CN1830865A - Method of producing ecological cementing material using electrolytic manganese slag - Google Patents
Method of producing ecological cementing material using electrolytic manganese slag Download PDFInfo
- Publication number
- CN1830865A CN1830865A CNA2006100509604A CN200610050960A CN1830865A CN 1830865 A CN1830865 A CN 1830865A CN A2006100509604 A CNA2006100509604 A CN A2006100509604A CN 200610050960 A CN200610050960 A CN 200610050960A CN 1830865 A CN1830865 A CN 1830865A
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- electrolytic manganese
- cementing material
- manganese residues
- balling
- transported
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
An ecological cementing material used as the additive of cement or the coating material of wall is prepared from the dregs of electrolytic Mn, lime stone, anthractive and fluorite through mixing, grinding, homogenizing, stirring, adding water, stirring, sphericizing and calcining.
Description
Technical field: the present invention relates to produce the method for ecological cementing material, particularly a kind of method of utilizing electrolytic manganese residues to produce ecological cementing material.
Background technology: present electrolytic manganese residues is used for a kind of acid industrial pollution waste residue with manganese, a large amount of dischargings causes the permanent pollution in arable land and brings serious water pollution to rivers, does not up to the present also utilize electrolytic manganese residues to produce the method for ecological cementing material.
Summary of the invention: the object of the present invention is to provide a kind of method of utilizing electrolytic manganese residues to produce ecological cementing material, the ecological cementing material that utilizes this method to produce, not only can make cement mixture uses, also can produce high trickle powder, be used for body of wall and whitewash, and can reduce the pollution of electrolytic manganese residues environment.
Formation of the present invention: it is made up of following components in weight percentage: Wingdale 382～50.1%, electrolytic manganese residues 43.1～55%, hard coal 4～5%, fluorite 0.9～1.8%.
To carry out grinding after the above-mentioned raw materials mixing, the warehouse-in homogenizing is transported to biaxial rneader, and add water and stir, balling-up, kiln is sintered into the gelling material grog.
Carry out grinding after will above-mentioned raw materials mixing, fineness control 0.08 tails over 10% ± 1, enter the pre-homogenizing of silos after, be transported to biaxial rneader by the bottom of the reservior and add water in advance, amount of water is 11% ± 1, and wet feed stirs the back to the pan-pelletizer balling-up, the balling-up particle diameter should be controlled at 6～8mm, accounts for 80%, and pellet is transported to the kiln calcining by belt, firing temperature should be controlled at 800 ℃ ± 50 ℃, clinker strength 3 days, anti-folding 2.8mPa, resistance to compression 12.8mPa, 28 days, anti-folding 4.9mPa, resistance to compression 26.8mPa.
Compared with the prior art, electrolytic manganese residues of the present invention is a kind of industrial residue, through us research and test, it can produce ecological cementing material, after this material produce, it can be used as cement mixture and uses, and also can produce a kind of high trickle powder, mix cement, also available micro mist whitewashes as body of wall.
Advantage: 1, the electrolytic manganese residues consumption is big; 2, starting material are through grinding, and fineness is thin; 3, balling-up plasticity is good; 4, furnace output height because firing temperature is low, contains 2% manganese and 8% vitriol in the electrolytic manganese residues; 5, electrolytic manganese residues is through high-temperature calcination, contains 2% manganese and 10% ammonia in the electrolytic manganese residues and all is decomposed; 6, make micro mist, be used for body of wall, market outlook are good.
In a word: to the electrolytic manganese residues development and application, it not only solves environmental pollution, and it can produce ecological gelling material, and market is good, for electrolytic manganese factory has solved pollution problem for many years, also makes waste residue become precious, meets national economic development.
Description of drawings: accompanying drawing is a process flow sheet of the present invention.
Embodiment: Wingdale 53.5%, electrolytic manganese residues 40%, hard coal 5%, fluorite 1.5%, carry out grinding after the mixing, fineness control 0.08 tails over 10% ± 1, after entering the pre-homogenizing of silos, be transported to biaxial rneader by the bottom of the reservior and add water in advance, amount of water is 11% ± 1, wet feed stirs the back to the pan-pelletizer balling-up, and the balling-up particle diameter should be controlled at 6～8mm, accounts for 80%, pellet is transported to the kiln calcining by belt, firing temperature should be controlled at 800 ℃ ± 50 ℃, 3 days anti-folding 2.8mPa of clinker strength, resistance to compression 12.8mPa, 28 days anti-folding 4.9mPa, resistance to compression 26.8mPa.
Claims (3)
1. one kind is utilized electrolytic manganese residues to produce ecological cementing material, it is characterized in that it is made up of following components in weight percentage: Wingdale 38.2～50.1%, electrolytic manganese residues 43.1～55%, hard coal 4～5%, fluorite 0.9～1.8%.
2. the method for utilizing electrolytic manganese residues to produce ecological cementing material according to claim 1 is characterized in that: carry out grinding after above-mentioned raw materials is mixed, the warehouse-in homogenizing is transported to biaxial rneader, and add water and stir, balling-up, kiln is sintered into the gelling material grog.
3. the method for utilizing electrolytic manganese residues to produce ecological cementing material according to claim 1 and 2, it is characterized in that: carry out grinding after above-mentioned raw materials is mixed, fineness control 0.08 tails over 10% ± 1, after entering the pre-homogenizing of silos, be transported to biaxial rneader by the bottom of the reservior and add water in advance, amount of water is 11% ± 1, and wet feed stirs the back to the pan-pelletizer balling-up, the balling-up particle diameter should be controlled at 6～8mm, account for 80%, pellet is transported to the kiln calcining by belt, and firing temperature should be controlled at 800 ℃ ± 50 ℃, clinker strength 3 days, anti-folding 2.8mPa, resistance to compression 12.8mPa, 28 days, anti-folding 4.9mPa, resistance to compression 26.8mPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100509604A CN100545116C (en) | 2006-03-07 | 2006-03-07 | Utilize electrolytic manganese residues to produce the method for ecological cementing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100509604A CN100545116C (en) | 2006-03-07 | 2006-03-07 | Utilize electrolytic manganese residues to produce the method for ecological cementing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1830865A true CN1830865A (en) | 2006-09-13 |
| CN100545116C CN100545116C (en) | 2009-09-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100509604A Expired - Fee Related CN100545116C (en) | 2006-03-07 | 2006-03-07 | Utilize electrolytic manganese residues to produce the method for ecological cementing material |
Country Status (1)
| Country | Link |
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| CN (1) | CN100545116C (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101306425B (en) * | 2008-06-24 | 2010-06-02 | 卿富安 | Electrolytic manganese slag comprehensive utilization technique |
| CN101811737A (en) * | 2010-04-19 | 2010-08-25 | 湘西自治州矿产与新材料技术创新服务中心 | Method for preparing manganese sulfate from sulfur-containing waste residue |
| CN101367629B (en) * | 2008-09-16 | 2010-12-15 | 重庆大学 | Manufacture of sulphur aluminate cements with electrolytic manganesium residue and method of manufacturing the same |
| CN102206052A (en) * | 2010-03-30 | 2011-10-05 | 贵州省建筑材料科学研究设计院 | Method for cement production utilizing electrolytic manganese slag as cement mineralizer |
| CN102491423A (en) * | 2011-12-01 | 2012-06-13 | 湘西自治州矿产与新材料技术创新服务中心 | Method for preparing manganese sulfate from sulfur-containing slag |
| CN102838299A (en) * | 2012-09-12 | 2012-12-26 | 南宁市伟达科技有限公司 | Method for producing cement by electrolytic manganese residue and red mud |
| CN102923977A (en) * | 2012-11-15 | 2013-02-13 | 吉首大学 | Method capable of utilizing sulfate-free electrolytic manganese residue to prepare common silica cement |
| CN101543830B (en) * | 2009-05-05 | 2014-10-01 | 湖北声荣环保节能科技有限公司 | Comprehensive utilization method for recycling manganese oxide slag |
| CN104986974A (en) * | 2015-07-21 | 2015-10-21 | 湖南省小尹无忌环境能源科技开发有限公司 | Method for preparing ecological active residues by treating electrolytic manganese residues by virtue of rotary kiln plant |
| CN105060741A (en) * | 2015-07-24 | 2015-11-18 | 湖南省小尹无忌环境能源科技开发有限公司 | Method for preparing ecological active residues by treating electrolytic manganese residues by using tunnel kiln device |
| CN105130222A (en) * | 2015-07-21 | 2015-12-09 | 湖南省小尹无忌环境能源科技开发有限公司 | Method of preparing special sulfate cementing material through treatment on electrolytic manganese residue in fluidized bed boiler |
| CN105130217A (en) * | 2015-07-21 | 2015-12-09 | 湖南省小尹无忌环境能源科技开发有限公司 | Method of producing ecological activated slag through treatment on electrolytic manganese residue in vertical kiln factory |
| CN110183120A (en) * | 2019-05-13 | 2019-08-30 | 中冶武汉冶金建筑研究院有限公司 | Utilize the method for original state electrolytic manganese residues and steel slag tailing slurry production activity of cement admixture |
| CN110642543A (en) * | 2019-11-21 | 2020-01-03 | 石晶 | Alkaline cementing material produced by electrolytic manganese slag |
| CN110723917A (en) * | 2019-10-31 | 2020-01-24 | 青川天隆新材料开发有限责任公司 | Resource utilization method of electrolytic manganese slag |
| CN111689755A (en) * | 2020-05-26 | 2020-09-22 | 华南理工大学 | Method for preparing composite modified magnesium oxysulfate cementing material by utilizing electrolytic manganese slag |
| CN112358210A (en) * | 2020-11-22 | 2021-02-12 | 贵州大学 | Preparation method of electrolytic manganese slag-barium slag cement |
| CN113105202A (en) * | 2021-04-15 | 2021-07-13 | 武汉中科固废资源产业技术研究院有限公司 | Full-solid waste material and preparation method and application thereof |
-
2006
- 2006-03-07 CN CNB2006100509604A patent/CN100545116C/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101306425B (en) * | 2008-06-24 | 2010-06-02 | 卿富安 | Electrolytic manganese slag comprehensive utilization technique |
| CN101367629B (en) * | 2008-09-16 | 2010-12-15 | 重庆大学 | Manufacture of sulphur aluminate cements with electrolytic manganesium residue and method of manufacturing the same |
| CN101543830B (en) * | 2009-05-05 | 2014-10-01 | 湖北声荣环保节能科技有限公司 | Comprehensive utilization method for recycling manganese oxide slag |
| CN102206052A (en) * | 2010-03-30 | 2011-10-05 | 贵州省建筑材料科学研究设计院 | Method for cement production utilizing electrolytic manganese slag as cement mineralizer |
| CN101811737A (en) * | 2010-04-19 | 2010-08-25 | 湘西自治州矿产与新材料技术创新服务中心 | Method for preparing manganese sulfate from sulfur-containing waste residue |
| CN102491423A (en) * | 2011-12-01 | 2012-06-13 | 湘西自治州矿产与新材料技术创新服务中心 | Method for preparing manganese sulfate from sulfur-containing slag |
| CN102838299A (en) * | 2012-09-12 | 2012-12-26 | 南宁市伟达科技有限公司 | Method for producing cement by electrolytic manganese residue and red mud |
| CN102923977A (en) * | 2012-11-15 | 2013-02-13 | 吉首大学 | Method capable of utilizing sulfate-free electrolytic manganese residue to prepare common silica cement |
| CN105130222A (en) * | 2015-07-21 | 2015-12-09 | 湖南省小尹无忌环境能源科技开发有限公司 | Method of preparing special sulfate cementing material through treatment on electrolytic manganese residue in fluidized bed boiler |
| CN104986974A (en) * | 2015-07-21 | 2015-10-21 | 湖南省小尹无忌环境能源科技开发有限公司 | Method for preparing ecological active residues by treating electrolytic manganese residues by virtue of rotary kiln plant |
| CN105130217A (en) * | 2015-07-21 | 2015-12-09 | 湖南省小尹无忌环境能源科技开发有限公司 | Method of producing ecological activated slag through treatment on electrolytic manganese residue in vertical kiln factory |
| CN105130217B (en) * | 2015-07-21 | 2017-06-23 | 湖南省小尹无忌环境能源科技开发有限公司 | The method that electrolytic manganese residues ecologic active slag is managed with shaft kiln factory and office |
| CN105060741A (en) * | 2015-07-24 | 2015-11-18 | 湖南省小尹无忌环境能源科技开发有限公司 | Method for preparing ecological active residues by treating electrolytic manganese residues by using tunnel kiln device |
| CN110183120A (en) * | 2019-05-13 | 2019-08-30 | 中冶武汉冶金建筑研究院有限公司 | Utilize the method for original state electrolytic manganese residues and steel slag tailing slurry production activity of cement admixture |
| CN110183120B (en) * | 2019-05-13 | 2021-08-17 | 中冶武汉冶金建筑研究院有限公司 | Method for producing cement active admixture by using undisturbed electrolytic manganese slag and steel slag tail mud |
| CN110723917A (en) * | 2019-10-31 | 2020-01-24 | 青川天隆新材料开发有限责任公司 | Resource utilization method of electrolytic manganese slag |
| CN110642543A (en) * | 2019-11-21 | 2020-01-03 | 石晶 | Alkaline cementing material produced by electrolytic manganese slag |
| CN111689755A (en) * | 2020-05-26 | 2020-09-22 | 华南理工大学 | Method for preparing composite modified magnesium oxysulfate cementing material by utilizing electrolytic manganese slag |
| CN112358210A (en) * | 2020-11-22 | 2021-02-12 | 贵州大学 | Preparation method of electrolytic manganese slag-barium slag cement |
| CN113105202A (en) * | 2021-04-15 | 2021-07-13 | 武汉中科固废资源产业技术研究院有限公司 | Full-solid waste material and preparation method and application thereof |
| CN113105202B (en) * | 2021-04-15 | 2022-07-12 | 武汉中科固废资源产业技术研究院有限公司 | Full-solid waste material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100545116C (en) | 2009-09-30 |
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Granted publication date: 20090930 Termination date: 20100307 |