CN1840224A - Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof - Google Patents
Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof Download PDFInfo
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- CN1840224A CN1840224A CNA2005100461386A CN200510046138A CN1840224A CN 1840224 A CN1840224 A CN 1840224A CN A2005100461386 A CNA2005100461386 A CN A2005100461386A CN 200510046138 A CN200510046138 A CN 200510046138A CN 1840224 A CN1840224 A CN 1840224A
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Abstract
The invention discloses an accelerant and application of removing air contaminant NOx and carbon-smoke granule, which is characterized by the following: the accelerant uses copper for active component; the copper spreader carrier is on activated carbon or the compound of carbon-smoke granule and cerium oxide; the mass ratio of activated carbon or carbon-smoke granule and cerium oxide is 0.1-1; the weight percentage content of compound spreader carrier copper is 5-10. The invention adopts Cu/C-CeO2 accelerant to removing nitrogen oxide and carbon-smoke granule, which can come into effect of removing the two contaminants.
Description
Technical field
The present invention relates to the removal of air pollutants NOx and carbon soot particles, specifically a kind of catalyst and application thereof that nitrogen oxide reduction and soot particulate are eliminated.
Background technology
Environmental pollution is modern society's one big problem all the time.Pollute from 20 beginnings of the century " London smog " and " photochemical fog ", to the acid rain that still exists now, greenhouse effects and ozone hole effect, the employing of each new technology, the invention of new material and the use of new forms of energy all can bring new problem of environmental pollution.Along with oil, the use of fossil fuels such as coal, and with gasoline, diesel oil is the use of the engine of fuel, problem of environmental pollution is never serious as today.
With gasoline, diesel oil is that the engine of fuel can discharge multiple harmful components in operating process, mainly contains carbon monoxide (CO), hydrocarbon (HC), oxysulfide (SOx), nitrogen oxide (NOx), soot particulate (PM
10) (being carbon particle under the multiple situation) etc.Nitrogen oxide wherein and soot particulate are the higher pollutants of discharging content in the motor exhaust.Nitrogen oxide is because impurities from fuel or O at high temperature
2And N
2Directly chemical combination produces, the incomplete or decomposition generation of soot particulate fuel combustion under hot conditions; NOx itself is a toxic gas, and in air it can and O
2And the SOx formation acid rain that reacts, can make the plant in the environment withered, natural ecosystems are had serious destructive; " photochemical fog " that NOx forms under strong ultraviolet ray irradiation has the strong impulse effect to people's eyes, throat, and causes headache, respiratory disease, even cause death.The PM that particle is tiny
10Very easily be inhaled into people's lung, cause the multiple pathology of lung with the form of dust; While PM
10The nytron compounds is had stronger suction-operated, can cause bigger infringement to respiratory system after being sucked by the people.Therefore reducing or eliminating the nitrogen oxide and the soot particulate that enter in the atmosphere is importance of control air-polluting.
The elimination of nitrogen oxide is mainly undertaken by catalytic reduction method, mainly adopts ammonia as reducing agent; Ammonia selects catalyzing and reducing nitrogen oxides to be acknowledged as now to eliminate the effective method of nitrogen oxide under the oxidizing atmosphere from industrial waste gas, in Japan and the industrialization of some industrially developed country; But this process ammonia needs the measure control addition, and leakage or reaction not exclusively cause secondary pollution easily; The oxidized final generation NH of sulphur-containing substance in the course of reaction
4HSO
4, (NH
4)
2S
2O
7, obstruction, corrosion reaction pipeline, and make catalysqt deactivation.At the storage of the problems referred to above and ammonia, equipment and expense that transportation and use etc. are expensive are necessary to explore a kind of removing method of making reducing agent without ammonia.Hydrocarbon and carbon are the NOx reducing agents that can replace ammonia.Compare with hydrocarbon, cheap, the wide material sources of carbon, and in Chemical Manufacture and Diesel engine operating process, all can produce a large amount of in position because non-complete combustion of fuel or decompose the carbon soot particles of coking, reduce that the nitrogen oxide that discharges in stationary source and the mobile source fuel combustion process is a practicality and cheapness, the good method of killing two birds with one stone so make reducing agent with the carbon that produces.Teraoka people such as (document 1.Appl.Catal.B 5 (1995) L181) starts with from perovskite and spinels oxide; with the carbon soot particles mechanical mixture, the nitrogen oxide and the carbon soot particles of having simulated on fixed bed reactors in the power operation process are eliminated simultaneously with it.Querini people such as (document 2.Catalysis Today 75 (2002) 465-470) has prepared with La
2O
3Oxide is a carrier, Co, K are that the supported catalyst of active component is used for nitrogen oxide and carbon soot particles is eliminated simultaneously, and it is active but also can promote carbon to swallow the burning of particle effectively that this catalyst of proof not only has very high nitrogen oxide and carbon soot particles catalytic reaction under aerobic conditions.Suzuki (document 3.Energy﹠amp; Fuels 16 (2002) 1173-1177) etc. the people adopts active carbon (activated carbon) to replace carbon soot particles through screening, and Pd is carried on Al
2O
3, obtained that under oxygen free condition nitrogen oxide reduction is had very highly active Pd/activated carbon-Al
2O
3Catalyst.
Summary of the invention
The object of the present invention is to provide a kind of cheapness, effect good catalyst and application thereof that nitrogen oxide reduction and soot particulate are eliminated.At nitrogen oxide (NOx) that produces in Chemical Manufacture and the Diesel engine operating process and carbon soot particles (C), the present invention is in catalyzing and reducing nitrogen oxides effectively, and carbon soot particles also is used as reducing agent and is converted into CO
2, reach the purpose of eliminating simultaneously.
To achieve these goals, the technical solution used in the present invention is:
The catalyst of a kind of while nitrogen oxides reduction, elimination carbon soot particles, this catalyst is active component with copper, as reducing agent, catalyst carrier is CeO to adopt active carbon (carbon soot particles that generates in simulation Chemical Manufacture and the automobile engine operating process)
2Reactant is NO and C, reacts to be
Or CO+N
2Copper is supported on the mixture of active carbon (carbon soot particles) and cerium oxide, and active carbon (carbon soot particles) is 0.1～1 with the mass ratio of cerium oxide, and the weight percentage that mixture supports copper is 5～10%; With copper is active component, and copper is supported on the mixture of active carbon or carbon soot particles and cerium oxide, and the mass ratio of active carbon or carbon soot particles and cerium oxide is 0.1～1, and the weight percentage that mixture supports copper is 5～10%;
Described catalyst can prepare according to the following procedure:
(1) gets active carbon or carbon soot particles and wash the back drying for standby with red fuming nitric acid (RFNA);
(2) with catalyst carrier CeO
2Mix with above-mentioned active carbon of having handled or carbon soot particles mechanical agitation, with equi-volume impregnating catalyst activity component Cu is impregnated on the carrier, under 70～80 ℃, in water-bath, add thermal agitation 1～3 hour then, follow 100～110 ℃ of following dryings 8～10 hours;
(3) with roasting 〉=0.5 hour in 450-550 ℃ of following nitrogen atmosphere of solid after the drying,, obtain 60～80 purpose particles and be finished product at last with catalyst compressing tablet grinding and sieving.
The weight percentage that supports copper when mixture is 5%, and active carbon (carbon soot particles) is 0.5 o'clock with the mass ratio of cerium oxide, and catalyst has best reactivity; The weight percentage that supports copper when mixture is 7.5%, and active carbon (carbon soot particles) is 0.1 o'clock with the mass ratio of cerium oxide, and catalyst has best reactivity.
Catalyst provided by the invention is to adopt infusion process to be supported on the mixture of active carbon (carbon soot particles) and cerium oxide active component.The active carbon (carbon soot particles) that to cross through nitric acid treatment carry out mechanical mixture with cerium oxide earlier, and the impregnation mixture by soluble copper salt and active carbon (carbon soot particles) and cerium oxide again is after water-bath adds thermal agitation and drying and roasting obtains catalyst; Calcination atmosphere is a nitrogen, 450～550 ℃ of sintering temperatures, and roasting time is generally 〉=and 30 minutes;
When can be used for the nitrogen oxide (NOx) that produces in Chemical Manufacture and the Diesel engine operating process and carbon soot particles (C), eliminates by described catalyst reaction, [O in the unstripped gas
2]/[NO] concentration ratio is 0.2～50, reaction temperature is at 100～700 ℃, reaction pressure is a normal pressure; Reaction temperature the best is between 400～600 ℃, and oxygen concentration the best is 1%, and the unstripped gas air speed is 12000h
-1
The present invention has following advantage:
Simulate the carbon soot particles that generates in Chemical Manufacture and the power operation process with active carbon, adopt Cu/C-CeO first
2Catalyst is eliminated simultaneously to nitrogen oxide and carbon soot particles, though carbon soot particles is a pollutant, the NO reduction can be generated N under certain reaction condition
2, self can also transform simultaneously and generate CO
2, reached two kinds of effects that pollutant is eliminated simultaneously.
1. effect is good.The present invention is a reducing agent with active carbon (carbon soot particles) only, and wherein active carbon (carbon soot particles) is as reactant elder generation and support C eO
2Mix; Reaction Cu/CeO
2Make catalyst, in very wide temperature range internal reaction function admirable, transformation efficiency of the oxides of nitrogen can reach 100%.
2. anti-poisoning performance is good.Catalyst provided by the invention has anti-preferably sulfur dioxide and anti-water vapour performance.After adding sulfur dioxide and steam respectively at a certain temperature, catalyst still has good reactivity.
3, feasibility is good, is suitable for practical application.Method for preparing catalyst provided by the invention is simple, active carbon is made the reducing agent catalyzing and reducing nitrogen oxides have good reaction activity, because all can produce a large amount of in Chemical Manufacture and Diesel engine operating process because fuel combustion is incomplete or the carbon soot particles of decomposition coking, eliminating when therefore adopting this catalyst for nitrogen oxide and carbon soot particles has great realistic meaning.
The specific embodiment
Following effect of illustrating this catalyst by embodiment better.
Embodiment 1 Cu/C-CeO
2Preparation of catalysts
Here with cupric 5% (weight percentage), the weight ratio of active carbon and cerium oxide is 1: 10 Cu/C-CeO
2Come the preparation process of catalyst system therefor among the general the present invention of description for example.Active carbon is commercially available cocoanut active charcoal, CeO
2Make by the cerous nitrate decomposition.
(1) used active carbon with red fuming nitric acid (RFNA) in 70 ℃ of washings 1 hour down, after be washed to neutrality, at last in 110 ℃ down dry 12 hours standby;
(2) with catalyst carrier CeO
23.000 gram mixed 10 minutes with the above-mentioned active carbon of having handled 0.3000 gram mechanical agitation, with equi-volume impregnating catalyst activity component Cu is impregnated on the carrier, dip time is 5 hours, the precursor of Cu is the nitrate of Cu, under 72 ℃, in water-bath, add thermal agitation 2 hours then, follow 110 ℃ of following dryings 8 hours;
(3) roasting 0.5 hour in last 500 ℃ of following nitrogen atmospheres, at last with catalyst compressing tablet grinding and sieving, it is standby to obtain 60～80 purpose particles.
Embodiment 2 Cu/C-CeO
2Preparation of catalysts
Difference from Example 1 is,
(2) with catalyst carrier CeO
23.000 gram mixed 10 minutes with the above-mentioned active carbon of having handled 0.3000 gram mechanical agitation, with equi-volume impregnating catalyst activity component Cu is impregnated on the carrier, dip time is 3 hours, the precursor of Cu is the nitrate of Cu, under 80 ℃, in water-bath, add thermal agitation 3 hours then, follow 100 ℃ of following dryings 10 hours;
(3) roasting 1 hour in last 450 ℃ of following nitrogen atmospheres, at last with catalyst compressing tablet grinding and sieving, it is standby to obtain 60～80 purpose particles.
Embodiment 3 Cu/C-CeO
2Preparation of catalysts
Difference from Example 1 is,
(2) with catalyst carrier CeO
23.000 gram mixed 10 minutes with the above-mentioned active carbon of having handled 0.3000 gram mechanical agitation, with equi-volume impregnating catalyst activity component Cu is impregnated on the carrier, dip time is 6 hours, the precursor of Cu is the nitrate of Cu, under 75 ℃, in water-bath, add thermal agitation 1 hour then, follow 105 ℃ of following dryings 9 hours;
(3) roasting 2 hours in last 550 ℃ of following nitrogen atmospheres, at last with catalyst compressing tablet grinding and sieving, it is standby to obtain 60～80 purpose particles.
Comparative example 1
With several custom catalysts carrier A l
2O
3, MgO, ZrO
2, CeO
23.000 gram evenly mixes with the above-mentioned active carbon of having handled 0.3000 gram, obtains C-Al
2O
3, C-MgO, C-ZrO
2, C-CeO
2Catalyst is standby.
Comparative example 2
Pressing similarly to Example 1, method gets Co/C-CeO respectively
2, Fe/C-CeO
2And Ni/C-CeO
2Catalyst.
Comparative example 3
Pressing similarly to Example 1, method gets Co/C-Al respectively
2O
3, Fe/C-MgO and Ni/C-ZrO
2Catalyst.
Eliminate nitrogen oxide and soot particulate simultaneously under application examples 1 aerobic conditions
Here only with cupric 5% (weight percentage), the weight ratio of active carbon and cerium oxide is 1: 10 Cu/C-CeO
2For example is described activity of such catalysts test among the present invention prevailingly.
Active testing carries out in fixed bed reactors (or microreactor).Before the reaction, nitric oxide, oxygen and helium fully mix in the stainless steel blender, catalyst in the active testing (containing the micro activated carbon particle as reactant) consumption 0.3ml, feed the pending nitric oxide and the gaseous mixture of oxygen, unstripped gas air speed (GHSV) is 12000h
-1, reaction pressure is a normal pressure, reactor places in the temperature control electric furnace, 100～700 ℃ of reaction temperatures.With online chromatography analysis product, catalyst activity is a standard with the conversion ratio (%) that nitric oxide is converted into nitrogen, and nitrogen oxide is reduced into nitrogen and then is converted into CO as the carbon soot particles of reducing agent
2As a rule, because the generation of pollutant carbon soot particles is less than the discharge capacity of nitrogen oxide, and carbon soot particles is again reactant, so only weigh the quality of catalyst here with the removal ability of nitrogen oxide.Reaction result under the different situations is respectively referring to shown in the table 1-8.
Test result analysis example 1
Table 1 has been listed the catalyst activity property testing comparison that comparative example 1 prepared catalyst is undertaken by application examples 1, and the result shows CeO in several oxide carriers
2Have best NO+C reactivity, under the situation that inactive component exists, have the highest NO conversion ratio.
Table 1 oxide carrier is to the influence of NO+C reaction NO conversion ratio (%)
| Carrier | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| Al 2O 3 MgO ZrO 2 CeO 2 | 0 0 0 0 | 0 0 1.4 1.9 | 1.0 0.6 2.2 4.7 | 2.6 5.2 4.1 10.4 | 5.5 11.0 5.2 14.2 | 14.0 30.7 13.1 34 | 16.0 38.4 30.1 53.3 |
Annotate: active carbon/carrier=1/10 (percentage by weight), GHSV=12000h
-1, NO=2000ppm, O
2=1%, He is a balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 2
Table 2 has been listed catalyst activity property testing that comparative example 2 prepared catalyst undertake by application examples 1 relatively, and the result shows and works as CeO
2During as carrier, Cu/C-CeO in several active components of adding
2Have best NO+C reactivity, can reach more than 79% at the conversion ratio of 500 ℃ of NO on this catalyst.
Table 2 active component is to the influence of NO+C reaction NO conversion ratio (%)
| Active component | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| Co/C-CeO 2 Fe/C-CeO 2 Ni/C-CeO 2 Cu/C-CeO 2 | 0 0 0 0 | 0.7 1.0 1.3 2.7 | 3.1 14.3 8.9 12.0 | 12.3 25.7 23.4 24.4 | 13.0 70.1 32.4 79.1 | 21.1 76.0 41.4 99.0 | 32.1 88.1 49.4 100 |
Annotate: active carbon/carrier=1/10 (percentage by weight), active component content 5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, He is a balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 3
Table 3 has been listed the catalyst activity property testing comparison that comparative example 2 prepared catalyst are undertaken by application examples 1, and the result shows when active component is copper, in several carriers that use, with coming to the same thing that test result analysis example 2 obtains, Cu/C-CeO
2Has best NO+C reactivity.
Table 3 active component is to the influence of NO+C reaction NO conversion ratio (%)
| Active component | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| Cu/C-Al 2O 3 Cu/C-MgO Cu/C-ZrO 2 Cu/C-CeO 2 | 0 0 0 0 | 0 0 3.2 2.7 | 9.0 2.7 8.8 12.0 | 23.5 7.2 18.3 24.4 | 55.5 15.1 34.0 79.1 | 68.4 30.0 43.5 99.0 | 77.5 41.2 58.9 100 |
Annotate: active carbon/carrier=1/10 (percentage by weight), active component content 5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, He is a balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 4
Table 4 has been listed the influence of reaction temperature to catalyst activity, and activity of such catalysts increases along with the rising of reaction temperature, and particularly when reaction temperature during at 400～500 ℃, activity promptly increases, and NO almost reaches fully and transforms in the time of 600 ℃.
Table 4 reaction temperature is to Cu/C-CeO
2The influence of catalyst n O+C reaction NO conversion ratio (%)
| Reaction temperature (℃) | 100 | 200 | 300 | 400 | 500 | 600 | 700 |
| NO conversion ratio (%) | 0 | 2.7 | 12.0 | 24.4 | 79.1 | 99 | 100 |
Annotate: active carbon/carrier=1/10 (percentage by weight), Cu%=5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, He is a balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 5
Table 5 has been described the influence of ratio (mass ratio) variation of active carbon and cerium oxide to the NO conversion ratio, along with the increase of active carbon and cerium oxide ratio, and the corresponding increase of the conversion ratio of NO.At active carbon content is 5: 10 o'clock, and reaction temperature rises to 500 ℃ from 400 ℃, and the NO conversion ratio can promptly be increased to 100% from 46.5%.
Table 5 active carbon and carrier mass ratio (carbon soot particles content)
To Cu/C-CeO
2The influence of catalyst n O+C reaction NO conversion ratio (%)
| Active carbon: cerium oxide (mass ratio) | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| 1∶10 2∶10 5∶10 10∶10 | 0 0 0 0 | 2.7 6.6 1.5 1.0 | 12.0 13.8 20.0 14.7 | 24.4 33.7 46.5 44.0 | 79.1 82.1 100 100 | 99.0 100 100 100 | 100 100 100 100 |
Annotate: Cu%=5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, He is a balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 6
As shown in Table 6, along with the continuous increase of oxygen content, the NO conversion ratio reduces gradually, CO in the product
2Growing amount increases gradually, illustrates under excess oxygen and is unfavorable for the conversion of NO, and a large amount of carbon is with oxygen generation combustion reaction.When oxygen content was 1%, the NO conversion ratio was the highest.
Table 6 oxygen content is to Cu/C-CeO
2The influence of catalyst n O+C reaction NO conversion ratio (%)
| Oxygen content (%) | 0 | 1 | 2 | 5 | 10 |
| NO conversion ratio (%) | 49.1 | 83.5 | 68.8 | 64.5 | 53.5 |
| CO 2Growing amount (ppm) | 177 | 367 | 1257 | 1460 | 1987 |
Annotate: active carbon/carrier=1/10 (percentage by weight), Cu%=5%, GHSV=12000h
-1, NO=2000ppm, He are balance gas, reaction temperature is 500 ℃, and catalyst loading amount 0.3ml, reaction pressure is a normal pressure.
Test result analysis example 7
In reaction gas, add 200ppm SO
2And then catalyst carried out active testing, table 7 has compared reaction gas and has added SO
2The catalyst activity of front and back compares, and from experimental data as can be seen, catalyst activity is adding SO
2The back changes less, illustrates that catalyst has certain anti-SO
2Ability.
Table 7 SO
2To Cu/C-CeO
2The influence of catalyst n O+C reaction NO conversion ratio (%)
| Gas composition | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| NO+O 2 NO+O 2+SO 2 | 0 0 | 1.5 5.2 | 20.0 13.3 | 46.5 44.3 | 100 100 | 100 100 | 100 100 |
Annotate: active carbon/carrier=5/10 (percentage by weight), Cu%=5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, SO
2=200ppm, He are balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Test result analysis example 8
In reaction gas, add 10%H
2O and then catalyst carried out active testing, table 8 has compared reaction gas and has added H
2Catalyst activity before and after the O compares, and from experimental data as can be seen, catalyst activity is adding H
2Change behind the O less because the H that adds
2O content is higher, illustrates that catalyst has good anti-H
2The O ability.
Table 8 H
2O is to Cu/C-CeO
2The influence of catalyst n O+C reaction NO conversion ratio (%)
| Gas composition | Reaction temperature (℃) | ||||||
| 100 | 200 | 300 | 400 | 500 | 600 | 700 | |
| NO+O 2 NO+O 2+H 2O | 0 0 | 1.5 7.7 | 20.0 15.5 | 46.5 44.9 | 100 100 | 100 100 | 100 100 |
Annotate: active carbon/carrier=5/10 (percentage by weight), Cu%=5%, GHSV=12000h
-1, NO=2000ppm, O
2=1%, H
2O=10%, He are balance gas, catalyst loading amount 0.3ml, and reaction pressure is a normal pressure.
Use method of the present invention, can make the percent reduction of nitrogen oxide reach 100%, also removed carbon soot particles effectively simultaneously, reach the removal effect of killing two birds with one stone.
Claims (5)
- One kind simultaneously nitrogen oxides reduction, eliminate the catalyst of carbon soot particles, it is characterized in that: be active component with copper, copper is supported on the mixture of active carbon or carbon soot particles and cerium oxide, the mass ratio of active carbon or carbon soot particles and cerium oxide is 0.1～1, and the weight percentage that mixture supports copper is 5～10%;Described catalyst can prepare according to the following procedure:(1) gets active carbon or carbon soot particles and wash the back drying for standby with red fuming nitric acid (RFNA);(2) with catalyst carrier CeO 2Mix with above-mentioned active carbon of having handled or carbon soot particles mechanical agitation, with equi-volume impregnating catalyst activity component Cu is impregnated on the carrier, under 70～80 ℃, in water-bath, add thermal agitation 1～3 hour then, follow 100～110 ℃ of following dryings 8～10 hours;(3) with roasting 〉=0.5 hour in 450-550 ℃ of following nitrogen atmosphere of solid after the drying,, obtain 60～80 purpose particles and be finished product at last with catalyst compressing tablet grinding and sieving.
- 2. according to the catalyst of the described while nitrogen oxides reduction of claim 1, elimination carbon soot particles, it is characterized in that: the mass ratio of active carbon or carbon soot particles and cerium oxide is 0.5, and the weight percentage that mixture supports copper is 5%.
- 3. according to the catalyst of the described while nitrogen oxides reduction of claim 1, elimination carbon soot particles, it is characterized in that: the mass ratio of active carbon or carbon soot particles and cerium oxide is 0.1, and the weight percentage that mixture supports copper is 7.5%.
- The described while nitrogen oxides reduction of claim 1, eliminate the Application of Catalyst of carbon soot particles, it is characterized in that: this catalyst is used for nitrogen oxide and the carbon soot particles that Chemical Manufacture and Diesel engine operating process produce, [O in the unstripped gas 2]/[NO] concentration ratio is 0.2～50, reaction temperature is between 100～700 ℃, the unstripped gas air speed is 12000h -1
- 5. according to the Application of Catalyst of the described while nitrogen oxides reduction of claim 4, elimination carbon soot particles, it is characterized in that: described reaction temperature is 400～600 ℃, and oxygen concentration is 1% in the unstripped gas.
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|---|---|---|---|
| CNB2005100461386A CN100391580C (en) | 2005-03-30 | 2005-03-30 | Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100461386A CN100391580C (en) | 2005-03-30 | 2005-03-30 | Catalyst capable of reducing nitric oxides and eliminating soot particle simultaneously and application thereof |
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|---|---|
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| CN100391580C CN100391580C (en) | 2008-06-04 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693192B (en) * | 2009-10-23 | 2011-09-21 | 中国科学院过程工程研究所 | Process for preparing nitric oxide adsorbent with high adsorption capacity |
| CN105251502A (en) * | 2014-12-02 | 2016-01-20 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Mercury-free catalyst for acetylene hydrochlorination |
| CN106310871A (en) * | 2016-08-31 | 2017-01-11 | 浙江奇彩环境科技股份有限公司 | Method for joint degradation of waste gases in coal chemical industry |
| CN112844394A (en) * | 2019-11-27 | 2021-05-28 | 中国科学院大连化学物理研究所 | CuO-CeO2Preparation method of supported catalyst and application of supported catalyst in tail gas NOxAnd application in anaerobic elimination of CO |
-
2005
- 2005-03-30 CN CNB2005100461386A patent/CN100391580C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693192B (en) * | 2009-10-23 | 2011-09-21 | 中国科学院过程工程研究所 | Process for preparing nitric oxide adsorbent with high adsorption capacity |
| CN105251502A (en) * | 2014-12-02 | 2016-01-20 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | Mercury-free catalyst for acetylene hydrochlorination |
| CN106310871A (en) * | 2016-08-31 | 2017-01-11 | 浙江奇彩环境科技股份有限公司 | Method for joint degradation of waste gases in coal chemical industry |
| CN112844394A (en) * | 2019-11-27 | 2021-05-28 | 中国科学院大连化学物理研究所 | CuO-CeO2Preparation method of supported catalyst and application of supported catalyst in tail gas NOxAnd application in anaerobic elimination of CO |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100391580C (en) | 2008-06-04 |
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