CN1796305A - Biomembrane draining treament system and treating method - Google Patents
Biomembrane draining treament system and treating method Download PDFInfo
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- CN1796305A CN1796305A CNA2004101024404A CN200410102440A CN1796305A CN 1796305 A CN1796305 A CN 1796305A CN A2004101024404 A CNA2004101024404 A CN A2004101024404A CN 200410102440 A CN200410102440 A CN 200410102440A CN 1796305 A CN1796305 A CN 1796305A
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- 238000001914 filtration Methods 0.000 claims abstract description 22
- 239000012528 membrane Substances 0.000 claims abstract description 12
- 241000894006 Bacteria Species 0.000 claims description 50
- 239000010408 film Substances 0.000 claims description 31
- 239000010409 thin film Substances 0.000 claims description 29
- 230000006578 abscission Effects 0.000 claims description 24
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Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Biological Treatment Of Waste Water (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
This invention describes an innovative biomembrane water-filtration system, comprising a biological filtration bed section and a membrane separation section. The biological filtration bed section, operated either in the fixed bed mode or in the moving bed mode, has such two functions as biological treatment and quick filtration, and has such advantages as high load, high efficiency, high stability and simplicity for operation. The membrane separation section uses membrane filtration modules to remove the particles in the effluent water from the biological filtration bed section, thus producing high quality clarified water.
Description
Technical field
The present invention relates to a kind of biomembrane draining treament system of innovation, formed by " bacteria bed district " and " divided thin film abscission zone ".
Background technology
(membrane bioreactor MBR) is applied to two stage biological and handles film usually, to remove COD, suspended solids (SS) and nitrogen-containing pollutant etc. from bioreactor technology.Because have the characteristic of biological treatment and membrane filtration, its water quality treatment can reach the effect near tertiary treatment, therefore also be fit to as the waste water recycling pretreatment unit.At present the more sophisticated MBR technology of development mainly belongs to solid-liquid separating type (solid-liquidseparation type), and it utilizes ultra-filtration (UF) or micro-filtration (MF) film to separate concentrated biological mud usually, to obtain the good flowing water water quality that goes out.
Because water flux density (flux, the m of unit of thin-film module
3/ m
2.day) be one of MBR technology most important control parameters, its hydraulic detention time (HRT), volume load, thin-film module pressure with MBR is relevant, and relate to and building and running cost, and the factor that influences flux is exactly a SS concentration except that water quality treatment and SS character.Though the manageable relatively amount of pollutant of SS concentration height is also higher, sludge concentration Gao Yihui causes the reduction of MBR flux and increasing of working pressure.
This case applicant announces No. 593167 and discloses a kind of water treatment method that carries out from bio-reactor in film in Taiwan, this reactor comprises a groove that includes the microorganism mixed solution; A plurality of porous carriers in this mixed solution; And a filtration module that is immersed in this mixed solution, it has one and penetrates side and this mixed solution and only see through this filtration module and this and penetrate side and be fluid communication.This method comprises an influent stream water is imported mixed solution in this groove; One negative pressure source is applied to this penetrates side, make liquid in this groove see through this filtration module and penetrate effluent from this and go out this groove; And these a plurality of porous carriers are contacted with this filtration module by mode to this mixed solution aeration, so reduce the incrustation on this filtration module.Though the technology of this patent can solve the partly problem of incrustation, but still its limitation arranged, because the microorganism mud and the filtration module of biological treatment are in together in the same reaction groove, make and keep higher suspension solids content (microorganism mud height simultaneously, be easy to decomposing pollutant), and the high water flux density of thin-film module becomes awkward.This summary of the invention of announcing No. 593167 Taiwan patent will be merged in this case in the reference mode.
Summary of the invention
Main purpose of the present invention is to provide a kind of and overcomes known film and can not have the higher suspension solids content simultaneously concurrently and keep the new technology of the shortcoming of high water flux density from bio-reactor.
In order to realize the foregoing invention purpose, the present invention proposes to utilize the notion of biological treatment and solid-liquid separation function distinguishing, the biomembrane draining treament system of being finished comprises bacteria bed district (biologicalfiltration bed zone) and divided thin film abscission zone (membrane separation zone).The bacteria bed district utilizes porous carrier (carriers) as Biomedia (media), because of it has the chance that vast surface-area can increase suspended solids in the waste water (SS) interception, and provide space as microorganic adhesion, growth and propagation, therefore can accumulate the biofilm microorganisms of a large amount of and specific group, help to reach the purpose of removing all contaminations.Because the bacteria bed district is a kind of mode of sludge immobilization growth, the SS concentration that goes out flowing water can reach very low degree, significantly alleviate the load of subsequent thin film disengaging zone solid-liquid separation, so, the flux of membrane filtration module (module) and stability obviously increase, and can produce the second best in quality clarifying treatment water.And, effective control to membrane filtration module surface dirt (fouling), reduce film pressure (transmembrane pressure) and energy waste and back flushing frequency, and then effectively prolong membrane filtration module work-ing life, also can shorten the hydraulic detention time (HRT) of treatment trough and reduce the volume in divided thin film abscission zone relatively, help the cost that reduces construction and Operation and Maintenance.
The present invention has following advantage:
Promote treatment trough efficient;
The mud solid-liquid separation is simple;
The functional stabilization height, water quality treatment is good;
Be applicable to low concentration wastewater, can under high hydraulic load, operate;
Reduce and be provided with and running cost.
Embodiment
The present invention discloses a kind of biomembrane draining treament system, comprises bacteria bed district groove and divided thin film abscission zone groove, and wherein this bacteria bed district groove comprises mixed solution and a plurality of porous carriers in this mixed solution that include microorganism; And this divided thin film abscission zone groove comprises the formed treating water of flowing water and that goes out that is received from this bacteria bed district groove and is immersed in the subsurface filtration module of this treating water, and it has one and penetrates side and this treating water and only see through this filtration module and this and penetrate side and be fluid communication.
Preferable, this bacteria bed district groove further comprises an aerator that is arranged at this bacteria bed district trench bottom.Better, this bacteria bed district groove further comprises one and is arranged in this bacteria bed district groove and is positioned at the supporting network of this aerator top, is used to prevent the bottom of these a plurality of porous carriers near this bacteria bed district groove.Better, this bacteria bed district groove further comprises one and is arranged in this bacteria bed district groove and is positioned at the filter screen of this a plurality of porous carriers top, is used to prevent that these a plurality of porous carriers from flowing out this bacteria bed district groove with going out flowing water.
Preferable, this divided thin film abscission zone groove further comprises an aerator that is arranged at the bottom in this divided thin film abscission zone groove.
Preferable, this porous carrier is to be made by inorganic or organic porous material.
Preferable, this porous carrier is a foam polymer precursor.
Preferable, this filtration module comprises micro-filtration film (microfiltration (MF) membrane), ultrafilter membrane film (ultrafiltration (UF) membrane), ceramic membrane (ceramic membrane), chemically woven fabrics film, the film of weaving cotton cloth, porous reticulated structure thing or their mixing.
The present invention also discloses a kind of water treatment method that uses biomembrane draining treament system of the present invention, comprise and an influent stream water imported this bacteria bed district groove and after wherein being detained for some time, flow out this bacteria bed district groove, wherein at least one part pollutent in this influent stream water decomposed for Institute of Micro-biology in for some time that is stranded in this bacteria bed district groove; The flowing water that goes out of this bacteria bed district groove is imported this divided thin film abscission zone groove; Reach the side that penetrates that negative pressure source is applied to this filtration module, make treating water in this divided thin film abscission zone groove see through this filtration module and penetrate effluent from this and go out, so the pollutent of lower aq is arranged compared to this influent stream glassware for drinking water from the effusive through-fall of this divided thin film abscission zone groove.
Preferable, this porous carrier is to operate with fixed bed or moving-bed mode, wherein microorganism mud or suspended solids are blocked or are attached on the porous carrier, to carry out the biological decomposition reaction of pollutent.
Preferable, this bacteria bed district groove is to operate with aerobic (aerobic), anoxic (anoxic) or anaerobism (anaerobic) mode.
The present invention is the processing of the waste water in described " water treatment " general reference tap water, tap water, municipal effluent, industry and other source in full.
Disclosed biomembrane draining treament system is the innovation biological treatment of waste water system in conjunction with " bacteria bed district " and " divided thin film abscission zone ", comprises the configuration of integrated configuration and groove-splitting, respectively as shown in Figures 1 and 2.
The influent stream water conservancy is quantitatively squeezed into bacteria bed district reactive tank 10 with influent stream water pump 3, see through gas blower 6 squeeze into air or oxygen 7 to the aerator (not being shown among the figure) of reactive tank 10 bottoms, bacteria bed district so that the required oxygen of biological treatment system in the bacteria bed district reactive tank 10 to be provided.Gas 7 also can be hydrogen, nitrogen or the carbonic acid gas that is used for the anaerobic microflora, perhaps for being used for nitrogen, methane or the biogas of anaerobe system.The present invention adds porous biological carrier 11 in bacteria bed district reactive tank 10, it can use inorganic or organic porous material to make, for example pottery, foam polymer precursor etc.This porous biological carrier 11 has the chance that vast surface-area can increase suspended solids in the waste water (SS) interception, and provide space as microorganic adhesion, growth and propagation, therefore can accumulate the biofilm microorganisms of a large amount of and specific group, help to reach the purpose of removing all contaminations.This bacteria bed district reactive tank 10 from the bottom one highly the place be provided with a bottom filter screen 12 support this porous biological carrier 10 avoid the precipitation be affixed on the bottom; And from the top one highly the place be provided with a upper sieve 13 and prevent that this porous biological carrier 10 from flowing out these bacteria bed district reactive tanks 10.
Go out flowing water and be imported into a divided thin film abscission zone reactive tank 20 by these reactive tank 10 tops, bacteria bed district are effusive, be provided with a membrane filtration module 21 in it, see through gas blower 6 ' squeeze into air or oxygen 7 ' to the aerator 22 of reactive tank 20 bottoms to provide further biological treatment required oxygen.Gas 7 ' also can be the hydrogen, nitrogen or the carbonic acid gas that are used for the anaerobic microflora, perhaps for being used for nitrogen, methane or the biogas of anaerobe system.Penetrate liquid (permeate) and promptly go out flowing water 9, see through out flowing water pump 8 and extract out.
The present invention has and promotes that treatment trough efficient meets the water quality standard of releasing, reduces secondary pollution, advantages such as the mud solid-liquid separation is simple, high stability, especially be fit to handle under high hydraulic load, operate, be provided with and running cost to reduce, suit the demand of present industry fully.Be highly suitable for the characteristic that low concentration wastewater is handled based on biomembrane draining treament system of the present invention, also can be referred to as a kind of senior biologic treating technique on the location.
The comparison of the technology of the present invention and traditional active sludge handling procedure can find out obviously that treatment scheme significantly simplifies, as shown in Figure 3.The water quality treatment of the technology of the present invention is good, and the water quality that adds after sand filtration and UF filter with the traditional active sludge handling procedure is close, and land area only is the traditional active sludge program half.
Scope and the object of the technology of the present invention in practical application comprises as two stage biological and handle to remove COD in the waste water, uses flowing water and can meet the water quality standard of releasing, or well can include the recycling system in because of water quality.Also can be serially connected with after the existing two stage biological treatment system, remove difficult decomposing organic matter in the waste water, reduce the tertiary treatment cost.Still can be applicable to the former water pre-treatment of tap water in addition, remove organism, ammonia nitrogen and nitrate nitrogen etc., and surface water and underground water regulation, remove organism, nitrogen-containing pollutant etc. in the water.
The present invention will further be understood by following embodiment, and this embodiment but not is used to limit the scope of the invention as illustrative purposes only.
Description of drawings
Fig. 1 shows the synoptic diagram of biomembrane draining treament system of the present invention, and wherein " bacteria bed district " and " divided thin film abscission zone " is integrated configuration.
Fig. 2 shows the synoptic diagram of biomembrane draining treament system of the present invention, and wherein " bacteria bed district " and " divided thin film abscission zone " is the groove-splitting configuration.
Fig. 3 shows the process block diagram of microbial film drainage handling procedure of the present invention and conventional process program.
Fig. 4 goes out the flowing water flux to the mapping of time, its orbicular spot be the prior art film from bio-reactor program (MBR), square points is represented microbial film drainage handling procedure of the present invention (BioMF).
Fig. 5 was a film pressure to the mapping of time, its orbicular spot be the prior art film from bio-reactor program (MBR), square points is represented microbial film drainage handling procedure of the present invention (BioMF).
What Fig. 6 showed microbial film drainage handling procedure of the present invention goes out flowing water COD and the influent stream water COD mapping to the time.
Fig. 7 removes rate to the mapping of time for COD, its orbicular spot be the prior art film from bio-reactor program (MBR), square points is represented microbial film drainage handling procedure of the present invention (BioMF).
Reference numeral
3.. influent stream water pump 6,6 ' .. gas blower 7,7 ' .. air
Go out flowing water 8.. go out flowing water pump 9..
10.. bacteria bed district reactive tank 11.. porous biological carrier
12.. bottom filter screen 13.. upper sieve
20.. divided thin film abscission zone reactive tank 21.. membrane filtration module
22.. aerator
Embodiment
Embodiment and reference examples
The embodiment part, the present invention's (BioMF method) carries out function and effect comparison with the prior art film from bioreactor process (MBR method), below will be divided into explanations such as material, equipment, method, function and effect:
(1) material, apparatus and method for
The waste water that present embodiment is primarily aimed at certain the chemical research institute district test that experimentizes is to inquire into and the relatively function and the effect of the inventive method and MBR method.Mould plant distributing style such as Fig. 1 that present embodiment adopts, mould plant comprise inflow pump, outflow pump, under meter, BioMF reactive tank, air compressor machine, various bucket groove etc.Wherein, rectangle BioMF reactive tank is the acryl manufacturing, and effective volume is 24L, and wherein 16L is bacteria bed district and all the other 8L are the divided thin film abscission zone.
The filling porous property of the volume carrier in bacteria bed district about 70%, it is compressible polyurethane (Polyurethane is called for short a PU) foaming carrier, and it is fan-shaped that carrier is, and every carrier diameter is 2.2cm, and thickness is 2cm, volume is 4.5cm
3, its essential property is as shown in following table:
Density | Tensile strength | The rate of extending |
28±5(kg/m 3) | 0.8~0.84(kg/cm 2) | 240%~250% |
Divided thin film disposes membrane filtration module in the abscission zone, comprises one group of vacuum pressure gauge and tubular type peristaltic pump, and the one group of air flowmeter of arranging in pairs or groups, and carries out aeration by the bottom land aeration head and mixes and oxygen supply.Membrane filtration module adopts the independently developed film filter material of applicant, is with the manufacturing of polyester (PET) material, belongs to the netted filter material of opening hole, and average hole diameter size is 20 μ m.This membrane filtration module comprises a square casket and is fixed in the interior two-layer flat reticulated structure thing of this square casket, and a spacing that wherein has 2mm between this two-layer tabular reticulated structure thing flows channel as crossing film water, and is provided with the supporting structure thing in this channel.Edge is sealed around this square casket only stays one to go out overflow pipe and communicate with this passage, and the reticulated structure object plane of its both sides amasss (filtration area) about altogether 855cm
2
(2) function and effect
The function of BioMF program of the present invention and preceding case MBR program and effect comparison are illustrated with regard to membrane filtration module flux (flux), mistake film pressure (TMP, transmembrane pressure), COD removal ability etc. respectively.
1. flux ratio
In the experimental session, the membrane filtration module variations of flux of BioMF and MBR program is shown in Fig. 4.Starting initial stage flux is strengthened gradually by little, and the flux of BioMF program can reach about 0.4~0.5m after 15 days
3/ m
2And the flux of MBR program only can maintain 0.2m .day,
3/ m
2.day about, the flux of BioMF obviously is better than the MBR program.In other words, the thin-film module of BioMF can be smaller, helps just to be set as this reduction.
2. cross film pressure relatively
In the experimental session, the membrane filtration module of BioMF and MBR program is crossed the film pressure variation and is shown in Fig. 5.The starting initial stage crosses film pressure and strengthens gradually along with flux changes by little, and peak pressure (is equivalent to 0.2kg/cm about 20kPa
2) about, but (be equivalent to 0.8kg/cm above 80kPa with the pressure of period MBR program
2), the mistake film pressure of BioMF is obviously low than MBR program, and power cost is certain also lower.
3.COD the removal ability relatively
The BioMF program is in the variation of experimental session into and out of flowing water COD as seen from Figure 6, and influent stream water COD concentration range is very big, between 100~600mg/L, go out flowing water COD concentration then quite stable maintain between 15~60mg/L.
If relatively BioMF and MBR program are at experimental session COD clearance, the BioMF program can surpass 90% at the clearance of experimental session COD as seen from Figure 7, also obviously is better than MBR program (clearance of COD on average about 85%).
Confirm that from above experimental result being provided with of bacteria bed of the present invention district can promote known film going out the flowing water flux, reduce it and cross film pressure and promote its COD and remove ability from bio-reactor.
Claims (11)
1. a biomembrane draining treament system comprises bacteria bed district groove and divided thin film abscission zone groove, and wherein this bacteria bed district groove comprises mixed solution and a plurality of porous carriers in this mixed solution that include microorganism; And this divided thin film abscission zone groove comprises the formed treating water of flowing water and that goes out that is received from this bacteria bed district groove and is immersed in the subsurface filtration module of this treating water, and it has one and penetrates side and this treating water and only see through this filtration module and this and penetrate side and be fluid communication.
2. biomembrane draining treament system as claimed in claim 1, wherein this bacteria bed district groove further comprises an aerator that is arranged at this bacteria bed district trench bottom.
3. biomembrane draining treament system as claimed in claim 1, wherein this divided thin film abscission zone groove further comprises an aerator that is arranged at the bottom in this divided thin film abscission zone groove.
4. biomembrane draining treament system as claimed in claim 2, wherein this bacteria bed district groove further comprises one and is arranged in this bacteria bed district groove and is positioned at the supporting network of this aerator top, is used to prevent the bottom of these a plurality of porous carriers near this bacteria bed district groove.
5. biomembrane draining treament system as claimed in claim 2, wherein this bacteria bed district groove further comprises one and is arranged in this bacteria bed district groove and is positioned at the filter screen of this a plurality of porous carriers top, is used to prevent that these a plurality of porous carriers from flowing out this bacteria bed district groove with going out flowing water.
6. biomembrane draining treament system as claimed in claim 1, wherein this porous carrier is to be made by inorganic or organic porous material.
7. biomembrane draining treament system as claimed in claim 1, wherein this porous carrier is a foam polymer precursor.
8. biomembrane draining treament system as claimed in claim 1, wherein this filtration module comprises micro-filtration film, ultrafilter membrane film, ceramic membrane, non-woven membrane, the film of weaving cotton cloth, porous reticulated structure thing or their mixing.
9. water treatment method that uses each described biomembrane draining treament system in the claim 1 to 8, comprise and an influent stream water imported this bacteria bed district groove and after wherein being detained for some time, flow out this bacteria bed district groove, wherein at least one part pollutent in this influent stream water decomposed for Institute of Micro-biology in for some time that is stranded in this bacteria bed district groove; The flowing water that goes out of this bacteria bed district groove is imported this divided thin film abscission zone groove; Reach the side that penetrates that negative pressure source is applied to this filtration module, make treating water in this divided thin film abscission zone groove see through this filtration module and penetrate effluent from this and go out, so the pollutent of lower aq is arranged compared to this influent stream glassware for drinking water from the effusive through-fall of this divided thin film abscission zone groove.
10. method as claimed in claim 9, wherein this porous carrier is to operate with fixed bed or moving-bed mode, wherein microorganism mud or suspended solids are blocked or are attached on the porous carrier, to carry out the biological decomposition reaction of pollutent.
11. method as claimed in claim 9, wherein this bacteria bed district groove is to operate with aerobic, anoxic or anaerobism mode.
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CN103459331A (en) * | 2011-03-31 | 2013-12-18 | 株式会社久保田 | Sewerage clarification facility |
TWI448436B (en) * | 2012-05-30 | 2014-08-11 | Univ Tamkang | Biofilm filtration system |
CN105621605A (en) * | 2016-02-26 | 2016-06-01 | 江苏万城清逸环保有限公司 | Treatment device for wastewater filtered by biological membrane |
CN105693021A (en) * | 2016-02-26 | 2016-06-22 | 江苏万城清逸环保有限公司 | Biomf mobile emergency water purification system |
CN110627204A (en) * | 2019-09-25 | 2019-12-31 | 苏伊士水务工程有限责任公司 | Carrier fixed bed bioreactor and water treatment system |
CN113636721A (en) * | 2021-08-12 | 2021-11-12 | 河南工业大学 | Device and method for treating secondary effluent of sewage plant |
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