CN1821114A - Process for preparing composite floculating agent of aluminium sulfate and slaked lime - Google Patents

Process for preparing composite floculating agent of aluminium sulfate and slaked lime Download PDF

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Publication number
CN1821114A
CN1821114A CN 200610055189 CN200610055189A CN1821114A CN 1821114 A CN1821114 A CN 1821114A CN 200610055189 CN200610055189 CN 200610055189 CN 200610055189 A CN200610055189 A CN 200610055189A CN 1821114 A CN1821114 A CN 1821114A
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China
Prior art keywords
polyacrylamide
tai
ace
white lime
charged ion
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CN 200610055189
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Chinese (zh)
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陈扬明
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Lvye Environment Protection Science And Technology Development Co Ltd Nanpin
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Lvye Environment Protection Science And Technology Development Co Ltd Nanpin
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Priority to CN 200610055189 priority Critical patent/CN1821114A/en
Publication of CN1821114A publication Critical patent/CN1821114A/en
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Abstract

The present invention discloses the preparation process of composite flocculant of aluminum sulfate and slaked lime, and belongs to the field of water treating technology in environment protection. The composite flocculant is prepared with aluminum sulfate, slaked lime polyacrylamide and vanadium oxide and through mixing, and may have active carbon added for eliminate high chroma in sewage. The composite flocculant can deposit various kinds of pollutant for separation, and test shows that the composite flocculant has CODcr and BOD5 eliminating rate over 60%, and suspended matter and chroma eliminating rate over 90%.

Description

The preparation method of composite flocculation agent such as Tai-Ace S 150, white lime
Technical field
The present invention relates to the processing of the water pollution in the environmental protection, a kind of specifically neutrality, nontoxic, the preparation method of composite flocculation agent such as Tai-Ace S 150, white lime fast and efficiently.
Background technology
" Agenda 21 " that United Nations Conference on Environment and Development is passed through, this common strategy of proposition human kind sustainable development.In this strategy; environment protection is the basic substance that embodies Sustainable development; and the protection water resources; administering the water pollution is the important step of protection environment, the fast development of industrial economy, the waste water that industrial and mining enterprises discharged; the muddy water that the civil construction engineering is produced; and institute's sewage effluent in the human daily life, oneself constantly derives, to cause " environmental hazard problem " because of dealing with improperly.Both made will reach emission standard and also waste time and energy, gigantic project, cost of investment is too high, and does not reach pre-its effect or the like.Greatly develop Water Treatment Chemicals to water saving, administer sewage and play an important role.Water conditioner is a process water, domestic water, in the wastewater treatment process the chemical agent that must use.Use through these chemical agents makes water reach certain mass and asks, thus the purpose that reaches discharging or utilize again.The main effect of water treatment agent is the control incrustation scale, and the formation of dirt reduces foam, reduces the corrosion with the water contact material, removes the suspended solids and the toxic substance that anhydrate and be, deodorization and discoloration, softening and stabilizing water quality etc.Therefore water treatment agent comprises flocculation agent (flocculation agent), Scale inhibitors, inhibiter, dispersion agent, deodorant, prefilming agent, defoamer, discoloring agent, sequestrant, oxygen scavenger, sterilizing agent and ion exchange resin or the like.
At present, water conditioner mainly contains following several both at home and abroad:
A, the agent of circulation cooling process mainly comprise inhibiter, Scale inhibitors, sterilant and supporting prefilming agent, the agent that disappears clearly, sterilizing agent and defoamer etc.
B, Biocidal algae-killing agent-process water sterilant, present China's only liquid chlorine of usefulness that puts into production, minority kinds such as quaternary ammonium salt, and developed machine sulphur season phosphonium salt abroad in recent years, fosthiazate etc.
C, in recent years, China develops aspect inorganic flocculating agent (agglutinant) rapidly, but it is single to show kind aspect organic polymer coargulator, except that polyacrylamide (PAM), have only sodium polyacrylate and a small amount of polyamine, the seriation level of polyacrylamide is very low.
Flocculation sedimentation is a kind of not only economy but also easy water conditioning method that generally is used for improving water treatment efficiency at present abroad, in natural water and waste water, there are some colloidal solids usually, also usually be with a little natural and made all cpds, or make the water muddiness, or make water band look.People usually will be to muddiness, and the water body of band look carries out purifying treatment, thus the R and D of beginning coagulation technology.When some pharmaceutical chemicalss drop in the water body of desire processing, because coagulation can make the compound formation fine particle that is dissolved in the water, that is " breakdown of emulsion ", or be not dissolved in the micelle surface modification of water, mainly destroyed the balance of electrostatic repulsion and Van der Waals force, thereby micelle is taken off surely, and this class chemical agent is commonly referred to as flocculation agent, condensing agent.Becoming larger particle and can make from the micelle adhesion, also is to put up a bridge between micelle and volume is swept the medicament of effect, and custom is called flocculant.Yet present chemical processing agent ubiquity complex process processing speed is slow, the problem that cost high is.
Show from the pertinent data retrieval that comprises Chinese patent, have the report of 9 relevant water treatment flocculants at present in the Chinese patent, as: CN98118051.5 " composite flocculant for water treatment "; CN02138937.3 " a kind of method and its equipment for preparing flocculation agent "; CN200510018852.4 " environment friendly water treatment flocculant and blending process " or the like.From existing technical Analysis, the use active calcium oxide and the polymer alumina that have are composited; Have plenty of the use that combines with electrolytic process of conventional flocculation agent; What have adds aluminium salt, silicate or the like in alkaline solution under the ultrasonic wave effect.Do not find at present the relevant report of the flocculation agent of compound preparations such as using Tai-Ace S 150, white lime as yet.
Summary of the invention
In order to overcome the complex process of existing chemical treatment flocculation agent technology, the cost height, processing speed waits a series of problems slowly, the objective of the invention is to provide a kind of cost low, neutral, nontoxic, the preparation method of composite flocculation agent such as Tai-Ace S 150, white lime fast and efficiently.
The technical solution adopted for the present invention to solve the technical problems is: the preparation method of composite flocculation agent such as a kind of novel Tai-Ace S 150, white lime is characterized in that:
Prescription: Tai-Ace S 150 (AS) 60~45%, white lime (CaOH) 43~25%, polyacrylamide (PAM) positively charged ion 6~3%, polyacrylamide (PAM) negatively charged ion 3~6%; Vanadium oxide (V 2O 5) 3~6%.Wherein under the state of high chroma sewage, can add gac (C) 3~5%.
Described Aluminium Sulphate usp (powder) is: 90~120 orders; Described white lime is: 100~200 orders; Described polyacrylamide positively charged ion or negatively charged ion are: crystalline particles; Described vanadium oxide is a catalyzer, and it is shaped as: powder; Described gac is: powder.
Technological process:
A, with Tai-Ace S 150 and white lime uniform mixing, wait to rise again to room temperature through reaction heating;
B, add vanadium oxide catalyst again after polyacrylamide positively charged ion and polyacrylamide negatively charged ion mixed and mix;
C, the mixture of Tai-Ace S 150 and white lime in the A technology and the polyacrylamide in the B technology and vanadium oxide mixture remix is even is flocculation agent of the present invention.
D, when sewage is high chroma, in the B process mixture, can add gac again, mix as the usefulness of further removing look.
Product after the present invention's preparation can be widely used in the processing of various sewage, and the process of its processing is:
To detention tank dispensing (flocculation agent of the present invention), upper strata to emissions adjustment pond is to discharging behind settling tank again, and lower floor discharges to the thickened sludge retention basin to water extracter and utilizes.
The invention has the beneficial effects as follows: because the present invention is that a kind of novel flocculation agent is different with existing flocculation agent (agglutinant), better absorption is taken off surely and volume is swept precipitating action because Tai-Ace S 150 has, and is acid; Lime has strong absorption and decolorization, is alkalescence; Polyacrylamide has intensive absorption and charge neutralization to charged colloid in the water body, and non-polar group, has certain hydrophobic interaction, obviously changes the cross section state and the surface energy of colloidal grain surface; Improve colloidal and take off steady ability and settleability, and also have the intensive germicidal action.Long-pending above each the medicament advantage of medicament of the present invention, through by scientific process, under catalyst action, synergy is arranged, play synergistic effect, make this medicament that electrical neutralization, absorption bridge linking effect not only be arranged, and have intermolecular winding package action, make floc particle thick rapidly, also can bring into play the filtrating aid function that dewaters preferably at short notice the mud of different properties, different degree of spoilage.So composite flocculation agent of the present invention, to all types of sewage can both in 2~10 minutes throwing out take place, thereby can make and save land seizure area and capital construction cost in the sewage treatment project, and in enterprise's dirt (giving up) water treatment operation process, operation cost still is lower than the operation cost on the traditional technology.Meet the requirement of recycling economy and economizing economy, reach the save land effect of material-saving of energy-saving and water-saving.The present invention a kind ofly can carry out various types of dirty materials disposable settlement separate with a kind of flocculation agent under various conditions.Analytical test result through relevant departments utilizes the sewage chemical CODcr of product treatment of the present invention can remove more than 60% biochemical BOD 5Can remove more than 60%, suspended substance (SS) can be removed more than 90%, and colourity can be removed more than 90%.Therefore, the present invention is a high efficiency novel flocculant very advanced in a kind of sewage disposal medicament.
Embodiment
Embodiment 1:
Get 50 kilograms in 100 order Tai-Ace S 150 (AS), 35 kilograms of 200 order white limes (CaOH), 5 kilograms of polyacrylamide (PAM) positively charged ions, 5 kilograms of polyacrylamide (PAM) negatively charged ion; Vanadium oxide (V 2O 5) 5 kilograms.
A, with Tai-Ace S 150 and white lime uniform mixing, wait to rise again to room temperature through reaction heating;
B, add vanadium oxide catalyst again after polyacrylamide positively charged ion and polyacrylamide negatively charged ion mixed and mix;
C, the mixture of Tai-Ace S 150 and white lime in the A technology and the polyacrylamide in the B technology and vanadium oxide mixture remix is even is 100 kilograms of the present invention's flocculation agent.
Embodiment 2:
Get 55 kilograms in 110 order Tai-Ace S 150 (AS), get 30 kilograms of 210 order white limes (CaOH), 6 kilograms of polyacrylamide (PAM) positively charged ions, 6 kilograms of polyacrylamide (PAM) negatively charged ion; Vanadium oxide (V 2O 5) 3 kilograms.Wherein under the state of high chroma sewage, can add 3 kilograms of gacs (C).
A, with Tai-Ace S 150 and white lime uniform mixing, wait to rise again to room temperature through reaction heating;
B, add vanadium oxide catalyst again after polyacrylamide positively charged ion and polyacrylamide negatively charged ion mixed and mix;
C, the mixture of Tai-Ace S 150 and white lime in the A technology and the polyacrylamide in the B technology and vanadium oxide mixture remix is even is 100 kilograms of the present invention's flocculation agent.
D, in the B process mixture, can add 3 kilograms of gacs again, mix as the usefulness of further removing look.

Claims (7)

1, the prescription of composite flocculation agents such as a kind of Tai-Ace S 150, white lime is characterized in that:
Tai-Ace S 150 (AS) 60~45%, white lime (CaOH) 43~25%, polyacrylamide (PAM) positively charged ion 6~3%, polyacrylamide (PAM) negatively charged ion 3~6%; Vanadium oxide (V 2O 5) 3~6%.
2. prescription according to claim 1 is characterized in that under the state of high chroma sewage: can add gac (C) 3~5%.
3. prescription according to claim 1 is characterized in that: described Aluminium Sulphate usp (powder) is: 90~120 orders.
4. prescription according to claim 1 is characterized in that: described white lime is: 100~200 orders.
5. the technological process of composite flocculation agent such as a Tai-Ace S 150, white lime is characterized in that:
A, with Tai-Ace S 150 and white lime uniform mixing, wait to rise again to room temperature through reaction heating;
B, add vanadium oxide catalyst again after polyacrylamide positively charged ion and polyacrylamide negatively charged ion mixed and mix;
C, the mixture of Tai-Ace S 150 and white lime in the A technology and the polyacrylamide in the B technology and vanadium oxide mixture remix is even is flocculation agent of the present invention.
6. technological process according to claim 2 when sewage is high chroma, is characterized in that: can add gac again in the B process mixture, mix except that look.
7. the product after the present invention's preparation can be widely used in the processing of various sewage, the feature for the treatment of processes is: throw flocculation agent to detention tank, be stirred to flocculation again through rationally, solidliquid mixture is after pressure filter (water extracter) is handled, sludge part landfill or utilization again, separating liquid are that water quality up to standard can be used as recycling or discharging.
CN 200610055189 2006-02-23 2006-02-23 Process for preparing composite floculating agent of aluminium sulfate and slaked lime Pending CN1821114A (en)

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CN 200610055189 CN1821114A (en) 2006-02-23 2006-02-23 Process for preparing composite floculating agent of aluminium sulfate and slaked lime

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101618900B (en) * 2009-08-10 2011-02-09 浙江商达水务有限公司 Inorganic flocculating agent for treating waste water during carpet production
CN102356047A (en) * 2009-03-17 2012-02-15 勒瓦研究开发股份有限公司 Composition based on calcium hydroxide, method for production thereof and use of same for treating water and mud
CN103570110A (en) * 2012-07-24 2014-02-12 上海纳米技术及应用国家工程研究中心有限公司 Efficient composite absorbing and flocculating agent used for printing and dyeing waste water treatment, preparation method thereof and applications thereof
CN104355356A (en) * 2014-11-20 2015-02-18 东莞市台腾环保材料科技有限公司 Sewage treatment agent as well as preparation method and application thereof
CN105293724A (en) * 2015-11-27 2016-02-03 济南昊泽环保科技有限公司 Industrial wastewater treatment agent and preparation method thereof
CN105293603A (en) * 2015-11-30 2016-02-03 欣格瑞(山东)环境科技有限公司 Heavy metal wastewater treatment medicament and treatment method of heavy metal wastewater
CN108395138A (en) * 2018-04-08 2018-08-14 赵顺全 A kind of accelerator for cement slurry
CN112047428A (en) * 2020-07-31 2020-12-08 东营东方化学工业有限公司 Reverse demulsifier composition and method for performing reverse demulsification by using same

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102356047A (en) * 2009-03-17 2012-02-15 勒瓦研究开发股份有限公司 Composition based on calcium hydroxide, method for production thereof and use of same for treating water and mud
CN101618900B (en) * 2009-08-10 2011-02-09 浙江商达水务有限公司 Inorganic flocculating agent for treating waste water during carpet production
CN103570110A (en) * 2012-07-24 2014-02-12 上海纳米技术及应用国家工程研究中心有限公司 Efficient composite absorbing and flocculating agent used for printing and dyeing waste water treatment, preparation method thereof and applications thereof
CN103570110B (en) * 2012-07-24 2015-02-18 上海纳米技术及应用国家工程研究中心有限公司 Preparation method of efficient composite absorbing and flocculating agent used for printing and dyeing waste water treatment and applications thereof
CN104355356A (en) * 2014-11-20 2015-02-18 东莞市台腾环保材料科技有限公司 Sewage treatment agent as well as preparation method and application thereof
CN105293724A (en) * 2015-11-27 2016-02-03 济南昊泽环保科技有限公司 Industrial wastewater treatment agent and preparation method thereof
CN105293603A (en) * 2015-11-30 2016-02-03 欣格瑞(山东)环境科技有限公司 Heavy metal wastewater treatment medicament and treatment method of heavy metal wastewater
CN108395138A (en) * 2018-04-08 2018-08-14 赵顺全 A kind of accelerator for cement slurry
CN112047428A (en) * 2020-07-31 2020-12-08 东营东方化学工业有限公司 Reverse demulsifier composition and method for performing reverse demulsification by using same

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