CN1817787A - Method and device for decomposing water - Google Patents

Method and device for decomposing water Download PDF

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CN1817787A
CN1817787A CN 200510118283 CN200510118283A CN1817787A CN 1817787 A CN1817787 A CN 1817787A CN 200510118283 CN200510118283 CN 200510118283 CN 200510118283 A CN200510118283 A CN 200510118283A CN 1817787 A CN1817787 A CN 1817787A
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channel
water
chamber
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刘之政
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Abstract

Method and apparatus for decomposing water are disclosed. The process is carried out by inputting laser energy consistent with water molecule normal frequency into high-temperature and pressure water vapor through light reaction chamber to have infrared laser chemical reaction, forming water vapor in forward chemical reaction state to accelerate chemical reaction through catalytic reaction zone, adsorptive dissipative catalytic reacting by catalyst, decomposing multiple links into oxy-hydrogen molecule gas in chemical reaction, mixing oxy-hydrogen gas at high-temperature and pressure with carbon dioxide gas inputted and high-temperature nitrogen, passing supersonic speed through expansion cavity and optical resonance cavity by nozzle, converting molecular kinetic energy and potential energy in mixed gas flow into laser energy with consistent frequency, inputting it into water vapor of light reaction chamber to have infrared laser chemical reaction, decomposing energy circulating, separating mixed gas flow into hydrogen flow and oxygen flow through magnetic filed zone, inputting hydrogen and oxygen produced and carbon monoxide into pneumatic laser to produce exciting energy, outputting laser energy with consistent frequency into light reaction chamber from circulating pneumatic laser with nitrogen and left heat-energy exchanger, and infrared laser chemical reacting in water vapor to produce energy inputting device. It can produce starting, filling and adjusting energy of system, input water and produce hydrogen and oxygen, and realize total energy circulation of system.

Description

Method and apparatus for decomposing water
The invention relates to a method for decomposing water and a device thereof, which are used for preparing hydrogen and oxygen from water.
At present, various methods for decomposing water into hydrogen and oxygen, such as an electrolysis method, a thermochemical cycle hydrogen production method, a thermoelectric cycle hydrogen production method, a photochemical hydrogen production method and the like, are limited by Carnot efficiency and high temperature resistant materials, and the reaction is complex and the efficiency is low, so that the practical purpose is difficult to achieve. According to published data, various thermochemical cycle hydrogen production and thermoelectric cycle hydrogen production methods of research experiments in various countries, such as steam-iron cycle hydrogen production, cesium-water cycle hydrogen production, lithium-water mixed hydrogen production and the like researched in the United states, have the common characteristics that thermal energy required by matching thermochemical cycle reaction is required, and a plurality of factors such as equipment corrosion and environmental pollution limit development and application. The high-temperature electrolysis thermoelectric cycle hydrogen production needs surplus electric energy. The solar energy hydrogen production is limited by climate and geographical conditions, and the investment is very large, so that the popularization and the application are difficult.
A new method for decomposing water is sought in physicochemical and photochemical theories, a large amount of water can be decomposed into atomic gas within the range of 1000 ℃, oxyhydrogen gas reconstructed into bonds can be separated, and the bond-forming heat energy released when the atoms form bonds into hydrogen and oxygen molecules can be recycled, so that the energy of substances produced by a system device is larger than the energy input into the system through energy conversion and heat energy circulation in the system. At present, no method and device for energy conversion and bond-forming heat energy recycling in the processes of decomposition, separation and chemical bond forming exist in the world.
The invention aims to exchange heat energy between a heat absorbing material flow and a heat releasing material flow by utilizing a reversible chemical reaction process of water molecules. Laser energy consistent with the simple vibration frequency of water molecules is input into water vapor at 1000 ℃ to carry out infrared laser chemical reaction, the input light energy enables the chemical reaction to be in a forward reaction state, and most of the water molecules are decomposed by the decomposed mixed water vapor to be further adsorbed and dissociated in the catalytic reaction to be reconstructed into hydrogen and oxygen molecules. The hydrogen-oxygen mixed gas converts the kinetic energy and the potential energy of the hydrogen-oxygen mixed gas into laser energy through an energy conversion device, and the laser energy is input into water vapor to carry out infrared laser chemical reaction, so that energy decomposition circulation is formed. The hydrogen-oxygen mixture is separated into hydrogen gas and oxygen gas by the magnetic field region. The high-temperature airflow discharge system and the low-temperature reactant flow input system carry out heat energy exchange to form heat energy internal circulation. The produced and stored hydrogen and oxygen are input into a 'pneumatic laser', and form excitation energy together with the input gasified carbon gas, and laser energy is input into water vapor to supplement energy required by infrared laser chemical reaction through an energy transfer medium nitrogen, a heat energy exchanger and the laser to form a circulating pneumatic laser. The produced and stored hydrogen and oxygen are input into an energy input device, and a chemical reaction is combusted to generate heat energy which is used for starting energy of the system and supplementing energy in a heat energy cycle, so that the total energy cycle in the system is realized. Through the circulation of the laser energy and the heat energy converted from the heat energy in the system, the energy of the substances produced by the system is larger than the energy input into the system, and the purpose of inputting water to produce hydrogen and oxygen is achieved.
The method is realized by that 1000 ℃ water is subjected to laser chemical and catalytic chemical reactions in a light reaction chamber at the center of a system device, oxyhydrogen molecules which absorb energy and are decomposed and reconstructed into bonds release heat energy (energy conservation), high-temperature airflow is discharged outwards from a hydrogen pipe and an oxygen pipe in a channel with the center extending outwards along a plane spiral, the water is pumped into the central reaction chamber from the outside through the channel, high-temperature gas flows outwards, the heat energy is transferred to water molecules outside the tube in a heat release process, and the heat energy in the water flowing towards the center absorbing tube is an endothermic process, so that forced convection heat exchange is formed. By utilizing the natural law that decomposed atoms are inevitably synthesized into molecules and release heat energy, liquid water at room temperature is heated to high-temperature water gas to be decomposed, the high-temperature water gas is continuously heated through a water gas channel of a central structure body, enters a flow storage chamber of a pneumatic laser device and is further heated to the temperature of near 900 ℃ and flows into an energy input device to be supplemented and regulated by external input energy, the high-temperature high-pressure water gas at the temperature of 1000 ℃ flows into a central light reaction chamber, the high-temperature high-pressure water gas provides heat energy required by activated molecules in laser chemical reaction and chemical catalytic reaction, and therefore energy circulation of heat energy exchange is formed. Laser energy is input into a reaction chamber to carry out infrared laser chemical reaction and catalytic reaction to generate oxyhydrogen gas, the oxyhydrogen gas has kinetic energy and potential energy required by laser output of a pneumatic laser and is mixed with high-temperature nitrogen flowing out of the rear part of an energy converter spray pipe, the high energy levels of hydrogen and oxygen molecules collide with nitrogen molecules to transfer energy, the metastable state energy level of the nitrogen molecules stores a large amount of vibration energy, high-temperature and high-pressure gas flow enters an expansion cavity from a nozzle at supersonic speed andis mixed with the input carbon dioxide gas in a mixing region, the gas is subjected to adiabatic expansion and is cooled suddenly to generate differential relaxation, the vibration energy of the nitrogen molecules is transferred to the high energy level of the carbon dioxide molecules in collision through resonance, energy particles jumping downwards at the upper energy level are supplemented continuously, and the lower energy level, hydrogen molecules and a small amount of water molecules are subjected to deactivation reaction and are rapidly relaxed and evacuated to form particle. Therefore, photons are continuously emitted between an upper energy stage and a lower energy stage, optical oscillation is generated in the optical resonant cavity, laser output can be generated, 10.6 micron pulse laser is output through Q modulation, mode locking and frequency stabilization, secondary frequency doubling in the optical path is 2.65 micron laser, the secondary frequency doubling is amplified through the power of the laser amplifier, and the secondary frequency doubling is input into the optical reaction chamber from the right optical path. The stored hydrogen and oxygen produced by the system and the input carbon monoxide form excitation energy to excite the pneumatic laser on the left side of the system, output 2.65 micron giant pulse laser and input light into the light reaction chamber from the left light path. Because the light wave frequency of the input laser is consistent with the simple vibration frequency of the water molecules, the water molecules absorb the laser energy to generate infrared laser chemical reaction, and are decomposed into hydrogen and oxygen atoms which are reconstructed into bonds to be hydrogen and oxygen molecules. The input laser energy enables the laser chemical reaction balance to be in a forward reaction state, mixed water vapor with most water molecules decomposed in the water vapor passes through the catalytic reaction area, and water molecules which are not decomposed are adsorbedand dissociated in the catalytic reaction and are reconstructed into hydrogen and oxygen molecules. The oxyhydrogen mixture enters an energy converter, thereby forming a laser decomposition energy cycle. The mixed gas flow of oxygen and hydrogen passing through the optical resonant cavity passes through the magnetic field region, and oxygen molecules are paramagnetic substances, have the physical property of precession along magnetic lines of force and deflect to N magnetic poles in the flow. The hydrogen molecules, the nitrogen molecules and the carbon dioxide molecules are diamagnetic substances, have the physical property of precessing along the magnetic lines in the reverse direction, and are biased to the S magnetic pole in the flow. Oxygen gas biased to the N magnetic pole is introduced into the oxygen chamber, and the mixture gas biased to the S magnetic pole is introduced into the hydrogen chamber. Oxygen flows through the flow guider, enters the gas splitter and is split into the oxygen pipe, exchanges heat energy with water molecules input from the outside in the outer channel of the pipe, and is sucked out by the suction pump at the outlet and sent to the oxygen storage tank. The mixed gas flows through the flow guider, enters the gas splitter, is split and enters the hydrogen pipe, exchanges heat energy with water molecules input from the outside in the outer channel of the pipe, is sucked out by the suction pump at the outlet and sent to the gas separator, and is separated into hydrogen, carbon dioxide and nitrogen which are respectively sent to respective storage tanks. Pumping carbon dioxide gas and nitrogen gas into the system for cyclic utilization. The hydrogen and oxygen in the storage tank are sent to the hydrogen-oxygen fuel cell to generate electric energy. The electric energy is input into the laser amplifier and is converted into the optical energy to be input into the light reaction chamber, and the requirement of the initial energy of the infrared laser chemical reaction is met. The electric energy is also a power energy source of a water pump, an air pump and the like in the system. The hydrogen and oxygen are input into an energy input device to be used as system starting energy, supplement energy and adjust energy. Inputting a pneumatic laser as excitation energy. Thereby constituting the total energy cycle of the system. The residual energy which satisfies the energy cycle is the output energy of the system. Can output electric energy outwards, and can also output hydrogen and oxygen outwards. In unit time, when 80-45% of hydrogen and oxygen produced by the system are input back into the system to meet the requirement of total energy circulation, the system can output 20-55% of hydrogen and oxygen outwards.
Starting of the system device: water, hydrogen and oxygen in an energy input device are input from the outside, wherein heat energy generated by oxy-hydrogen combustion reaction heats liquid water to 1100 ℃ of water vapor, the water vapor and the nitrogen entering a central area are gradually heated to 900 ℃ along a generated oxy-hydrogen flow channel and discharged out of the system, so that the system obtains heat energy for storage, and the heat energy in the system is promoted to circulate. The gas dynamic laser is activated to cause the decomposition energy to circulate. The stored hydrogen and oxygen produced by the system are fed back into the system to promote total energy recycling. And (4) closing the external energy input of the reaction chamber after the energy input device, and normally operating the system. And closing the energy circulation loop and stopping the system.
The method of the present invention can also achieve the object by using a photoreaction chamber having a water vapor temperature of 900 to 1100 ℃ and a water vapor pressure of 20 to 30kgf/cm2. The laser frequency of the input light reaction chamber is 3802-3663 cm-1(laser wavelength 263-2.73um). The laser energy input was: the continuous input power of the laser is 1-5 kw/cm2. Power of laser pulse inputIs 2 to 8Mw/cm2
The device of the invention achieves the purpose as follows: the system device comprises a right heat exchanger (A), a left heat exchanger (B), a decomposition reactor (C), an energy converter (D), a hydrogen-oxygen separator (E), a pneumatic laser (F), an energy input device (G), an auxiliary system (L) and a control system component (H). (A, B, C, D, E, F, G) are respectively connected with components (middle wall body) a, (right end cover) b, (right front upper body) c, (right rear upper body) d, (gas storage chamber cover) e, (right front lower body) f, (right rear lower body) g, (gas splitter) h, (fluid director) i, (left end cover) j, (left front body) k, (left rear body) l, (ring body seat cover) m, (flow director) o, (fluid director) n, (right vacuum heat insulator) r, (left vacuum heat insulator) p, (ring vacuum heat insulator) q, (right vacuum heat insulator cover) t, (left vacuum heat insulator cover) s. Wherein q is arranged on (A, B), h is arranged in (A), o is arranged in (B), r and p are fixed on q, a ceramic foam heat insulation layer is arranged between A, B and r, p and q, and the integral body (A) is fixed on the machine base. (C, D, E, F, G) the components a, b, c, d, e, f, g, h, i, j, k, l, m and n are connected with each other to form a central structure (B), each component has a water gas channel and a nitrogen gas channel which are communicated with each other, and is a high-low temperature heat energy exchange and heat energy circulation channel, and is also a connecting component and a structural component forming each working air chamber, and is a high-temperature heat source of the system. Assembled in the whole body (A), and t and s are respectively fixed on two sides of the body (B), thereby forming a system device.
The right heat exchanger of the device is a planarspiral formed by rolling metal plates, forms a single spiral channel which can extend outwards from inside to outside and is in an annular structure. The left and right ends of the channel are welded and sealed. A plurality of internal-thread or corrugated heat-conducting metal tubes are arranged in the device, n hydrogen tubes are arranged on the left side, n oxygen tubes are arranged on the right side, and the tubes and the walls are fixed by positioning frames. The outlet at the inner end of the channel is communicated with the gas splitter, and the inlet at the outer end of the channel is communicated with the metering water pump. The inner end inlets of the hydrogen pipe and the oxygen pipe surrounded by water are respectively communicated with the hydrogen chamber and the oxygen chamber of the gas splitter, and the hydrogen chamber and the oxygen chamber at the outer outlet end are respectively communicated with the air suction pump. The outer part of the ring structure is provided with a heat insulation layer, the outer part of the layer is provided with a vacuum heat insulator, the inner side of the hollow outer layer is provided with a gold foil or aluminum foil reflection layer, and the whole ring structure is supported on the machine base. Thus constituting (A)
The left heat exchanger of the device is a planar spiral formed by rolling metal plates to form a double-spiral channel which can extend outwards freely from inside to outside and is in a ring-shaped structure, and the left end and the right end of the channel are welded and sealed. The inlet of the channel at the inner side of the double-spiral line is communicated with a bypass, and the outlet is communicated with a gas separator. The inlet of the outer channel is communicated with the metering nitrogen pump, and the outlet is communicated with the guider. The annular structure body and the right side are on the same horizontal axis, and the annular structure body and the right side are supported on the machinebase together, and have the same structure as the thermal insulation layer and the vacuum heat insulator on the right side. Thus constituting (B)
The 'decomposition reactor' of the device consists of a gas storage chamber, a light reaction chamber and a catalytic reaction chamber. The inlet of the circular air storage chamber is communicated with the outlet of the energy input device through a water gas channel a. The lower part of the gas flow port is communicated with the photoreaction chamber, and the width of the gas flow port is equal to the diameter of the section of the laser beam or the side length of a rectangle. The airflow inlet is connected with the bed seat by an arc line, and the left side and the right side are provided with laser input windows to form a light reaction chamber. And a nitrogen flow cooling channel is arranged outside the chamber wall, the inlet of the channel is communicated with the outlet of the nitrogen channel a, the outlet of the channel is communicated with the inlet of the nitrogen channel e, and the nitrogen channel e is communicated with the upper chamber of the pneumatic laser through the nitrogen channel on the outer wall of the water channel a. The air storage chamber is provided with a thermometer and a pressure gauge. The catalyst bed in the bed seat sliding chute of the catalytic reaction area can move left and right and can be replaced through the outlet of the b. The catalyst bed is internally provided with a cooling water channel, and the outlet and the inlet are communicated with the inlet and the outlet of the water channel of a in a pressing mode. Thus, the component (C) is constituted.
The energy converter of the device consists of array spray pipes, an optical resonant cavity and an optical path. The nozzle body is provided with a nitrogen channel communicated with the nitrogen channel of the nozzle body g and communicated with the upper air chamber of the pneumatic laser through the nitrogen channel a. Two sides of the rear part of the nitrogen channel of the nozzle body are provided with a plurality of output holes communicated with the airflow mixing chamber. The central axis of the left and right nozzle bodies is provided with an ejector, and a carbon dioxide gas channel and a cooling water channel are arranged in the ejector. And the inlet of the carbon dioxide channel is communicated with the outlet of the carbon dioxide channel of the f, and the inlet is communicated with an external carbon dioxide metering air pump. The inlet of the cooling water channel is communicated with the outlet of the water channel of g, the inlet of the water channel of g is communicated with an external metering water pump, the outlet of the cooling water channel is communicated with the inlet of the water channel of f, and the outlet of the cooling water channel is communicated with the inlet of the water channel of a. The left and right spray pipe bodies and the ejector form a three-airflow intersection nozzle to form a nozzle, an expansion cavity and an airflow mixing area, thereby forming a single-row spray pipe. The array spray pipes are formed by n single-array spray pipes. The optical resonant cavity is composed of a, b, c and d, a Brewster window is arranged on a, a rectangular concave spherical reflector is arranged behind the window, a cooling water chamber is arranged in the optical resonant cavity, an inlet is communicated with a g water channel, and an outlet is communicated with a left magnet water channel in the a. The cooling water chamber is internally provided with a photodiode which is communicated with the resonant cavity through a small hole at the center of the mirror. And b, a rectangular plane reflector is arranged on the upper part, a spherical convex lens at the center is double-layered facing the resonant cavity, a saturated absorption medium is arranged in the middle, the spherical convex lens and the reflector at the side a form the resonant cavity, and the spherical convex lens and the frequency stabilizer are fixed on the upper part to form an output window. An electro-optical switch, a polarizer, a convex lens 1, a frequency multiplier 1 and a 90 ℃ refraction reflector 1 are arranged on a beam axis, and a 90 ℃ refraction reflector 2, a convex lens 2, a frequency multiplier 2, a convex lens 3, a laser amplifier, a convex lens 4 and an input window lens are arranged on an input beam axis of the photoreaction suffocation. This constitutes (D).
The hydrogen-oxygen separator of the device of the invention consists of a magnetic field and a fluid director: the main magnets on a are provided with cooling water channels, the inlet of the cooling water channel is communicated with the outlet of the cooling water chamber of the internal reflector a, and the outlet of the cooling water channel of the internal reflector a is communicated with the water vapor channel of a. The magnetic force lines form a magnetic flux loop from right to left. The three-layer structure of the fluid director, one layer is the flow guiding room, two layers are the front and back rooms, the three layers are the left and right rooms, the left air chamber of the flow guiding room of the first layer communicates with the left air chamber of the third layer through the front air chamber of the second layer, the right air chamber of the flow guiding room of the first layer communicates with the right air chamber of the third layer through the back air chamber of the second layer. The outside of the chamber is provided with a water-gas channel, the inlet of the chamber is communicated with the water-gas channel of h through a water-gas channel f, the outlet of the chamber is communicated with the water-gas channel of g, and the outlet of the chamber is communicated with the water-gas channel of l through a water-gas channel of a. The left side of the three layers is provided with a hydrogen chamber, the outlet of the three layers is communicated with the hydrogen chamber of the h through an f airflow channel, the right side of the three layers is provided with an oxygen chamber, and the outlet of the three layers is communicated with the oxygen chamber of the h through an f airflow channel. The guide plates of the magnetic chambers are fixed on a transverse shaft, and the transverse shaft can move left and right through an operating mechanism outside the system to finely adjust the separation position of hydrogen and oxygen. Thus, the (E) is constituted.
"gas dynamic laser" of the device of the invention: the device consists of a current collector, a combustion exciter, an array spray pipe, an optical resonant cavity, a light path and a diffuser. Placed to the left of the system. Is formed by a, j, k, l and m which are mutually connected, wherein m is a ring body seat for installing an 'energy input device', and a water-air channel inlet is communicated with water-air channel outlets of k and l. A laser delivery pipe is arranged below the ring body seat and extends from j to the light reaction chamber through a. The current collectors hermetically connected with the j, k, l and a form an upper air chamber and a lower air chamber, the upper air chamber is provided with a nitrogen inlet communicated with the nitrogen channel at the upper part of the a, and an outlet communicated with the nitrogen channel of the g through the nitrogen channel at the middle part of the a. The combustion exciter is arranged on the collector, wherein the hydrogen and oxygen nozzles in the combustion chamber are respectively communicated with an external hydrogen and oxygen metering pump through hydrogen and oxygen conveying pipes and a carbon monoxide gas nozzle in the combustion chamber through a safety valve, and are communicated with an external carbon monoxide metering pump through a carbon monoxide gas conveying pipe. An igniter is arranged in the combustion chamber. The wall of the combustion chamber is externally provided with a cooling water-gas storage chamber, the inlet of the cooling water-gas storage chamber is communicated with the water-gas flow chamber a, and the outlet of the cooling water-gas storage chamber is respectively communicated with the inlets of the water-gas channels k and l. k. The outlet of the water-gas channel is communicated with the inlet of the water-gas channel m. The nitrogen gas jet hole around the combustion chamber is communicated with the annular nitrogen gas chamber, and the inlet is communicated with the upper gas chamber. The lower air chamber has array nozzles connected to k and l, the nozzle body has cooling water flow channel, the inlet is communicated with k and the outlet is communicated with l. The array of nozzles form a nozzle and an expansion chamber. The adjacent optical resonant cavities are the same in structure as the right, the output laser enters the light reaction chamber from the left side through the delivery pipe through the light path, and the light path is provided with a laser frequency modulator consisting of a synchrotron. And the outlet of the exhaust gas flow channel is communicated with the inlet of the n gas flow channels. The outlet of the n airflow channel is communicated with the inlet of the o airflow channel. And the outlet of the gas flow channel is communicated with the output gas flow channel of the (B). (B) The outlet of the output airflow channel is communicated with an external gas separator. (B) The inlet of the input airflow channel is communicated with an external metering nitrogen pump, and the outlet is communicated with the n airflow channel through the l airflow channel and communicated with the upper air chamber through the k airflow channel, the a airflow channel, the c airflow channel, the d airflow channel, the e airflow channel and the a airflow channel. This constitutes (F). (F) And (B) are combined to form an energy cycle gas dynamic laser.
The energy input device of the device consists of a machine body, a rear burner, a rearreaction chamber, a front burner and a front reaction chamber, and is assembled on a ring body seat. A water-gas channel is formed between the water-gas pipe assembled with the ring body seat and the chamber body, the inlet of the water-gas channel is communicated with the outlet of the water-gas channel of the ring body seat, and the inlet of the water-gas channel of the ring body seat is communicated with the outlets of the k and l water-gas channels. The annular chamber body consists of a chamber body and a chamber sleeve, a cooling water chamber is arranged between the chamber body and the chamber sleeve and communicated with an external metering water pump through a water channel inlet, and a plurality of water mist nozzles are arranged around the rear reaction chamber and communicated with the cooling water chamber. The center of the rear burner is an oxygen nozzle, the periphery of the rear burner is a hydrogen nozzle, each of the rear burner is provided with a hydrogen channel and an oxygen channel which are respectively communicated with an external hydrogen metering pump and an external oxygen metering pump through safety valves, and the rear burner is connected with a chamber body to form a rear reaction chamber. The middle part of the machine body is provided with a goose egg-shaped front burner, and the two sides of the machine body are fixed on the inner wall of the chamber body by hollow wing bodies. The center of the front burner is provided with an oxygen nozzle, the periphery of the front burner is provided with a hydrogen nozzle, and oxygen and hydrogen channels are communicated with an external metering oxygen pump and a hydrogen pump through a ring body and oxygen and hydrogen channel outlets in the rear burner through safety valves. The nozzle openings of the front and the rear burners are provided with igniters and catalyst rods. The ring water-gas channel between the ring body seat and the chamber body and the tail end of the chamber body are gradually contracted to form an air flow port converged with the outlet of the front reaction chamber, and the air port is externally and gradually enlarged into an original water-gas pipe which is communicated with the air storage chamber on the right side (C) through the water-gas channel a. Thus, the (G) is constituted.
The invention adopts the method and the device as follows: when the system starts, an inlet water pump of the 'energy input device' pumps water into the rear reaction chamber to form spray mist, an inlet air pump simultaneously pumps hydrogen and oxygen into the front and rear burners, oxyhydrogen flame with the central temperature of 3000 ℃ is generated in the front and rear reaction chambers, and the thermochemical reaction formula is as follows:
the water mist is gasified into 850-950 ℃ water vapor to flow inIn the front reaction chamber, the oxyhydrogen gas flame generated by the front reaction chamber heats the water vapor to 1050-1100 ℃ and flows into the decomposition reactor, and the water vapor is discharged out of the system along the oxyhydrogen mixed gas flow channel to become room-temperature liquid water. The heat balance and the heat transfer inside the system promote the water and the nitrogen stored in the system to be gradually heated, so that the heat energy is stored inside the system. The stored liquid water is gradually heated into high-temperature water vapor which enters the middle ring water vapor channel of the (G) and passes through the gas port and the water vapor at the outlet of the front reaction chamberConverging, supplementing the pressure drop generated by water gas consumption by the inlet water pump of the step (A), and enabling the system to enter a forced convection heat exchange state. (G) Continuously inputting moderate heat energy to promote the temperature of water gas input into the central structureto be gradually increased, gradually increasing the pressure of the water gas, closing a hydrogen and oxygen input air pump and an input water pump of a rear reaction chamber when the temperature of the water gas flow passing through the (G) annular water gas channel is increased to 850-900 ℃, adjusting the energy input of a front reaction chamber, forcibly pushing the water gas entering the annular water gas channel through an air port by high-temperature high-pressure water gas flow generated by oxyhydrogen gas flame, and mixing the water gas and the oxygen gas into the annular water gas channel to be 1000 ℃ and 25kgf/cm2The temperature and pressure values are stabilized, and water vapor enters the light reaction chamber. And (D) turning off the air pump and the water pump in the step (G), starting the pneumatic laser on the left, turning on the gasified carbon gas, the hydrogen gas and the oxygen gas input into the air pump in the step (F), and generating a chemical reaction in the combustion chamber, wherein the thermochemical reaction formula is as follows:
carbon monoxide gas and oxygen gas are combusted to generate carbon dioxide molecular gas, hydrogen gas and oxygen gas are combusted to generate water molecular gas, and released heat energy forms high-temperature mixed gas at 1800-2000 ℃. The nitrogen gas heated by the heat energy stored in the system reaches 870-920 ℃, the high-temperature and high-pressure nitrogen gas in the upper gas chamber enters the combustion chamber to be mixed with high-temperature fuel gas, and the mixing ratio is as follows: n is a radical of275-85% of molecules and CO28-13% of molecule, H26-12% of O molecules. The molecules in the mixed gas flow cause the nitrogen molecules to store a large amount of vibration energy in a metastable energy level in collision. The high-temperature high-pressure air flow enters the expansion cavity through the array spray pipe nozzle at supersonic speed, and the air flow is suddenly and rapidly cooled and expanded, so that the air flowMiddle CO2The relaxation speed difference between molecular energy levels forms the particle number inversion of upper and lower energy levels, CO2Lower molecular energy level and H2The deactivation reaction of O molecule is rapidly relaxed and exhausted, CO2Upper molecular energy level and N2The molecular vibration energy is resonantly coupled to generate energy transfer, and the vibration energy is continuously transferred to CO2And on the high energy level of the molecule, energy particles jumping downwards at the upper energy level are continuously supplemented, so photons are continuously emitted between the upper energy level and the lower energy level, optical oscillation is generated in an optical resonant cavity, 10.6um wavelength rectangular beam giant pulse laser is output through Q adjustment, mode locking and frequency stabilization, an adjustable electronic energy wave emitted by a synchronous accelerator in a light path interacts with a light wave, and the 10.6um wavelength laser is frequency-modulated into 2.65um wavelength laser which is input into a light reaction chamber from the left side of the system. Because the laser light wave frequency (wavelength) is consistent with the simple vibration frequency of the water molecules, the water molecules can absorb photon energy to a decomposition energy threshold, an energy-rich molecular region with the decomposition energy threshold is formed in a window light beam input region, an infrared laser chemical reaction is generated, and the infrared laser chemical reaction is further diffused into an optical induction reaction and an optical catalytic reaction. The input of laser energy enables most water molecules in water vapor of the light reaction chamber to be decomposed and reconstructed into second bonds which are hydrogen and oxygen molecules, the hydrogen and oxygen molecules with the second bonds have the physical and chemical properties of the molecules, and the vibration frequency of the molecules is not consistent with the laser light wave frequency, so that the laser energy is not absorbed to generate decomposition. The water vapor in the positive chemical reaction state in the chemical reaction equilibrium, most decomposed mixed water vapor pass through a catalyst bed, and oxyhydrogen molecules are physically adsorbed on the catalyst and pass through a catalytic reaction zone along with the gas flow in elastic collision. The water molecules which are not decomposed are chemically adsorbed by the catalyst, so that adsorption dissociation chemical reaction is generated, and the water molecules are decomposed and reconstructed into oxyhydrogen molecules. The chemical reaction is carried out by a laser chemical reaction and a catalytic chemical reaction in a standard state delta H of 101.3kpa and 298K in a photoreaction chamberθEnthalpy of chemical reaction:
the energy reflected by the decomposition and absorption of water molecules in the light reaction chamber is equivalent to the energy releasedby the recombination of atoms into bonds and hydrogen and oxygen molecules, and the energy is conserved. Also corresponding to the actual enthalpy of the chemical reaction at high temperature and high pressure. The input of laser energy into the light reaction chamber increases the temperature of the reactant gas, which increases the kinetic and potential energy of the molecules in the gas stream. The mixed gas flow of hydrogen and oxygen passing through the catalytic reaction zone is mixed with high-temperature nitrogen input from the rear part of the spray pipe body, and the molecular collision enables the metastable state energy level of nitrogen molecules to store a large amount of vibration energy. The high-temperature high-pressure mixed airflow enters the expansion cavity from airflow ports on two sides of the ejector at supersonic speed and is mixed with the carbon dioxide gas input by the ejector, and the mixing proportion is as follows: (H)2、O2) 50-60% of molecules. (N)2、CO2) 40-50% of molecules, wherein N280-90% of molecules, CO210-20% of molecules. The airflow is rapidly cooled and expanded in the expansion cavity, energy particles between energy levels of carbon dioxide molecules relax fast and slowly to form upper and lower energy level particle number inversion, the deactivation reaction of the lower energy level with hydrogen molecules and a small amount of water molecules is evacuated, the upper energy level and the nitrogen molecule vibration energy are resonantly coupled to generate energy transfer, the vibration energy is continuously transferred to the high energy level of the carbon dioxide molecules, the energy particles which jump downwards are continuously supplemented, photons are continuously emitted between the upper energy level and the lower energy level, optical oscillation is generated in the optical resonant cavity, 10.6um wavelength laser output is generated in an output window, secondary frequency doubling is2.65um wavelength laser in an optical path after Q adjustment, mode locking and frequency stabilization, the secondary frequency doubling is amplified by a laser amplifier in the optical path, and the laser is input into the reaction. The laser amplifier is an adjustable multi-stage optical power amplifier with energy input from outside, and the small-energy laser output initially is amplified in power step by step, so that the initial laser energy input to the right side of the optical reaction chamber can be quickly reachedDesign laser energy output value in "energy converter". In the laser beam input area of the right window of the light reaction chamber, an energy-rich molecular area with a decomposition energy threshold is formed to generate an infrared laser chemical reaction, and then the infrared laser chemical reaction is diffused into a light induction reaction and a light catalytic reaction. Laser energy (Joule/cm) input to the light reaction chamber2) Satisfy the flow rate of the water gas (kg/cm)2The infrared laser chemical reaction is carried out in the time of/s), and stable laser energy circulation is formed in the light path when the energy condition required by the forward chemical reaction state is formed in the reaction equilibrium. The mixed gas flow enters a magnetic field region, oxygen molecules are paramagnetic substances, have the physical property of precession along magnetic lines, and are deflected to an N magnetic pole through the magnetic field region. The hydrogen molecules, the nitrogen molecules and the carbon dioxide molecules are diamagnetic substances and can move in the reverse direction along magnetic lines of force and deflect to the S magnetic pole through a magnetic field area. Oxygen molecules deflected to the N magnetic pole are guided into the two layers of the right oxygen asphyxia chamber, enter the right oxygen asphyxia chamber of the three layers and enter the oxygen tube in the step (A) through the oxygen channel. The mixture of hydrogen molecules, nitrogen molecules and carbon dioxide molecules deflected to the S magnetic pole is introduced into the front gas chamber of the second layer, enters the hydrogen chamber on the left of the third layer, and enters the hydrogen pipe in the step (A) through the hydrogen channel. The high temperature and high pressure gas flow enters the expansion chamber to expand adiabatically and the mixed gas flow with pressure lower than the ambient atmospheric pressure is discharged out of the system through an external air suction pump. The high-heat gas in the oxygen and hydrogen pipes is discharged outwards to transfer heat energy to water molecules outside the pipes, the high-heat gas is subjected to forced convection heat exchange with water flow pumped into the channel from the outside, the high-temperature gas flow is gradually reduced to room-temperature gas, the room-temperature gas is discharged out of the system, and the room-temperature gas is separated into hydrogen, oxygen, nitrogen, carbon dioxide and water through the gas separator and is respectively sent to respective storage tanks. And returning the nitrogen and the carbon dioxide in the storage tank to the input system for cyclic utilization. The hydrogen and oxygen in the storage tank are input into a hydrogen-oxygen fuel cell to generate electric energy and output. The hydrogen and oxygen in the storage tank are transmitted to users as fuel energy. The liquid water pumped into the channel from the outside is gradually heated to be gaseous water, and the gaseous water enters the water-gas channel of the central structure body to continuously absorb heat energy to become 850-920 ℃ and 18-22 kgf/cm2The water gas enters the gas outlet of the front reaction chamber in the step (G) to be supplemented with heat energy and is pushed through the gas port by the high-temperature high-pressure water gas flow to reach 1000 ℃ and 25kgf/cm2The water vapor enters the light reaction chamber at a stable temperature and pressure valueEnergy circulation in heat energy exchange.
The negative pressure working air flow of the expansion cavity of the left pneumatic laser enters a diffuser through a resonant cavity, is expanded into high-temperature mixed air flow slightly higher than the atmospheric pressure, and enters a left heat exchanger through an n air flow channel to be discharged out of the system. The nitrogen flows continuously absorb heat energy through nitrogen channels n, k, a, c, d and e in the central structure body, the temperature of the air flow reaching the upper air chamber is 870-920 ℃, and the pressure is 20-22 kgf/cm2. The circulation flow of the energy transfer medium nitrogen in the nitrogen channel (F, B, C, G) forms a thermal energy circulation, and the energy circulation pneumatic laser is formed.
The "auxiliary system" (L) of the device of the invention is constituted by a metering pump α1: adjusting water pressure and flow m of input system3/cm2Metering water pump α2Regulating the pressure and temp of water in reaction chamber after regulation, metering water pump α3Adjusting the temperature of the internal reflector, the main magnet, the catalyst bed and the cooling water of the ejector, and metering a hydrogen pump β1And metering oxygen pump gamma1Adjusting the post-reaction water vapor temperature after (G) and measuring the hydrogen pump β2And metering oxygen pump gamma2Adjusting the temperature of water vapor at the outlet of the reaction chamber before G, and measuring the hydrogen pump β3And metering oxygen pump gamma3: and (F) adjusting the excitation energy of the burner and the mixing ratio of water molecules. Carbon monoxide metering air pump ω: adjusting (F) the mixing ratio of carbon dioxide molecules. Metering nitrogen pump δ: adjusting the pressure and flow m of nitrogen in the system3/cm2And s. Metering a carbon dioxide gas pump epsilon: adjusting the pressure and flow m of carbon dioxide gas in the system3/cm2Getter pump η1Regulating the exhaust pressure of hydrogen pipe in the step (A) η2Regulating the exhaust pressure of the oxygen pipe in the step (A). Gas separator theta1: separating the mixed gas discharged from the hydrogen pipe in the step (A) into hydrogen, nitrogen and carbon dioxide. Theta2Separating the mixed gas discharged from the step (B) into nitrogen gas, carbon dioxide gas and water. Iota hydrogen gas tank, kappa oxygen gas tank, lambda nitrogen gas tank, mu carbon dioxide gas tank, tau carbon monoxide gas tankWater storage tank _, hydrogen-oxygen fuel cell v: and hydrogen and oxygen are converted into electric energy.
Control system (L) of the device of the invention: a computer performs information processing and program control. From inside the system (pressure gauge ρ)1、ρ2) ... giving information of gas pressure kgf/cm2. (thermometer pi)1、π2) ... given gas temperature information ℃. (metering water pump α)1、α2、α3) ... water flow information kg/cm2Gas flow information m given (gas flow meter β, γ, δ, ε, ω)3/cm2And s. (optical frequency meter.) the laser frequency information HZ/s given. Given laser input energy information kJ/cm2And the like, and performs computer information processing and control according to a programming.
The following is further described in conjunction with the drawings and examples, but the specific embodiments are not limited to the following specific description;
FIG. 1 is a block diagram of the reaction scheme of the apparatus of the present invention.
FIG. 2 is a sectional view showing the overall structure of the system of the apparatus of the present invention.
Figure 3 is a cross-sectional view of the right thermal energy exchanger a-a of the device part of the invention.
Fig. 4 is a cross-sectional view of the left heat exchanger B-B of the device component of the invention.
FIG. 5 is a schematic view of the gas splitter of FIG. 3 of the apparatus of the present invention.
FIG. 6 is a view showing a structure of a decomposition reactor which is a component of the apparatus of the present invention.
Fig. 7 is a block diagram of an energy converter of the components of the apparatus of the present invention.
FIG. 8 is an enlarged view of the array of nozzles of FIG. 7 of the apparatus of the present invention.
FIG. 9 is a schematic diagram of the hydrogen-oxygen separator of the apparatus component of the present invention.
FIG. 10 is a block diagram of an energy input device of a component of the apparatus of the present invention.
FIG. 11 is a diagram of a gas dynamic laser configuration of a component of the apparatus of the present invention.
FIG. 12 is a block diagram of the combustion actuator of FIG. 11 of the apparatus of the present invention.
FIG. 13 is a view of the internal airflow path of element a of the device of the present invention.
FIG. 14 is a schematic view of the device assistance system and control system of the present invention.
The device of the method of the invention is a central structure body which is formed by G, C, D, E, F parts and is connected with each other through a, b, c, d, e, f, g, i, j, k, l, m and n components. The outer surface is an assembly plane, the inner surface is a functional air chamber for connecting all functional components and configurations, a water gas channel, a nitrogen gas channel and a carbon dioxide gas channel which are communicated with each other are arranged in the component to form a whole body (B) to be assembled in the whole body (A), the air flow channel of the A and the air flow channel of the B are communicated with each other to form an output air flow channel and an input air flow channel, and a high-low temperature heat energy exchange and heat energy circulation channel is formed. FIG. 1 is a block diagram of a reaction flow in the system, and FIGS. 2, 3 and 4 are structural diagrams.
The component 'energy input device' (G) is positioned at the upper left of figure 2 and is a component for inputting and supplementing system starting energy, figure 10 is a structural diagram, an annular body 1 made of a high-temperature alloy material K214 is cast, a combustion chamber sleeve 2 made of an internal nested GH3170 material is arranged, a water chamber 3 is arranged between the annular body and the chamber sleeve, nozzles 4 are distributed around the combustion chamber, and the water chamber is connected with an external metering water pump α through a water inlet channel 62In communication, a burner 7 made of K214 material is arranged on the central axis of the front part of the ring body, and a burner 8 connected with the ring body by a screw 5 is arranged on the rear part of the ring body, so that a front reaction chamber 9 and a rear reaction chamber 10 are formed. The burner 7 is welded on both sides to the inner wall of the ring body by wing-shaped connecting pieces 28, the center of the burner is provided with an oxygen nozzle 11 and a hydrogen nozzle12, and the nozzle opening is provided with an igniter 13 and a catalyst rod 14. The oxygen nozzle of the burner 7 is connected with an external metering oxygen pump gamma through an oxygen channel 15 via a safety valve 2572In communication, the ambient hydrogen nozzle is connected by the hydrogen passage 16 through the safety valve 258 to the external metering hydrogen pump β2Communicated with the oxygen nozzle of the burner 8, the oxygen nozzle is communicated with an external oxygen pump gamma through an oxygen passage 17 via a safety valve 2591The surrounding hydrogen nozzles are communicated with hydrogenLine 18 passes through a safety valve 260 and an external hydrogen pump β1And (4) communication. The ring body 1 and the water-gas pipe 20 form a ring-shaped water-gas channel 21, which is contracted inwards together with the tail end of the ring body to form a gas port 22, and the gas port is expanded to form a water-gas pipe 29 which is communicated with the pipe e through the water-gas pipe a. The ring body and the water and gas pipe are assembled in a ring body seat m, the ring body seat is fixed on p by a flange disc 52, and the right side is connected with a by a screw 23. The ring seat water gas passage 25 is in communication with the outlet 211 of the water gas passage 210 of k and the outlet 213 of the water gas passage 212 of 1 via the inlet 24. The nitrogen chamber 197 on the right side of the ring body seat is communicated with the nitrogen passage 40 of the ring body seat through a nitrogen passage 30 and a nitrogen passage 40.
Hydrogen and oxygen in an external storage tank are pumped into front and rear burners, an igniter 13 ignites oxyhydrogen gas at a nozzle opening to perform combustion chemical catalytic reaction, oxyhydrogen gas flames 27 with the central temperature of 3000 ℃ are generated in front and rear reaction chambers, water in the external storage tank is simultaneously pumped into the rear reaction chamber, spray water mist is formed around the combustion chamber, the water vapor gasified to 800-850 ℃ enters the front reaction chamber, the oxyhydrogen gas flames in the front reaction chamber heat the water vapor to 1050-1100 ℃ and passes through a gas port 22 through a water gas pipe 29 to pass through a (C) middle gas storage chamber, and is discharged out of the system along a produced substance gas flow channel to become room temperature water, heat in the system is balanced and transferred, the temperature and the pressure of the stored water in the system are gradually increased, and the pressure drop generated by the flow of1Supplementing to gradually form a temperature of 800-850 ℃ and a pressure of 18-22 kgf/cm2The high-temperature high-pressure water vapor flows through the water vapor channel 21, the air port 22 and the water vapor pipe 29 to flow through the air storageA chamber. At this time, the water pump, the hydrogen pump and the oxygen pump of the rear reaction chamber are closed, the water flow of the water-gas channel 21 is pushed through the gas port 22 to enter the water-gas pipe 29 by means of high-temperature and high-pressure water gas generated by the hydrogen flame of the front reaction chamber, the input energy of the front reaction chamber is adjusted, and the water gas supplemented with the obtained heat energy is adjusted to 1000 ℃ and 25kgf/cm2The water gas with stable temperature and pressure value flows into the photoreaction chamber 37 through the water gas pipe 29 and the gas storage chamber 36 to form internal thermal energy circulation. Through the input of hydrogen and oxygen fuels, thermal energy storage (similar to clock spring energy storage) is carried out when the system is started, and the purposes of supplementing and adjusting the thermal energy of the system are achieved.
The component "decomposition reactor" (C), located at the upper right in FIG. 2, is carried outLaser chemical reaction and catalytic reaction. Fig. 6 is a structural view. The components c, d and e are cast by using a high-temperature alloy material K4002, the components c, d and e are connected by screws 32, the component a on the left is connected by screws 33, and the component b on the right is connected by screws 34. The outer surface is a mounting plane and the inner surface is configured as a gas reservoir 35, a gas flow inlet 36, a photoreaction chamber 37, and a catalyst bed holder 38. Wherein the inner wall of the light reaction chamber is coated with high-temperature reflecting material. c has a nitrogen gas channel 39 inside, d has a nitrogen gas channel 45 inside, e has a nitrogen gas channel 40 inside. The outlet 44 of the c nitrogen channel is in communication with the inlet 31 of the e nitrogen channel and the inlet is in communication with the outlet 173 of the a nitrogen channel. The outlet 43 of the d nitrogen channel is in communication with the inlet 31 of the e nitrogen channel and the inlet is in communication with the outlet 172 of the a nitrogen channel. The nitrogen passage 40 of e communicates with the upper plenum 197 of (G) via the nitrogen passage 30 of a. The photoreaction chamber is provided with a left distance reduction block 47, a right distance reduction block 48, a left laser input window 49, a right laser input window 50 and a left and right input window lens 53. The gas storage chamber is provided with a thermometer pi1Pressure gauge rho1. The catalyst bed is a matrix of interconnected mesh-shaped structure made of alloy copper tubes or aluminum tubes 54, which are cooling water channels (57), and the outside of the tubes are carrier alumina (Al) formed by alumina gel compression molding2O3)55, the surface of the calcined platinum is impregnated with platinum chloride 56, and the platinum is reduced into metal platinum through the technological processes of roasting, reduction, activation and the like. Or other methods andprocess flows are adopted to manufacture the catalyst with specificity, memorability and selectivity through experiments, and the catalyst has the function of memory selection on the spectrum and the electronic energy spectrum of the water molecule. The cooling water passage 57 of the catalyst bed has its inlet in pressure communication with the outlet 58 of the a-water passage 63 and its outlet in pressure communication with the inlet 59 of the a-water passage 64. The water passage 64 has an outlet 261 communicating with a water chamber 262. The catalyst bed can move left and right, and is connected with the elastic block 61 through the upper sealing cover plate 60 of the component b in a compression joint way, so that the catalyst bed is convenient to replace. Thereby forming a catalytic reaction zone 62 around the catalyst bed.
1000℃、25kgf/cm2High-temperature and high-pressure water vapor enters the photoreaction chamber 37 through the inlet 36 after the pressure of the gas storage chamber is equalized, and water molecules are completely radiated by laser because the width of the inlet is equal to the diameter or the side length of the cross section of the laser energy column. The wavelength of the infrared laser input from the left and right sides is 2.65um (frequency 3756 cm)-1) The light wave frequency and the simple vibration frequency of water molecules are 3756cm-1And the water molecules can resonantly absorb the infrared laser energy to reach the decomposition energy threshold, and an energy-rich molecular region with the decomposition energy threshold is formed in a section of window beam three-dimensional radiation angle. Laser energy input to the light reaction chamber: the power of laser pulse input is 2-8 MW/cm2The continuous input power of the laser is 1-5 kw/cm2And the reaction temperature of the airflow in the photoreaction chamber reaches 1250-1350 ℃. The decomposed atoms in the water vapor are reconstructed into bonds which are hydrogen and oxygen molecules, the energy absorbed by the decomposition and the energy released by the bonds are equivalent, and the energy is conserved. The water vapor at 1000 ℃ contains a large amount of activated molecules, and the infrared laser chemical reaction of the energy-rich molecule area is carried out, and the light induction reaction and the light catalytic reaction are carried out simultaneously. The laser energy decomposes most water molecules in the water vapor to form a mixed water vapor in a positive reaction state in chemical reaction equilibrium, and the mixed water vapor enters a catalytic reaction zone 62, and hydrogen and oxygen are introduced into the mixed water vaporMolecules are physically adsorbed on the catalyst, and pass through the catalytic reaction zone along with the gas flow in elastic collision, water molecules are chemically adsorbed on the catalyst, and are subjected to adsorption dissociation chemical reaction to form bonds, namely hydrogen and oxygen molecules, and pass through the catalytic reaction zone. The light reaction chamber and the catalytic reaction region decompose and reconstruct hydrogen and oxygen molecules of bonds, have the physical and chemical properties of the hydrogen and oxygen molecules, and photon energy is not absorbed by the molecules and is not decomposed because the light wave frequency is inconsistent with the vibration frequency of the hydrogen and oxygen molecules. The wall of the photoreaction chamber is normally heated by the nitrogen flow. The enthalpy in the 1000 ℃ water vapor provides the thermal energy of the activated molecules in the laser chemical reaction and the catalytic reaction, and the infrared laser energy provides the water molecule decomposition energy.
The unit "energy converter" (D) is located below the catalyst bed, fig. 7 is a block diagram and fig. 8 is a diagram of the array nozzle of fig. 7. The nozzle body 67 made of high temperature resistant alloy copper or stainless steel material has a nitrogen passage 69 therein and is fixed to f, g by screws 41. The inlet of the nitrogen channel 69 is in communication with the outlet 71 of the g in-line nitrogen channel, and the g in-line nitrogen channel 70 has an inlet in communication with the outlet 212 of the a in-line nitrogen channel 213. The rear portion of the channel 69 has a plurality of apertures 72 in communication with a gas flow mixing chamber 83. The central axis between the two spraying pipe bodies is providedAn eductor 73 of copper alloy or DZ3 material having a carbon dioxide gas passage 74 and a cooling water passage 76, the passage 74 having a plurality of spray holes 75 communicating with a gas mixing chamber 85, an inlet communicating with the outlet 77 of the carbon dioxide gas passage 78 of f, and 78 communicating with an external carbon dioxide gas metering pump ε through the inlet 79, the inlet of the cooling water passage 76 communicating with the outlet 81 of the water passage 80 in g, and the water passage 80 communicating with an external water metering pump α through the inlet 923And (4) communication. The outlet of the water passage 76 is in communication with the inlet 82 of the f water passage 68, and the outlet of the water passage 68 is in communication with the inlet 58 of the a water passage 63. The left and right nozzle bodies and the ejector are combined to form a single-row nozzle consisting of a left and right jet flow port 84, an airflow mixing chamber 83, an airflow mixing chamber 85 and an expansion cavity 86, and n nozzle bodies are combined to form an array nozzle. And the unstable optical resonant cavity 87 adjacent to the expansion cavity consists of f cavity walls, g cavity walls, a left reflector and a right output window. The left side is fixed in the a and is a rectangular concave spherical reflector 88 which is integrated with the left pneumatic laser reflector 89 in a back-to-back mode (or can be separated), a cooling water chamber 90 is arranged in the mirror body, the inlet of the cooling water chamber is communicated with the a water channel 64 through a water pipeline 91, and the outlet of the cooling water chamber is communicated with the left magnet body cooling water channel inlet 116 through a water pipeline 93. The mirror has a small hole 94 in the center that communicates with a photodiode 95. A brewster window 96 is provided in front of the mirror. The right output window is fixed on the b and is provided with a rectangular plane reflector 97, a convex spherical lens 98 arranged in an output round hole at the center of the reflector, a double layer facing the resonant cavity and a saturated absorption medium arranged in the middle. The frequency stabilizer 99, the polarizer 100, the electro-optical switch 101, the thyratron 102, the lambda/4 wave plate 103 and the high-voltage loop 104 are arranged, and therefore the Q-switching, mode-locking, frequency-stabilizing and output window is formed. The output laser light path 42 is provided with a convex lens 105, a frequency multiplier 106, a 90-degree refractor 107, a frequency multiplier 108, an optical amplifier 109, and an input window 50. Thus, an energy converter and a laser energy circulating light path are formed.
The chemical reaction in the catalytic reaction zone is carried out according to the forward chemical reaction parameters, and the reverse chemical reaction (hydrogen-oxygen combustion reaction condition) does not exist. The high-temperature high-pressure hydrogen-oxygen mixed gas flow passing through the catalytic reaction zone 62 absorbs the laser energy, the gas flow heat bath temperature is 1250-1350 ℃, and the kinetic energy is 25kgf/cm2Having an enthalpy of 1375.8 kJ/kg. Kinetic energy (molecular velocity) of molecules in air flowApparent pressure) and the potential energy of the molecule (energy quantum between molecular energy levels) can satisfy the gas dynamic laser output condition. The temperature of thenitrogen flow input from the nitrogen channel 69 through the nozzle 72 is 870-920 ℃, and the gas pressure is 25kgf/cm2And is mixed with the hydrogen-oxygen gas flow in the mixing chamber 83, and the high-energy-level hydrogen and oxygen molecules collide with the nitrogen molecules to carry out resonance energy transfer, so that the metastable energy level of the nitrogen molecules stores a large amount of vibration energy. The mixed gas flows through the jet port 84 into the expansion chamber 86 where it mixes with the gas flow in the gas flow mixing zone 85The carbon dioxide gas input from the nozzle 75 is mixed, and the mixing ratio of the gas flow is as follows: (H)2、O2) 50-60% of molecules (N)2、CO2) 40-50% of molecules; wherein N is280-90% of molecules, CO210-20% of molecules. The collision between molecules in the airflow and the vibration energy of nitrogen molecules are transferred to the high energy level of carbon dioxide molecules by resonance coupling in the collision with the carbon dioxide molecules. When the mixed gas flow passes through the jet orifice at supersonic speed, the mixed gas flow is suddenly frozen at a certain point, the vibration temperature and the translational temperature of the gas are suddenly separated, the gas is rapidly adiabatically expanded in the expansion cavity, the heat energy of the gas is rapidly changed into kinetic energy, the translational temperature of molecules is rapidly reduced, the relaxation speed of energy molecules on the molecular energy level is rapid, and the population inversion distribution of the upper energy level and the lower energy level is formed. The energetic molecules of the low energy level of the carbon dioxide molecule are rapidly relaxed and evacuated in the deactivation reaction of hydrogen molecules and a small number of water molecules due to the rapid relaxation. Energy quantum on the high energy level of carbon dioxide moleculesrelaxes slowly, energy particles of high energy level down-hopping are continuously supplemented in the collision with nitrogen molecules, so that photons are continuously emitted between the upper energy level and the lower energy level, signal gain and optical oscillation are generated in an optical resonant cavity, 10.6um wavelength pulse laser output (or continuous output) is generated in an output window of the resonant cavity, secondary frequency doubling is 2.65um wavelength laser in an optical path 42, the laser is amplified by a laser amplifier 109 and is input into the optical reaction chamber 37, infrared laser chemical reaction and catalytic chemical reaction are carried out, and laser decomposition energy circulation is formed. The energy converter is essentially a pneumatic laser, generates carbon dioxide molecules of laser output, and the excitation energy comes from the energy on the high energy level of hydrogen molecules and oxygen molecules, and is transmitted to the nitrogen molecules through collision, and the nitrogen molecules transmit energy to the carbon dioxide molecules, so that the purpose of achieving the purpose of generating the carbon dioxide gas is achievedThe kinetic energy and potential energy of molecules in the air flow are converted into laser energy.
The component 'oxyhydrogen separator' (E) is positioned below the optical resonant cavity and is used for separating oxyhydrogen molecules in the mixed gas flow. FIG. 9 is a block diagram: the left main magnet 111, the right main magnet 112 and the auxiliary magnet 113 made of Fe-Co series high temperature alloy permanent magnetic material form a magnetic field region 114, the left main magnet is fixed on a, a cooling water gas channel 115 is arranged around the left main magnet, an inlet 116 is communicated with an outlet of the reflector cooling water chamber 90 through a water gas pipe 93, and an outlet 117 is communicated with an inner water gas channel 263 of a. Inside b is provided a right main magnet 112. A plurality of auxiliary magnets 113 are arranged between the left and right main magnets and assembled on the f and g to form a magnetic flux loop with opposite polarities repelling to the left and the right. The upper end of the secondary magnet is provided with a shunting nozzle 118 made of non-magnetic material copper. The fluid director i made of the high-temperature alloy material K419 is fixed on f and g by screws 120. And each independent magnetic chamber 122 is formed between the auxiliary magnet and the upper plane of the fluid director by a partition plate 121, and a guide plate 123 in each magnetic chamber is fixed on a shaft 124 capable of moving left and right, so that the separation position of hydrogen and oxygen is finely adjusted through the outside. The flow director consists of three layers of air chambers, and each air chamber is provided with a water-air channel 136. The guide plate forms a left guide chamber and a right guide chamber, one layer is the left guide chamber and the right guide chamber of each magnetic chamber, the second layer is the front air chamber and the rear air chamber of the fluid director, and the third layer is the left air chamber and the right air chamber of the fluid director. The left guide chamber 129 of the first layer and the front air chamber 131 of the second layer are communicated with the left air chamber 135 of the third layer. The first right guide chamber 126 and the second rear chamber 128 communicate with the third right chamber 133. Left plenum 135 is in communication with hydrogen plenum 144 of f via outlet 143 of gas flow path 142. The right gas chamber 133 is in communication with the oxygen chamber 141 of f via the outlet 140 of the gas flow passage 139. The inlet 125 of the water gas channel 136 is in communication with the water gas channel 146 of f and the outlet 137 is in communication with the inlet 169 of the water gas channel 170 of g. The g water gas channel has an outlet 171 in communication with an inlet 264 of the a water gas channel 263. Thereby constituting a oxyhydrogen gas separation device.
The high-temperature high-pressure airflow is rapidly cooled and expanded through the expansion cavity 86, the temperature is reduced to 350-390 ℃, and the pressure is reduced to 0.1-0.3 atm. 25-35% of energy of air flow passing through the optical resonant cavity is lost and output to the resonant cavity (quantum efficiency)Rate limited). Mixing the gas flow under the action of an external suction pumpInto the magnetic field region, O2The molecule is paramagnetic substance, has the physical property of generating precession along the direction of magnetic force line, and is biased to N magnetic pole in the flow, H2、N2、CO2The molecule is diamagnetic, has the physical property of reverse precession along the direction of magnetic force line, and is biased to S magnetic pole and O magnetic pole in the flow2The air is guided by the deflector into the right air chamber 126, H2、N2、CO2The mixture is directed by the baffle into the left air chamber 129. The gas in the left guide chamber of the first layer flows through the front gas chamber 131 of the second layer into the left gas chamber 135 of the third layer, enters the hydrogen chamber of the third layer through the hydrogen channel 142, and is divided into hydrogen pipes by the gas splitter in (A). The gas in the right guide chamber of the first layer flows through the rear gas chamber 128 of the second layer into the right gas chamber 133 of the third layer, enters the oxygen chamber of f through the oxygen channel 139, and is divided into oxygen pipes by the gas splitter in (A). Thereby achieving the purpose of hydrogen-oxygen separation.
The component 'right heat energy exchanger' (A) is a component device for exchanging heat energy of high-temperature and low-temperature inlet and outlet materialflows. Fig. 3 is a structural view of a right heat exchanger, which is a sectional view a-a of fig. 2, and fig. 5(a-1) is a structural view of a gas splitter of fig. 3. The right heat energy exchanger is a plane spiral channel which is coiled by an alloy aluminum plate or a copper plate or an antioxidant steel plate material and extends from inside to outside, the plane spiral channel is in an annular structure body, two ends of the plane spiral channel are welded and sealed by sealing plates 151 to form a single spiral channel 156, and the channel can extend outwards at will according to needs, so that the design requirements of heat energy exchange are met. N internal thread aluminum tubes or copper tubes 153 are arranged in the channel, n hydrogen tubes 145 communicated with the left air chamber 144 are arranged on the left side, the outlet is communicated with the end air chamber 161, and is communicated with an external suction pump theta through an outlet 1622And (4) communication. N oxygen pipes 154 are arranged on the right side and communicated with the right gas chamber 141, and the outlet of the oxygen pipes is communicated with the tail gas chamber 160 and is communicated with an external air suction pump theta through an outlet 1641In communication, the tubes in the channel are fixed with the support 155, and the water chamber 158 at the outer end of the channel 156 is connected with the external metering water pump α through the inlet 1571In communication, the outlet at the inner end is in communication with the inlet 149 of the "gas splitter" water gas chamber 148. The outer surface of the annular structure is provided with a heat insulation layer 164 made of ceramic foam or other heat insulation materials, vacuum heat insulators q, r, s, n and o are assembled outside the heat insulation layer, the interior of each heat insulator is vacuumized 165, and the inner wall of the outer layer166 has a gold or aluminum foil reflective layer 167 that reflects infrared heattoward the center. The heat exchanger is integrally fixed to the frame 256. Thereby constituting a high and low temperature heat energy exchanger.
The mixed gas flow through the optical resonator 87 enters the magnetic field area 114, and is divided into the hydrogen chamber 135 and the oxygen chamber 133, due to the change of the volume of the gas flow channel and the molecular velocity, the expansion chamber 350 ~ 390 ℃ low pressure gas flow in the fluid director rises to 850 ~ 950 ℃ high temperature low pressure gas flow, it relies on the external suction pump η1、η2The mixture of hydrogen gas from hydrogen chamber 135 flows through gas flow path 142 into diverging chamber 144 of f, the mixture is split into hydrogen tubes 145, flows out of end plenum 161, and passes through getter pump η from outlet 1621Enters a gas separator theta1Is separated into H2、N2、CO2Gas is respectively sent into H2Iota, N gas storage tank2Gas storage tank lambda, CO2The oxygen from the oxygen chamber 133 flows through the flow channel 139 into the diversion chamber 141 of f, is diverted into each oxygen tube 154, flows out of the end chamber 160, passes through the getter pump η from the outlet 1642Into O2Gas storage tank water passes through metering water pump α1The water chamber 158 is pumped from the inlet 157, through the water channel 152 into the water gas chamber 148 of h, through the water gas channel 146 into the water gas channel 136 of i in the central structure, through the water gas channels 170, 263, 262, 190, 210, 211, 25, 21 to the water gas pipe 29. The 850-950 ℃ high-temperature air flow discharged from the air chambers 133 and 135 is discharged out of the system along the hydrogen and oxygen channels, the heat energy is transferred to water molecules outside the wall, the process of gradually cooling is realized, and the 35-45 ℃ normal-temperature air flow is discharged from the outlets 164 and 162. Pumping the room temperature water of 15-25 ℃ from the inlet 157 into the water channel 152 through the water chamber 158,the absorption of the heat energy of the channel wall is a gradual temperature rise process, liquid water is gradually heated into high-temperature water vapor, the high-temperature water vapor is changed into high-temperature water vapor at 750-850 ℃ when flowing into the water vapor channel 136, a forced convection heat exchange state is formed, and the heat exchange efficiency reaches 85-95%. The water and air flow continuously absorbs heat energy through the water and air channel of the central structure body, the water and air flowing through the water and air channel 21 are heated to 850-950 ℃, the heat and the water flow are increased under the constant volume state, the water and air pressure is increased along with the increase of the water and air pressure, and the water and air flow becomes high temperatureHigh pressure water vapor. Mixing with high-temperature high-pressure water vapor generated by oxygen flame to obtain heat energy supplement, and making the high-temperature high-pressure water vapor with stable temperature and pressure value of 900-1100 ℃ enter the light reaction chamber 37 to form heat energy circulation in the system. The heat energy exchange is a natural process without external energy input, and provides heat energy for activating molecules in infrared laser chemical reaction and catalytic chemical reaction.
The component "gas dynamic laser" (F), is a component device that generates laser energy. Fig. 11 is a structural view, and fig. 12 is a structural view of the combustion actuator of fig. 11. The 'circulating gas dynamic laser' is composed of a combustion exciter 185, a current collector 182, an array nozzle 215, an unstable optical resonant cavity tone 220, a light path 207, a diffuser 221 and a left heat exchanger (B). Current collectors made of high temperature material GH3170 are connected to k, l, a, j to form an upper air chamber 197 and a lower air chamber 198. The upper chamber has a combustion actuator made of a high temperature material K419 mounted on the collector 182, and may be arranged in one to several numbers as required. The combustion actuator is conveniently constructed of three layers, with the central carbon monoxide gas port 174 in the upper combustion chamber 185 communicating with gas flow passage 173 and with the outer carbon monoxide gas metering gas pump ω via carbon monoxide gas line 175. The middle oxygen flow channel 176, the outlet of which is communicated with the oxygen jet 177 around the jet 174, the inlet of which is connected with the external metering oxygen pump gamma through the oxygen pipe 178 via the safety valve 1793The lower layer is an annular hydrogen channel 186, the outlet of the annular hydrogen channel is communicated with the hydrogen jet port 180 around the combustion chamber, and the inlet of the annular hydrogen channel is communicated with an external metering hydrogen pump β through a safety valve 182 by a hydrogen pipe 1863And (4) communication. Wherein, a ceramic foam thermal insulating layer 188 is arranged outside the hydrogen and oxygen tubes of the copper material. The upper layer and the middle layer are connected by screws 194, the middle layer and the lower layer are connected by screws 195 to form the combustion exciter, and the combustion exciter is connected to the current collection through screws 196. An annular nitrogen passage 184 is provided between the collector and the combustion actuator, and has a nitrogen inlet 183 communicating with an upper plenum 197 and an outlet 186 communicating with the combustion chamber. The combustion chamber is provided with an igniter 208. Adjacent to the combustion chamber is an air flow mixing chamber 187. The lower air chamber 198 is provided with a thermometer Pi 2 and a pressure gauge rho2. The outer wall of the combustion chamber is a flow storage chamber 190, a water vapor inlet 189 is communicated with an outlet 192 of the water vapor chamber 262, an outlet 191 is communicated with the water vapor channel 210 of the 1,an outlet 203 is in communication with the water gas channel 211 of k. The outlets 201, k of l are in communication with the inlet 24 of the water gas channel 25 of the "energy input" m. The upper chamber has a nitrogen outlet 204 in communication with the nitrogen channel 209 of a, and 209 and 213 are in communication with the nitrogen channel 70 of g via an outlet 212. A nozzle 215 made of high temperature alloy copper or stainless steel and an array of n nozzles fixed on k, l by screws 217 form a nozzle 218 and an expansion chamber 219. The nozzle body has a cooling water vapor passage 216 therein, the inlet of which is communicated with the water vapor passage outlet 199, and the outlet of which is communicated with the water vapor passage inlet 200. An unstable optical resonant cavity 220 adjacent to the expansion cavity, a rectangular concave spherical reflector 89 is arranged on the right side, a photodiode 95 is arranged in a small hole at the center of the reflector communicated with the resonant cavity, a Brewster window 96 is arranged in front of the reflector, a plane reflector 204 is arranged on the left side, a rectangular convex lens at the center is double-layered towards the resonant cavity edge, and a saturated absorption medium is arranged in the middle to form the optical resonant cavity. The frequency stabilizer 99, the polarizer 100, the electro-optical switch 101, the thyratron 102, the lambda/4 wave plate 103 and the high-voltage loop 104 form a Q-switching, frequency-stabilizing and mode-locking output window, a refractor 107, a synchrotron 206, a convex lens 105 and an input window 49 form laser output in a light path 207An optical path. The optical resonant cavity is communicated with a diffuser 221, and the diffuser is communicated with the n. The flow guide chamber has an exhaust flow path 224 communicating via flow path 226 of member i with inlet 227 of o-plenum 229, which has outlet 230 communicating with (B) exhaust flow path 232. The baffle compartment has an inlet flow passage 238 communicating with the inlet flow passage 235 of (B) via an o flow passage 237. The "left heat exchanger" and the "gas dynamic laser" are combined to form a "circulation gas dynamic laser", and fig. 4 is a structural view, which is a B-B sectional view of fig. 2. The double- spiral channels 232 and 235 which are plane spiral and can be arbitrarily extended from the inside to the outside according to requirements are rolled by an alloy aluminum plate, a copper plate or an antioxidant steel plate. It surrounds the central structure B and is in an annular structure. The inner and outer sides of the channel are welded to the upper and lower ends of the o, forming exhaust flow channel 232 and input flow channel 235. The inlet at the inner end of the exhaust gas flow path 232 communicates with the outlet 230 of the o-plenum 229, and the outlet at the outer end passes through the plenum 247 from the outlet 248 to the gas separator θ2And (4) communication. The inlet airflow channel 235 passes through the outer end air chamber 250 and enters from the inlet249 is communicated with an external nitrogen metering pump delta, the outlet of the inner end of the input airflow channel is communicated with an airflow channel 237 of a central structure B, and 237, 238, 241, 244, 243, 39, 45, 40, 30 and 197 in the central structure are communicated with each other. The annular structure is provided with an insulating layer 251, a ceramic foam insulating material 252 is arranged in the middle of (A, B), an annular vacuum heat insulator 253 is arranged outside the insulating layer, the inside of the heat insulator is vacuumized 254, the inner wall of the outer layer is provided with a gold foil or aluminum foil reflecting layer 255, and the (A) are fixedon a machine base 256 together on the same horizontal axis. Thereby constituting a thermal energy cycling gas dynamic laser.
The temperature of the nitrogen in the upper air chamber is 870-920 ℃, the pressure is 20-25/amt, the nitrogen enters the combustion chamber 185 from the nitrogen channel 184, and the nitrogen is mixed with the mixed combustion gas of 1700-2000 ℃ and 20-30/amt of the combustion chamber to form 1300-1600 ℃ and 20-30 kgf/cm2The combined gas flow enters lower plenum 198. In the gas flow mixing, nitrogen molecules and molecules generated by combustion reaction collide with each other to carry out resonance energy transfer, so that the metastable state energy level of the nitrogen molecules is promoted to store a large amount of vibration energy. The supersonic velocity of the mixed gas stream enters the expansion chamber 219 through 218 and the rapid change in temperature and pressure of the gas stream creates the aerodynamic effect described above for a 10.6um laser output. 30-40% of energy of the airflow passing through the optical resonant cavity 220 is lost and output (limited by quantum efficiency) in the resonant cavity, the temperature of the high-temperature and high-pressure airflow entering the expansion cavity is reduced to 350-390 ℃, the pressure of the high-temperature and high-pressure airflow is reduced to 0.1-0.3 amt, the airflow enters the diffuser 221 through the optical resonant cavity 220, the pressure of the airflow is increased to 1.1-1.3 amt, the mixed airflow with the temperature increased to 950-1050 ℃ (energy conservation) enters the airflow chamber 229 of the o in the B through the airflow channel 224 of the n, enters the exhaust airflow channel 232 through the outlet 230, is exhausted from the outlet 248 through the outlet air chamber 247, the temperature of the mixed airflow is reduced to 35-45 ℃, and the mixed airflow2Separation into N2Gas, CO2Gas, H2And the O molecules are respectively sent into a nitrogen storage tank lambda, a carbon dioxide storage tank mu and a water storage tank kappa. The nitrogen gas with the temperature of 15-25 ℃ in the storage tank lambda is pumped into the air chamber 250 from the inlet 249 by the metering nitrogen gas pump delta, enters the nitrogen gas channels 237, 238, 241, 244, 243, 172, 173, 45, 39, 40 and 30 of the central structure body, reaches the upper air chamber 197, and the temperature of the nitrogen gas flow rises to 870-920 ℃. Is discharged from the diffuser 221The high temperature gas flow is a gradual cooling process, which conducts heat to the input gas flow outside the wall of the gas flow channel. The pumping of room temperature nitrogen into the inlet flow channel 235 absorbs the heat of the outlet flow from the channel walls, which is a gradual temperature rise. Thereby being in a forced convection heat exchange state. The heat exchange efficiency reaches 85-90%. The central structure is a high-temperature hot body with the average temperature of 1000 ℃, the high-temperature hot body is provided with nitrogen flow channels communicated with each other, and the nitrogen flow in the 235 is continuously heated through the nitrogen flow channels of the central structure and reaches the upper air chamber to become the high-temperature high-pressure nitrogen flow. The nitrogen accounts for 75 percent of the laser working substance85%, so the circulation of thermal energy in the nitrogen stream constitutes a thermal energy circulating gas dynamic laser.
The above-mentioned "components" are connected by means of "members" to constitute a system device. The interconnections form an input material flow channel and an output material flow channel. A central structure of a chemical reaction process and an energy generation process which are positioned in the center of the system is surrounded by a heat energy exchanger, and high-low temperature heat energy exchange between material flows in and out of the system is formed to form internal circulation of heat energy. By utilizing the gas dynamics principle, the kinetic energy and the potential energy of reaction gas flow in the chemical reaction process are converted into laser energy to form the decomposition energy circulation of water. When the laser light wave frequency is consistent with the normal vibration frequency of the water molecules, the water molecules can absorb light energy to a decomposition energy threshold value in a resonance mode to generate infrared laser chemical reaction, the absorption of the light energy accelerates the chemical reaction rate, the chemical reaction equilibrium constant is increased, the chemical reaction is promoted to be in a positive chemical reaction state, and then catalytic chemical reaction is generated. The thermal energy circulation inside the system is realized by the thermal energy storage when the system is started (similar to clock spring energy storage). The exchange of thermal energy between the output gas and the input stream within the system provides thermal energy for activating molecules in chemical and catalytic reactions. The mutual energy addition relation of the thermal energy, the infrared laser chemical reaction and the catalytic reaction is formed. FIG. 1 is a block diagram of the energy cycle of the system, a chemical reaction process.
The control system (L) of the device of the invention is operated by an information processing centre, fig. 14 is a schematic view of a metering water pump α1Given water flowQuantity information kg/cm2The water pressure increases along with the increase of the flow and temperature of water, and the water pressure in the water gas channel is also reflected, the metering water pump α2Given water flow information kg/cm2Water vapor temperature and pressure in the reaction chamber after (G) is reacted out, metering pump α3Given water flow information kg/cm2The temperature of the cooling water in the channels of 90, 111, 76 and 57 is reflected in the second step, a hydrogen metering pump β is arranged1Oxygen pump gamma1Given gas flow information m3/cm2(s) temperature and pressure of water vapor in the reaction chamber after reaction of (G) and a hydrogen metering pump β2Oxygen pump gamma2Given gas flow information m3/cm2And/s, the temperature and pressure of water vapor in the gas storage chamber in the step (C) are obtained. Gas flow information m given by carbon dioxide gas pump epsilon3/cm2S, reaction of CO in the gas flow in the expansion chamber in (D)2The percentage ratio of molecules. Gas flow information m given by metering nitrogen pump delta3/cm2(S) the temperature of the nitrogen in the upper gas chamber in the step (F) is reflected, the nitrogen channel in a constant volume state is formed, the flow rate and the temperature of the nitrogen are increased, the pressure of the nitrogen is increased, and therefore the pressure of the nitrogen in the nitrogen channel is also reflected, and the hydrogen metering pump β3Oxygen pump gamma3And gas flow information m given by the carbon monoxide gas pump omega3/cm2S, the temperature and pressure of the combustion gas in the combustion chamber and N in (F) are obtained2、CO2、H2The percentage ratio of O molecules. Thermometer pi1、π2Giving temperature information of the DEG C. Pressure gauge rho1、ρ2Giving atm pressure information. The optical frequency meter gives laser frequency information cm-1(HZ/s). Input laser power information kJ/cm given by optical power meter2. Relevant information such as electric power information kw/h of the oxyhydrogen combustion battery and the like is input into the information processing center, and the system is operated and controlled through a preset programming program.

Claims (15)

1. A method of decomposing water, characterized by: high-temperature and high-pressure water vapor enters a light reaction chamber in the center of the system, absorbs infrared laser energy to perform laser chemical reaction, and forms mixed water vapor in which most water molecules are decomposed in a forward chemical reaction state. Further accelerating the reaction process through the catalytic reaction zone, and the undecomposed water molecules are adsorbed, dissociated and catalytically reacted, and are completely decomposed and reconstructed into bonds of hydrogen and oxygen molecular gases. Mixing with the input high-temperature nitrogen, and storing a large amount of vibration energy on the energy level of nitrogen molecules in collision. When high-temperature high-pressure airflow enters the expansion cavity at supersonic speed, the high-temperature high-pressure airflow is mixed with input carbon dioxide gas and enters an energy converter, the kinetic energy and potential energy of molecules in the airflow are converted into infrared laser energy to be output, and the infrared laser energy is input into the light reaction chamber from the right side of the system through a light path to form decomposition energy circulation. The 'energy converter' discharges oxyhydrogen gas in the mixed gas and is separated into the mixed gas flow and oxygen flow in the magnetic field area. The high-temperature mixed gas is discharged into a right heat exchanger, and is discharged out of the system along hydrogen and oxygen pipelines in a spiral channel which surrounds a chemical reaction zone and extends outwards from the center, and the high-temperature mixed gas is gradually reduced into output airflow which is slightly higher than the room temperature. External room temperature water is pumped into the channel to perform forced convection heat exchange with a pipeline surrounded by water, the gradually-heated water vapor enters an energy input device at the center, and the water vapor becomes stable high-temperature and high-pressure water vapor after energy supplement and enters the light reaction chamber to form heat energy circulation in the system. The produced and stored hydrogen and oxygen are input into a 'pneumatic laser', and form excitation energy together with input carbon monoxide gas, and form a 'circulating pneumatic laser' through an energy transfer medium nitrogen and a 'left heat exchanger', and the output laser energy is input into a light reaction chamber from the left side of the system and forms decomposition energy together with the input laser energy from the right side, so that infrared laser chemical reaction is generated, and decomposition energy circulation is formed. The produced and stored hydrogen and oxygen are input into an energy input device to generate combustion chemical reaction energy which is used as system starting, supplementing and regulating energy. And the total energy circulation of the system is realized. The produced hydrogen and oxygen are returned to the input system, and the rest of the energy circulation of the system is the energy of the output substances of the system. The energy of the substances produced by the system is larger than the energy input into the system, and the purpose of inputting water to produce hydrogen and oxygen is achieved.
2. The infrared laser chemical reaction method for decomposing water according to claim 1, characterized in that: the temperature of the water gas entering the light reaction chamber (37) in the step (C) is 900 to 1100 ℃, and the pressure of the water gas is 20 to 30kgf/cm2. The infrared laser frequency of the input light reaction chamber is 3802-3663 cm-1(wavelength 2.63-2.73um). The laser energy input was: the continuous input power of the laser is 1-5 kw/cm2. The power of laser pulse input is 2-8 MW/cm2
3. The method of decomposing water according to claim 2, characterized by: the wavelength of 2.65um (3756 cm) is input from the left and right windows-1Frequency) infrared laser energy to the photo-reaction chamber, high temperature, high pressure water vaporEntering the light reaction chamber, the simple vibration frequency of water molecules is 3756cm-1(2.65um wavelength), when the light wave frequency of the photon is consistent with the normal vibration frequency of the water molecule, the water molecule can resonantly absorb the laser energy to the decomposition energy threshold, an energy-rich molecular area with the decomposition energy threshold is formed in the window incident beam area of the light reaction chamber, and atoms decomposed by the absorbed light energy can be diffused into infrared laser chemical reaction, light induction reaction and light catalytic reaction in the process of reconstructing bonds into hydroxyl molecules. The chemical reaction is delta H in the standard state of 101.3kpa and 298KθEnthalpy of chemical reaction:
the actual chemical reaction process is that under the conditions of constant temperature, pressure and material flow, the chemical reaction equilibrium of the infrared laser is in a forward chemical reaction state by means of the input infrared laser energy, and most water molecules in the water gas are decomposed and reconstructed into bonds of hydrogen and oxygen molecules. The bonded hydrogen and oxygen molecules have the physical and chemical properties of molecules, and because the vibration frequency of the molecules is different from the laser wave frequency, the molecules do not absorb laser energy to generate decomposition. The mixed gas in the forward chemical reaction state passes through the catalytic reaction zone, hydrogen molecules and oxygen molecules in the gas flow are physically adsorbed on the catalyst, the gas flow passes through the catalytic reaction zone along with the gas flow in the elastic collision, water molecules which are not decomposed are chemically adsorbed on the catalyst, adsorption and dissociation are generated, chemical reaction is carried out, the chemical reaction is reconstructed into bonds of hydrogen and oxygen molecules, and the hydrogen and oxygen mixed gas becomes hydrogen and oxygen mixed gas and enters the energy converter.
4. The method of energy conversion and decomposition of an energy cycle of claim 1, wherein: the chemical reaction in the catalytic reaction zone is carried out according to the forward chemical reaction parameters, and the reverse chemical reaction (hydrogen-oxygen combustion reaction condition) does not exist. The hydrogen-oxygen mixed gas and the input high-temperature nitrogen gas are mixed in a gas chamber (83), and collision energy transfer enables the nitrogen molecules to store a large amount of vibration energy on the metastable state energy level. The high-temperature high-pressure mixed air flow enters a mixing area (85) from nozzles (84) at two sides to be mixed with carbon dioxide molecules input by an ejector (73), and the mixing proportion is as follows: (H)2、O2) 50-60% of molecules. (N)2、CO2) 40-50% of molecules; wherein N is280-90% of molecules and CO210-20% of molecules. The nitrogen molecules and the carbon dioxide molecules are in collision resonance coupling, and the vibration energy is transferred to the high energy level of the carbon dioxide molecules. The high-temperature high-pressure airflow enters an expansion cavity (86) at supersonic speed for rapid cooling and expansion, the relaxation speed of energy particles on the energy level of carbon dioxide molecules forms the inversion of the numbers of particles on upper and lower energy levels, the energy particles on the lower energy level react with hydrogen molecules and a small amount of water molecules in a deactivation manner to rapidly relax and empty, and the energy particles on the upper energy level and the lower energy level react with nitrogen moleculesThe collision is supplemented continuously, so that photons are continuously emitted between an upper energy level and a lower energy level, optical oscillation is generated in an optical resonant cavity (87), and laser pulse output (also laser continuous output) with the wavelength of 10.6um is generated by an output window (98) formed by combining Q-switching, mode-locking and frequency-stabilizing technologies. Second multiplication in the optical pathLaser with 2.65um wavelength is amplified by the power of a laser amplifier (109) in the optical path, and then laser energy (which is a multi-stage optical power amplifying device and adjusts the laser energy by increasing and decreasing the amplification stages) is input into a reaction chamber (37) from the right side of the system through a window (50) to form a decomposition energy cycle. The purpose of converting kinetic energy and potential energy in the hydrogen-oxygen mixed gas flow into infrared laser energy isachieved.
5. The oxyhydrogen gas separation method according to claim 1, wherein: according to the different magnetism of hydrogen and oxygen molecules in an external magnetic field. In the air flow channel, a magnetic field region is arranged to form N, S magnetic pole magnetic flux loop, and the molecules in the mixed air flow are moved by precession along the magnetic lines of force according to their respective magnetic physical properties through the magnetic field region to achieve the separation purpose. What needs to be separated in the high temperature mixed gas stream is oxygen molecules. O is2The magnetic moment of the molecule is not zero, is a paramagnetic substance, has the physical property of precession along magnetic lines when passing through a magnetic field area, and enters the oxygen chamber by deviating to one side of the N magnetic pole during movement. H2、N2、CO2The magnetic moment of the molecule is zero, the molecule is a diamagnetic substance, is not restricted by a magnetic field when passing through a magnetic field region, has the micro property of reverse precession, and is deflected to one side of the S magnetic pole to enter the hydrogen chamber during movement.
6. The method of thermal energy exchange and thermal energy cycle of claim 1, wherein: a single spiral channel (152) is formed by rolling a heat conducting plate, optionally extending outwards from the center, and surrounds the central chemical reaction chamber of the system and the high-temperature heat source of the energy generating device, and the outermost layer of the single spiral channel is provided with an insulating layer and a heat insulating device. A plurality of heat-conducting hydrogen pipes and oxygen pipes are arranged in the channel, so that after high-temperature mixed gas flow in the center of thesystem passes through the magnetic field region, the oxygen flow is discharged out of the system along the oxygen pipes (154) in the channel, and the hydrogen is discharged out of the system along the hydrogen pipes (145) in the channel along with the mixed gas flow. External room temperature water is pumped along a helical channel (152) into a water gas channel in the ' central structure ' into the ' energy input. The hydrogen and oxygen pipes surrounded by water flow in the channel have high and low temperature difference between the inside and outside of the pipe and between the inner wall and the outer wall of the channel, so that forced convection heat transfer state is formed between the high temperature air flow discharged from the center and the low temperature water flow input from the outside. The central high temperature gas stream exhaust system gradually reduces to a low temperature gas stream slightly above room temperature. The room temperature water pumped into the center is gradually heated into high temperature water airflow, and the high temperature and high pressure water airflow becomes stable state and enters the light reaction chamber (37) through the heat energy supplement of the 'energy input device', and provides heat energy for infrared laser chemical reaction and catalytic reaction activated molecules. And thus forms a thermal energy cycle.
7. The energy cycling gas dynamic laser of claim 1, wherein: the stored hydrogen and oxygen produced by the system are input into a gas dynamic laser, wherein the oxygen and the input carbon monoxide gas are combusted in a combustion chamber (185) to generate carbon dioxide molecules and release heat energy. The incoming hydrogen and oxygen are combusted in the combustion chamber (185) to produce water molecules and release thermal energy. The thermochemical reaction formula is as follows:
the method comprises the following steps of generating 1800-2000 ℃ mixed gas in a combustion chamber, enabling 870-920 ℃ nitrogen of an upper air chamber (197) to enter the combustion chamber along a peripheral air flow channel (183) of the combustion chamber, and mixing the mixed gas with high-temperature and high-pressure mixed gas which is generated by burning carbon dioxide and water in the following mixing ratio: n is a radical of275-85% of molecules, CO28-13% of molecule, H26-12% of O molecules. The molecules in the mixed gas stream cause the metastable energy levels of the nitrogen molecules to store a significant amount of vibrational energy during collisions. The supersonic speed of the high-temperature high-pressure mixed gas flow enters an expansion cavity (219) through an array nozzle (218), the gas flow is rapidly cooled and expanded, energy particles on molecular energy level relax fast and slowly to form upper and lower energy level particle number inversion, carbon dioxide molecules and water molecules collide and deactivate reaction, the lower energy level fast relaxation is evacuated, the energy particles collide with nitrogen molecules to generate energy resonance coupling, the vibration energy of the nitrogen molecules is transferred to the high energy level of the carbon dioxide molecules, the energy particles jumping up and down are continuously supplemented, therefore, photons are continuously emitted between the upper and lower energy levels, optical oscillation is generated in an optical resonant cavity (220), and the photons are outputThe window (98) outputs 10.6um rectangular beam giant pulse laser (can output continuous laser), the adjustable electronic energy wave emitted by a synchronous accelerator (206) in the light path interacts with the light wave, the laserwith the wavelength of 10.6um is frequency-modulated into laser with the wavelength of 2.65um (frequency modulation can also be adopted by a frequency doubling method or other methods), the laser is input into the reaction chamber (37) from the left side of the system through the window (49), and the laser energy input from the right side forms water molecule decomposition energy, so that the infrared laser chemical reaction is in a forward chemical reaction state. Forming laser decomposition energy cycle. The working gas flow passing through the optical resonant cavity enters a diffuser (221) to be pressurized and then enters a left heat exchanger, and high-temperature mixed gas is discharged out of the system through an inner side channel (232) of a double-spiral channel which can be extended outwards from inside to outside optionally. The room temperature energy transfer medium nitrogen is pumped into the outer gas flow channel (235) from the outside, enters the nitrogen flow channel of the central structure body, and enters the upper gas chamber (197) through the nitrogen flow channels of k, a, c, d, e and a. The high-temperature airflow discharged from the inner channel and the low-temperature airflow pumped into the outer channel are subjected to forced convection heat exchange, so that the high-temperature airflow discharged from the center to the outside is gradually reduced to be a low-temperature airflow slightly higher than the room temperature, and the low-temperature airflow is discharged out of the system. The room temperature nitrogen pumped into the channel is gradually heated to a high temperature nitrogen stream into the upper plenum (197). The nitrogen accounts for more than 80% of the laser working medium, so the nitrogen as the energy transfer medium forms thermal energy circulation to form the energy circulation pneumatic laser. Or a carbon dioxide electric excitation pneumatic laser or an energy transfer HF chemical laser can be configured on the left side of the system to output 10.6um wavelength giant pulse laser (continuous laser output can be realized), and laser with the wavelength of 2.65um is input into the light reaction chamber from the left side of the system through frequency modulation.
8. The method of starting energy, energy replenishment, energy regulation in a system according to claim 1, wherein: the stored hydrogen and oxygen produced by the system are input into the energy input device, and a combustion chemical reaction is generated in the front reaction chamber and the rear reaction chamber, and the thermochemical reaction formula is as follows:
under the action of platinum catalyst, hydrogen and oxygen with central temperature of about 3000 deg.C are formedA gas flame. The rear reaction chamber (10) is provided with a rear burner (8), the hydrogen-oxygen flame of the combustion chemical reaction gasifies the externally pumped water mist (4) to become high-temperature high-pressure water vapor which enters the front reaction chamber (9), and the high-temperature high-pressure water vapor is the starting energy of the system and is the initial stored heat energy of the system. When the stored thermal energy meets the system energy cycle, the input hydrogen, oxygen pump and input water pump of the rear burner are turned off. The front reaction chamber is provided with a front burner (7), oxyhydrogen gas flame generated by combustion chemical reaction can supplement heat energy for water vapor with the temperature of 850-950 ℃ flowing into the front reaction chamber in the water vapor channel (21) and water vapor with the temperature of 850-900 ℃ flowing into the front reaction chamber in the rear reaction chamber. The input amount of hydrogen and oxygen can be adjusted to change the temperature of the combustion chemical reaction, so as to achieve the purpose of adjusting the temperature of high-temperature water vapor, and the air flow is adjusted to 900-1100 ℃ and 20-30 kgf/cm2At a stable temperature and pressure value, water vapor enters the photoreaction chamber (37).
9. The method for decomposing water according to claim 1, which provides a system apparatus for decomposing water, characterized in that: the system device comprises a right heat exchanger (A), a left heat exchanger (B), a decomposition reactor (C), an energy converter (D), a hydrogen-oxygen separator (E), a pneumatic laser (F), an energy input device (G), an auxiliary system (L) and a control system component (H). The (A, B, C, D, E, F, G) parts are connected with the components (middle wall body) a, (right end cover) b, (right front upper body) c, (right rear upper body) d, (gas storage chamber cover) e, (right front lower body) f, (right rear lower body) g, (gas splitter) h, (fluid director) i, (left end cover) j, (left front body) k, (left rear body) l, (ring body seat cover) m, (fluid director) n, (shunt) o, (right vacuum heat insulator) r, (left vacuum heat insulator) p, (ring vacuum heat insulator) q, (right vacuum heat insulator cover) t, (left vacuum heat insulator cover) s, respectively. Wherein q, h, o are assembled at (A, B) and t, s are fixed at q. The ceramic foam heat insulation layer is arranged between the (A, B) and the t, s and q, and the integral body (A) is fixed on the machine base (256). (C, D, E, F, G) the central structural body (B) is formed by connecting the components a, b, c, d, e, f, g, i, j, k, l, m and n. Each component is provided with a water-gas channel and a nitrogen channel which are communicated with each other and are high-temperature and low-temperature heat energy exchange and heat energy circulation channels. The components and the structures forming the working air chambers are high-temperature heat sources of the system and are assembled in the whole body (A). t and s are fixed to both ends of (B), respectively, thereby constituting a system device.
10. The device of claim 1, 9 for generating a thermal energy cycle, comprising a right thermal energy exchanger element, characterized in that: is made by rolling an alloy aluminum plate, a copper plate and an antioxidant steel plate (150)A single spiral channel in the form of a flat spiral, optionally extending from the inside to the outside, in the form of a toroidal structure surrounding a central structure, the left and right ends of the channel being sealed by welding with closure plates (151), a plurality of internally threaded or corrugated copper or aluminium alloy tubes (153) being arranged within the channel and held within the channel by retaining brackets (155) thereby forming exhaust channels (145, 154) within the channel and an inlet water channel (152) within the channel outside the tube, an inlet (157) at the outer end of the channel and an external metering pump α1The outlet at the inner end of the channel is communicated with an h water gas chamber inlet (149), the outlet at the inner end of the pipeline (145) is communicated with the f hydrogen chamber 144 and is communicated with a left air chamber (135) of the i through an air flow channel (142), the outlet at the outer end is communicated with an air chamber (161) and is communicated with an external suction pump η through an outlet (162)1The outlet at the inner end of the pipeline (154) is communicated with the f oxygen chamber 141 and is communicated with the i right air chamber (133) through a gas flow channel (139), the outlet at the outer end is communicated with the air chamber (163) and is communicated with an external suction pump η through an outlet (164)2And (4) communication. A ceramic foam heat insulation layer (165) is arranged outside the annular structure, a vacuum heat insulator q(166) is arranged outside the layer, and a gold or aluminum foil reflection layer (168) is arranged inside the hollow outer layer. The entire ring structure is supported on a stand (256). The gas chambers of the central flow deflectors (135, 133) discharge high-temperature gas flows at 850-950 ℃, oxygen gas flows are shunted in the gas chambers (141) and enter the oxygen pipes to be discharged through the outlets (164), and mixed gas flows are shunted in the gas chambers (144) and enter the hydrogen pipes to be discharged through the outlets (162). Water with the temperature of 15-25 ℃ is pumped into the water channel (152) from the external inlet (157) and enters the water-air channel (136) of the central fluid director, so that a forced convection heat transfer state is formed, and the high-temperature air flow discharged out of the system is gradually reduced to low-temperature air flow with the temperature of 35-45 ℃. The room temperature water in the input channel is gradually heated into high temperature water vapor of 750-850 ℃. The heat exchange efficiency is 85-95%.
11. The "decomposition reactor" component device for generating laser chemical and catalytic reactions according to claims 1 and 9, characterized in that: the components are connected by a gas storage chamber, a light reaction chamber and a catalytic reaction zone through a component a, a component b, a component c and a component d. The combined cross section of the inner sides of the components c, d and e made of high-temperature material K419 is provided with a thermometer Pi in a circular air storage chamber (35)1Pressure gauge rho1The air storage chamber and the light reflection chamber (37) are provided with rectangular airflow openings (36) which are communicated, and the width of each airflow opening is equal to the diameter of the section of the laser energy column (51) or the length of the side of the rectangle. The water-gas inlet of the gas storage chamber is communicated with the water-gas pipe (29) through a water-gas channel (46). The airflow port (36) is connected with the bed seat chute (38) in an arc line to form a light reaction chamber (37). The catalyst bed (52) in the chute can be changed by moving the bed left and right through the outlet (60) of b. c is internally provided with a nitrogen channel (39), the inlet of the nitrogen channel is communicated with the outlet (173) of the nitrogen channel a, and the outlet (44) is communicated with the inlet (31) of the nitrogen channel (40) of the nitrogen channel e. d is internally provided with a nitrogen channel (45), the inlet of the nitrogen channel is communicated with the outlet (172) of the nitrogen channel a, and the outlet (43) of the nitrogen channel is communicated with the inlet (31) of the nitrogen channel (40) of e. The nitrogen channel (40) is communicated with the nitrogen channel (30) a.The light reaction chamber is provided with a left distance reduction block (47), a right distance reduction block (48), a left laser input window (49) and a right laser input window (50), and the inner wall of the light reaction chamber is provided with a high-temperature resistant reflecting layer, so that the infrared laser chemical reaction chamber is formed. The catalyst bed is made of alloy aluminum or copper pipe and is communicated with a mesh-shaped structural substrate (54) which is a cooling water channel (57), and alumina Al is arranged outside the pipe2O2The catalyst carrier (55) formed by gel compression molding is impregnated with platinum chloride (56) on the surface after being calcined, and is reduced into metal platinum through the technological processes of calcination, reduction, activation and the like. Or other methods and process flows are adopted to manufacture the catalyst with specificity, memorability and selectivity through experiments, and the catalyst has the function of memory selection on the spectrum and the electronic energy spectrum of the water molecule. The inlet of the cooling water channel is connected with the outlet (58) of the water channel (63) in a pressing mode, the outlet is connected with the inlet (59) of the water channel (64) in a pressing mode, and the water channel (64) is provided with an outlet (261) which is communicated with the water air chamber (262). The a water channel (63) is communicated with the g water channel 80. The catalyst bed can move left and right, and is connected with the component B through a sealing cover plate (60) and an elastic block (61) in a pressing connection modeReplacement is facilitated, thereby forming a catalytic reaction zone (62) around the catalyst bed. High-temperature and high-pressure water enters the gas storage chamber (35) through the water vapor channel (46) for pressure equalization, and then enters the photoreaction chamber (37) from the window (36), and is irradiated by laser energy input by the window (49, 50), infrared laser chemical reaction is generated in the photoreaction chamber, a forward chemical reaction state with most of water molecules decomposed is formed, and the forward chemical reaction state enters the catalytic reaction zone (62) to accelerate the chemical reaction process. The oxyhydrogen molecules that have been decomposed and reconstituted in the infrared laser chemical reaction are physically adsorbed on the catalyst and pass through the catalytic reaction zone with the gas stream in elastic collisions. The water molecules which are not decomposed are chemically adsorbed by the catalyst, and are adsorbed, dissociated and catalyzed by the catalyst to perform chemical reaction, and the hydroxide molecule gas which is decomposed and reconstructed into bonds enters the reaction zone (D).
12. The "energy converter" unit device for forming cycle of decomposed energy "according to claims 1 and 9, wherein the nozzle body (67) made of high temperature resistant alloy copper or stainless steel material has nitrogen gas channel (69) therein, inlet is communicated with outlet (71) of the" g "inner nitrogen gas channel, the" g "inner nitrogen gas channel (70) has inlet communicated with outlet (212) of the" a "nitrogen gas channel (213), a plurality of small holes (72) communicated with air flow mixing chamber (83) are arranged on both sides of rear portion of the nozzle body, the nozzle body is fixed on the" f "and" g "by screws (68), ejector (73) is provided on central axis of the left and right nozzle bodies, cooling water channel (76) therein, inlet is communicated with outlet (81) of the" g "inner water channel (80), outlet is communicated with inlet (82) of the" f "inner water channel, the" g "water channel has inlet (92) and external metering water pump α3And (4) communication. The ejector is provided with a carbon dioxide gas channel (74), the inlet of the carbon dioxide gas channel is communicated with the outlet (77) of the carbon dioxide gas channel in the f, and the inner gas channel (78) of the f is provided with an inlet (79) communicated with an external carbon dioxide gas metering pump epsilon. A plurality of small jet flow holes (75) are arranged below the ejector and communicated with the airflow mixing area (85). An array nozzle is composed of n nozzle bodies to form two side jet ports (84) and an expansion cavity (86). Is composed of f, g, a and bThe unstable optical resonant cavity (87) is internally provided with a rectangular concave spherical reflector (88) which is connected with a left reflector (89) into a whole mirror body (which can be separately arranged), a cooling water chamber (90) is arranged inside the unstable optical resonant cavity, an inlet (91) is communicated with a water channel (63), and an outlet is communicated with a water pipeline (9)3) Is communicated with the inlet (116) of the cooling water channel of the left magnet body. The laser converter is characterized in that a Brewster window (86) is arranged in front of the mirror, a laser output window (98) which combines Q-switching, mode-locking and frequency-stabilizing technologies is adopted on the b, a secondary frequency doubling technology is combined in an optical path, a laser amplifier (109) is arranged, and laser output by the output window (98) enters the photoreaction chamber (37) from the input window (50) through the optical path (42), so that the energy converter is formed. Oxyhydrogen air flow passing through a catalytic reaction zone is mixed with high-temperature nitrogen flow input from a mixing chamber (197) in a mixing chamber (83), the mixed gas passes through a nozzle (84) at supersonic speed and is mixed with input carbon dioxide molecules (85), the high-temperature high-pressure air flow is rapidly cooled and expanded in an expansion cavity (86) to generate differential relaxation, so that the energy level of the carbon dioxide molecules forms reverse distribution, photons are continuously radiated between an upper energy level and a lower energy level, optical oscillation is generated in a resonant cavity (87), 10.6um laser output is generated in an output window, 2.65um laser with secondary frequency multiplication in an optical path is input into the catalytic reaction chamber through a window (50), infrared laser chemical reaction and catalytic chemical reaction are carried out, and laser decomposition energy circulation is formed. The mixed gas flow through the optical resonator enters (E).
13. The oxyhydrogen separator device according to claims 1 and 9, wherein: the hydrogen-oxygen separator is composed of a magnetic field region and a fluid director, adopts high temperature resistant Fe-Co alloy series permanent magnet materials, is internally provided with a main magnet (111) in a, is internally provided with a cooling water-gas flow channel (115), and an inlet (116) of the channel is communicated with a reflector cooling water chamber (90) through a water-gas pipe (110). The outlet (117) is communicated with the a water gas channel (263). A main magnet (112) is arranged in the b. The middle of the magnetic flux loop is provided with a plurality of auxiliary magnets (113) which are assembled on the f and the g to form a magnetic flux loop with opposite polarities repelling to the left and the right. The upper end part of the auxiliary magnet is provided with a shunting nozzle (118) made of non-magnetic material copper. A partition plate (121) is arranged between the auxiliary magnet and the upper plane of the fluid director to form each independent magnetic chamber (114), a guide plate (123) of each magnetic chamber is fixed on a shaft (124) capable of moving left and right, and the separation position of hydrogen and oxygen is finely adjusted through the outside. The flow guider consists of three layers of air chambers, and each air chamber is provided with a water-gas channel (136). The guide plate forms a left air chamber and a right air chamber (122) which are guided, one layer is the left air chamber and the right air chamber of each magnetic chamber, the second layer is the front air chamber and the rear air chamber of the flow guider, and the third layer is the left air chamber and the right air chamber of the flow guider.The left air chamber (129) of the first layer is communicated with the front air chamber (131) of the second layer and the left air chamber (135) of the third layer. The right air chamber (126) of the first layer is communicated with the rear air chamber (128) of the second layer and the right air chamber (133) of the third layer. The left plenum (135) is in communication with the hydrogen plenum (144) of f via an outlet (143) of the gas flow channel (142). The right gas chamber (133) is communicated with the oxygen chamber (141) of the gas flow channel (139) through an outlet (140). The inlet (125) of the water-gas channel (136) is communicated with the water-gas channel (146) of the f, and the outlet (137) is communicated with the water-gas channel in the g(170) Is connected to the inlet (169). The flow guider is connected on the f and g by screws (120) to form the hydrogen-oxygen separator device. The mixed gas flow passing through the optical resonant cavity enters the magnetic field region and is separated into O2Gas flow and H2、N2、CO2The gas streams are mixed. The mixed gas flow enters the front gas chamber of the second layer through the left gas chamber of the first layer, reaches the left gas chamber of the third layer, enters the h through a gas flow channel (142), and is shunted into a hydrogen pipe discharge system. The oxygen flow enters the second-layer rear air chamber through the first-layer right air chamber, reaches the third-layer right air chamber, enters the h through the air channel (139), and is shunted into the oxygen pipe to be discharged out of the system.
14. The thermal energy cycling "cycling gas dynamic laser" assembly device as claimed in claims 1 and 9, wherein: the current collector (182) is connected with the I, k, a and j to form an upper air chamber (197) and a lower air chamber (198), and one or more combustion exciters (185) can be arranged between the upper air chamber and the lower air chamber. The combustion actuator is composed of a three-layer structure for ease of manufacture, the upper layer being a central carbon monoxide gas passage (173), the outlet communicating with a nozzle (174) of the combustion chamber and the inlet communicating with an external carbon monoxide gas metering pump omega through a carbon monoxide gas pipe (175). An oxygen passage (176) with a middle layer around the carbon monoxide gas passage, an outlet communicated with a nozzle (177) of the combustion chamber, an inlet communicated with an external metering oxygen pump gamma through an oxygen pipe (178) and a safety valve (179)3The lower layer is a ring hydrogen chamber (186) with an outlet communicated with jet flow holes (180) distributed around the combustion chamber and an inlet connected with an external metering hydrogen pump β via a hydrogen pipe (181) and a safety valve (182)3And (4) communication. Wherein a high temperature resistant ceramic thermal insulation layer (188) is arranged outside the hydrogen and oxygen tubes. The combustion chamber is made of a high-temperature resistant material K419, and the inner wall of the combustion chamber is provided with a high-temperature resistant reflecting layer. Upper layer and middle layerThe layers are connected by screws (194), the middle layer and the lower layer are connected by screws (195) to form a combustion exciter, and the combustion exciter is connected to the current collector through screws (196). An annular nitrogen channel (184) is arranged around the combustion exciter, high-temperature nitrogen in the upper air chamber (197) enters the combustion chamber from an inlet (183) through the nitrogen channel along a nozzle (186) around the combustion chamber, and is mixed with high-temperature carbon dioxide gas and water gas to enter the lower air chamber. The upper gas chamber is provided with a nitrogen outlet communicated with an inlet (204) of a nitrogen channel (209), and an outlet (43) of the nitrogen channel (209) is communicated with a nitrogen channel (70) of g. The lower air chamber (198) is provided with a thermometer pi2Pressure gauge rho2. The outer wall of the combustion chamber is provided with a water-gas storage chamber (190), the water-gas storage chamber is provided with a water-gas inlet (189) communicated with an outlet (192) of a water-gas chamber (262), the water-gas storage chamber is provided with an outlet (191) communicated with a water-gas channel (210) of the combustor, and an outlet (193) communicated with a water-gas channel (211) of the combustor. The water vapor channel outlet (201) of the I and the water vaporchannel outlet (202) of the k are communicated with the inlet (24) of the water vapor channel (25) of the m in the G. The combustion chamber has an igniter (208) and adjacent to the combustion chamber is a gas flow mixing chamber (187). A spray pipe (215) made of high-temperature alloy copper or stainless steel and an array spray pipe consisting of n spray pipes are fixed on k and l by screws (217), a cooling water air channel (216) is arranged in the spray pipe body, the inlet of the spray pipe is communicated with the outlet (199) of the l air channel, and the outlet of the spray pipe is communicated with the outlet of the l air channelThe port is in communication with a k water gas channel inlet (200). The array of nozzles form a nozzle (218) and an expansion cavity (219). An unstable optical resonant cavity (220) adjacent to the expansion cavity, a rectangular concave spherical reflector (89) is arranged on the right side, a cooling water chamber (90) is arranged in the reflector body, a photodiode (95) is arranged in a small hole formed in the center of the reflector and communicated with the resonant cavity, a Brewster window (96) is arranged in front of the reflector, a planar reflector (204) is arranged on the j side, a rectangular convex lens at the center is double-layer facing the resonant cavity, and a saturated absorption medium is arranged in the middle to form the optical resonant cavity. A frequency regulator (99), a polarizer (100), an electro-optical switch (101), a thyristor (102), a lambda/4 wave plate (103) and a high-voltage loop (104) form a Q-switching, frequency-stabilizing and mode-locking output window, and a refractor (107), a synchrotron (206), a convex lens (105) and an input window (49) form a laser output optical path (203) in an optical path (207). The optical resonant cavity is communicated with a diffuser (221), and the diffuser is communicated with the n. The flow guide chamber has an exhaust flow passage (224) passing through an air flow passage (226) ofthe member l and an o-chamber (229)The inlet (227) is in communication with the o-chamber, and the o-chamber has an outlet (230) in communication with the (B) exhaust flow path (232). The diversion chamber has an input airflow channel (238) in communication with the input airflow channel (235) of (B) via an airflow channel (237) of o. The left heat exchanger is a double-spiral channel (232, 235) which is coiled by alloy aluminum or copper or antioxidant steel plates into a plane spiral shape and can be freely extended from inside to outside as required, the double-spiral channel surrounds a central structural body (B) and is in a ring-shaped structural body, the inner side and the outer side of the channel are welded at the upper end and the lower end of an o, the inlet of an inner side channel (232) is communicated with the outlet (230) of an o air chamber (229), and an inner side exhaust air flow channel passes through an outlet air chamber (247) and is communicated with an external gas separator theta through an outlet (248)3And (4) communication. The outer channel is communicated with the air chamber (250) and is provided with an inlet (249) communicated with the external nitrogen metering pump 6, and the outlet of the channel is communicated with the air flow channel (237) of the central structure body (B). The central structures (237, 238, 241, 244, 243, 39, 45, 40, 30, 197) communicate with each other, thereby constituting a circulating gas dynamic laser. Input CO gas and O2Combustion of gas in a combustion chamber to produce CO2Molecular gas. Input of H2Gas and O2Combustion of gas in a combustion chamber to produce H2And O molecular gas. Mixing combustion gas with input high temperature N2The gas passes through (218) at a mixing supersonic speed (187), enters (219, 220 and 221), is discharged with 950-1050 ℃ high-temperature mixed gas flow, is discharged out of the system through an air flow channel (224, 226, 229, 232 and 247)through an outlet (248), and becomes 35-45 ℃ low-temperature mixed gas flow. When the nitrogen with the room temperature of 15-25 ℃ is pumped into the air chamber (250) from the inlet (249), enters the air flow channel (235) and reaches the nitrogen channel (238) of the central structure body, the temperature rises to 750-850 ℃, the nitrogen continuously passes through the air flow channels (241, 244, 243, 39, 45, 40 and 30) and reaches the upper air chamber (197), the nitrogen continuously absorbs heat energy in the air flow channels, and the temperature reaches 870-920 ℃. Thereby constituting a thermal energy cycling gas dynamic laser.
15. System start-up energy, supplementary energy, energy regulation method according to claims 1 and 9The "energy input device" component device of (1), characterized in that: the energy input device consists of a machine body (1), a rear burner (8), a rear reaction chamber (10), a front burner (7), a front reaction chamber (9) and a ring body seat m. Front jet combustionA water chamber (3) is formed between a chamber body (2) made of a K419 high-temperature resistant material and GH3170 material assembled in the rear reaction chamber and the machine body, a plurality of water mist nozzles (4) are arranged around the rear reaction chamber body and communicated with the water chamber, and the water chamber is communicated with an external metering water pump α through a water channel from an inlet (6)2And (4) communication. An oxygen nozzle (11) at the center of the rear burner is communicated with an external metering oxygen pump gamma through an oxygen channel inlet (17) through a safety valve (255)1The peripheral hydrogen nozzle (12) is communicated with an external metering hydrogen pump β through a hydrogen channel inlet (18) through a safety valve (256)1And (4) communication. An oxygen nozzle (11) of the front burner is communicated with an external metering oxygen pump gamma through an oxygen channel (15) through a safety valve (257)2The peripheral hydrogen nozzle (12) is communicated with an external hydrogen pump β through a hydrogen channel (16) through a safety valve (258)2The front reaction chamber and the rear reaction chamber are provided with igniters (13), a platinum catalyst rod (14) is assembled in a ring body seat m, the machine body is fixed on a left vacuum heat insulator cover s through a flange plate (52), a water gas pipe (20) is assembled on a ring water gas channel (21) between the interior of the ring body seat and the machine body, an inlet (26) is formed in the periphery of the water gas channel and communicated with a water gas channel (25) of the ring body seat, the left side of an inlet (24) of the water gas channel is communicated with an outlet (211) of the water gas channel (210), the right side of the inlet is communicated with an outlet (213) of a water gas channel (212), the water gas pipe and the end part of the machine body gradually contract inwards and gradually restore to the original state to form a water-gas junction air port (22), the ring body seat is connected with a, k and l through screws (23 and 32), an upper air chamber (30) of a, water is communicated with a nitrogen gas channel (30) of a, water is pumped into the rear reaction chamber from the outside in a mist form, hydrogen gas pumped into the rear reaction chamber, hydrogen gas reaction chamber to ignite and combust to form hydrogen gas energy which the central temperature reaches 3000 ℃ under the action of the platinum catalyst, and further enters a high-hydrogen-oxygen-gas flame system which is heated by a water-gas-water-gas-water-gas system, and then enters1The room temperature water pumped into the system is gradually heated, when the temperature of the water vapor flowing through the water vapor channel (21) reaches 750-850 ℃, the water pump and the hydrogen and oxygen pumps of the rear reaction chamber are closed, and the hydrogen and oxygen pumps depend on the hydrogen and oxygen of the front reaction chamberThe gas flame heats the water vapor to a stable temperature and pressure value of 900-1100 ℃. The temperature of the oxyhydrogen flame of the front burner is adjustable, and the heat energy lost in the heat energy circulation can be supplemented and adjusted.
CN 200510118283 2005-10-21 2005-10-21 Method and device for decomposing water Pending CN1817787A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101920934A (en) * 2010-03-21 2010-12-22 刘之政 Method for decomposing water and device thereof
CN102120563A (en) * 2010-10-26 2011-07-13 曾凯 Oxyhydrogen source pre-cracking device and water energy combustion principle and control method
CN103466545A (en) * 2013-09-30 2013-12-25 中国大唐集团科学技术研究院有限公司 Photochemical circulating hydrogen preparing method and hydrogen preparing system thereof
CN108603467A (en) * 2016-01-04 2018-09-28 林闰植 Fuel efficiency is improved using output wave and increases the device of internal combustion engine output
CN115304027A (en) * 2022-08-31 2022-11-08 中山大学 Method for preparing hydrogen by laser total hydrolysis

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101920934A (en) * 2010-03-21 2010-12-22 刘之政 Method for decomposing water and device thereof
CN102120563A (en) * 2010-10-26 2011-07-13 曾凯 Oxyhydrogen source pre-cracking device and water energy combustion principle and control method
CN103466545A (en) * 2013-09-30 2013-12-25 中国大唐集团科学技术研究院有限公司 Photochemical circulating hydrogen preparing method and hydrogen preparing system thereof
CN103466545B (en) * 2013-09-30 2015-06-03 中国大唐集团科学技术研究院有限公司 Photochemical circulating hydrogen preparing method and hydrogen preparing system thereof
CN108603467A (en) * 2016-01-04 2018-09-28 林闰植 Fuel efficiency is improved using output wave and increases the device of internal combustion engine output
CN115304027A (en) * 2022-08-31 2022-11-08 中山大学 Method for preparing hydrogen by laser total hydrolysis

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