CN1807683A - Normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof - Google Patents
Normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof Download PDFInfo
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- CN1807683A CN1807683A CN 200610200127 CN200610200127A CN1807683A CN 1807683 A CN1807683 A CN 1807683A CN 200610200127 CN200610200127 CN 200610200127 CN 200610200127 A CN200610200127 A CN 200610200127A CN 1807683 A CN1807683 A CN 1807683A
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Abstract
The invention discloses a normal temperature fast bonderite and producing method of metal plastic deformation, which is characterized by the following: the bonderite is composed of phosphoric acid, methyl ethyl ketone or acetone, eldopaque, manganese dihydrogen phosphate, calcium nitrate, zinc nitrate and water; the method comprises the following steps: mixing, emulsifying, restirring; the raw materials of bonderite is at a low price, which can be used at normal temperature. The method is easy to product, which reduces the costs of conversion.
Description
Technical field
The present invention relates to normal temperature phosphating agent of using in the drawing process in a kind of Wire Rope Production and preparation method thereof.
Background technology
Special steel and senior middle school's steel surface are carried out bonderizing, are that wireline and extraordinary steel wire comprise an important procedure in the steel wire drawing process in the doughnut.At present, to the various phosphorization agents (claiming phosphatization liquid again) that use in special steel and the senior middle school's steel surface processing, though can satisfy the needs that wire drawing is produced substantially.But still exist the phosphatization effect not satisfactory to some extent, and the use of phosphorization agent has many restricted conditions, and to the temperature requirement height of environment for use, high problem consumes energy; And considerable waste sludge discharge is all arranged basically, exist and solve the problem of environmental pollution that the secondary emission waste residue brings.The problems referred to above are directly having a strong impact on quality, output and the cost that wire drawing is produced.
Summary of the invention
The objective of the invention is to: a kind of normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof is provided.Phosphorization agent of the present invention can use at normal temperatures, and phosphatization speed is fast, only needs several seconds, and phosphatization is effective, and non-corrosiveness does not almost have waste sludge discharge.
Technical scheme of the present invention: normal temperature quick phosphorizing agent for metal plastic deformation, the weight proportion of its feed composition is as follows, and consumption is a weight part;
5～12 parts of phosphoric acid, 3～13 parts in butanone or acetone,
0.4～1.0 part of Resorcinol, 0.02～0.08 part of phosphate dihydrogen manganese,
0.04～0.14 part in nitrocalcite, 0.02～0.08 part of zinc nitrate,
20～30 parts in water.
Above-mentioned normal temperature quick phosphorizing agent for metal plastic deformation, the weight proportion of reasonable feed composition is as follows;
6～11 parts of phosphoric acid, 4～12 parts in butanone or acetone,
0.5～0.9 part of Resorcinol, 0.03～0.07 part of phosphate dihydrogen manganese,
0.06～0.13 part in nitrocalcite, 0.03～0.07 part of zinc nitrate,
22～28 parts in water.
Above-mentioned normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof is characterized in that: better the weight proportion of feed composition is as follows;
7～10 parts of phosphoric acid, 5～11 parts in butanone or acetone,
0.6～0.8 part of Resorcinol, 0.04～0.06 part of phosphate dihydrogen manganese,
0.08～0.12 part in nitrocalcite, 0.04～0.06 part of zinc nitrate,
23～26 parts in water.
Aforesaid normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof is made by following step;
A, in reactor, add entry and butanone, under agitation add phosphate dihydrogen manganese, nitrocalcite and zinc nitrate, obtain A liquid after mixing thoroughly;
B, in mulser, add entry and phosphoric acid carries out emulsification, after emulsification 3-5 minute B liquid;
C, A liquid is added in the B liquid, stirs and add Resorcinol down, after mixing thoroughly finished product.
Compared with prior art, the invention provides a kind of new phosphorization agent and preparation method thereof.Phosphorization agent of the present invention is raw materials used cheap, and finished product can use at normal temperatures, and phosphatization speed is fast, only needs several seconds, can satisfy the thickness of wire drawing needs, does not almost have waste sludge discharge, and often reusable, the time is long, and the phosphatization area is big, can reach 40m
2/ Kg.Have the making of being easy to, cost of manufacture is low, and is easy to use, save energy, and phosphatization is effective, the erosion resistance height, hardness (intensity) height, lubricity is good, and phosphatization speed is fast, nontoxic free of contamination characteristics.The phosphorization agent that can be used as wireline and extraordinary steel wire drawing process and coating process uses.Also can be used as the phosphorization agent of cold extrusion, cold forging production usefulness.
Embodiment
Embodiment 1.Make normal temperature quick phosphorizing agent for metal plastic deformation by following step.
A, in reactor, add entry 20Kg and butanone 6Kg, under agitation add phosphate dihydrogen manganese 0.05Kg, nitrocalcite 0.09Kg and zinc nitrate 0.07Kg, obtain A liquid after mixing thoroughly;
B, in mulser, add entry 8Kg and phosphoric acid 7Kg carries out emulsification, after emulsification 3-5 minute B liquid;
C, A liquid is added in the B liquid, stirs and add Resorcinol 0.6Kg down, after mixing thoroughly finished product.
Embodiment 2.Make normal temperature quick phosphorizing agent for metal plastic deformation by following step.
A, in reactor, add entry 16Kg and acetone 6Kg, under agitation add phosphate dihydrogen manganese 0.03Kg, nitrocalcite 0.08Kg and zinc nitrate 0.06Kg, obtain A liquid after mixing thoroughly;
B, in mulser, add entry 8Kg and phosphatase 11 0Kg carries out emulsification, after emulsification 3-5 minute B liquid;
C, A liquid is added in the B liquid, stirs and add Resorcinol 0.8Kg down, after mixing thoroughly finished product.
Embodiment 3.Make normal temperature quick phosphorizing agent for metal plastic deformation by following step.
A, in reactor, add entry 15Kg and butanone 8Kg, under agitation add phosphate dihydrogen manganese 0.05Kg, nitrocalcite 0.1Kg and zinc nitrate 0.05Kg, obtain A liquid after mixing thoroughly;
B, in mulser, add entry 8Kg and phosphoric acid 8.5Kg carries out emulsification, after emulsification 3-5 minute B liquid;
C, A liquid is added in the B liquid, stirs and add Resorcinol 0.7Kg down, after mixing thoroughly finished product.
Claims (4)
1. normal temperature quick phosphorizing agent for metal plastic deformation, it is characterized in that: the weight proportion of this phosphorization agent feed composition is as follows, and consumption is a weight part;
5～12 parts of phosphoric acid, 3～13 parts in butanone or acetone,
0.4～1 part of Resorcinol, 0.02～0.08 part of phosphate dihydrogen manganese,
0.04～0.14 part in nitrocalcite, 0.02～0.08 part of zinc nitrate,
20～30 parts in water.
2. normal temperature quick phosphorizing agent for metal plastic deformation according to claim 1 is characterized in that: described weight proportion is as follows;
6～11 parts of phosphoric acid, 4～12 parts in butanone or acetone,
0.5～0.9 part of Resorcinol, 0.03～0.07 part of phosphate dihydrogen manganese,
0.06～0.13 part in nitrocalcite, 0.03～0.07 part of zinc nitrate,
22～28 parts in water.
3. normal temperature quick phosphorizing agent for metal plastic deformation according to claim 2 is characterized in that: described weight proportion is as follows;
7～10 parts of phosphoric acid, 5～11 parts in butanone or acetone,
0.6～0.8 part of Resorcinol, 0.04～0.06 part of phosphate dihydrogen manganese,
0.08～0.12 part in nitrocalcite, 0.04～0.06 part of zinc nitrate,
23～26 parts in water.
4. prepare the method for the described normal temperature quick phosphorizing agent for metal plastic deformation of arbitrary claim in the claim 1 to 3, it is characterized in that: make by following step;
A, in reactor, add entry and butanone or acetone, under agitation add phosphate dihydrogen manganese, nitrocalcite and zinc nitrate, obtain A liquid after mixing thoroughly;
B, in mulser, add entry and phosphoric acid carries out emulsification, after emulsification 3-5 minute B liquid;
C, A liquid is added in the B liquid, stirs and add Resorcinol down, after mixing thoroughly finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006102001273A CN100376718C (en) | 2006-02-15 | 2006-02-15 | Normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006102001273A CN100376718C (en) | 2006-02-15 | 2006-02-15 | Normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1807683A true CN1807683A (en) | 2006-07-26 |
| CN100376718C CN100376718C (en) | 2008-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006102001273A Expired - Fee Related CN100376718C (en) | 2006-02-15 | 2006-02-15 | Normal temperature quick phosphorizing agent for metal plastic deformation and preparation method thereof |
Country Status (1)
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| CN (1) | CN100376718C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967632A (en) * | 2010-11-19 | 2011-02-09 | 江苏泰力钢绳有限公司 | Steel wire surface processing method |
| CN102212814A (en) * | 2011-06-02 | 2011-10-12 | 厦门大学 | Phosphating liquid and preparation method thereof |
-
2006
- 2006-02-15 CN CNB2006102001273A patent/CN100376718C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967632A (en) * | 2010-11-19 | 2011-02-09 | 江苏泰力钢绳有限公司 | Steel wire surface processing method |
| CN101967632B (en) * | 2010-11-19 | 2013-08-21 | 江苏泰力钢绳有限公司 | Steel wire surface processing method |
| CN102212814A (en) * | 2011-06-02 | 2011-10-12 | 厦门大学 | Phosphating liquid and preparation method thereof |
| CN102212814B (en) * | 2011-06-02 | 2012-07-04 | 厦门大学 | Phosphating liquid and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100376718C (en) | 2008-03-26 |
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Granted publication date: 20080326 Termination date: 20100215 |