CN1834271A - Method of preparing High W content Ni-W alloy for high temp superconduct - Google Patents
Method of preparing High W content Ni-W alloy for high temp superconduct Download PDFInfo
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- CN1834271A CN1834271A CN 200610076274 CN200610076274A CN1834271A CN 1834271 A CN1834271 A CN 1834271A CN 200610076274 CN200610076274 CN 200610076274 CN 200610076274 A CN200610076274 A CN 200610076274A CN 1834271 A CN1834271 A CN 1834271A
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- 238000000034 method Methods 0.000 title claims abstract description 39
- 229910001080 W alloy Inorganic materials 0.000 title claims abstract description 15
- 238000000137 annealing Methods 0.000 claims abstract description 63
- 238000005245 sintering Methods 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002887 superconductor Substances 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- 238000001953 recrystallisation Methods 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000007858 starting material Substances 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 18
- 229910045601 alloy Inorganic materials 0.000 abstract description 10
- 239000000956 alloy Substances 0.000 abstract description 10
- 238000005097 cold rolling Methods 0.000 abstract description 10
- 239000007788 liquid Substances 0.000 abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 9
- 238000002490 spark plasma sintering Methods 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 5
- 239000002245 particle Substances 0.000 abstract description 2
- 230000005389 magnetism Effects 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 description 24
- 230000005291 magnetic effect Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 229910021521 yttrium barium copper oxide Inorganic materials 0.000 description 11
- 229910052759 nickel Inorganic materials 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 5
- 239000010408 film Substances 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009770 conventional sintering Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000002595 magnetic resonance imaging Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000001272 pressureless sintering Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
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Abstract
This invention discloses a method for manufacturing high W-content Ni-W alloy substrates used on high-temperature superconductors. Low W-content (3-5 at. %) Ni-W alloy substrates have good cubic structure, but also have strong magnetism in liquid nitrogen temperature range and no mechanical strength. The method in this invention comprises the steps of: (1) mixing Ni powders and W powders with particle sizes of 3-6 mum, performing spark plasma sintering at 800-1300 deg.C, and keeping the temperature for 0-10 min, (2) cold-rolling the Ni-W sheets at room temperature with small pass strains of 3-8%, and performing intermediate annealing at 300-800 deg.C for 0.5-6 h when the strain is 30-80% until the total strain is more than 95%, and (3) annealing in a mixture of Ar and H2 at 1000-1400 deg.C for 0.5-3 h to obtain uniform Ni-W alloy substrates with W content in the range of 7.01-9.5 mol.%. The high W-content alloy substrates have such advantages as simple sintering process, low magnetism in liquid nitrogen temperature range and high mechanical strength.
Description
Technical field
The present invention relates to the Ni-W base band preparation method of the high W content of a kind of polycrystal, belong to the technical field of high-temperature superconducting coating tenacity strip and superconducting thin film preparation.
Background technology
With Bi is that superconducting tape is compared, and is called for short the YBa of YBCO
2Cu
3O
7.01-δSuperconductor possesses the ability of the bigger electric current of carrying in magnetic field, and application prospect is boundless.It is the important step that realizes its practical application that the fragility high temperature superconducting materia is made line, band.In recent years, the deposition superconducting film had been obtained very big progress with the research of preparation line, band on the employing polycrystalline tough metal base band, had successfully prepared high performance YBCO coating conductor.But the TEXTURE STATE of base band directly has influence on the TEXTURE STATE of epitaxially grown superconducting film thereon, and influences the electrical property of superconduction, so TEXTURE STATE is extremely important to the base band material.
Pure nickel is a kind of base band material that is widely used.This is because pure nickel has good working performance, drastic deformation and the very easy formation in annealing back strong cubic texture 100}＜100 〉, be most nickel crystallites with the 100} face is parallel to the face that rolls of base band, again with＜100〉direction is parallel to the rolling direction of base band.But the intensity of pure nickel is not high, and mechanical property is relatively poor; Its Curie temperature is 627.01K, is ferromegnetism under the normal temperature, makes the YBCO coating conductor meet difficulty in using as the upfield of Magnetic resonance imaging etc.; And because the effect of magnetic hysteresis loss, the pure nickel base band can cause energy waste in AC applications.
The alloying of nickel is to solve the not high and ferromagnetic effective way of removal of pure nickel intensity, and wherein nickel tungsten has obtained paying close attention to widely.The Ni-W alloy base band possesses four advantages: strong cubic texture occurs after (1) violent cold rolling and recrystallization annealing; (2) strength of materials improves, and mechanical property is better; (3) with other Ni alloy phase ratios better oxidation-resistance is arranged, such as Ni-Cr, Ni-V, Ni-Fe; (4) magnetic is very little.Therefore, the Ni-W base band be easier to commercially produce can be under liquid nitrogen temperature 7.017.01K and in the magnetic field HTS YBCO band of bearing great current.
As the substrate material of YBCO, the Ni-W base band had both required to have very strong cubic texture, required to have alap magnetic at liquid nitrogen temperature again, did not preferably have magnetic.According to nickel tungsten binary phase diagram and bibliographical information, during when the atomic percent arrival of W in the Ni-W alloy or above about 9at.%, promptly the Ni-9at%W base band can reach nonmagnetic at liquid nitrogen temperature.But as long as W content in the Ni-W alloy atomic percent above about 5.6% o'clock, the stacking fault energy of alloy sharply descends, cause the cubic texture intensity of alloy base band sharply to descend, and the cubic texture intensity of base band is not high, just can not adopt epitaxially grown method preparation to have the YBCO superconducting film of high electrical performance thereon.Still does not have at present successfully preparation in the world and have very that strong cubic texture contains the report that the W amount meets or exceeds the nickel-tungsten alloy base-band of 7at%W, promptly both had very strong cubic texture, complete nonmagnetic or have very low magnetic at liquid nitrogen temperature again.All be to adopt to contain the low W content nickel-tungsten alloy base-band of W amount at present both at home and abroad at 3-5at.%, though such base band material has good cubic texture, but still has very strong magnetic at liquid nitrogen temperature, influence is application or the AC applications of YBCO coating conductor in the upfield of preparation in the above, and physical strength is lower, is unfavorable for preparing the superconductive long strip material.
Summary of the invention
The present invention adopts the powder metallurgy process preparation to contain the Ni-W alloy of W up to 7.01～9.5at.%.After this by controlling the deformation and the recrystallization annealing process of Ni-W alloy, comprising the controlled rolling total deformation, pass deformation and process annealing process form certain modulated structure, adopt certain annealing temperature then, annealing atmosphere and annealing time carry out recrystallization annealing, obtain having strong 100}＜100〉Ni7.01～9.5at.%W alloy base band of recrystallization texture, because the content height of alloying constituent W, alloy base band does not have magnetic or has very low magnetic at liquid nitrogen temperature, the strip and the process high temperature annealing that roll into simultaneously after 0.8 micron still have very high physical strength later on, highly beneficial to subsequent preparation YBCO superconductive long strip, can be used to deposit the YBCO high temperature superconducting film.
Be characterised in that among the present invention that it may further comprise the steps successively:
1) use Ni powder and W powder to be starting material, purity is weight percentage more than 99.9%, and granularity is 3～6 microns, and the atomic percent of alloying constituent W is 7.01% to 9.5%; Nickel powder and tungsten powder are mixed, be encased in then and carry out discharge plasma sintering in the mould; Sintering temperature is 800 ℃～1300 ℃, and the sintered heat insulating time is 0～10 minute; Sintering pressure is 30-80MPa;
2) at room temperature the Ni-W plate is carried out cold rollingly, adopt 3～8% little pass deformation; In cold-rolled process, deflection whenever reaches 30～80% and carries out a process annealing, and annealing temperature is at 300～800 ℃, and annealing time is 0.5～6 hour; Total deflection is greater than 95%;
3) adopt H
2Volume percent be 4～7% Ar mixing H
2Atmosphere is carried out recrystallization annealing, 1000～1400 ℃ of annealing temperatures, and annealing time is 0.5～3 hour.
Discharge plasma sintering technique Spark Plasma Sintering, be called for short SPS and be a kind of fast, the material preparation New Machining Technology of low temperature, energy-saving and environmental protection.This technology is directly to feed pulsed electrical energy between the pressurization powder particle, and the plasma body that is produced by spark discharge moment heats, and utilizes heat effect, field-effect etc. to carry out short period of time agglomerating new technology at low temperature.The electric energy of its consumption has only 1/5～1/3 of conventional sintering technologies such as pressureless sintering PLS, hot pressed sintering HP, hot isostatic pressing HIP.SPS can obtain the material of homogeneous, densification.The atomic percent that the present invention adopts discharge plasma sintering technique to obtain the W that composition is even, crystal grain is tiny is 7.01% to 9.5% Ni-W alloy block, makes sintering process simplification and rapid simultaneously.
Because the stacking fault energy of the nickel tungsten of high W content is low, the resistance of dislocation glide is big in cold-rolled process, easily form twin and can not get the alloy base band of strong cubic texture at last, we find to carry out the content that process annealing can reduce twin in the alloy base band under study for action in the operation of rolling, finally obtain very strong cubic texture.Carry out process annealing and can eliminate the strain that forms in the deformation process, reduce the resistance of dislocation glide in the follow-up deformation process, thereby reduce the formation of twin.But annealing temperature can not be too high, and annealing time can not be oversize, otherwise perfect recrystallization in annealing process, and follow-up deflection can not superpose and form big total deformation, can not form strong cubic texture and surpass 95% big total deformation.With h
0, h
1, h
2... and h
nRepresent respectively thickness before original depth, the process annealing for the first time, the thickness before the process annealing for the second time ... with final thickness, total deformation is with (h
n-h
1)/h
1Calculate.Deflection before each process annealing is with (h
n-h
N-1)/ h
nCalculate.Be total deformation be not be deflection before each process annealing numeral add and, but the summation of actual all distortion.
In addition, adopting very little pass deformation also is in order to reduce the amount of twin in the prepared base band, to obtain having the alloy base band of very strong cubic texture at last.Through our research, pass deformation is 3～8% suitable.
Description of drawings:
111 of the Ni-7.01%W strip utmost point figure (a) and 200 utmost point figure (b) among Fig. 1: the embodiment 1;
111 of the Ni-7.01%W strip utmost point figure (a) and 200 utmost point figure (b) among Fig. 2: the embodiment 2;
111 of the Ni-8.5%W strip utmost point figure (a) and 200 utmost point figure (b) among Fig. 3: the embodiment 3;
111 of the Ni-9.5%W strip utmost point figure (a) and 200 utmost point figure (b) among Fig. 4: the embodiment 4.
Embodiment
Below in conjunction with drawings and Examples the present invention is described in further details.
It is starting material that example 1. adopts Ni powder and W powder, and purity is weight percentage 99.9%, and Ni powder degree is 4～6 microns, and W powder degree is 3～4 microns, and W accounts for that the composition atomic percent is 7.01% in the alloy.The mould of packing into after mixing carries out the SPS sintering.Sintering temperature is 800 ℃, and the sintered heat insulating time is 10 minutes.Sintering pressure is 80MPa.Obtained density and be 97.2% Ni-7.01%W piece.
The Ni-7.01%W piece is carried out cold rolling and recrystallization annealing, and cold rolling pass deformation is 7～8%, and total deformation is 97%, and in cold-rolled process, deflection reaches 80% and carries out a process annealing, 800 ℃ of annealing temperatures, annealing time 0.5 hour.Adopt H then
2Volume percent be 4%Ar+H
2Mixed atmosphere carries out recrystallization annealing, 1000 ℃ of annealing temperatures, and annealing time is 3 hours.Obtained having very strong, single-orientated 100}＜100〉strip of texture, Fig. 1 is its (111) and (200) utmost point figure.Obtain extraordinary cubic texture Ni-7.01%W base band material, can be used for the preparation of follow-up YBCO coating superconducting material.
Example 2. adopts the Ni-7.01%W piece of preparation in the example 1, carrying out cold rolling and recrystallization annealing, cold rolling pass deformation is 5～6%, total deformation is 95%, in cold-rolled process, deflection whenever reaches 60% and carries out a process annealing, carries out 2 process annealing altogether, 300 ℃ of annealing temperatures, annealing time 6 hours.Adopt H then
2Volume percent be 4%Ar+H
2Mixed atmosphere carries out recrystallization annealing, 1100 ℃ of annealing temperatures, and annealing time is 2 hours.Obtained having very strong, single-orientated 100}＜100〉strip of texture, Fig. 2 is its (111) and (200) utmost point figure.Obtain extraordinary cubic texture Ni-7.01%W base band material, can be used for the preparation of follow-up YBCO coating superconducting material.
It is starting material that example 3. adopts Ni powder and W powder, and purity is weight percentage 99.9%, and Ni powder degree is 4～6 microns, and W powder degree is 3～4 microns, and W accounts for that the composition atomic percent is 8.5% in the alloy.The mould of packing into after mixing carries out the SPS sintering.Sintering temperature is 1300 ℃, does not carry out sintered heat insulating.Sintering pressure is 30MPa.Obtained density and be 97.5% Ni-9.5%W piece.
At room temperature the Ni-8.5%W piece is carried out cold rolling and recrystallization annealing, cold rolling pass deformation is 3～4%, and total deformation is 98%, in cold-rolled process, deflection whenever reaches 50% and carries out a process annealing, carries out 4 process annealing altogether, 500 ℃ of annealing temperatures, annealing time 3 hours.Adopt H then
2Volume percent be 7%Ar+H
2Mixed atmosphere carries out recrystallization annealing, 1400 ℃ of annealing temperatures, and annealing time is 0.5 hour.Obtained having certain intensity 100}＜100〉strip of texture, Fig. 3 is its (111) and (200) utmost point figure.
It is starting material that example 4. adopts Ni powder and W powder, and purity is weight percentage 99.9%, and Ni powder degree is 4～6 microns, and W powder degree is 3～4 microns, and W accounts for that the composition atomic percent is 9.5% in the alloy.The mould of packing into after mixing carries out the SPS sintering.Sintering temperature is 1200 ℃, is incubated 5 minutes.Sintering pressure is 50MPa.Obtained density and be 98% Ni-9.5%W piece.
At room temperature the Ni-9.5%W piece is carried out cold rolling and recrystallization annealing, cold rolling pass deformation is 4～5%, and total deformation is 99%, in cold-rolled process, deflection whenever reaches about 30% and carries out a process annealing, 600 ℃ of annealing temperatures, annealing time 1 hour carries out 6 process annealing altogether.Adopt H then
2Volume percent be 7%Ar+H
2Mixed atmosphere carries out recrystallization annealing, 1300 ℃ of annealing temperatures, and annealing time is 1 hour.Obtained having certain intensity 100}＜100〉strip of texture, Fig. 4 is its (111) and (200) utmost point figure.
The M-T curve of the test of process superconducting quantum interference device (SQUID), and learn among Ni-7.01at.%W strip among the embodiment 2, the embodiment 3 that by calculating the Curie temperature of Ni-9.5at.%W strip is respectively 174K, 85K and 1K in the Ni-8.5at.%W strip and embodiment 4, promptly to be higher than under the warm area that 85K and Ni-9.5at.%W strip be higher than 1K all be non-magnetic to the Ni-7.01at.%W strip being higher than 174K, Ni-8.5at.%W strip.Wherein the Curie temperature of Ni-9.5at.%W base band is non-magnetic fully well below 77K at liquid nitrogen temperature.Though and the Curie temperature 174K of Ni-7.01at.%W strip is higher than 77K, compares with the 328K of Ni-5at.%W strip or reduced 154K, the effect highly significant.
Claims (1)
1, a kind of preparation method who is used for the high W content Ni-W alloy of high-temperature superconductor is characterized in that it may further comprise the steps successively:
1) use Ni powder and W powder to be starting material, purity is weight percentage more than 99.9%, and granularity is 3～6 microns, and the atomic percent of alloying constituent W is 7.01% to 9.5%; Nickel powder and tungsten powder are mixed, be encased in then and carry out discharge plasma sintering in the mould; Sintering temperature is 800 ℃～1300 ℃, and the sintered heat insulating time is 0～10 minute; Sintering pressure is 30-80MPa;
2) at room temperature the Ni-W plate is carried out cold rollingly, adopt 3～8% little pass deformation; In cold-rolled process, deflection whenever reaches 30～80% and carries out a process annealing, and annealing temperature is at 300～800 ℃, and annealing time is 0.5～6 hour; Total deflection is greater than 95%;
3) adopt H
2Volume percent be 4～7% Ar mixing H
2Atmosphere is carried out recrystallization annealing, 1000～1400 ℃ of annealing temperatures, and annealing time is 0.5～3 hour.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329973A (en) * | 2011-09-21 | 2012-01-25 | 西安理工大学 | Preparation method for Ni-W alloy by using smelting method |
| CN103128524A (en) * | 2012-12-29 | 2013-06-05 | 北京工业大学 | Manufacture method for alloy long band with high cubic texture contents, high strength and low magnetism Ni-5at. %W |
| CN105525146A (en) * | 2016-01-17 | 2016-04-27 | 北京工业大学 | Method for improving content of cubic texture of Ni9.3W base band for YBCO superconductor |
| CN106077642A (en) * | 2016-07-16 | 2016-11-09 | 北京工业大学 | A kind of alloy nano-powder prepares the method for high-tungsten alloy base band billet used for coating conductor |
| CN106111987A (en) * | 2016-07-16 | 2016-11-16 | 北京工业大学 | The method of NiW alloy base belt for coated conductor billet prepared by a kind of alloy powder |
| CN108515174A (en) * | 2018-04-27 | 2018-09-11 | 合肥工业大学 | A kind of resistance to high temperature oxidation W-Cr-Ti composite material and preparation methods |
| CN109732087A (en) * | 2019-01-28 | 2019-05-10 | 中南大学 | A kind of preparation method of powder metallurgy Ti-Ta binary metal-metal-based layer-shaped composite material |
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| JP2004250788A (en) * | 2003-01-30 | 2004-09-09 | National Institute Of Advanced Industrial & Technology | Film depositing method |
| CN1312301C (en) * | 2005-09-23 | 2007-04-25 | 北京工业大学 | Prepn process of high temperature superconductive Ni-W alloy |
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2006
- 2006-04-21 CN CNB2006100762744A patent/CN100371482C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329973A (en) * | 2011-09-21 | 2012-01-25 | 西安理工大学 | Preparation method for Ni-W alloy by using smelting method |
| CN103128524A (en) * | 2012-12-29 | 2013-06-05 | 北京工业大学 | Manufacture method for alloy long band with high cubic texture contents, high strength and low magnetism Ni-5at. %W |
| CN103128524B (en) * | 2012-12-29 | 2015-07-22 | 北京工业大学 | Manufacture method for alloy long band with high cubic texture contents, high strength and low magnetism Ni-5at. %W |
| CN105525146A (en) * | 2016-01-17 | 2016-04-27 | 北京工业大学 | Method for improving content of cubic texture of Ni9.3W base band for YBCO superconductor |
| CN106077642A (en) * | 2016-07-16 | 2016-11-09 | 北京工业大学 | A kind of alloy nano-powder prepares the method for high-tungsten alloy base band billet used for coating conductor |
| CN106111987A (en) * | 2016-07-16 | 2016-11-16 | 北京工业大学 | The method of NiW alloy base belt for coated conductor billet prepared by a kind of alloy powder |
| CN108515174A (en) * | 2018-04-27 | 2018-09-11 | 合肥工业大学 | A kind of resistance to high temperature oxidation W-Cr-Ti composite material and preparation methods |
| CN109732087A (en) * | 2019-01-28 | 2019-05-10 | 中南大学 | A kind of preparation method of powder metallurgy Ti-Ta binary metal-metal-based layer-shaped composite material |
| CN110387512A (en) * | 2019-08-06 | 2019-10-29 | 北京科技大学 | A kind of cold rolled annealed preparation method of the high cobalt-nickel alloy Ultra-fine Grained plate of high tungsten |
| CN110387512B (en) * | 2019-08-06 | 2020-12-01 | 北京科技大学 | Cold rolling annealing preparation method of high-tungsten high-cobalt-nickel alloy superfine crystal plate |
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