coefficient CV and be 6% 100g/m 2Surface density.

Claims (30)

1, has the highest 250g/m 2Surface density and have by using 5*5cm 2Sample obtain, show as bondedfibre fabric less than the high uniformity of 10% surface density distribution variation coefficent CV, described bondedfibre fabric comprise by can not form with the long filament of adhesive nonwoven manufactured, by the long filament of statistical law lay.
2, comprise by non-melt and spin the bondedfibre fabric that the producing material material is formed by statistical law lay long filament.
3, by the bondedfibre fabric of claim 1 or 2, it is characterized by: described bondedfibre fabric has the long filament of being made up of fiber or monofilament.
4, by each bondedfibre fabric of claim 1 to 3, it is characterized by: described bondedfibre fabric has the uniformity that shows as less than 7% surface density distribution variation coefficent CV.
5, by each bondedfibre fabric of claim 1 to 4, it is characterized by: described bondedfibre fabric has by highstrenghtpiston's fiber or the long filament be made up of highstrenghtpiston's monofilament.
6, by each bondedfibre fabric of claim 1 to 5, it is characterized by: described bondedfibre fabric has the long filament of being made up of metal or metal alloy.
7, by each bondedfibre fabric of claim 1 to 6, it is characterized by: described bondedfibre fabric has the plastics that are added with additive, especially makes the long filament that dyeing and/or flame-retarded plastic are formed by spinning.
8, by each bondedfibre fabric of claim 1 to 7, it is characterized by: described bondedfibre fabric additionally has by statistical law lay and the monofilament made in the adhesive nonwoven process.
9, press the bondedfibre fabric of claim 8, it is characterized by: the monofilament of making in the adhesive nonwoven process is the monofilament that can ftracture, described ftracture monofilament by comprise at least two kinds mutually mutual exclusive, can ftracture, multicomponent monofilament that melting spins the polymer of making and form fiber derives, particularly the ftractureed monofilament of being made up of the combination of polyester/polyamide, polyester/polyolefin, polyamide/polyolefine, polyolefin/polyolefin, polyester/polyurethane, polyamide/polyurethane, polyolefin/polyurethane is derived.
10, by the bondedfibre fabric of claim 2, it is characterized by: described bondedfibre fabric only spins monofilament and/or the spun yarn that the fiber forming material made forms by non-melt and forms.
11, press the bondedfibre fabric of claim 2 or 10, it is characterized by: non-melt spins the material of making and selects from following these groups, these groups are by cotton, wool, cellulose and cellulose derivative, particularly viscose glue, Modal fibre, ammonia copper wire, cellulose acetate, half cellulose acetate, Triafol T; By polyacrylonitrile, aromatic polyamide (Aramide), non-thermal plasticity polyurethane, non-melt spin halogenated polyolefin, particularly polytetrafluoroethylene (PTFE), polyvinyl chloride or Vingon and natural rubber, polyvinyl alcohol or the carbon made and form.
12, by the bondedfibre fabric of claim 2 or 10, it is characterized by: it is that the polymer that forms fiber maybe can spin the polymer of making by the peeling process that non-melt spins the material of making.
13, bondedfibre fabric by claim 8, it is characterized by: the monofilament of making in the adhesive formed non-woven fabrics manufacture process spins the thermoplastic condensed polymer who makes from melting and derives out, described condensation polymer is from by polyester, polyamide, polyether-ketone, polyarylene sulfide, the poly (arylene ether) sulfone, Merlon, select in the group that protein and protein derivatives are formed, perhaps spin the thermoplastic polymer of making and derive out from fusible touching, described polymer is selected from the group of being made up of polyolefin and polyurethane, perhaps spin make material derived from other melting and come out, described material is from by metal and glass or by two or more these condensation polymers, select in the group that the combination of polymer or other material is formed.
14, by each bondedfibre fabric of claim 1 to 13, it is characterized by: described bondedfibre fabric is reinforced by adopting machinery, hydraulic machine and/or by the use of thermal means, particularly reinforces by adopting acupuncture or water bundle to spray.
15, be used for making the method for bondedfibre fabric, may further comprise the steps:
I) to a plurality of storage device A input long filaments, particularly comprise by non-melt and spin the fiber that the material made forms or the long filament of monofilament,
The long filament that ii) is different from the long filament that is arranged in storage device A in case of necessity to other storage device B input,
Iii) from storage device A, extract long filament out by at least one transport,
Iv) the long filament that will extract out in ii) in step I is laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric,
V) from storage device B, extract long filament by at least one transport out in case of necessity,
Vi) the long filament that will extract out in v) in step in case of necessity is laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric, and
Vii) add and solidify resulting unguyed nonwoven fabric by machinery, hydraulic machine, pneumatic and/or by the use of thermal means and/or by chemical bond.
16, make the method for bondedfibre fabric, may further comprise the steps:
Viii) input comprise by non-melt spin fiber that the producing material material forms or monofilament, from the long filament of the manufacturing equipment A ' of these long filaments, and draw these long filaments by at least one transport,
I) in case of necessity to a plurality of storage device A input long filaments, particularly comprise by non-melt and spin the fiber that the material made forms or the long filament of monofilament,
The long filament that ii) is different from the long filament that is arranged in storage device A in case of necessity to other storage device B input,
Iii) from storage device A, extract long filament by at least one transport out in case of necessity,
X) will be in step I) in the long filament extracted out be laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric,
Iv) the long filament that will extract out in ii) in step I is laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric,
V) from storage device B, extract long filament by at least one transport out in case of necessity,
Vi) the long filament that will extract out in v) in step in case of necessity is laid on the conveyer by statistical law with the form and the branch multilayer of unconjugated nonwoven fabric, and
Vii) by machinery, hydraulic machine, pneumatic and/or by the use of thermal means and/or by adopting chemical bond to reinforce resulting unguyed nonwoven fabric.
17, by the method for claim 15 or 16, it is characterized by: adopt reel or bar tube as storage device.
18, by the method for claim 16, it is characterized by: the equipment that adopts wet type or dry spinning equipment or be used for the secondary spinning is as other manufacturing equipment A '.
19, by each method of claim 15 to 18, it is characterized by: adopt pneumatic conveyor as transport.
20, by each method of claim 15 to 18, it is characterized by: come self-storing mechanism A and/or B and/or from the long filament of other manufacturing equipment A ' before entering transport by being arranged on the thread guide guiding of transport porch.
21, by each method of claim 15 to 20, it is characterized by: described method is implemented on adhesive nonwoven equipment, and wherein spinning and draw unit are provided with along the entire product fabric width.
22, by each method of claim 15 to 21, it is characterized by: described method is implemented on adhesive nonwoven equipment, being used for making and stretching the spinning pack of the monofilament finish as spinning and draw unit of single circle wherein is set, and described adhesive nonwoven equipment has a transfer system, utilize this transfer system that monofilament is flowed to the lay band, wherein the product fabric width can be by the transfer system adjustment.
23, by each method of claim 15 to 22, it is characterized by: long filament A and/or long filament A ' and also have the lay of long filament B press statistical law ground in case of necessity, not to the lay point of prior regulation carry out on the overlapped lay band that is distributed in a forward travel of minute multilayer.
24, by each method of claim 15 to 23, it is characterized by: except that long filament A and/or long filament A ' with also have the long filament B in case of necessity, lay monofilament C also, described monofilament C is made by the melt-spinning of the material that forms long filament in identical equipment, and after through a stretching device with long filament A and/or long filament A ' with also have long filament B to be laid on the lay band in case of necessity.
25, by the method for claim 24, it is characterized by: monofilament C by at least two kinds mutually mutual exclusive, can ftracture, melting spins the multicomponent monofilament that the polymer that forms fiber made is formed, described monofilament is handled by water spray in vii) in step and is ftractureed.
26, by each method of claim 15 to 25, it is characterized by: the motion of pressing statistical law of the lay that long filament is pressed statistical law by the lay unit, the motion of pressing statistical law by the lay band, by carrying out of the air between lay unit and the lay band by the motion of statistical law or by two or three combination in the described measure.
27, by each method of claim 15 to 26, it is characterized by: the long filament that is laid on the conveyer belt firmly remains on the conveyer by air negative pressure (suction).
28, by each method of claim 15 to 27, it is characterized by: reinforce by adopting the water bundle to spray.
29, by each bondedfibre fabric of claim 1 to 14 as textiles, as dress material, as household textiles or industrial textiles, as technical fabrics or as the matrix of the bondedfibre fabric of the dipping that applies, or the application in the filtration of fluid stream or liquid.
30, by each the application of bondedfibre fabric in fuel cell of claim 1 to 14.
CN 200610108355 2005-08-02 2006-08-02 Nonwoven fabrics and methods for making the same Pending CN1908277A (en)

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DE102005036209.5 2005-08-02
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102535014A (en) * 2011-12-14 2012-07-04 山东俊富非织造材料有限公司 Manufacturing method of collagen fiber web and application of spunbonded spundlaid in manufacturing method
CN102918191A (en) * 2010-03-22 2013-02-06 纳幕尔杜邦公司 Process for making nonwoven webs
CN103320968A (en) * 2013-07-12 2013-09-25 天津工业大学 Manufacturing method for filament non-woven fabric
CN103612443A (en) * 2013-11-19 2014-03-05 常熟市一心无纺制品有限公司 Non-woven fabric free of supporting combustion
CN109072518A (en) * 2016-04-27 2018-12-21 阿斯顿强生有限责任公司 Technical fabric, especially conveyer belt
CN109891016A (en) * 2017-01-16 2019-06-14 株式会社巴川制纸所 Metallic fiber nonwoven fabric
CN110359180A (en) * 2019-06-13 2019-10-22 大连华阳新材料科技股份有限公司 A method of improving spun-bonded non-woven product of production line uniformity
CN114787440A (en) * 2019-12-17 2022-07-22 兰精股份公司 Method for producing a spunbonded nonwoven

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102918191A (en) * 2010-03-22 2013-02-06 纳幕尔杜邦公司 Process for making nonwoven webs
CN102535014A (en) * 2011-12-14 2012-07-04 山东俊富非织造材料有限公司 Manufacturing method of collagen fiber web and application of spunbonded spundlaid in manufacturing method
CN103320968A (en) * 2013-07-12 2013-09-25 天津工业大学 Manufacturing method for filament non-woven fabric
CN103612443A (en) * 2013-11-19 2014-03-05 常熟市一心无纺制品有限公司 Non-woven fabric free of supporting combustion
CN109072518A (en) * 2016-04-27 2018-12-21 阿斯顿强生有限责任公司 Technical fabric, especially conveyer belt
CN109891016A (en) * 2017-01-16 2019-06-14 株式会社巴川制纸所 Metallic fiber nonwoven fabric
CN109891016B (en) * 2017-01-16 2022-04-29 株式会社巴川制纸所 Metal fiber non-woven fabric
CN110359180A (en) * 2019-06-13 2019-10-22 大连华阳新材料科技股份有限公司 A method of improving spun-bonded non-woven product of production line uniformity
CN114787440A (en) * 2019-12-17 2022-07-22 兰精股份公司 Method for producing a spunbonded nonwoven
CN114787440B (en) * 2019-12-17 2023-09-12 兰精股份公司 Method for producing a spunbonded nonwoven fabric

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