CN1861713A - Process of preventing building or ornament from being stuck and daubed adopting organic silicon - Google Patents
Process of preventing building or ornament from being stuck and daubed adopting organic silicon Download PDFInfo
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- CN1861713A CN1861713A CN 200610080448 CN200610080448A CN1861713A CN 1861713 A CN1861713 A CN 1861713A CN 200610080448 CN200610080448 CN 200610080448 CN 200610080448 A CN200610080448 A CN 200610080448A CN 1861713 A CN1861713 A CN 1861713A
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Abstract
The invention discloses a method to prevent the building or the decoration from being stuck or covered by the organic silicon. It covers the organic silicon compound on the buildings then to solidify under normal temperature to 300DEG C. Because of the organic silicon coating has the low surface energy, so the adhered or the paint is easy to clear. The organic compound can use the silicone oil, silicon rubber or the silicone resin to form the film which has the low toxic, polar and surface energy. The surface energy is less than 30mN/m according to the 30-50mN/m of the more organic adhesives. The water paint is difficulty to adhere because of its hydrophobicity.
Description
Technical field
The present invention relates to a kind of method that prevents that buildings or ornament are stuck or smear, particularly a kind of use organic silicon coating makes buildings or ornament is anti-paste or smearing method.
Background technology
The outside surface of buildings or communal facility, ornament etc. is often hidden by a large amount of paste (as non-setting adhesive), or smeared by oil paint, has a strong impact on attractive in appearance.But because used exterior wall surface coating mostly is the coating of kinds such as vinylformic acid, urethane, alkyd at present, or do not have the coating covering at all, make its surface energy higher, cause removing above-mentioned paste or smear very difficult.Organosilicon is the high molecular synthetic material that contains elemental silicon in the molecular structure, has been widely used in a plurality of fields such as health care, weaving, printing and building waterproof.Advantage such as that organic silicon coating has is nontoxic, harmless, stability and good weatherability, operation and maintenance cost are low.This type coating have low polarity, low surface tension and with high-performances such as organic solvent unmixability, therefore be present comparatively ideal release agent, be applied as the releasing agent of fabric finishing agent, processing mold, the releasing agent of food production and the anti-stick coating of antiseized paper tape etc.But present no-trump organic silicon coating still is used for the report of buildings or the subsides of ornament surface anti sticking.
Summary of the invention
The purpose of this invention is to provide a kind of coating of using organosilicon coating to form on buildings or ornament surface prevents by its stickup and the method for smearing.
At above-mentioned purpose, the present invention utilizes buildings or ornament surface process spraying, brushing or the dipping of silicoorganic compound in cleaning, again through the organic silicon coating more than formation one deck after normal temperature to the 300 ℃ curing.
Further, described silicoorganic compound are silicone oil and/or the silicon rubber and/or the silicone resin of solution or emulsion.
Further, in the solidification process of described silicoorganic compound, add linking agent and/or catalyzer.
Further, described silicone oil be dimethyl silicone oil or, methyl phenyl silicone oil or, Methyl Hydrogen Polysiloxane Fluid or, ethyl silicon oil or, Chlorophenylmethyl silicone oil or, the methyl hydroxy silicon oil or, contain nitrile silicone or, fluorine containing silicone oil or, organically-modified silicone oil or their any mixture.
Further, described silicon rubber be dimethyl silicone rubber or, methyl vinyl silicone rubber or, methyl phenyl silicone rubber or, trifluoropropyl siloxane or, nitrile silicone rubber or, ethyl silicon rubber or, hydroxy-end capped polydimethylsiloxane (methyl room temperature vulcanized silicone rubber) or, hydroxy-end capped diphenyl siloxane and dimethylsiloxane copolymer (methyl two phenyl room temperature vulcanized silicone rubbers) or, hydroxy-end capped dimethyl siloxane and Union carbide A-162 multipolymer or, hydroxy-end capped poly-β-nitrile ethyl-methyl siloxanes (self cure nitrile silicone rubber) or, hydroxy-end capped poly-γ-trifluoro propyl methylsiloxane (RTV fluorocarbon silicone rubber) or their any mixture.
Further, the activeconstituents of described silicone resin be METHYL TRICHLORO SILANE or, dimethyldichlorosilane(DMCS) or, phenyl-trichloro-silicane or, diphenyl dichlorosilane or, dichloromethyl phenylsilane or, Union carbide A-162 or, dimethyldiethoxysilane or, phenyl triethoxysilane or, the phenylbenzene diethoxy silane or, aminomethyl phenyl diethoxy silane or their any mixture, and/or the performed polymer that after hydrolysis, obtains of above-claimed cpd or their any mixture.
Further, described silicone oil, the solvent of silicon rubber or silicon resin solution be water or, methyl alcohol or, ethanol or, propyl alcohol or, butanols or, amylalcohol or, hexanol or, ethylene glycol or, phenylcarbinol or, pentane or, hexane or, heptane or, octane or, kerosene or, gasoline or, benzene or, toluene or, dimethylbenzene or, dme or, ether or, sherwood oil or, methyl ethyl ketone or, acetone or, tetracol phenixin or, chloroform or, methylene dichloride or, monochloroethane or, ethylene dichloride or, hexanaphthene or, dioxy ring six alkane or, tetrahydrofuran (THF) or, ethyl acetate or, butylacetate or or their any mixture, described emulsion is a water miscible liquid.
Further, described catalyzer be plumbous or, iron or, cobalt or, tin or, titanium or, manganese or, aluminium or, platinum or, their soluble salt of rhodium or their organometallic compound, or any mixture of above-mentioned soluble salt and organometallic compound; Or NaOH, KOH, H
2SO
4, amine, quaternary amine alkali or their any mixture.
Further, described linking agent be tetraethoxy or, contain the silane of alkoxyl group, amido, amide group, ketone group or their any mixture.
Further, the described silane that contains alkoxyl group, amido, amide group, ketone group be respectively vinyltrimethoxy silane, vinyltriethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane, anilinomethyl triethoxysilane, γ-An Bingjisanyiyangjiguiwan, γ-methacryloxypropyl trimethoxy silane, methyl triacetoxysilane, ethyl triacetoxysilane, methyl three butanone base silanes or, vinyl three butanone base silanes etc.
The present invention is being coated the organic silicon coating that the surface forms owing to have very low surface energy and paste or coating are smeared be easy to removing.In addition, the present invention is simple and practical, and required silicoorganic compound can be selected commercially available silicone oil, silicon rubber or the silicone resin of the suitable trade mark for use, and the organosilicone film of formation has characteristics such as low toxicity, low polarity, low surface tension.Its surface tension is generally less than 30 milli Newton/meter, and therefore the surface energy of most of organic binder bonds can make paste or oil paint be eliminated easily in 30-50 milli Newton/meter.And its hydrophobicity also can make water-borne coatings be difficult to adhere to.Thickness, degree of crosslinking that composition that can be by adjusting coating in the film process or coating, condition of cure come controlling diaphragm are to adapt to different demands.
Embodiment
Embodiment 1
The dimethyldichlorosilane(DMCS) of the METHYL TRICHLORO SILANE of 95 weight parts and 5 weight parts is with big water gaging hydrolysis, the throw out that produces after filtration, after the water washing with the NaOH aqueous solution, after heating 2 hours under 90～95 ℃, be diluted with water to 5%, filter and obtain sodium methyl silicate and poly-methyl silicon ether prepolymer solution.Resulting sodium methyl silicate/poly-methyl silicon ether prepolymer solution is coated on 30 centimetres of diameters equably, long 60 centimetres cylindrical cement lamp stand stand-in surface, 25 ℃ of ambient cures 48 hours obtain silicone resin coating.
Embodiment 2
To gather the Union carbide A-162 resin with ethanol and be made into 40% solution.The silicon resin solution that is made into is sprayed on 30 centimetres of diameters equably, long 60 centimetres cylindrical cement lamp stand stand-in surface, 25 ℃ of ambient cures 12 hours obtain silicone resin coating.Coating is colourless, unglazed and inviscid.
Embodiment 3
Washed glass immersed in the dimethyl silicone oil that viscosity was 0.2～0.5 handkerchief second take out after 3 minutes, put into baking oven and under 250～270 ℃, baked 3 hours, slowly cool to room temperature.Glass surface forms transparent organosilicone film, and recording surface tension is 25 milli Newton/meter.
Embodiment 4
(activeconstituents is hydroxy-end capped polysiloxane with the commercially available 107 methyl room temperature vulcanized silicone rubbers of 100 weight parts, molecular weight 140～250kDa), 10 weight part anilinomethyl triethoxysilanes, 1 weight part dibutyl tin dilaurate is dispersed in the gasoline of 900 weight parts.Above-mentioned coating is brushed equably in buildings brick wall surface, made the brick wall surface form transparent silicone rubber coating in 60 seconds with the infrared heating furnace baking, the temperature on control quilt baking surface is at 100 ± 10 ℃ therebetween.
Embodiment 5
In 100 parts by weight of ethanol, add the nitric acid of 25 weight parts and the Union carbide A-162 of 150 weight parts under stirring.Under the room temperature, mixture stirs 2h and forms performed polymer.After adding the thanomin of 0.2 weight part in the above-mentioned silicone resin performed polymer, rapidly it is brushed on steel guardrail surface, 80 ℃ solidified 2 hours down, obtain the transparent silicon resin coating.
Embodiment 6
Commercially available 851 silicone resins are diluted with water to 3%, are sprayed on buildings brick wall metope to be protected, 25 ℃ of ambient cures 48 hours obtain silicone resin coating.(activeconstituents is hydroxy-end capped polysiloxane with the commercially available 107 methyl room temperature vulcanized silicone rubbers of 100 weight parts in addition, molecular weight 140～250kDa), 10 weight part containing hydrogen silicone oils, the metatitanic acid fourth of 1 weight part is cruel to be dispersed in the normal hexane of 1000 weight parts with 6 weight part dibutyl tin dilaurates.Above-mentioned coating is brushed equably in above-mentioned silicone resin coating surface, made the brick wall surface form transparent silicone resin/silicon rubber compound coating in 30 seconds with the infrared heating furnace baking, the temperature on control quilt baking surface is at 150 ± 10 ℃ therebetween.
Embodiment 7
Hydroxy-end capped fluorine containing silicone oil and octadecyl trimethylammonium ammonia chloride (weight ratio 100: 1) in water with the fluorine containing silicone oil emulsion that forms 10% behind the ultra-sonic dispersion.Above-mentioned emulsion is sprayed at the synthetic glass surface, 70 ℃ of baking water cleanings after 10 hours down, the synthetic glass surface after the cleaning forms transparent organosilicone film.
Claims (10)
1, a kind of organosilicon that adopts prevents the method that buildings or ornament are stuck or smear, it is characterized in that, utilize buildings or ornament surface process spraying, brushing or the dipping of silicoorganic compound, again through the organic silicon coating more than formation one deck after normal temperature to the 300 ℃ curing in cleaning.
2, a kind of organosilicon that adopts according to claim 1 prevents the method that buildings or ornament are stuck or smear, and it is characterized in that, described silicoorganic compound are silicone oil and/or the silicon rubber and/or the silicone resin of solution or emulsion.
3, prevent the method that buildings or ornament are stuck or smear according to claim 2 or 3 described a kind of organosilicons that adopt, it is characterized in that, in the solidification process of described silicoorganic compound, add linking agent and/or catalyzer.
4, a kind of organosilicon that adopts according to claim 3 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, described silicone oil be dimethyl silicone oil or, methyl phenyl silicone oil or, Methyl Hydrogen Polysiloxane Fluid or, ethyl silicon oil or, Chlorophenylmethyl silicone oil or, the methyl hydroxy silicon oil or, contain nitrile silicone or, fluorine containing silicone oil or, organically-modified silicone oil or their any mixture.
5, a kind of organosilicon that adopts according to claim 4 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, described silicon rubber be dimethyl silicone rubber or, methyl vinyl silicone rubber or, methyl phenyl silicone rubber or, trifluoropropyl siloxane or, nitrile silicone rubber or, ethyl silicon rubber or, hydroxy-end capped polydimethylsiloxane or, hydroxy-end capped diphenyl siloxane and dimethylsiloxane copolymer or, hydroxy-end capped dimethyl siloxane and Union carbide A-162 multipolymer or, hydroxy-end capped poly-β-nitrile ethyl-methyl siloxanes or, hydroxy-end capped poly-γ-trifluoro propyl methylsiloxane or their any mixture.
6, a kind of organosilicon that adopts according to claim 5 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, the activeconstituents of described silicone resin be METHYL TRICHLORO SILANE or, dimethyldichlorosilane(DMCS) or, phenyl-trichloro-silicane or, diphenyl dichlorosilane or, dichloromethyl phenylsilane or, Union carbide A-162 or, dimethyldiethoxysilane or, phenyl triethoxysilane or, the phenylbenzene diethoxy silane or, aminomethyl phenyl diethoxy silane or their any mixture, and/or the performed polymer that after hydrolysis, obtains of above-claimed cpd or their any mixture.
7, a kind of organosilicon that adopts according to claim 6 prevents the method that buildings or ornament are stuck or smear, it is characterized in that described silicone oil, the solvent of silicon rubber or silicon resin solution be water or, methyl alcohol or, ethanol or, propyl alcohol or, butanols or, amylalcohol or, hexanol or, ethylene glycol or, phenylcarbinol or, pentane or, hexane or, heptane or, octane or, kerosene or, gasoline or, benzene or, toluene or, dimethylbenzene or, dme or, ether or, sherwood oil or, methyl ethyl ketone or, acetone or, tetracol phenixin or, chloroform or, methylene dichloride or, monochloroethane or, ethylene dichloride or, hexanaphthene or, dioxy ring six alkane or, tetrahydrofuran (THF) or, ethyl acetate or, butylacetate or or their any mixture; Described emulsion is a water miscible liquid.
8, a kind of organosilicon that adopts according to claim 7 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, described catalyzer be plumbous or, iron or, cobalt or, tin or, titanium or, manganese or, aluminium or, platinum or, their soluble salt of rhodium or their organometallic compound, or any mixture of above-mentioned soluble salt and organometallic compound; Or NaOH, KOH, H
2SO
4, amine, quaternary amine alkali or their any mixture.
9, a kind of organosilicon that adopts according to claim 8 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, described linking agent be tetraethoxy or, contain the silane of alkoxyl group, amido, amide group, ketone group or their any mixture.
10, a kind of organosilicon that adopts according to claim 9 prevents the method that buildings or ornament are stuck or smear, it is characterized in that, the described silane that contains alkoxyl group, amido, amide group, ketone group be respectively vinyltrimethoxy silane, vinyltriethoxysilane, vinyl tris silane, anilinomethyl triethoxysilane, γ-An Bingjisanyiyangjiguiwan, γ-methacryloxypropyl trimethoxy silane, methyl triacetoxysilane, ethyl triacetoxysilane, methyl three butanone base silanes or, vinyl three butanone base silanes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2006100804484A CN100509978C (en) | 2006-05-16 | 2006-05-16 | Process of preventing building or ornament from being stuck and daubed adopting organic silicon |
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|---|---|---|---|
| CNB2006100804484A CN100509978C (en) | 2006-05-16 | 2006-05-16 | Process of preventing building or ornament from being stuck and daubed adopting organic silicon |
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| Publication Number | Publication Date |
|---|---|
| CN1861713A true CN1861713A (en) | 2006-11-15 |
| CN100509978C CN100509978C (en) | 2009-07-08 |
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| CN101270261B (en) * | 2008-05-13 | 2010-06-16 | 刘国强 | Ice and snow resistant, anti-corrosion paint and uses thereof |
| CN101531881B (en) * | 2008-03-14 | 2012-04-18 | 上海橡胶制品研究所 | Bonding adhesive for bonding fluorocarbon silicone rubber with metals and preparation method thereof |
| CN102690536A (en) * | 2011-03-21 | 2012-09-26 | 上海宜瓷龙新材料科技有限公司 | Environment-friendly ceramic paint for building aluminum curtain walls and preparation method thereof |
| CN102744815A (en) * | 2012-07-19 | 2012-10-24 | 湖南罗比特化学材料有限公司 | Polyurethane foaming releasing agent and preparation method thereof |
| CN103600446A (en) * | 2013-10-29 | 2014-02-26 | 哈尔滨玻璃钢研究院 | High-temperature resistant toxicity-reducing release agent and its preparation method |
| CN104231919A (en) * | 2014-10-15 | 2014-12-24 | 大连海事大学 | Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof |
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| CN104327723A (en) * | 2014-10-28 | 2015-02-04 | 佛山市新翔星化工有限公司 | Transparent and high-elasticity organosilicon waterproofing agent and preparation method thereof |
| CN104497870A (en) * | 2014-12-15 | 2015-04-08 | 广西科技大学 | Preparation method of vinyltrimethoxysilane/zinc oxide superhydrophobic composite coating |
| CN106084960A (en) * | 2016-06-30 | 2016-11-09 | 禹州市远大塑料电器有限责任公司 | A kind of novel quartz stone anti-fouling agent and preparation technology thereof |
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| CN106318205A (en) * | 2016-08-31 | 2017-01-11 | 湖北新四海化工股份有限公司 | Organosilicon coating agent for external wall and preparation method of organosilicon coating agent |
| CN106398523A (en) * | 2016-08-31 | 2017-02-15 | 湖北新四海化工股份有限公司 | Organosilicon coating agent and preparation method thereof |
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- 2006-05-16 CN CNB2006100804484A patent/CN100509978C/en not_active Expired - Fee Related
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| CN101531881B (en) * | 2008-03-14 | 2012-04-18 | 上海橡胶制品研究所 | Bonding adhesive for bonding fluorocarbon silicone rubber with metals and preparation method thereof |
| CN101270261B (en) * | 2008-05-13 | 2010-06-16 | 刘国强 | Ice and snow resistant, anti-corrosion paint and uses thereof |
| CN102690536A (en) * | 2011-03-21 | 2012-09-26 | 上海宜瓷龙新材料科技有限公司 | Environment-friendly ceramic paint for building aluminum curtain walls and preparation method thereof |
| CN102744815A (en) * | 2012-07-19 | 2012-10-24 | 湖南罗比特化学材料有限公司 | Polyurethane foaming releasing agent and preparation method thereof |
| CN103600446A (en) * | 2013-10-29 | 2014-02-26 | 哈尔滨玻璃钢研究院 | High-temperature resistant toxicity-reducing release agent and its preparation method |
| CN103600446B (en) * | 2013-10-29 | 2015-11-18 | 哈尔滨玻璃钢研究院 | High temperature resistant attenuation releasing agent |
| CN104231919A (en) * | 2014-10-15 | 2014-12-24 | 大连海事大学 | Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof |
| CN104231920A (en) * | 2014-10-15 | 2014-12-24 | 大连海事大学 | Organic silicon middle connecting coating and preparation method thereof |
| CN104327723A (en) * | 2014-10-28 | 2015-02-04 | 佛山市新翔星化工有限公司 | Transparent and high-elasticity organosilicon waterproofing agent and preparation method thereof |
| CN104497870A (en) * | 2014-12-15 | 2015-04-08 | 广西科技大学 | Preparation method of vinyltrimethoxysilane/zinc oxide superhydrophobic composite coating |
| CN107406554A (en) * | 2015-02-09 | 2017-11-28 | 美国道康宁公司 | Multiphase acid-organosilicon crylic acid class mixes viscoelastic composition and preparation method thereof |
| CN106084960A (en) * | 2016-06-30 | 2016-11-09 | 禹州市远大塑料电器有限责任公司 | A kind of novel quartz stone anti-fouling agent and preparation technology thereof |
| CN106243997A (en) * | 2016-08-29 | 2016-12-21 | 无锡市宝来电池有限公司 | A kind of wear-resisting dirt resistance coatings of cell panel |
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| CN114920496B (en) * | 2022-07-05 | 2022-11-01 | 中国科学院兰州化学物理研究所 | Waterproof material and preparation method and application thereof |
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