CN1900131A - Method for bamboo liquifying substance phenolic glue - Google Patents
Method for bamboo liquifying substance phenolic glue Download PDFInfo
- Publication number
- CN1900131A CN1900131A CN 200610052421 CN200610052421A CN1900131A CN 1900131 A CN1900131 A CN 1900131A CN 200610052421 CN200610052421 CN 200610052421 CN 200610052421 A CN200610052421 A CN 200610052421A CN 1900131 A CN1900131 A CN 1900131A
- Authority
- CN
- China
- Prior art keywords
- bamboo
- liquifying
- phenolic glue
- substance
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 54
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 54
- 241001330002 Bambuseae Species 0.000 title claims abstract description 54
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 54
- 239000011425 bamboo Substances 0.000 title claims abstract description 54
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000003292 glue Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims description 14
- 239000000126 substance Substances 0.000 title claims description 13
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 150000001299 aldehydes Chemical class 0.000 claims description 12
- 238000009413 insulation Methods 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 3
- 150000001896 cresols Chemical class 0.000 claims description 3
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 239000013618 particulate matter Substances 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 claims 1
- 239000002023 wood Substances 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- -1 phenol compound Chemical class 0.000 abstract description 2
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229940089401 xylon Drugs 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003739 xylenols Chemical class 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The bamboo liquefying phenolic glue is prepared through heating phenol compound in 50-200 weight portions to 90-140 deg.c inside a reactor; adding acid catalyst in 10 -20 weight portions and bamboo powder in 50-150 weight portions through stirring to react to obtain liquid matter; cooling to 55 deg.c, regulating pH value with alkali to 8-12, adding water and aldehyde to react for 1 hr, heating to 80-100 deg.c and reacting for 1 hr; cooling and discharging. The bamboo liquefying phenolic glue is used as adhesive for bamboo and wood product. The present invention has low cost, and the produced bamboo liquefying phenolic glue has high plasticity.
Description
Technical field
The present invention relates to bamboo wood pulverizing back and under acidic conditions, produce the liquefaction thing, under alkaline condition, carry out addition polycondensation again and react the method that generates phenolic glue with aldehydes with the phenolic material reaction.
Background technology
In the later stage in last century, Wood liquefied research is set about by states such as Japan, and timber is in phenol or polyalcohol organic solvent, with making glue again behind an acidic catalyst reacting by heating generation timber liquefied matter.
CN1554724A discloses Chinese Academy Of Forestry Research Institute Of Wood Industry " preparation method of the wooden modified phenolic adhesive that liquefies " patented technology, increase the polarity small molecules and make solvent, with the mode of phenol with mixed solvent, under an acidic catalyst condition, react with wood powder, after producing timber liquefied matter, use and the wooden modified phenolic adhesive of Japan's essentially identical method production liquefaction.
Prior art is all made main raw material with timber and is come glue in a word, timber is long because of the arboreal growth cycle, raw material is in short supply day by day, higher, the difficult decomposition of the xylon polymerization degree, liquefaction condition requires higher, timber does not contain or seldom contains wax, lacks the advantage that the dewaxing meeting improves the liquefier flowability, thereby can not have the reaction of dewaxing and aldehydes matter to generate the advantage that alkylphenol improves liquefaction thing plasticity substantially.
Summary of the invention
At the above-mentioned deficiency of prior art, the purpose of this invention is to provide a kind of is the method for bamboo liquifying substance phenolic glue of main raw material with the bamboo powder.Its design philosophy is to utilize the growth cycle of bamboo short, abundant raw material; The polymerization degree of bamboo fibers and its xylogen is low, and hemicellulose components is many, decomposes easily, and liquefaction condition requires relatively low; Wax is rich on the bamboo wood surface, dewaxing, the flowability that help improve liquefier little in liquefaction reaction because of its surface tension, moreover bamboo fibers is than xylon porous, infiltration absorption is fast, therefore needn't add polarity small molecules solvent; Can generate alkylphenol with the phenols reaction after the natural wax fusing in the bamboo powder, liquefaction thing plasticity is improved; Bamboo fibers is more perfectly straight than xylon, and few distortion is pulverized easily, and powder process is convenient.Therefore say, select for use the bamboo powder to make main raw material by its many internal factor decision.
Purpose of the present invention can realize by following measure: production technique divides two steps to carry out:
(1) preparation of bamboo phenol liquified object: the phenolic compound that in reactor, adds the 50-200 weight part, heating, stirring, be warmed up to 90-140 ℃, add 10-20 weight part an acidic catalyst, add 50-150 weight part bamboo powder again, stir, insulation reaction 2h estimates no particulate matter, then liquefaction reaction is finished, be cooled to 40-70 ℃ standby.
(2) production of bamboo liquefaction substance phenolic glue: in the reactor that the bamboo phenol liquified object that is cooled to 40-70 ℃ is housed, add basic catalyst and transfer PH8-12, add entry, aldehydes, three's weight ratio is a bamboo liquefaction thing: water: aldehydes=1: 0.8-1.2: 0.8-1.2, insulation reaction 25-115min, be warming up to 80-100 ℃ in normal pressure, reaction 15-100min is when reaching the viscosity of setting, the addition polycondensation reaction is finished, cooling, blowing.
Purpose of the present invention can also be come perfect by following measure: the bamboo powder of 50-150 weight part is divided into 2-3 adding; Phenolic compound is at least a in phenol, cresols, xylenol, alkylphenol, the Resorcinol; The tart catalyzer is at least a in oxalic acid, phosphoric acid, hydrochloric acid, sulfuric acid, the acetate; Said aldehydes adds at twice; Said aldehydes is at least a in formaldehyde, acetaldehyde, the furfural; Said basic catalyst is NaoH, KOH, ammoniacal liquor, Ba (oH)
2In at least a.
Embodiment
The present invention is set forth below in conjunction with embodiment: among the present invention, 50-150 part bamboo powder can 1 property join reactor, fully stirs, also can divide and add for 2-3 time, treating that the bamboo powder that adds first liquefies fully promptly adds bamboo powder next time, whenever adds once the about 5-20 of insulation reaction minute.If reacted the slow acid that then adds.Whole liquefaction can be at normal pressure or is slightly carried out in the pressurization.In the glue step, aldehydes also can once add or add at twice, adds 2/3 of total amount first, and secondary adds 1/3 of remainder, and notices that pH value should maintain 8-12, and deficiency should be added.
Embodiment 1:
200 weight part phenol are poured in the reactor stir, be warmed up to 120 ℃, adding 15 weight part concentrated hydrochloric acids, adding granularity again is 200 purpose bamboo powder, 150 weight parts, fully stir, insulation reaction 1.5h bamboo phenol liquified object, to be cooled during to 50 ℃, add NaoH and transfer PH=9, by weight be bamboo phenol liquified object: water: the amount of formaldehyde=1: 1: 1 is with water, formaldehyde adding reactor, insulation reaction 1h heats up 90 ℃ under normal pressure, reacts 1h again, reaction is finished, cooling, blowing.
Embodiment 2:
150 weight part cresols are poured in the reactor, stirred, be warmed up to 90 ℃, add the 20 weight part vitriol oils, add 100 weight parts, 200 purpose bamboo powder again, fully stir insulation reaction 20min, add 50 weight part bamboo powder again, stir, insulation reaction 2h bamboo phenol liquified object.Follow-up one-tenth glue step is identical with embodiment 1, and catalyzer changes KOH into, and furfural adds at twice.
Embodiment 3:
200 weight part xylenols are poured in the reactor, stir, be warmed up to 140 ℃, add 20 weight part phosphoric acid, add 50 weight parts, 200 order bamboo powder again, fully stir, insulation reaction 15min adds 50 weight part bamboo powder again, fully stir, insulation reaction 15min adds 50 weight part bamboo powder for the third time again, fully stirs insulation reaction 2.5h again.Follow-up one-tenth glue step is identical with embodiment 1, and catalyzer changes Ba (OH) into
2Acetaldehyde adds at twice.
Above-mentioned three embodiment are preferred with embodiment 1.After total reaction times of three examples finished, the viscosity of its phenolic glue all reached the setting requirement.
Selected an acidic catalyst, basic catalyst, phenolic material and aldehydes consider that mainly the quality and the purposes of raw materials cost, source, speed of response, liquefaction thing and phenolic glue select.
Bamboo that the present invention makes liquefaction substance phenolic glue, outward appearance is the brown jelly, PH=0-12, solid content 45-55%, storage period＞90 day, bonding strength＞1.0Mpa.
It is low that the present invention has the raw material of selecting for use glue cost more reasonable, that make compared to existing technology, during the preparation bamboo phenol liquified object, do not need the polarity small molecules to make secondary solvent, can utilize this a kind of natural mode wax of bamboo wax to obtain alkylphenol, thereby increase advantage such as plasticity.
Claims (7)
1, a kind of method for bamboo liquifying substance phenolic glue is characterized in that two steps of branch carry out:
(1) preparation of bamboo phenol liquified object: the phenolic compound that in reactor, adds the 50-200 weight part, heating, stirring, be warmed up to 90-140 ℃, add 10-20 weight part an acidic catalyst, add 50-150 weight part bamboo powder again, stir, insulation reaction 2h estimates no particulate matter, then liquefaction reaction is finished, be cooled to 40-70 ℃ standby.
(2) production of bamboo liquefaction substance phenolic glue: in the reactor that the bamboo phenol liquified object that is cooled to 40-70 ℃ is housed, add basic catalyst and transfer PH8-12, add entry, aldehydes, three's weight ratio is a bamboo phenol liquified object: water: aldehydes=1: 0.8-1.2: 0.8-1.2, insulation reaction 25-115min, be warming up to 80-100 ℃ in normal pressure, reaction 15-100min is when reaching the viscosity of setting, the addition polycondensation reaction is finished, cooling, blowing.
2, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that the bamboo powder of 50-150 weight part is divided into 2-3 adding in the bamboo phenol liquified object preparation.
3, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that phenolic compound is at least a in phenol, cresols, xylenol, alkylphenol, the Resorcinol in the said bamboo phenol liquified object preparation.
4, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that an acidic catalyst is at least a in oxalic acid, phosphoric acid, hydrochloric acid, sulfuric acid, the acetate in the said bamboo phenol liquified object preparation.
5, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that said aldehydes adds at twice.
6, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that said aldehydes is at least a in formaldehyde, acetaldehyde, the furfural.
7, method for bamboo liquifying substance phenolic glue as claimed in claim 1 is characterized in that said basic catalyst is NaoH, KOH, ammoniacal liquor, Ba (oH)
2In at least a.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100524214A CN100432117C (en) | 2006-07-12 | 2006-07-12 | Method for bamboo liquifying substance phenolic glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100524214A CN100432117C (en) | 2006-07-12 | 2006-07-12 | Method for bamboo liquifying substance phenolic glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1900131A true CN1900131A (en) | 2007-01-24 |
| CN100432117C CN100432117C (en) | 2008-11-12 |
Family
ID=37656137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100524214A Expired - Fee Related CN100432117C (en) | 2006-07-12 | 2006-07-12 | Method for bamboo liquifying substance phenolic glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100432117C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619547B (en) * | 2009-07-27 | 2012-04-04 | 黄山学院 | Method of high-value comprehensive utilization of bamboo remainders |
| CN102504275A (en) * | 2011-11-21 | 2012-06-20 | 浙江省林业科学研究院 | Production method of bamboo phenolic alcohol liquefied products |
| CN102643399A (en) * | 2012-05-11 | 2012-08-22 | 南通新洋环保板业有限公司 | Preparation method of modified phenolic resin for bamboo container flooring |
| CN103289310A (en) * | 2013-06-13 | 2013-09-11 | 北京林业大学 | Wood liquefied substance foamed material and preparation method thereof |
| CN105111981A (en) * | 2015-09-21 | 2015-12-02 | 福建农林大学 | Application of bamboo powder |
| CN105754059A (en) * | 2016-05-18 | 2016-07-13 | 浙江大学 | Thermoplastic phenolic resin synthesized by liquefied bamboo waste as well as preparation method and application of thermoplastic phenolic resin |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0666155B1 (en) * | 1994-01-28 | 1998-04-08 | Forestry And Forest Products Research Institute | Wood piled with split and disrupted pieces and its manufacturing method and manufacturing apparatus |
| CN1554724A (en) * | 2003-12-23 | 2004-12-15 | 中国林业科学研究院木材工业研究所 | Process for preparing liquefied wood phenolic adhesive |
-
2006
- 2006-07-12 CN CNB2006100524214A patent/CN100432117C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619547B (en) * | 2009-07-27 | 2012-04-04 | 黄山学院 | Method of high-value comprehensive utilization of bamboo remainders |
| CN102504275A (en) * | 2011-11-21 | 2012-06-20 | 浙江省林业科学研究院 | Production method of bamboo phenolic alcohol liquefied products |
| CN102643399A (en) * | 2012-05-11 | 2012-08-22 | 南通新洋环保板业有限公司 | Preparation method of modified phenolic resin for bamboo container flooring |
| CN103289310A (en) * | 2013-06-13 | 2013-09-11 | 北京林业大学 | Wood liquefied substance foamed material and preparation method thereof |
| CN103289310B (en) * | 2013-06-13 | 2015-04-15 | 北京林业大学 | Wood liquefied substance foamed material and preparation method thereof |
| CN105111981A (en) * | 2015-09-21 | 2015-12-02 | 福建农林大学 | Application of bamboo powder |
| CN105111981B (en) * | 2015-09-21 | 2017-08-01 | 福建农林大学 | A kind of application of bamboo powder |
| CN105754059A (en) * | 2016-05-18 | 2016-07-13 | 浙江大学 | Thermoplastic phenolic resin synthesized by liquefied bamboo waste as well as preparation method and application of thermoplastic phenolic resin |
| CN105754059B (en) * | 2016-05-18 | 2018-05-04 | 浙江大学 | A kind of thermoplastic phenolic resin synthesized by bamboo wood scrap material liquefied substance and preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100432117C (en) | 2008-11-12 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20081112 Termination date: 20110712 |