CN1901767A - Organic electroluminescence display - Google Patents

Organic electroluminescence display Download PDF

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Publication number
CN1901767A
CN1901767A CN 200510085449 CN200510085449A CN1901767A CN 1901767 A CN1901767 A CN 1901767A CN 200510085449 CN200510085449 CN 200510085449 CN 200510085449 A CN200510085449 A CN 200510085449A CN 1901767 A CN1901767 A CN 1901767A
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Prior art keywords
organic electroluminescent
display
dielectric layer
encapsulating film
electroluminescent device
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CN 200510085449
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CN100461980C (en
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蔡亚萍
高一龙
王良元
曾启光
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Chunghwa Picture Tubes Ltd
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Chunghwa Picture Tubes Ltd
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Abstract

This invention relates to an electroluminescent display including a base board, multiple organic electroluminescent elements, a first packaging film, a second packaging film and a third packaging film, in which, these organic electroluminescent elements are set on the base board and include multiple EL elements of a first color light, a second color light and a third color light, and elements of different color lights use different packaging films to emit the optimum light intensity.

Description

Display of organic electroluminescence
Technical field
The present invention relates to a kind of display of organic electroluminescence (OrganicElectro-Luminescence Display, and be particularly related to a kind of display of organic electroluminescence that on the organic electroluminescent device of different color light, forms different encapsulating films respectively OELD).
Background technology
Because multimedia society is progressive rapidly, the technology of semiconductor element and display unit also has tremendous progress thereupon.With regard to display, because display of organic electroluminescence has the restriction of no visual angle, hangs down manufacturing cost, high answer speed (being about more than hundred times of liquid crystal), power saving, the DC driven that can be used in portable machine, operating temperature range is big and in light weight and can meet the characteristic requirement of multimedia era display with hardware device miniaturization and slimming or the like.Therefore, display of organic electroluminescence has great development potentiality, is expected to become follow-on novel flat-panel screens.
The luminous mechanism of display of organic electroluminescence combines in organic material layer with electronics by the hole launches photon, but because general organic material is mostly easily because of making moist or oxidation changes its material behavior, and then influence its luminous mechanism, even cause light-emitting component to lose efficacy.Therefore in the manufacture process of organic EL display panel, how to prevent that the organic material layer oxidation of making moist from being very important problem.
Figure 1A is a kind of partial cutaway schematic of known display of organic electroluminescence.Please refer to Figure 1A, known display of organic electroluminescence 100 comprises substrate 110, a plurality of organic electroluminescent device 120 and encapsulating film 130, wherein these organic electroluminescent devices 120 are arranged on the substrate 110, and organic electroluminescent device 120 comprises ruddiness, green glow and blue-ray organic electroluminescent element 120a, 120b, 120c respectively.Encapsulating film 130 coats these organic electroluminescent devices 120, to prevent that extraneous aqueous vapor and oxygen from entering in these organic electroluminescent devices 120, with the material and the characteristics of luminescence that keep these organic electroluminescent devices 120, wherein the material of encapsulating film 130 generally is to use silicon nitride.
Another kind of known display of organic electroluminescence is to use cap to prevent that extraneous aqueous vapor and oxygen from entering in these organic electroluminescent devices.Shown in Figure 1B, display of organic electroluminescence 101 comprises substrate 110, a plurality of organic electroluminescent device 120 and cap 140, and what wherein the material of cap 140 was commonly used is glass or metal.
Yet, in known display of organic electroluminescence 100,101, because ruddiness, green glow and blue-ray organic electroluminescent element 120a, 120b, ruddiness, green glow and blue light that 120c sent respectively are for the light transmittance of capping film 130 or cap 140 neither identical (wavelength because of ruddiness, green glow and blue light is neither identical).Therefore ruddiness, green glow and blue light can't show best luminous intensity simultaneously after by capping film 130 or cap 140.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of display of organic electroluminescence, the light that each organic electroluminescent device is sent can show best luminous intensity after passing encapsulating film.
The present invention proposes a kind of display of organic electroluminescence, comprise substrate, a plurality of organic electroluminescent device, first encapsulating film, second encapsulating film, and the 3rd encapsulating film, wherein these organic electroluminescent devices are arranged on the substrate, and these organic electroluminescent devices comprise a plurality of first coloured light organic electroluminescent devices, a plurality of second coloured light organic electroluminescent device and a plurality of the 3rd coloured light organic electroluminescent device.And first encapsulating film covers the first coloured light organic electroluminescent device, and second encapsulating film covers the second coloured light organic electroluminescent device, and the 3rd encapsulating film covers the 3rd coloured light organic electroluminescent device.
In a preferred embodiment, the thickness of above-mentioned first encapsulating film, second encapsulating film and the 3rd encapsulating film is neither identical.
In a preferred embodiment, above-mentioned first coloured light, second coloured light and the 3rd coloured light organic electroluminescent device are respectively ruddiness, green glow and blue-ray organic electroluminescent element.And the film thickness of first encapsulating film is greater than the film thickness of second encapsulating film, and the film thickness of second encapsulating film is greater than the film thickness of the 3rd encapsulating film.
In a preferred embodiment, above-mentioned first encapsulating film by one deck first low-refraction dielectric layer at least and at least one deck first high index of refraction dielectric layer pile up institute alternately and constitute.And the material of the first low-refraction dielectric layer comprises silicon dioxide, and the material of the first high index of refraction dielectric layer comprises silicon nitride.
In a preferred embodiment, above-mentioned second encapsulating film by one deck second low-refraction dielectric layer at least and at least one deck second high index of refraction dielectric layer pile up institute alternately and constitute.And the material of the second low-refraction dielectric layer comprises silicon dioxide, and the material of the second high index of refraction dielectric layer comprises silicon nitride.
In a preferred embodiment, above-mentioned the 3rd encapsulating film by one deck the 3rd low-refraction dielectric layer at least and at least one deck the 3rd high index of refraction dielectric layer pile up institute alternately and constitute.And the material of the 3rd low-refraction dielectric layer comprises silicon dioxide, and the material of the 3rd high index of refraction dielectric layer comprises silicon nitride.
In a preferred embodiment, above-mentioned organic electro-luminescent display unit comprises a plurality of passive type organic electroluminescent devices or a plurality of active organic electroluminescent element.
The present invention's display of organic electroluminescence adopts different encapsulating films because of the organic electroluminescent device at different color light, therefore can make each organic electroluminescent device luminous light by these encapsulating films after, can show best luminous intensity, and then the display quality of raising display.
State with other purpose, feature and advantage and can become apparent on the present invention for allowing, preferred embodiment cited below particularly, and cooperate appended accompanying drawing, be described in detail below.
Description of drawings
Figure 1A is a kind of partial cutaway schematic of known display of organic electroluminescence.
Figure 1B is the partial cutaway schematic of another kind of known display of organic electroluminescence.
Fig. 2 is the partial cutaway schematic of a kind of display of organic electroluminescence of preferred embodiment of the present invention.
Fig. 2 A is the enlarged diagram of ruddiness organic electroluminescent device in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.
Fig. 2 B is the enlarged diagram of green organic electrofluorescence element in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.
Fig. 2 C is the enlarged diagram of blue-ray organic electroluminescent element in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.
Fig. 3 A is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 A and wavelength.
Fig. 3 B is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 B and wavelength.
Fig. 3 C is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 C and wavelength.
The main element description of symbols
100: display of organic electroluminescence
110: substrate
120: organic electroluminescent device
120a: ruddiness organic electroluminescent device
120b: green organic electrofluorescence element
120c: blue-ray organic electroluminescent element
130: encapsulating film
200: display of organic electroluminescence
210: substrate
220: organic electroluminescent device
220a: the first coloured light organic electroluminescent device
220b: the second coloured light organic electroluminescent device
220c: the 3rd coloured light organic electroluminescent device
230a, 230b, 230c: encapsulating film
232a, 232a ', 232a ", 232b, 232b ', 232b ", 232c, 232c ', 232c ": the low-refraction dielectric layer
234a, 234a ', 234b, 234b ', 234c, 234c ': high index of refraction dielectric layer
A1, b1, c1: film thickness
Embodiment
Fig. 2 is the partial cutaway schematic of a kind of display of organic electroluminescence of preferred embodiment of the present invention.Please refer to Fig. 2, the present invention's display of organic electroluminescence 200 for example comprises substrate 210, a plurality of organic electroluminescent device 220, the first encapsulating film 230a, the second encapsulating film 230b and the 3rd encapsulating film 230c, wherein organic electroluminescent device 220 is arranged on the substrate 210, and these organic electroluminescent devices 220 comprise a plurality of first coloured light organic electroluminescent device 220a, the second coloured light organic electroluminescent device 220b and the 3rd coloured light organic electroluminescent device 220c.Organic electroluminescent device 220 for example is passive type organic electroluminescent device or active organic electroluminescent element.
Please continue with reference to Fig. 2, encapsulating film 230a, 230b, 230c cover respectively on the first coloured light organic electroluminescent device 220a, the second coloured light organic electroluminescent device 220b and the 3rd coloured light organic electroluminescent device 220c, enter in the organic electroluminescent device 220 to prevent extraneous oxygen and aqueous vapor.For the light that allows each organic electroluminescent device 220 be sent all can show best luminous intensity after by encapsulating film 230a, 230b, 230c, therefore encapsulating film 230a, 230b, the 230c that covers on each organic electroluminescent device 220a, 220b, the 220c is inequality.In a preferred embodiment, the thickness of the film thickness b1 of the film thickness a1 of the first encapsulating film 230a, the second encapsulating film 230b and the film thickness c1 of the 3rd encapsulating film 230c is neither identical.
In a preferred embodiment, the first coloured light organic electroluminescent device 220a, the second coloured light organic electroluminescent device 220b and the 3rd coloured light organic electroluminescent device 220c for example are respectively ruddiness, green glow and blue-ray organic electroluminescent element.And the film thickness a1 of the first encapsulating film 230a is greater than the film thickness b1 of the second encapsulating film 230b, and the film thickness b1 of the second encapsulating film 230b is greater than the film thickness c1 of the 3rd encapsulating film 230c.What is particularly worth mentioning is that, the method that forms above-mentioned encapsulating film 230a, 230b, 230c can directly utilize former when depositing the organic luminous layer of each organic electroluminescent device 220a, 220b, 220c employed planar mask (shadow mask).
Fig. 2 A is the enlarged diagram of ruddiness organic electroluminescent device in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.Please refer to Fig. 2 A, in a preferred embodiment of the present invention, cover encapsulating film 230a on the ruddiness organic electroluminescent device 220a and for example be and pile up institute alternately by one deck low-refraction dielectric layer 232a and at least one floor height refractive index dielectric layer 234a at least and constitute.At the encapsulating film 230a shown in Fig. 2 A is by three layers of low-refraction dielectric layer 232a, 232a ', 232a " with two floor height refractive index dielectric layer 234a, 234a ' pile up alternately the institute constitute, but be not in order to the qualification the present invention.In one embodiment, low-refraction dielectric layer 232a, 232a ', 232a " material for example be silicon dioxide, and the material of high index of refraction dielectric layer 234a, 234a ' for example is a silicon nitride.
Fig. 2 B is the enlarged diagram of green organic electrofluorescence element in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.Please refer to Fig. 2 B, compare with the film thickness of encapsulating film 230a on covering ruddiness organic electroluminescent device 220a, the film thickness that covers the encapsulating film 230b on the green organic electrofluorescence element 220b is thinner.In a preferred embodiment, encapsulating film 230b piles up institute by one deck low-refraction dielectric layer 232b and at least one floor height refractive index dielectric layer 234b at least to constitute alternately.At the encapsulating film 230b shown in Fig. 2 B for example by three layers of low-refraction dielectric layer 232b, 232b ', 232b " with two floor height refractive index dielectric layer 234b, 234b ' pile up alternately the institute constitute, but be not in order to the qualification the present invention.Low-refraction dielectric layer 232a, 232b ', 232b " material for example be silicon dioxide, and the material of high index of refraction dielectric layer 234a, 234b ' for example is a silicon nitride.
Fig. 2 C is the enlarged diagram of blue-ray organic electroluminescent element in a kind of display of organic electroluminescence of preferred embodiment of the present invention and covering encapsulating film thereon.Please refer to Fig. 2 C, compare with the film thickness of encapsulating film 230b on covering green organic electrofluorescence element 220b, the film thickness that covers the encapsulating film 230c on the blue-ray organic electroluminescent element 220c is thinner.In a preferred embodiment, encapsulating film 230c piles up institute by one deck low-refraction dielectric layer 232c and at least one floor height refractive index dielectric layer 234c at least to constitute alternately.At the encapsulating film 230c shown in Fig. 2 C for example by three layers of low-refraction dielectric layer 232c, 232c ', 232c " with two floor height refractive index dielectric layer 234c, 234c ' pile up alternately the institute constitute, but be not in order to the qualification the present invention.Low-refraction dielectric layer 232c, 232c ', 232c " material for example be silicon dioxide, and the material of high index of refraction dielectric layer 234c, 234c ' for example is a silicon nitride.
Organic electroluminescent device 220a, the 220b, the 220c that the present invention is directed to different color light adopt different encapsulating film 230a, 230b, 230c, this kind mode not only can reach and prevent that extraneous aqueous vapor and oxygen from entering among organic electroluminescent device 220a, 220b, the 220c and cause damage, but also organic electroluminescent device 220a, 220b, the 220c that can make various coloured light all can show best luminous intensity after by encapsulating film 230a, 230b, 230c, thereby can improve the display quality of display.
Below propose a plurality of experimental datas, it relates to the wavelength of encapsulating film structure, film thickness and light and the relation of penetrance, so that the present invention's the accessible effect of display of organic electroluminescence to be described:
Table one
The encapsulating film structure The refractive index of rete Film thickness (nm)
Low-refraction dielectric layer (silicon dioxide) 1.45683 49.92
High index of refraction dielectric layer (silicon nitride) 2.05201 8.62
Low-refraction dielectric layer (silicon dioxide) 1.45683 169.72
High index of refraction dielectric layer (silicon nitride) 2.05201 50.01
Low-refraction dielectric layer (silicon dioxide) 1.45683 125.80
Total dielectric layer structure 404.07
Table one is the encapsulating film shown in Fig. 2 A, and it has listed material, refractive index and the film thickness thereof of each layer dielectric layer.Fig. 3 A is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 A and wavelength.Please refer to table one, encapsulating film 230a is made of five layers of dielectric layer stack.Please refer to Fig. 3 A, when light by after the encapsulating film 230a, in wavelength is the scope of 600nm~700nm (promptly in red range), maximum penetrance (near 100%) is arranged really.Therefore, when ruddiness that ruddiness organic electroluminescent device 220a is sent by after the encapsulating film 230a, can show best luminous intensity.
Table two
The encapsulating film structure The refractive index of rete Film thickness (nm)
Low-refraction dielectric layer (silicon dioxide) 1.46132 29.96
High index of refraction dielectric layer (silicon nitride) 2.05861 10.86
Low-refraction dielectric layer (silicon dioxide) 1.46132 145.93
High index of refraction dielectric layer (silicon nitride) 2.05861 33.86
Low-refraction dielectric layer (silicon dioxide) 1.46132 103.24
Total dielectric layer structure 323.86
Table two is the encapsulating film shown in Fig. 2 B, and it has listed material, refractive index and the film thickness thereof of each layer dielectric layer.Fig. 3 B is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 B and wavelength.Please refer to table two, encapsulating film 230b is made of five layers of dielectric layer stack.Please refer to Fig. 3 B, when light by after the encapsulating film 230b, in wavelength is the scope of 475nm~550nm (promptly in green range), maximum penetrance (near 100%) is arranged really.Therefore, when green glow that green organic electrofluorescence element 220b is sent by after the encapsulating film 230b, can show best luminous intensity.
Table three
The encapsulating film structure The refractive index of rete Film thickness (nm)
Low-refraction dielectric layer (silicon dioxide) 1.46488 26.31
High index of refraction dielectric layer (silicon nitride) 2.06728 16.35
Low-refraction dielectric layer (silicon dioxide) 1.46488 118.77
High index of refraction dielectric layer (silicon nitride) 2.06728 22.32
Low-refraction dielectric layer (silicon dioxide) 1.46488 99.39
Total dielectric layer structure 283.14
Table three is the encapsulating film shown in Fig. 2 C, and it has listed material, refractive index and the film thickness thereof of each layer dielectric layer.Fig. 3 C is the graph of a relation that light passes through resulting penetrance of the encapsulating film shown in Fig. 2 C and wavelength.Please refer to table three, encapsulating film 230c is made of five layers of dielectric layer stack.Please refer to Fig. 3 C, when light by after the encapsulating film 230c, in wavelength is the scope of 375nm~475nm (promptly in blue light range), maximum penetrance (near 100%) is arranged really.Therefore, when blue light that blue-ray organic electroluminescent element 220c is sent by after the encapsulating film 230c, can show best luminous intensity.
In sum, the present invention's display of organic electroluminescence has following advantage:
(1), because the present invention's the employed encapsulating film of display of organic electroluminescence is to pile up institute alternately by multilayer dielectric layer to constitute, so can prevent effectively that extraneous oxygen and aqueous vapor from entering in the organic electroluminescent device.
(2), adopt different encapsulating films, therefore can make each organic electroluminescent device by encapsulating film after, can show best luminous intensity owing to the present invention is directed to the organic electroluminescent device of different color light, and then the display quality of raising display.
Though the present invention discloses as above with preferred embodiment; right its is not in order to limit the present invention; any person of ordinary skill in the field; without departing from the spirit and scope of the invention; when can doing a little change and improvement, so the present invention's protection range is as the criterion when looking the claim person of defining.

Claims (15)

1. display of organic electroluminescence comprises:
Substrate;
A plurality of organic electroluminescent devices are arranged on this substrate, and wherein above-mentioned organic electroluminescent device comprises a plurality of first coloured light organic electroluminescent devices, a plurality of second coloured light organic electroluminescent device and a plurality of the 3rd coloured light organic electroluminescent device;
First encapsulating film covers the above-mentioned first coloured light organic electroluminescent device;
Second encapsulating film covers the above-mentioned second coloured light organic electroluminescent device; And
The 3rd encapsulating film covers above-mentioned the 3rd coloured light organic electroluminescent device.
2. display of organic electroluminescence according to claim 1 is characterized in that the thickness of this first encapsulating film, this second encapsulating film and the 3rd encapsulating film is inequality.
3. display of organic electroluminescence according to claim 1, it is characterized in that the above-mentioned first coloured light organic electroluminescent device is the ruddiness organic electroluminescent device, the above-mentioned second coloured light organic electroluminescent device is the green organic electrofluorescence element, and above-mentioned the 3rd coloured light organic electroluminescent device is the blue-ray organic electroluminescent element.
4. display of organic electroluminescence according to claim 3 is characterized in that the film thickness of the film thickness of this first encapsulating film greater than this second encapsulating film.
5. display of organic electroluminescence according to claim 3 is characterized in that the film thickness of the film thickness of this second encapsulating film greater than the 3rd encapsulating film.
6. display of organic electroluminescence according to claim 1, it is characterized in that this first encapsulating film by one deck first low-refraction dielectric layer at least and at least one deck first high index of refraction dielectric layer pile up institute alternately and constitute.
7. display of organic electroluminescence according to claim 6 is characterized in that the material of this first low-refraction dielectric layer comprises silicon dioxide.
8. display of organic electroluminescence according to claim 6 is characterized in that the material of this first high index of refraction dielectric layer comprises silicon nitride.
9. display of organic electroluminescence according to claim 1, it is characterized in that this second encapsulating film by one deck second low-refraction dielectric layer at least and at least one deck second high index of refraction dielectric layer pile up institute alternately and constitute.
10. display of organic electroluminescence according to claim 9 is characterized in that the material of this second low-refraction dielectric layer comprises silicon dioxide.
11. display of organic electroluminescence according to claim 9 is characterized in that the material of this second high index of refraction dielectric layer comprises silicon nitride.
12. display of organic electroluminescence according to claim 1, it is characterized in that the 3rd encapsulating film by one deck the 3rd low-refraction dielectric layer at least and at least one deck the 3rd high index of refraction dielectric layer pile up institute alternately and constitute.
13. display of organic electroluminescence according to claim 12 is characterized in that the material of the 3rd low-refraction dielectric layer comprises silicon dioxide.
14. display of organic electroluminescence according to claim 12 is characterized in that the material of the 3rd high index of refraction dielectric layer comprises silicon nitride.
15. display of organic electroluminescence according to claim 1 is characterized in that above-mentioned organic electro-luminescent display unit comprises a plurality of passive type organic electroluminescent devices or a plurality of active organic electroluminescent element.
CNB2005100854493A 2005-07-20 2005-07-20 Organic electroluminescence display Expired - Fee Related CN100461980C (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112314056A (en) * 2018-06-25 2021-02-02 索尼半导体解决方案公司 Organic EL device and method for manufacturing organic EL device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0958617A1 (en) * 1996-06-12 1999-11-24 The Trustees Of Princeton University Patterning of thin films for the fabrication of organic multi-color displays

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112314056A (en) * 2018-06-25 2021-02-02 索尼半导体解决方案公司 Organic EL device and method for manufacturing organic EL device

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