CN1800043A - Thick oil, super thick oil effluent purifier - Google Patents
Thick oil, super thick oil effluent purifier Download PDFInfo
- Publication number
- CN1800043A CN1800043A CN 200510129945 CN200510129945A CN1800043A CN 1800043 A CN1800043 A CN 1800043A CN 200510129945 CN200510129945 CN 200510129945 CN 200510129945 A CN200510129945 A CN 200510129945A CN 1800043 A CN1800043 A CN 1800043A
- Authority
- CN
- China
- Prior art keywords
- thick oil
- viscous crude
- cationic
- super thick
- flocculating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The effluent water purification agent in said invention for heavy crude, super heavy crude is made up of inorganic flocculants, cationic organic macromolecular flocculants or one of them and hyper-branched polymer, which could effectively remove oil and foreign substance from produced sewage of heavy crude, super heavy crude with the characterization as follows: rapid flocculation, stable floccule body, less adherence to the wall, less usage, low cost and so on, promising application foreground.
Description
The present invention relates to a kind of disposing polluted water in oil technology, be used for the sewage disposal technology of viscous crude, super viscous crude extraction liquid specifically.
Viscous crude is the quasi-oil that viscosity is big, gum asphaltic content is high, China's viscous crude aboundresources, and the viscosity of crude of some oil field block is higher, belongs to super viscous crude.It is very difficult that a large amount of colloids that are rich in the viscous crude, bituminous matter and petroleum acid isopolarity material cause condensed oil sewage to handle, chemical agents such as viscosity-depression agent, unblocking agent particularly in the viscous oil recovery process, have been added again, make that sewage emulsification is serious, oleaginousness height, complicated component, variation water quality is big, and when exploitation, adhesive tape from the stratum went out a large amount of mineralogical compositions, the water hardness height, and foreign matter content is big, along with extraction liquid water content constantly increases, more increased the sewage disposal difficulty.
Handle at condensed oil sewage, cationic high-molecular flocculant at present commonly used, adopt cationic-type polyacrylamide as the Liaohe Oil Field, this method is by charge neutralization oil in water emulsion and mechanical impurity in the water to be flocculated, reach the water purifying purpose, but it is because very fast by the charge neutralization process, the adition process of polyacrylamide, the stirring velocity of sewage etc. all can be brought very big influence to treatment effect, make the treatment effect instability, and the flco thickness that produces, be bonded at easily on the wall, increased the difficulty that flco is handled.
Chinese patent CN 01106030.1 has announced a kind of linear low-molecular weight polymer of amine and inorganic flocculating agent and composite effluent purification method of dithiocarbamate saline flocculating agent that has a plurality of hydroxy functional groups, though this method can be removed oil and other mechanical impuritys in the extraction liquid preferably, but because the dosage of treatment agent is excessive, need reach about 550mg/L, make processing cost quite high.
Purpose of the present invention just provides a kind of oil removing, remove that mechanical impurity is effective, the treatment agent consumption is few, processing cost is low and flco adheres to few viscous crude, super thick oil effluent purifier at wall.
Viscous crude of the present invention, super thick oil effluent purifier are made up of inorganic flocculating agent, cationic organic polymer coargulator or a kind of and hyperbranched polymer among both.Wherein inorganic flocculating agent is polymerize aluminum chloride, polyaluminium sulfate, bodied ferric sulfate, potassium aluminium sulfate, Tai-Ace S 150, ferric sulfate, titanium tetrachloride, polynite and composite inorganic flocculation agent etc.; Cationic organic polymer coargulator is the homopolymer of cationic-type polyacrylamide, cationic modified starch, modified-cellulose, modified chitosan, dimethyl diallyl ammonium chloride and multipolymer, polyoxyethylene trimethyl ammonium chloride etc.; Hyperbranched polymer is that the end has hydroxyl (OH), the end has amido (NH
2) or the end have carboxyl (the various hyperbranched polymers that have the end polar group such as COOH).The adding mode of this water purification agent each component is to add hyperbranched polymer earlier, adds inorganic flocculating agent, cationic organic polymer coargulator again, also the two can be mixed by a certain percentage the back and add.
Since the hyperbranched polymer in the viscous crude of the present invention, super thick oil effluent purifier component by a large amount of ends active group in its molecule and the polar material in the viscous crude by generation molecular interactions such as hydrogen bonds, oil droplet and mechanical impurity are accumulated in around its molecule that is bordering on ball-type, add the mating reaction of organic or inorganic flocculation agent, make this water purification agent can remove oil and the impurity in viscous crude, the extremely-viscous crude sewage effectively, it is fast to have the flco of generation, flco is stable, adheres to advantages such as few at wall.This water purification agent can also be applied to the processing of with serious pollution oil-refining chemical sewage, waste water from dyestuff etc., is a kind of novel water purification agent, has a extensive future.
Below by specific embodiment viscous crude of the present invention, super thick oil effluent purifier and using method thereof are elaborated.In following each embodiment, all make apparatus plug graduated cylinder carry out the sewage disposal experiment, sewage quantity is 500mL, temperature is 70 ℃, the order of the water purification agent each component being pressed hyperbranched polymer, inorganic flocculating agent, cationic organic polymer coargulator adds in the sewage, whenever add a kind of component, concussion graduated cylinder 50 times mixes treatment agent and sewage.Under wavelength 664nm, survey the transmittance and the oleaginousness of water after static 30 minutes with 722 type spectrophotometers.
Embodiment 1:
Effluent purifier consists of: polymerize aluminum chloride 90mg/L, have the hyperbranched polymer 30mg/L of end hydroxyl, and total dosage 120mg/L, analytical results sees Table 1.
Embodiment 2:
Sewage-treating agent consists of: polymerize aluminum chloride 90mg/L, and cationic-type polyacrylamide 15mg/L has the hyperbranched polymer 15mg/L of end hydroxyl, and total dosage is 120mg/L, and analytical results sees Table 1.
The table of comparative analysis as a result of table 1. sewage disposal
| Sewage-treating agent | The total dosage mg/L of sewage-treating agent | Transmittance/% | Oleaginousness (mg/L) | ||
| Former water | Water outlet | Former water | Water outlet | ||
| Polymerize aluminum chloride | 500 | 0 | 45.9 | 13400 | 362 |
| Cationic polyacrylamide | 120 | 0 | 89.6 | 13400 | 58 |
| Embodiment 1 | 120 | 0 | 95.4 | 13400 | 22 |
| Embodiment 2 | 120 | 0 | 98.0 | 13400 | 17 |
As seen from Table 1, handle extremely-viscous crude sewage with viscous crude of the present invention, super thick oil effluent purifier, the water outlet transmittance all surpasses 95%, and treatment effect obviously is better than inorganic polymerize aluminum chloride and cationic-type polyacrylamide flocculation agent.
Claims (6)
1. a viscous crude, super thick oil effluent purifier is characterized in that it is made up of inorganic flocculating agent, cationic organic polymer coargulator or a kind of and hyperbranched polymer among both.
2. viscous crude according to claim 1, super thick oil effluent purifier is characterized in that: described inorganic flocculating agent is polymerize aluminum chloride, polyaluminium sulfate, bodied ferric sulfate, potassium aluminium sulfate, Tai-Ace S 150, ferric sulfate, titanium tetrachloride, polynite and composite inorganic flocculation agent etc.
3. viscous crude according to claim 1, super thick oil effluent purifier is characterized in that: homopolymer that described cationic organic polymer coargulator is cationic-type polyacrylamide, cationic modified starch, modified-cellulose, modified chitosan, dimethyl diallyl ammonium chloride and multipolymer, polyoxyethylene trimethyl ammonium chloride etc.
4. viscous crude according to claim 1, super thick oil effluent purifier is characterized in that: hyperbranched polymer be the end have hydroxyl (OH), the end have amido (NH2) or the end have carboxyl (the various hyperbranched polymers that have the end polar group such as COOH).
5. viscous crude according to claim 1, super thick oil effluent purifier, it is characterized in that: the adding mode of described inorganic flocculating agent, cationic organic polymer coargulator and hyperbranched polymer adds inorganic flocculating agent, cationic organic polymer coargulator more successively for adding hyperbranched polymer earlier.
6, viscous crude according to claim 1, super thick oil effluent purifier, the adding mode that it is characterized in that described inorganic flocculating agent, cationic organic polymer coargulator and hyperbranched polymer is: add hyperbranched polymer earlier, add blended inorganic flocculating agent and cationic polymers type flocculation agent by a certain percentage again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101299454A CN100334013C (en) | 2005-12-13 | 2005-12-13 | Thick oil, super thick oil effluent purifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101299454A CN100334013C (en) | 2005-12-13 | 2005-12-13 | Thick oil, super thick oil effluent purifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1800043A true CN1800043A (en) | 2006-07-12 |
| CN100334013C CN100334013C (en) | 2007-08-29 |
Family
ID=36810305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101299454A Expired - Fee Related CN100334013C (en) | 2005-12-13 | 2005-12-13 | Thick oil, super thick oil effluent purifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100334013C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103755969A (en) * | 2014-01-14 | 2014-04-30 | 四川一欣环境科技有限公司 | Chitosan and poly-dimethyl diallyl ammonium chloride compound and preparation method thereof |
| CN103772605A (en) * | 2014-01-23 | 2014-05-07 | 中国海洋石油总公司 | Preparation method of cationic polymer |
| CN103818975A (en) * | 2014-03-14 | 2014-05-28 | 石家庄聚业化工助剂有限公司 | Purifier and preparation method thereof |
| CN105217895A (en) * | 2015-10-30 | 2016-01-06 | 无锡市嘉邦电力管道厂 | Heavy crude sewage water treating method |
| CN105540693A (en) * | 2016-01-07 | 2016-05-04 | 苏州法斯特信息科技有限公司 | Composite BOD removing material and preparing method thereof |
| CN106145257A (en) * | 2016-09-08 | 2016-11-23 | 合肥智慧殿投资管理有限公司 | A kind of condensed oil sewage inorganic agent and its preparation method and application |
| CN106905993A (en) * | 2017-03-24 | 2017-06-30 | 诗茵（海南）环保科技有限公司 | A kind of environment protection treating technique of mineral oil discarded object |
| CN107326122A (en) * | 2016-05-26 | 2017-11-07 | 许婷 | A kind of leather processing inorganic agent and preparation method thereof |
| CN108821402A (en) * | 2018-05-28 | 2018-11-16 | 福州兴创云达新材料科技有限公司 | A kind of preparation method of cation collagen flocculant |
| CN108975476A (en) * | 2018-07-24 | 2018-12-11 | 芜湖市棠华建材科技有限公司 | The composite modified water treatment agent of plant |
| CN109264819A (en) * | 2018-08-13 | 2019-01-25 | 大唐（北京）水务工程技术有限公司 | A kind of organic-inorganic composite degreaser and its preparation method and application |
| CN109422309A (en) * | 2017-09-04 | 2019-03-05 | 中国石油天然气股份有限公司 | Silicon removing agent and treatment process of thick oil sewage |
| CN110357306A (en) * | 2019-07-24 | 2019-10-22 | 杰瑞环境工程技术有限公司 | A kind of oily waste water preprocess method |
| CN111333165A (en) * | 2020-03-13 | 2020-06-26 | 西安三化机电科技有限公司 | Paint mist coagulant and preparation method thereof |
| CN112358022A (en) * | 2020-11-18 | 2021-02-12 | 浙江九环环境科技有限公司 | Flocculating agent and preparation method thereof |
| CN113979601A (en) * | 2021-11-24 | 2022-01-28 | 杭州大地海洋环保股份有限公司 | Method for treating oil stain wastewater |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU935481A1 (en) * | 1980-08-01 | 1982-06-15 | Горьковский Государственный Институт По Проектированию Предприятий Нефтеперерабатывающей И Нефтехимической Промышленности | Process for purifying effluents |
| AU5824794A (en) * | 1993-02-10 | 1994-08-29 | Russian-American Closed Joint-Stock Company | Polymer absorbent for use in purifying aqueous media contaminated by oil or oil products and a process for purifying such media |
| CN1216751A (en) * | 1998-09-15 | 1999-05-19 | 中国科学院生态环境研究中心 | Coagulation method for treating oil prodn. waste water of oil field polymers |
-
2005
- 2005-12-13 CN CNB2005101299454A patent/CN100334013C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103755969A (en) * | 2014-01-14 | 2014-04-30 | 四川一欣环境科技有限公司 | Chitosan and poly-dimethyl diallyl ammonium chloride compound and preparation method thereof |
| CN103772605A (en) * | 2014-01-23 | 2014-05-07 | 中国海洋石油总公司 | Preparation method of cationic polymer |
| CN103818975A (en) * | 2014-03-14 | 2014-05-28 | 石家庄聚业化工助剂有限公司 | Purifier and preparation method thereof |
| CN103818975B (en) * | 2014-03-14 | 2015-08-12 | 石家庄聚业化工助剂有限公司 | A kind of water purification agent and preparation method thereof |
| CN105217895A (en) * | 2015-10-30 | 2016-01-06 | 无锡市嘉邦电力管道厂 | Heavy crude sewage water treating method |
| CN105540693A (en) * | 2016-01-07 | 2016-05-04 | 苏州法斯特信息科技有限公司 | Composite BOD removing material and preparing method thereof |
| CN107326122A (en) * | 2016-05-26 | 2017-11-07 | 许婷 | A kind of leather processing inorganic agent and preparation method thereof |
| CN107354247A (en) * | 2016-05-26 | 2017-11-17 | 许婷 | A kind of leather processing inorganic agent and preparation method thereof |
| CN106145257A (en) * | 2016-09-08 | 2016-11-23 | 合肥智慧殿投资管理有限公司 | A kind of condensed oil sewage inorganic agent and its preparation method and application |
| CN106905993A (en) * | 2017-03-24 | 2017-06-30 | 诗茵（海南）环保科技有限公司 | A kind of environment protection treating technique of mineral oil discarded object |
| CN109422309A (en) * | 2017-09-04 | 2019-03-05 | 中国石油天然气股份有限公司 | Silicon removing agent and treatment process of thick oil sewage |
| CN108821402A (en) * | 2018-05-28 | 2018-11-16 | 福州兴创云达新材料科技有限公司 | A kind of preparation method of cation collagen flocculant |
| CN108975476A (en) * | 2018-07-24 | 2018-12-11 | 芜湖市棠华建材科技有限公司 | The composite modified water treatment agent of plant |
| CN109264819A (en) * | 2018-08-13 | 2019-01-25 | 大唐（北京）水务工程技术有限公司 | A kind of organic-inorganic composite degreaser and its preparation method and application |
| CN110357306A (en) * | 2019-07-24 | 2019-10-22 | 杰瑞环境工程技术有限公司 | A kind of oily waste water preprocess method |
| CN111333165A (en) * | 2020-03-13 | 2020-06-26 | 西安三化机电科技有限公司 | Paint mist coagulant and preparation method thereof |
| CN112358022A (en) * | 2020-11-18 | 2021-02-12 | 浙江九环环境科技有限公司 | Flocculating agent and preparation method thereof |
| CN113979601A (en) * | 2021-11-24 | 2022-01-28 | 杭州大地海洋环保股份有限公司 | Method for treating oil stain wastewater |
| CN113979601B (en) * | 2021-11-24 | 2023-09-19 | 杭州大地海洋环保股份有限公司 | Greasy dirt waste water treatment method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100334013C (en) | 2007-08-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100334013C (en) | Thick oil, super thick oil effluent purifier | |
| Katrivesis et al. | Revisiting of coagulation-flocculation processes in the production of potable water | |
| Zeng et al. | Feasibility investigation of oily wastewater treatment by combination of zinc and PAM in coagulation/flocculation | |
| Li et al. | Effects of papermaking sludge-based polymer on coagulation behavior in the disperse and reactive dyes wastewater treatment | |
| Lin et al. | Effect of Al (III) speciation on coagulation of highly turbid water | |
| Bouatay et al. | Use of the cactus cladodes mucilage (Opuntia Ficus Indica) as an eco-friendly flocculants: process development and optimization using stastical analysis | |
| Zhang et al. | Understanding the impact of chemical conditioning with inorganic polymer flocculants on soluble extracellular polymeric substances in relation to the sludge dewaterability | |
| AU2012215865B2 (en) | Method and apparatus for sludge flocculation | |
| CN100497193C (en) | High polymer composite coagulant for treatment of oily waste water and making method thereof | |
| Zhou et al. | Hydrophobic modification of cationic microblocked polyacrylamide and its enhanced flocculation performance for oily wastewater treatment | |
| Li et al. | Bio-refractory organics removal and floc characteristics of poly-silicic-cation coagulants in tertiary-treatment of coking wastewater | |
| Zhao et al. | Effect of Enteromorpha polysaccharides on coagulation performance and kinetics for dye removal | |
| CN103265104A (en) | Nano powder-organic polymer composite flocculating agent | |
| US11242492B2 (en) | Methods of treating tailings | |
| CN101786739A (en) | Oil extraction wastewater treatment method used for oilfield reinjection | |
| Kamaruddin et al. | Sustainable Treatment of Palm Oil Mill Effluent (POME) by using Pectin and Chitosan in Jar Test Protocol –Sequential Comparison | |
| CN111453827A (en) | Combined treating agent for oily paint spraying wastewater and using method thereof | |
| Wu et al. | Understanding synergistic mechanisms of silicate decorated polyaluminium chloride and organic polymer flocculation for enhancing polymer-flooding wastewater treatment | |
| Lee et al. | Improvement of flocculation efficiency of water treatment by using polymer flocculants | |
| AU715446B2 (en) | Enhanced flocculation of minerals slurry with polymer blends | |
| WO2013060280A1 (en) | Sludge dewatering with dual polymer conditioning | |
| JP3726294B2 (en) | Muddy water treatment method | |
| JP6073109B2 (en) | Decolorization method of wastewater subjected to anaerobic biological treatment | |
| Zeng et al. | Experimental study on chitosan composite flocculant for treating papermaking wastewater | |
| CN111302600A (en) | Conditioner for improving dewatering performance of sludge in water supply plant and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070829 Termination date: 20101213 |