CN1805689A - Fungicidal mixtures based on a trizolopyrimidine derivative - Google Patents
Fungicidal mixtures based on a trizolopyrimidine derivative Download PDFInfo
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- CN1805689A CN1805689A CN 200480016628 CN200480016628A CN1805689A CN 1805689 A CN1805689 A CN 1805689A CN 200480016628 CN200480016628 CN 200480016628 CN 200480016628 A CN200480016628 A CN 200480016628A CN 1805689 A CN1805689 A CN 1805689A
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- 238000009333 weeding Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to fungicidal mixtures with cooperative effective dose, containing as active components: 1) a triazolopyrimidine derivative of formula (I), and 2) benomyl of formula (II), in a synergistically effective quantity. The invention also relates to a method for combating harmful fungi using mixtures of compounds (I) and (II), in addition to composition that comprising said mixtures.
Description
The present invention relates to Fungicidal mixture, comprise following compound as active component with cooperative effective quantity:
1) triazolopyrimidine derivative of formula I:
With
2) benomyl of formula II (benomyl):
In addition, the present invention relates to a kind of mixture methods for fighting harmful mushrooms of using Compound I and Compound I I, and Compound I and the purposes of Compound I I in such mixture of preparation and the composition that comprises these mixtures.
Compound I, i.e. 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine, its preparation and known by document (WO 98/46607) to the effect of harmful fungoid.
The mixture of triazolopyrimidine derivative and benomyl is known by EP-A 988 790 prevailingly.Compound I is disclosed included by the generality of the document, but unclear mentioning.Therefore, the combination of Compound I and benomyl is new.
Compound I I, promptly N-butyl-2-acetylamino benzo imidazoles-1-formamide, its preparation and to the effect of harmful fungoid known (US 3 631 176 by document equally; Common name: benomyl).
Be described to that at the Synergistic mixture of the triazolo pyrimidine described in the EP-A 988 790 various diseases, the especially wheat of cereal class, fruits and vegetables and the mildew of barley or the gray mold of apple are had Fungicidally active.Yet these mixtures are also unsatisfactory to the fungicidal action of Oomycete (Oomycetes) harmful fungoid.
The biological behavior of Oomycete fungi obviously is different from Ascomycetes (Ascomycetes), deuteromycetes (Deuteromycetes) and Basidiomycetes (Basidiomycetes), because the Oomycete fungi biologically more is being closely related with algae rather than fungi.Therefore, only can very limitedly be used for Oomycete fungi to " real fungi " as the knowledge of the Fungicidally active of Ascomycetes, deuteromycetes and Basidiomycetes fungi about reactive compound.
The Oomycete fungi causes relevant economically infringement to various crop plants.In many areas, in the cultivation of potato and tomato, be most important plant disease by infecting of causing of phytophthora infestans (Phytophthora infestans).In wine-growing, the downy mildew of grape vine causes significant infringement.
There is demand in new compositions for antagonism Oomycete fungi in agricultural always, because harmful fungoid has had drug resistance widely to commercially available product such as metalaxyl (metalaxyl) and structure similar activity compound.
Consider the control of effective drug resistance and under alap rate of application to effective control of Oomycete harmful fungoid, the purpose of this invention is to provide in the minimum of reactive compound and may use the mixture that under the total amount harmful fungoid is had abundant activity.
We find that this purpose is realized by the defined mixture of beginning.In addition, we also find can obtainable control to compare with only using the unification compound, simultaneously, i.e. associating or separately administered compound I and Compound I I, or administered compound I and Compound I I provide better control (Synergistic mixture) to the Oomycete fungi successively.
When the preparation mixture, preferably use pure reactive compound I and II, wherein can add other antagonism harmful fungoid or other insects as required, as the reactive compound of insect, spider or nematode, or weeding or growth regulating-activity compound or fertilizer.
Other reactive compounds suitable on above-mentioned meaning are especially for being selected from following reactive compound:
Acyl group alanine class, as M 9834 (benalaxyl), metalaxyl, fenfuram (ofurace) Huo Evil frost spirit (oxadixyl),
Amine derivative, as aldimorph, dodine (dodine), dodemorfe (dodemorph), butadiene morpholine (fenpropimorph), fenpropidin (fenpropidin), guazatine (guazatine), biguanide spicy acid salt (iminoctadine), luxuriant amine of Luo Evil (spiroxamine) or tridemorph (tridemorph)
Anilino-pyrimidine, as pyrimethanil (pyrimethanil), mepanipyrim (mepanipyrim) or encircle third pyrimidine (cyprodinyl),
Antibiotic, as cycloheximide (cycloheximide), griseofulvin (griseofulvin), spring thunder element (kasugamycin), myprozine (natamycin), Polyoxin (polyoxin) or streptomycin (streptomycin),
Azole, as Bitertanol (bitertanol), bromuconazole (bromoconazole), cyproconazole (cyproconazole) Difenoconazole (difenoconazole), alkene azoles alcohol (dinitroconazole), oxole bacterium (epoxiconazole), RH-7592 (fenbuconazole), Fluquinconazole (fluquinconazole), Flusilazole (flusilazole), own azoles alcohol (hexaconazole), IMAZALIL (imazalil), cycltebuconazole (ipconazole), encircle penta azoles bacterium (metconazole), nitrile bacterium azoles (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), Prochloraz (prochloraz), prothioconazole, simeconazole, Tebuconazole (tebuconazole), fluorine ether azoles (tetraconazole), triazolone (triadimefon), triadimenol (triadimenol), fluorine bacterium azoles (triflumizole) or triticonazole (triticonazole)
The dicarboximide class, as different third fixed (iprodione), myclozolin (myclozolin), sterilization profit (procymidone) or the vinclozolin (vinclozolin),
Dithiocarbamates, as ferbam (ferbam), Dithane A40 (nabam), maneb (maneb), mancozeb (mancozeb), metham-sodium (metam), Carbatene (metiram), propineb (propineb), polycarbamate (polycarbamate), tmtd (thiram), ziram (ziram) or zineb (zineb)
Heterocyclic compound, as anilazine (anilazine), Boscalid (boscalid), carbendazim (carbendazim), carboxin (carboxin), oxycarboxin (oxycarboxin), cyanogen frost azoles (cyazofamid), dazomet (dazomet), Delan (dithianon) azolactone bacterium (famoxadone), Fenamidone (fenamidone), fenarimol (fenarimol), furidazol (fuberidazole), flutolanil (flutolanil), furan pyrazoles spirit (furametpyr), Isoprothiolane (isoprothiolane), third oxygen goes out and embroiders amine (mepronil), nuarimol (nuarimol), picobenzamide, probenazole (probenazole), proquinazid, pyrifenox (pyrifenox), pyroquilon (pyroquilon), quinoxyfen (quinoxyfen), silicon metsulfovax (silthiofam), thiabendazole (thiabendazole), thifluzamide (thifluzamide), thiophanate methyl (thiophanate-methyl), tiadinil, tricyclazole (tricyclazole) or triforine (triforine)
The copper fungicide agent, as bordeaux mixture (Bordeaux mixture), Cupravit, Kocide SD, copper oxide, (alkali formula) copper sulphate or Copro,
Nitrophenyl derivative, as binapacryl (binapacryl), karathane (dinocap), dinobuton (dinobuton) or different third disappear (nitrophthal-isopropyl),
The phenylpyrrole class, as fenpiclonil (fenpiclonil) Huo Fu Evil bacterium (fludioxonil),
Sulphur,
Other fungicide, as thiadiazoles element (acibenzolar-S-methyl), benzene metsulfovax (benthiavalicarb), carpropamide (carpropamid), tpn (chlorothalonil), cyflufenamid, cymoxanil (cymoxanil), dazomet (dazomet), diclomezine (diclomezine), two chlorine zarilamids (diclocymet), the mould prestige of second (diethofencarb), Hinosan (edifenphos), Guardian (ethaboxam), fenhexamid (fenhexamid), fentinacetate (fentin acetate), zarilamid (fenoxanil), ferimzone (ferimzone), fluazinam (fluazinam), fosetyl (fosetyl), fosetyl (fosetyl-aluminum), iprovalicarb (iprovalicarb), hexachloro-benzene (hexachlorobenzene), metrafenone, Pencycuron (pencycuron), hundred dimension spirits (propamocarb), Rabcide (phthalide), tolelofos-methyl (tolclofos-methyl), pcnb (quintozene) or zoxamide (zoxamide)
The strobilurins class, as nitrile Fluoxastrobin (azoxystrobin), dimoxystrobin, fluoxastrobin (fluoxastrobin), imines bacterium (kresoxim-methyl), fork phenalgin acid amides (metominostrobin), orysastrobin, ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin) or oxime bacterium ester (trifloxystrobin)
The sulfenic acid derivative, as difoltan (captafol) but bacterium pellet (captan), Euparen (dichlofluanid), folpet (folpet) or tolyfluanid (tolylfluanid),
Cinnamamide and similar compound are as dimethomorph (dimethomorph), fluorine biphenyl bacterium (flumetover) or flumorph (flumorph).
In an embodiment of mixture of the present invention, Compound I and II and another fungicide III or two kinds of fungicide III and IV mix.
The mixture of preferred compound I and II and component III.The mixture of special preferred compound I and II.
In the time of the mixture of Compound I and Compound I I or Compound I and Compound I I, i.e. associating or independent the use the Oomycete plant pathogenic fungi, especially phytophthora infestans on potato and the tomato and the grape on the grape vine are given birth to single shaft mould (Plasmopara viticola) and are had very high activity.In them some play systemic action and therefore can come protective plant as blade face and soil effect fungicide.
They are for prevent and treat Oomycete fungi particular importance on various crop plants such as vegetable plant (for example cucumber, Kidney bean and cucurbitaceous plant), potato, tomato, grape vine and corresponding seed.
They are particularly suitable for preventing and treating the late blight that caused by phytophthora infestans on tomato and the potato and give birth to the mould grape vine downy mildew that causes of single shaft by grape.
In addition, the combination of The compounds of this invention I and II also is suitable for preventing and treating other pathogene, belongs to and grape spore (Botrytis) genus as the chain lattice spore (Alternaria) in the septoria musiva in the cereal class (Septoria) genus and handle rest fungus (Puccinia) genus and vegetables, fruit and the grape vine.
Compound I and Compound I I can be simultaneously, i.e. associating or use separately, or use successively, under situation about using separately, the result of prophylactico-therapeutic measures is not subjected to the influence of order of administration usually.
Usually, Compound I and Compound I I are with 100: 1-1: 100, preferred 10: 1-1: 50, especially 5: 1-1: 20 weight ratio is used.
If suitable, component III and IV and Compound I are with 20: 1-1: 20 ratio is mixed.
Depend on the type and the required effect of compound, the rate of application of mixture of the present invention is 5-2000g/ha, preferred 50-1500g/ha, especially 50-750g/ha.
Correspondingly, the rate of application of Compound I is generally 1-1000g/ha, preferred 10-750g/ha, especially 20-500g/ha.
Correspondingly, the rate of application of Compound I I is generally 1-1000g/ha, preferred 10-750g/ha, especially 20-500g/ha.
In seed treatment, the rate of application of mixture is generally the 1-1000g/100kg seed, preferred 1-200g/100kg, especially 5-100g/100kg.
In the control of plant-pathogenic harmful fungoid, the using of independent or the co-administered or Compound I of Compound I and Compound I I and the mixture of Compound I I by before or after the plant seeding or before or after plant emerges seed, plant or soil spraying or dusting being carried out.
Mixture of the present invention or Compound I and II can be changed into conventional preparaton, for example solution, emulsion, suspension, pulvis, powder, paste and particle.Administration form depends on specific purpose; In each case, should guarantee the meticulous and distribution equably of The compounds of this invention.
Preparaton prepares in a known way, for example prepares by reactive compound is mixed with solvent and/or carrier, if the words that need are used emulsifier and dispersant.Suitable solvent/auxiliary agent is mainly :-water, arsol (as Solvesso product, dimethylbenzene), paraffin (as mineral oil fractions), alcohols (as methyl alcohol, butanols, amylalcohol, benzylalcohol), ketone (as cyclohexanone, gamma-butyrolacton), pyrrolidones (NMP, NOP), acetic acid esters (ethylene acetate), glycol, fatty acid diformamide, fatty acid and fatty acid ester.Can also use solvent mixture in principle.
-carrier is as natural minerals (as kaolin, clay, talcum, chalk) that grinds and the synthetic mineral (as silica, the silicate of high degree of dispersion) that grinds; Emulsifier such as nonionic and anion emulsifier (as polyoxyethylene aliphatic alcohol ether, alkylsulfonate and arylsulphonate) and dispersant such as lignin sulfite waste liquor and methylcellulose.
Suitable surfactant is a lignosulphonic acid, naphthalene sulfonic acids, phenolsulfonic acid, the alkali metal salt of dibutyl naphthalene sulfonic acids, alkali salt and ammonium salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, aliphatic alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, also have sulfonated naphthalene and the condensation product of formaldehyde and the condensation product of naphthalene derivatives and formaldehyde, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, polyoxyethylene octylphenol ether, the ethoxylation isooctylphenol, octyl phenol, nonyl phenol, alkyl phenol polyethylene glycol ethers, tributyl phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, pure and mild fatty alcohol/ethylene oxide condensation product, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
In being suitable for preparing the direct material of spray solution, emulsion, paste or oil dispersion and being to mineral oil fractions such as the kerosene or the diesel oil of high boiling point, the oil that also has coal tar and plant or animal origin, aliphatic series, ring-type and aromatic hydrocarbon such as toluene, dimethylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof, methyl alcohol, ethanol, propyl alcohol, butanols, cyclohexanol, cyclohexanone, isophorone, intensive polar solvent such as methyl-sulfoxide, N-Methyl pyrrolidone or water.
Powder, but broadcasting sowing can be by with active substance with solid carrier mixes or grind together and prepare with material and dusting product.
Particle (as coating particle, impregnated granules and homogeneous particle) can prepare by reactive compound and solid carrier are adhered to.The solid carrier example is that ore deposit soil is as silica gel, silicate, talcum, kaolin, activated clay (Attaclay), lime stone, lime, chalk, bole, loess, clay, dolomite, diatomite, calcium sulphate, magnesium sulfate, magnesia, the synthetic mineral that grinds, fertilizer such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, the product of plant origin such as flour, bark powder, wood powder and shuck powder, cellulose powder and other solid carrier.
Preparaton comprises 0.01-95 weight % usually, the reactive compound of preferred 0.1-90 weight %.At this moment, this reactive compound is with 90%-100%, and the purity (according to NMR spectrum) of preferred 95%-100% is used.
Under classify the preparaton example as:
1. the product of dilute with water
A) water-soluble concentrate (SL)
With 10 weight portion reactive compounds in the water-soluble or water-soluble solvent.Perhaps, add wetting agent or other auxiliary agent.Reactive compound is through water dilution dissolving.
B) dispersed concentrate (DC)
Be dissolved in 20 weight portion reactive compounds in the cyclohexanone and add dispersant such as PVP(polyvinyl pyrrolidone).Dilute with water obtains dispersion.
C) missible oil (EC)
Be dissolved in 15 weight portion reactive compounds in the dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (concentration is 5% in each case).Dilute with water obtains emulsion.
D) emulsion (EW, EO)
Be dissolved in 40 weight portion reactive compounds in the dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (concentration is 5% in each case).Introduce this mixture in water and make equal phase emulsion by emulsifier (Ultraturax).Dilute with water obtains emulsion.
E) suspension (SC, OD)
In the ball mill that stirs, 20 weight portion reactive compounds are pulverized and adding dispersant, wetting agent and water or organic solvent, obtain reactive compound suspension in small, broken bits.Dilute with water obtains stable reactive compound suspension.
F) water-dispersible granule and water-soluble granular (WG, SG)
With the grinding in small, broken bits of 50 weight portion reactive compounds and adding dispersant and wetting agent, be made into water dispersible or water-soluble granular by commercial plant (as extruder, spray tower, fluid bed).Dilute with water obtains stable active compound dispersion or solution.
G) water dispersible pow-ders and water-soluble powder (WP, SP)
75 weight portion reactive compounds are ground in the rotor-stator mill and adding dispersant, wetting agent and silica gel.Dilute with water obtains stable active compound dispersion or solution.
2. the product of using without dilution
H) but dusting powder (DP)
Fully mix with the grinding in small, broken bits of 5 weight portion reactive compounds and with 95% kaolin in small, broken bits.But this obtains the dusting product.
I) particle (GR, FG, GG, MG)
With the grinding in small, broken bits of 0.5 weight portion reactive compound and in conjunction with 95.5% carrier.Current methods be extrude, atomized drying or bed process.The particle that this obtains using without dilution.
J) ULV solution (UL)
10 weight portion reactive compounds are dissolved in organic solvent such as the dimethylbenzene.The product that this obtains using without dilution.
Reactive compound can be directly, with its preparaton form or type of service prepared therefrom (but as directly spray solution, powder, suspension or dispersion, emulsion, oil dispersion, paste dusting product, broadcast sowing), by spraying, atomizing, dusting, broadcast sowing or water and use with material or particle form.Type of service depends on the purpose that is intended to fully; Be intended to guarantee in each case that the best of reactive compound of the present invention may distribute.
Moisture type of service can be prepared by emulsion concentrates, paste or wettable powder (sprayable powder, oil dispersion) by adding entry.Be preparation emulsion, paste or oil dispersion, can be with this material directly or be dissolved in back homogenizing in water in oil or the solvent by wetting agent, tackifier, dispersant or emulsifier.Yet, can also prepare by active substance, wetting agent, tackifier, dispersant or emulsifier with if suitable, concentrate and this concentrate that solvent or oil are formed are suitable for dilute with water.
Promptly can in relative broad range, change with the activity compound concentration in the preparation.Be generally 0.0001-10%, preferred 0.01-1%.
Reactive compound also can successfully be used for ultra low volume method (ULV), wherein can use to comprise the preparaton that surpasses 95 weight % reactive compounds, or even use the reactive compound that does not contain additive.
Various types of oil, wetting agent, adjuvant, weed killer herbicide, fungicide, other agricultural chemicals or bactericide all can add in the reactive compound, if suitable, just add (bucket mixes) before the next-door neighbour uses.These reagent usually can with reagent of the present invention with 1: 10-10: 1 weight ratio is mixed.
Compound I and II or mixture or corresponding preparaton be by the mixture with the antifungal effective dose, or Compound I and II handle harmful fungoid and maybe need to prevent and treat their plant, seed, soil, zone, material or space and use under situation about using separately.Use and before or after harmful fungoid infects, to carry out.
The fungicidal action of compound and mixture can confirm by following test:
With reactive compound separately or combined preparation become to contain the acetone or the DMSO liquid storage of 0.25 weight % reactive compound.Emulsifier Uniperol with 1 weight %
EL (based on the wetting agent with emulsification and peptizaiton of ethoxylated alkylphenol) adds in this solution, and water with this mixture diluted to desired concn.
Application Example-to give birth to the activity of the mould grape vine downy mildew that causes of single shaft by grape
Cultivar is sprayed to the drip point for the grape pot rattan leaf of " M ü ller-Thurgau " with activity compound concentration aqueous suspension as described below.The leaf downside being given birth to the mould moisture zoospore suspension of single shaft with grape in second day inoculates.Then grape vine is at first placed 24 ℃ steam-laden chamber to reach 48 hours, place 20-30 ℃ greenhouse to reach 5 days then.After during this period of time, once more plant is placed moist chamber to reach 16 hours, to promote the sporangiophore eruption.Naked eyes are measured the disease development degree on the leaf downside then.
The naked eyes that will infect leaf area are measured percentage and are changed into effectiveness with respect to the percentage of untreated control:
Use the Abbot formula to render a service (E) by following calculating:
E＝(1-α/β)·100
α corresponding to the fungal infection percentage of handling plant and
β is corresponding to the fungal infection percentage of (contrast) plant of being untreated.
Effectiveness is that the infect level of the level that infects of plant corresponding to the untreated control plant handled in 0 expression; Effectiveness is that 100 expression processing plants are infected.
The expection of active compound combinations is renderd a service and is used Colby formula [Colby, S.R. " Synergistic and the antagonism that calculate combinations of herbicides respond ", weeds (Weeds)
15, 20-22,1967] determine and with observed effectiveness relatively.
Colby formula: E=x+y-xy/100
Expection when the E working concentration is the mixture of the reactive compound A of a and b and B is renderd a service, represents with % with respect to untreated control,
Effectiveness when the x working concentration is the reactive compound A of a is represented with the % with respect to untreated control,
Effectiveness when the y working concentration is the reactive compound B of b is represented with the % with respect to untreated control.
Used control compounds is compd A and B, and it is known by the benomyl mixture described in the EP-A 988 790:
Table A-independent reactive compound
| Embodiment | Reactive compound | The concentration [ppm] of reactive compound in spray liquid | Render a service, with respect to the % of untreated control |
| 1 | - | Contrast (being untreated) | (84% infects) |
| 2 | I | 1 0.25 | 17 0 |
| 3 | II (benomyl) | 4 1 | 0 0 |
| 4 | Contrast A | 1 0.25 | 0 0 |
| 5 | Contrast B | 1 0.25 | 17 5 |
Table B-is according to mixture of the present invention
| Embodiment | The mixture concentration mixing ratio of reactive compound | The effectiveness of observing | The effectiveness of calculating *) |
| 6 | I+II 0.25+4ppm 1∶16 | 29 | 0 |
| 7 | I+II 1+1ppm 1∶1 | 41 | 17 |
*) effectiveness of using the Colby formula to calculate
Table C-comparative trial-by EP-A 988 790 known mixture
| Embodiment | The mixture concentration mixing ratio of reactive compound | The effectiveness of observing | The effectiveness of calculating *) |
| 8 | A+II 0.25+4ppm 1∶16 | 0 | 0 |
| 9 | A+II 1+1ppm 1∶1 | 0 | 0 |
| 10 | B+II 0.25+4ppm 1∶16 | 0 | 5 |
| 11 | B+II 1+1ppm 1∶1 | 5 | 17 |
*) effectiveness of using the Colby formula to calculate
Result of the test shows under all mixing ratios, the observed effectiveness of mixture of the present invention is significantly higher than the effectiveness of using the expection of Colby formula, and invalid in the control of Oomycete fungi by the benomyl mixture of the known contrast reactive compound of EP-A 988 790.
Claims (10)
1. Fungicidal mixture comprises following compound as active component with cooperative effective quantity:
1) triazolopyrimidine derivative of formula I:
With
2) benomyl of formula II:
2. Fungicidal mixture, with 100: 1-1: 100 weight ratio comprises formula I compound and formula II compound.
3. Fungicidal composition comprises the liquid or solid carrier and as claim 1 or 2 desired mixtures.
4. method of preventing and treating the Oomycete harmful fungoid comprises with the Compound I as claimed in claim 1 of effective dose and Compound I I and handles seed, soil or the plant that fungi, its habitat maybe need to prevent fungal attack.
5. as the desired method of claim 4, wherein simultaneously, i.e. associating or separately, or use Compound I as claimed in claim 1 and II successively.
6. as the desired method of claim 4, wherein the amount with 5-2000g/ha will be applied on the soil or plant that will prevent fungal attack as claim 1 or 2 desired mixtures.
7. as claim 4 or 5 desired methods, wherein use as claim 1 or 2 desired mixtures with the amount of 1-1000g/100kg seed.
8. as each desired method among the claim 4-7, it is mould wherein to prevent and treat the living single shaft of harmful fungoid grape.
9. seed comprises as claim 1 or 2 desired mixtures with the amount of 1-1000g/100kg.
10. Compound I as claimed in claim 1 and Compound I I are suitable for preventing and treating purposes in the composition of Oomycete fungi in preparation.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10327865 | 2003-06-18 | ||
| DE10327865.6 | 2003-06-18 | ||
| DE10332431.3 | 2003-07-16 |
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| Publication Number | Publication Date |
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| CN1805689A true CN1805689A (en) | 2006-07-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200480016628 Pending CN1805689A (en) | 2003-06-18 | 2004-06-08 | Fungicidal mixtures based on a trizolopyrimidine derivative |
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|---|---|
| CN (1) | CN1805689A (en) |
| ZA (1) | ZA200600460B (en) |
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