CN1824884A - Self-cleaning suiting containing nano-functional material and method for making garment products - Google Patents
Self-cleaning suiting containing nano-functional material and method for making garment products Download PDFInfo
- Publication number
- CN1824884A CN1824884A CN 200510011359 CN200510011359A CN1824884A CN 1824884 A CN1824884 A CN 1824884A CN 200510011359 CN200510011359 CN 200510011359 CN 200510011359 A CN200510011359 A CN 200510011359A CN 1824884 A CN1824884 A CN 1824884A
- Authority
- CN
- China
- Prior art keywords
- lining
- garment products
- cleaning
- low temperature
- self
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to nm functional material self-cleaning suit face fabric that adopts low temperature plasma surface process technology to take dipping or spraying process with halothane residue triethoxy silicane compound containing nm level solid particle to pure wool or wool terylene blending face fabric to make the face fabric has super water discharging and oil discharging feature to achieve the purpose of self-cleaning. The invention could make the face fabric more handsome and prolong useful life, and it also has great social and economic benefits in environment and energy saving aspects.
Description
Technical field
The invention belongs to the garment material manufacture field, relate to the self-cleaning suiting that contains nano-functional material, and with nano self-cleaning pure wool or the clothes prepared of hair bamboo/polyester blended fabric.
Background technology
Western-style clothes is as commercial affairs and regular social clothes, and is fastidious with its lining, comfortable and easy to wear, in many styles, in great social life of modern times and be subjected to people's extensive employing day by day as civilian dress.Western-style clothes adopts pure wool or hair bamboo/polyester blended fabric to make mostly, because lining is subjected to the influence of himself composition, often has more serious Electrostatic Absorption situation, makes lining easily adsorb dust impurity, and for this reason, lining needs regular washing.Be the cleaning that keeps lining, well-pressed smooth, the complicated technology of a cover washing, flatiron will be arranged.Common way is to send the washing of professional garment dry cleaning shop with western-style clothes, but so not only time-consuming but also bothersome; And the mode of washing that no matter adopts dry-cleaning or wash all will produce washing agent to the influence of environment and the significant wastage of the energy and resource.
In recent years along with the enhancing of people's environmental consciousness, and to the raising of energy savings understanding, people have constantly carried out the technical research of a large amount of relevant automatically cleaning materials.
Disclosing the window glass with self-cleaning function in the Japanese patent laid-open 9-71437 communique, is to give thin film of titanium oxide at glass surface.Disclosing the instrument cloche with self-cleaning function in the Japanese patent laid-open 9-72761 communique, also is to have utilized titanium oxide.
The Chinese patent of applying in the former work of the inventor, promptly adopt in the application number 01141502.9 the Organic fluoride finishing agent to fabric flood, coating or spraying, the performance of having given the not only hydrophobic but also oleophobic of fabric.Put down in writing among the Chinese patent publication number CN 1284525A, apparent contact angle increases monotonously with the increase of roughness factor, be that the apparent contact angle of the big more liquid of roughness on material surface is big more, therefore having used average grain diameter in this invention is nano level solia particle, because nano_scale particle has very big specific area, thereby improve roughness factor.
Summary of the invention
One of purpose of the present invention is to provide a kind of being used to prepare the automatically cleaning lining that contains nano-functional material that clothes are used, and the pure wool or the hair that especially contain nano-functional material are washed blending (described hair bamboo/polyester blended fabric generally hair content should be lower than 50%) lining.
Two of purpose of the present invention provides a kind of self-cleaning suiting (comprising the leisure western-style clothes) that contains nano-functional material.
Three of purpose of the present invention provides a kind of preparation method who contains the automatically cleaning lining of nano-functional material.
The present invention at first at wool surface structure nanoscale concaveconvex structure, increases lining microcosmic specific area greatly at first by with this dry process technology of surface modification of low temperature plasma physics and chemical modification being carried out in the lining surface.When utilizing lower temperature plasma technology to handle fabric, various active particle such as the ion that contains in the system, excited state molecule, free radical and fiber surface carry out various interactions.This is handled and can produce corrasion to fiber surface, and its reason has two kinds substantially: a kind of is the ise of the particle hits fiber surfaces such as electronics, ion in the system; Another kind is that chemism in the system is to the chemical etching of fiber surface.Be exactly that these two kinds of corrasions make the lining surface produce the nanoscale concaveconvex structure.Secondly, the present invention uses and contains fluoroalkyl triethoxysilane compound, and this compound structure is:
This compound has the triethoxysilicane groups, so the bond strength height of it and lining, does not need high-temperature cross-linking just to have fabulous water, the oil repellent refused simultaneously, and is simple to the treatment process of lining, saves the energy.
Further add the nanoscale solids particle in using simultaneously and give pure wool or hair bamboo/polyester blended fabric with high roughness factor, strengthened nanostructured, improved the nanostructured durability, thereby further improve hydrophobic, oleophobic performance, make pure wool or the hair bamboo/polyester blended fabric do not get wet, oily dirt free, have self-cleaning function.
Described lining is blending (described hair bamboo/polyester blended fabric generally hair content should the be lower than 50%) lining of pure wool or wool and terylene.
The functional self-cleaning suiting of nano material and the preparation method of garment products of containing of the present invention, this method may further comprise the steps:
(1) Low Temperature Plasma Treating lining surface treatment
With lining or garment products Low Temperature Plasma Treating, described Low Temperature Plasma Treating processing conditions is:
Low Temperature Plasma Treating electric current 1～100A; 1～50 meter/minute of cloth speed.
(2) surface dressing
Step (1) is flooded with lining after the Low Temperature Plasma Treating or garment products or spray with containing fluoroalkyl triethoxysilane compound working solution;
A) described dip finishing condition is:
Working solution: the ethanolic solution that contains fluoroalkyl triethoxysilane compound that contains 0.1wt%～3wt% nanoscale solids particle and 0.01wt%～3wt%; Surplus is an ethanol.
Bath raio: 1: 10～1: 60;
Pad technology: pad 15～60 ℃ of temperature, pad 0.1～2 minute time, mangle, pick-up rate is lining to be dried in 70～90% o'clock; Or
Exhaust technology: exhaust 15～60 ℃ of temperature, 10～40 minutes exhaustion time, liquid carrying rate is lining or goods to be dried in 50～120% o'clock;
Drying operation: 40～90 ℃ of bake out temperatures, 5～30 minutes preliminary drying time; Make lining or garment products bone dry.
Or b) described spraying finishing condition is:
Working solution: the ethanolic solution that contains fluoroalkyl triethoxysilane compound that contains 0.1wt%～3wt% nanoscale solids particle and 0.01wt%～3wt%; Surplus is an ethanol.
Spray art: under the room temperature (as 25 ℃) lining or garment products are sprayed, then lining or garment products are carried out preliminary drying, 40～70 ℃ of preliminary drying temperature, 5～30 minutes preliminary drying time; Make lining or garment products bone dry.
The described fluoroalkyl triethoxysilane compound structure that contains is:
Wherein n is 2,4,8,10,12.
Described nanoscale solids particle is selected from silica that particle diameter is 1～100nm, silicon nitride, hydrotalcite, titanium oxide, zinc oxide or the mixture etc. of arbitrary proportion between them.The total use amount of mixing inorganic solid particles when using remains unchanged.Nanoscale solids particle with bigger serface plays the effect that improves roughness factor, thereby water and the contact angle of wet goods liquid on material surface are further increased.
The present invention is by adopting the low temperature plasma process for treating surface, and the fluoroalkyl triethoxysilane compound that contains that will contain the nanoscale solids particle is handled with dipping or spray method pure wool or hair bamboo/polyester blended fabric, make the lining after the processing have the character of super-hydrophobic oleophobic, neither get wet and oily dirt free, thereby reach the automatically cleaning purpose.This nano self-cleaning technology not only makes pure wool or hair bamboo/polyester blended fabric and garment products is more attractive in appearance, increase service life, and has significant social and economic benefit in environmental protection, aspect energy-conservation.
The specific embodiment
Embodiment 1: the pure wool lining pad processing
With the pure wool lining, after carrying out the low temperature plasma surface treatment under 15 meters/minute of treated electric current 10A, the cloth speed, put into working solution, its working solution consist of average grain diameter 30nm titanium oxide 0.5wt%, contain fluoroalkyl triethoxysilane compound (wherein n=2) 1wt% ethanolic solution; bath raio was 1: 60; 20 ℃ of dippings 1 minute, mangle then, making pick-up rate is 80%; put baking oven into; 50 ℃ of preliminary dryings 10 minutes, continue to cure 1.5 minutes at 80 ℃, obtain nano self-cleaning pure wool lining.This lining (100% pure Australia hair) is used to make western-style clothes.
Embodiment 2: the hair terylene fabric pad processing
With hair terylene fabric (60% Australia's hair, 40% terylen), after carrying out the low temperature plasma surface treatment under 15 meters/minute of treated electric current 10A, the cloth speed, put into working solution, it consists of the silica 0.2wt% of average grain diameter 30nm, contain fluoroalkyl triethoxysilane compound (wherein n=6) 1.2%; bath raio is 1: 60; at 20 ℃ of dippings 1 minute, mangle then, making pick-up rate is 80%; put baking oven into; 50 ℃ of preliminary dryings 10 minutes, continue to cure 1.5 minutes, obtain nano self-cleaning hair terylene fabric at 70 ℃.
Embodiment 3: the spraying of pure wool lining is handled
With Australia's hair side material at room temperature, after carrying out the low temperature plasma surface treatment under 10 meters/minute of treated electric current 20A, the cloth speed, use working solution, it consists of the zinc oxide 1.5wt% of average grain diameter 50nm, the fabric of the ethanolic solution that contains fluoroalkyl triethoxysilane compound (wherein n=8) 2wt% after to above-mentioned air low temperature Cement Composite Treated by Plasma sprayed, and puts baking oven then into, 40 ℃ of preliminary dryings 10 minutes, continuation was cured 1 minute at 80 ℃, obtained nanometer Australia hair automatically cleaning lining.
Embodiment 4: the spraying of pure wool western-style clothes is handled
With Australia's pure wool western-style clothes at room temperature, after carrying out the low temperature plasma surface treatment under 10 meters/minute of treated electric current 20A, the cloth speed, use working solution, it consists of the hydrotalcite 1.5wt% of average grain diameter 30nm, the western-style clothes of the ethanolic solution that contains fluoroalkyl triethoxysilane compound (wherein n=10) 2wt% after to above-mentioned air low temperature Cement Composite Treated by Plasma sprayed, and puts baking oven then into, 40 ℃ of preliminary dryings 10 minutes, continuation was cured 1 minute at 80 ℃, obtained nanometer pure wool western-style clothes automatically cleaning lining.
Claims (7)
1. preparation method who contains the self-cleaning suiting and the garment products of nano-functional material, it is characterized in that: this method may further comprise the steps:
(1) Low Temperature Plasma Treating lining surface modification
With lining or garment products Low Temperature Plasma Treating, Low Temperature Plasma Treating electric current 1～100A; 1～50 meter/minute of cloth speed;
(2) surface dressing
Step (1) is flooded with lining after the Low Temperature Plasma Treating or garment products or sprayed;
A) described dip finishing condition is:
Working solution: contain the ethanolic solution that contains fluoroalkyl triethoxysilane compound of 0.1wt%～3wt% nanoscale solids particle and 0.01wt%～3wt%, surplus is an ethanol;
Bath raio: 1: 10～1: 60;
Pad technology: pad 15～60 ℃ of temperature, carry out mangle after padding, pick-up rate is lining to be dried in 70～90% o'clock; Or
Exhaust technology: exhausting 15～60 ℃ of temperature, is lining or goods to be dried in 50～120% o'clock at liquid carrying rate;
Drying operation: 40～70 ℃ of bake out temperatures make lining or garment products bone dry; Or b) described spraying finishing condition is:
Working solution: contain the ethanolic solution that contains fluoroalkyl triethoxysilane compound of 0.1wt%～3wt% nanoscale solids particle and 0.01wt%～3wt%, surplus is an ethanol;
Spray art: under the room temperature lining or garment products are sprayed, then lining or garment products are carried out preliminary drying, 40～70 ℃ of preliminary drying temperature make lining or garment products bone dry;
Described nanoscale solids particle is selected from silica that particle diameter is 1～100nm, silicon nitride, hydrotalcite, titanium oxide, zinc oxide or the mixture of arbitrary proportion between them.
2. method according to claim 1 is characterized in that: the described fluoroalkyl triethoxysilane compound structure that contains is:
Wherein n is 2,4,8,10,12.
3. method according to claim 1 is characterized in that: described padding 0.1～2 minute time.
4. method according to claim 1 is characterized in that: 10～40 minutes described exhaustion time.
5. method according to claim 1 is characterized in that: 5～30 minutes described preliminary drying time.
6. method according to claim 1 is characterized in that: described lining or garment products are the blended yarn woven fabric or the garment products of pure wool or wool and terylene.
7. method according to claim 6 is characterized in that: the hair content of the blended yarn woven fabric of described wool and terylene or garment products is not less than 50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510011359 CN1824884A (en) | 2005-02-25 | 2005-02-25 | Self-cleaning suiting containing nano-functional material and method for making garment products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510011359 CN1824884A (en) | 2005-02-25 | 2005-02-25 | Self-cleaning suiting containing nano-functional material and method for making garment products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1824884A true CN1824884A (en) | 2006-08-30 |
Family
ID=36935705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510011359 Pending CN1824884A (en) | 2005-02-25 | 2005-02-25 | Self-cleaning suiting containing nano-functional material and method for making garment products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1824884A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102080313A (en) * | 2010-12-08 | 2011-06-01 | 中原工学院 | Pipelined clothes atomization post-treatment device applicable to nano after-finishing |
| CN102230279A (en) * | 2011-05-11 | 2011-11-02 | 武汉纺织大学 | Method for preparing single-side non-ironing textile |
| CN101532240B (en) * | 2008-12-19 | 2012-05-09 | 东华大学 | Method for modifying nanometer sol Vectran fiber by plasma treatment |
| CN103266393A (en) * | 2013-05-14 | 2013-08-28 | 东华大学 | Preparation method for water-repellent oil-repellent flame-retardant protective suit fabric |
| CN103388512A (en) * | 2013-07-02 | 2013-11-13 | 武汉纺织大学 | Fiber product having adsorption and self-cleaning functions on exhaust gas of diesel engine |
| CN103462267A (en) * | 2013-08-21 | 2013-12-25 | 东华大学 | Preparation method of underground worker protecting suit fabric |
| CN103478910A (en) * | 2013-08-21 | 2014-01-01 | 昆山铁牛衬衫厂 | Easy-to-clean shirt |
| CN104088146A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Preparation method of waterproof and snow-proof wool fabric |
| CN104088145A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Preparation method of waterproof woolen fabric |
| CN104088148A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Surface-modified functional yak hair/wool fabric |
| CN104088147A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Functional woolen fabric with super-hydrophobicity |
| CN104088144A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Novel waterproof yak hair/wool fabric |
| CN104099783A (en) * | 2014-07-13 | 2014-10-15 | 成都市绿科华通科技有限公司 | Preparation method of super-hydrophobic modified yak hair |
| CN106120339A (en) * | 2016-07-06 | 2016-11-16 | 烟台大学 | A kind of air and oil have the fabric of ultra-hydrophobicity and preparation method and purposes |
| CN103388512B (en) * | 2013-07-02 | 2016-11-30 | 武汉纺织大学 | A kind of have absorption and the fibre of self-cleaning function to diesel engine vent gas |
| WO2022028412A1 (en) | 2020-08-03 | 2022-02-10 | 江苏菲沃泰纳米科技股份有限公司 | Hydrophobic and oleophobic coating, preparation method therefor, and product |
-
2005
- 2005-02-25 CN CN 200510011359 patent/CN1824884A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101532240B (en) * | 2008-12-19 | 2012-05-09 | 东华大学 | Method for modifying nanometer sol Vectran fiber by plasma treatment |
| CN102080313B (en) * | 2010-12-08 | 2012-09-05 | 中原工学院 | Pipelined clothes atomization post-treatment device applicable to nano after-finishing |
| CN102080313A (en) * | 2010-12-08 | 2011-06-01 | 中原工学院 | Pipelined clothes atomization post-treatment device applicable to nano after-finishing |
| CN102230279A (en) * | 2011-05-11 | 2011-11-02 | 武汉纺织大学 | Method for preparing single-side non-ironing textile |
| CN103266393B (en) * | 2013-05-14 | 2015-05-13 | 东华大学 | Preparation method for water-repellent oil-repellent flame-retardant protective suit fabric |
| CN103266393A (en) * | 2013-05-14 | 2013-08-28 | 东华大学 | Preparation method for water-repellent oil-repellent flame-retardant protective suit fabric |
| CN103388512A (en) * | 2013-07-02 | 2013-11-13 | 武汉纺织大学 | Fiber product having adsorption and self-cleaning functions on exhaust gas of diesel engine |
| CN103388512B (en) * | 2013-07-02 | 2016-11-30 | 武汉纺织大学 | A kind of have absorption and the fibre of self-cleaning function to diesel engine vent gas |
| CN103462267A (en) * | 2013-08-21 | 2013-12-25 | 东华大学 | Preparation method of underground worker protecting suit fabric |
| CN103478910A (en) * | 2013-08-21 | 2014-01-01 | 昆山铁牛衬衫厂 | Easy-to-clean shirt |
| CN103462267B (en) * | 2013-08-21 | 2015-09-30 | 东华大学 | A kind of preparation method of underground labour's protective garment fabric |
| CN104088146A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Preparation method of waterproof and snow-proof wool fabric |
| CN104088144A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Novel waterproof yak hair/wool fabric |
| CN104099783A (en) * | 2014-07-13 | 2014-10-15 | 成都市绿科华通科技有限公司 | Preparation method of super-hydrophobic modified yak hair |
| CN104088147A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Functional woolen fabric with super-hydrophobicity |
| CN104088148A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Surface-modified functional yak hair/wool fabric |
| CN104088145A (en) * | 2014-07-13 | 2014-10-08 | 成都市绿科华通科技有限公司 | Preparation method of waterproof woolen fabric |
| CN106120339A (en) * | 2016-07-06 | 2016-11-16 | 烟台大学 | A kind of air and oil have the fabric of ultra-hydrophobicity and preparation method and purposes |
| WO2022028412A1 (en) | 2020-08-03 | 2022-02-10 | 江苏菲沃泰纳米科技股份有限公司 | Hydrophobic and oleophobic coating, preparation method therefor, and product |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1824884A (en) | Self-cleaning suiting containing nano-functional material and method for making garment products | |
| CN1854384A (en) | Production of feather dress fabric with self-cleaning function | |
| CN101397754B (en) | Method for preparing floride-free super-hydrophobic cotton fabric | |
| US20110223823A1 (en) | Superhydrophilic wool fabric with wash fastness and nano-finishing method for preparing the same | |
| Khan et al. | Development of UV protective, superhydrophobic and antibacterial textiles using ZnO and TiO 2 nanoparticles | |
| CN105563577B (en) | A kind of method for improving wood surface super-hydrophobic film mechanical stability | |
| CN102021819B (en) | Fluorine-free superhydrophobic finishing agent containing modified nano silicon dioxide hydrosol and application thereof | |
| CN107326651B (en) | Multi-functional super-hydrophobic textile finishing agent, preparation method and application | |
| CN102587129B (en) | Preparation method of bionic super-hydrophobic antifouling dacron textile | |
| CN102321974B (en) | Preparation method of superhydrophobic ultraviolet resistant textile | |
| CN101768854A (en) | Freon-free super hydrophobic UV resistant cotton fabric and method for preparing same | |
| EP1475426A1 (en) | Process for the production of removable soil- and water-resistant surface coatings | |
| CN108587381B (en) | Processing technology of UV-cured fluorine-containing wear-resistant hydrophobic coating | |
| CN106397894A (en) | Preparation method of butyronitrile gloves | |
| CN101225599B (en) | Hydrophilised nano finishing method for surface of keratin porous material fabric | |
| CN1193130C (en) | Finishing process for nano three-protective dacron fabrics | |
| CN101074524A (en) | Production of non-woven cotton cloth with coating function finishing | |
| CN1277019C (en) | Nano self cleaning silk broadcloth and products | |
| Lv et al. | Robust, infrared-reflective, superhydrophobic and breathable coatings on polyester fabrics | |
| Memon et al. | Study of wrinkle resistant, breathable, anti-UV nanocoated woven polyester fabric | |
| CN101250596A (en) | Preparation method of self-cleaning leather or product containing nano functional material | |
| CN1410623A (en) | Treatment method of fabric possessing ultra biphilic/ultra biphobic composite functions at same time | |
| TWI287059B (en) | A manufacturing method of water repellent textiles manufactured from a metallic oxide colloidal solution | |
| CN1710179A (en) | Nano antifouling antiultravoilet coated fabric and garment, and its processing method | |
| JP5506265B2 (en) | Textile treatment agent, antibacterial and antifungal fiber product manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |