CN1866409A - Long-lasting grounding anti-corrosion resistance reduction agent (modified type) - Google Patents

Long-lasting grounding anti-corrosion resistance reduction agent (modified type) Download PDF

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Publication number
CN1866409A
CN1866409A CN 200610092963 CN200610092963A CN1866409A CN 1866409 A CN1866409 A CN 1866409A CN 200610092963 CN200610092963 CN 200610092963 CN 200610092963 A CN200610092963 A CN 200610092963A CN 1866409 A CN1866409 A CN 1866409A
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oxide
corrosion
reducing agent
graphite
resistance reducing
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CN 200610092963
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CN100498978C (en
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龚循礼
满国民
李国庆
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Xiao Zhusheng
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Abstract

The invention discloses a long-acting ground antiseptic resistance-reducing agent (modified), which is characterized by the following: consisting of sodium base alta-mud and graphite; making each item of parameter satisfy all index; keeping resistance property stable under multitime industrial frequency and punching electricity action; protecting ground metal; reducing erosion rate from 0.0245 mm per year to 0.0064 mm per year.

Description

Long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model)
Technical field
The invention belongs to the physics resistance reducing agent, relate to a kind of long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model) that reduces the power equipment earth resistance, prevents the earth electrode corrosion, it is applied in the system of electric power, post and telecommunications, oil, railway, skyscraper, computer, telephone room and other employing ground network.
Background technology
In order to reduce the earth resistance of power equipment, the ground connection that makes power equipment under normal circumstances, a situation arises for accident down and under the thunderbolt situation, and the earth potential of power equipment installation place is fixing in allowed limits, to guarantee the safety of the person and equipment.Since the disclosed CN1062888C long service life, corrosion-proof, and electric resistance reducing agent for earthing launch products, because its resistance-reducing performance excellence is highly commended by customers deeply.Though conduct electricity very well but its weak point is the potassium chloride that adds in its composition, bury ground after, As time goes on its Corrosion Protection to the ground connection metallic object is relatively poor.
Summary of the invention
The objective of the invention is to address the above problem, provide a kind of electric conductivity better, the long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model) that corrosion resistance is more excellent.
The inventor is through repetition test repeatedly, research, selected for use electric conductivity better, the more excellent a kind of nonmetal breeze graphite of corrosion resistance substitutes potassium chloride in the former invention and makes it long service life, corrosion-proof, and electric resistance reducing agent for earthing to fall the resistance decay resistance after improving better, so propose following technical scheme: a kind of long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model), it is made up of bentonite and graphite, wherein each weight percentages of components is: bentonite 50-99%, graphite 1-50% contains silica in the bentonite, titanium oxide, iron oxide, aluminium oxide, calcium oxide, potassium oxide, sodium oxide molybdena.The weight percent content of each essential element is as shown in table 1 in the bentonite.
Table 1
Composition Silica Titanium oxide Iron oxide Aluminium oxide Calcium oxide Potassium oxide Sodium oxide molybdena
Content (%) 40-70% 0.01-3% 0.5-9% 2-20% 1-7% 0.1-6% 1-6%
The effect of each composition is respectively: silica has extremely strong suction, water holding capacity, be mainly used in and store electrolyte and moisture, and higher expansion character is arranged, can make resistance reducing agent closely wrap the metal earth electrode, starvation plays the unpolarizing that stops oxygen to the intrusion of earth electrode; Titanium oxide can keep the stability of resistance reducing agent except that possessing electric action; Sodium oxide molybdena, potassium oxide etc. are active metal oxide, have good electric conductivity, can reduce the industrial frequency electric resistance rate greatly; Calcium oxide, iron oxide, aluminium oxide etc. have stronger moisture absorption, form the jelly of crystalloid or crystallization defective mode, in the expansion that takes place under water and other the material effect between crystal, enlarged the contact-making surface of earth electrode and the earth, improve the compaction rate that earth electrode contacts with the earth, thereby reduced earth resistance.Simultaneously, the colloid that it forms can prevent the evaporation of moisture and the loss of conductive materials, and this is the main cause that keeps long-acting.Graphite: its fixed carbon content is 60-99%.Graphite is a kind of nonmetallic mineral that has good electric conductivity and have stronger decay resistance, its chemical property is more stable, have higher electric stability and high osmosis, can around the soil electrode, form infiltration area widely, to all pressing advantageous particularly, it is the scalable pH value also, makes it be slightly larger than 7, and earth electrode is had good anticorrosive effect.
Long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model) is a kind of solid particle sprills; it also can be solid modules; its resistance reducing effect is remarkable especially; metal earth electrode anti-corrosion protection had king-sized effect; under power frequency heavy impulse current effect repeatedly; electrical resistivity property is stable, to all pressing advantageous particularly, earth electrode good especially corrosion-resisting function is arranged.
The inventor entrusts State Grid Corporation of China's Wuhan High Voltage Research Institute in March, 2006 long service life, corrosion-proof, and electric resistance reducing agent for earthing ((modified model)) to be carried out the impulse current resistance test, the power current resistance test, pH value, resistance reducing agent are tested steel earth electrode corrosion test etc., ask for an interview table 2.
Table 2 long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model) pilot project gathers
Sequence number The pilot project title Requirement Test value Estimate
1 The resistivity measurement test ρ≤5Ω·m ρ=1.26Ω·m Meet the requirements
2 Physicochemical property certification test a, loss-of-coolant experiment (LOCE) b, cyclic test c, the test of water logging bubble ρ≤6Ω·m ρ=1.44Ω·m ρ=1.335Ω·m ρ=1.265Ω·m Meet the requirements
3 The impulse current tolerance ΔR%≤20% ΔR%≤1.07% Meet the requirements
4 The power current tolerance ΔR%≤20% ΔR%≤1.51% Meet the requirements
5 The pH measurement test PH value is in the 7-12 scope PH=7.1 Meet the requirements
6 The experiment of resistivity temperature characterisitic Carry out
7 Resistance reducing agent is to metal earth electrode corrosion test Surface average corrosion rate (mm/) Scope (mm/)
A, pure resistance reducing agent are to metal earth electrode rate of corrosion experiment with measuring Surface average corrosion rate≤0.03mm/ Round steel: 0.0139 band steel: 0.0155 zinc-plated round steel: 0.0044 zinc-coated flat steel sheet: 0.0050 0.0098-0.0195 0.0166-0.0211 0.0010-0.0061 0.0037-0.0054 Meet the requirements
B, bury when ground resistance reducing agent to metal earth electrode rate of corrosion experiment with measuring Average corrosion rate≤0.05mm/ Round steel: 0.0136 band steel: 0.0191 zinc-plated round steel: 0.0064 zinc-coated flat steel sheet: 0.0069 0.0098-0.0150 0.0153-0.0257 0.0053-0.0080 0.0057-0.0076 Meet the requirements
The invention has the beneficial effects as follows its stable chemical performance; whole indexs of its every technical parameter all meet the requirements; resistivity 1.26 Europe rice; under repeatedly power frequency and impulse current effect, electrical resistivity property is stable, and is desirable to the protection of metal grounding anti-corrosion; average corrosion rate (is example with zinc-plated round steel) is reduced to 0.0064mm/ by 0.0245mm/; prepare easyly, cost is low, easy construction.
Embodiment
The invention will be further described below in conjunction with embodiment.
A kind of long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model), it is made up of sodium bentonite and graphite, wherein each weight percentages of components is: sodium bentonite 50-99%, graphite 1-50%, the weight percent content of each essential element is silica: 40-70%, titanium oxide 0.01-3%, iron oxide 0.5-9%, aluminium oxide 2-20%, calcium oxide 1-7%, potassium oxide 0.1-6%, sodium oxide molybdena 1-6% in the sodium bentonite, and the fixed carbon content in the graphite is 60-90%.With sodium bentonite pulverize, abrasive dust, mix to mix well getting final product with graphite powder.It can use the method for applying and the soak method done, and general main is the soak method.Prepare a bulk of iron sheet at the construction field (site), resistance reducing agent is added water on stir with spade, around the earth electrode that then resistance reducing agent is laid in, its construction technology is the same with ready-mixed concrete easy.
The sodium bentonite that each component content of the prescription of the embodiment of the invention meets table 1 ratio is 90%, graphite powder is 10%, and its fixed carbon content is 81%.Sodium bentonite main component content is: silica: 53%, titanium oxide 1%, iron oxide 7%, aluminium oxide 15%, calcium oxide 5%, potassium oxide 4%, sodium oxide molybdena 5%.The fixed carbon content of graphite powder is 81%.

Claims (2)

1, a kind of long service life, corrosion-proof, and electric resistance reducing agent for earthing (modified model), it is characterized in that: it is made up of bentonite and graphite, wherein each weight percentages of components is: bentonite 50-99%, graphite 1-50%, the weight percent content of each essential element is silica: 40-70%, titanium oxide 0.01-3%, iron oxide 0.5-9%, aluminium oxide 2-20%, calcium oxide 1-7%, potassium oxide 0.1-6%, sodium oxide molybdena 1-6% in the bentonite, and the fixed carbon content in the graphite is 60-90%.
2, long service life, corrosion-proof, and electric resistance reducing agent for earthing according to claim 1 (modified model) is characterized in that: it is that a kind of solid particle sprills also can be solid modules.
CNB2006100929634A 2006-06-13 2006-06-13 Modified grounding anti-corrosion resistance reduction agent Expired - Fee Related CN100498978C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101882477A (en) * 2010-06-25 2010-11-10 国网电力科学研究院武汉南瑞有限责任公司 Long-acting antiseptic resistance-reducing agent
CN101719393B (en) * 2008-12-30 2012-01-04 中国瑞林工程技术有限公司 Biological bacteria grounded resistance-reducing agent
CN103198872A (en) * 2013-03-20 2013-07-10 国家电网公司 Resistance-reducing composition and application to soil thereof
CN104103334A (en) * 2014-06-19 2014-10-15 国家电网公司 Novel high-efficiency anti-corrosive physical resistance reducing agent for galvanized steel grounding grid
CN104449560A (en) * 2014-11-18 2015-03-25 国网河南省电力公司漯河供电公司 Environment-friendly long-acting grounding device anticorrosive agent and preparation method of anticorrosive agent
CN106654616A (en) * 2016-10-07 2017-05-10 常州市鼎升环保科技有限公司 Preparing method for corrosion-resisting grounding material
CN108123232A (en) * 2016-11-29 2018-06-05 国网河南省电力公司安阳供电公司 It is a kind of that there is conductive anticorrosive grounding body and preparation method thereof
CN109349277A (en) * 2018-10-08 2019-02-19 湖北捷地安电气有限公司 A kind of environmental protection rush vegetation growth type grounding resistance-reducing material

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101719393B (en) * 2008-12-30 2012-01-04 中国瑞林工程技术有限公司 Biological bacteria grounded resistance-reducing agent
CN101882477A (en) * 2010-06-25 2010-11-10 国网电力科学研究院武汉南瑞有限责任公司 Long-acting antiseptic resistance-reducing agent
CN103198872A (en) * 2013-03-20 2013-07-10 国家电网公司 Resistance-reducing composition and application to soil thereof
CN103198872B (en) * 2013-03-20 2016-08-03 国家电网公司 A kind of fall hinders compositions and the application in soil thereof
CN104103334A (en) * 2014-06-19 2014-10-15 国家电网公司 Novel high-efficiency anti-corrosive physical resistance reducing agent for galvanized steel grounding grid
CN104449560A (en) * 2014-11-18 2015-03-25 国网河南省电力公司漯河供电公司 Environment-friendly long-acting grounding device anticorrosive agent and preparation method of anticorrosive agent
CN106654616A (en) * 2016-10-07 2017-05-10 常州市鼎升环保科技有限公司 Preparing method for corrosion-resisting grounding material
CN106654616B (en) * 2016-10-07 2018-11-30 东阳市特意新材料科技有限公司 A kind of preparation method of corrosion-resistant earthing material
CN108123232A (en) * 2016-11-29 2018-06-05 国网河南省电力公司安阳供电公司 It is a kind of that there is conductive anticorrosive grounding body and preparation method thereof
CN108123232B (en) * 2016-11-29 2020-04-21 国网河南省电力公司安阳供电公司 Grounding body with conductive and corrosion-resistant functions and preparation method thereof
CN109349277A (en) * 2018-10-08 2019-02-19 湖北捷地安电气有限公司 A kind of environmental protection rush vegetation growth type grounding resistance-reducing material

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