CN1785495A - Bubbling tower reactor having damping internal construction member - Google Patents
Bubbling tower reactor having damping internal construction member Download PDFInfo
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- CN1785495A CN1785495A CN 200510061602 CN200510061602A CN1785495A CN 1785495 A CN1785495 A CN 1785495A CN 200510061602 CN200510061602 CN 200510061602 CN 200510061602 A CN200510061602 A CN 200510061602A CN 1785495 A CN1785495 A CN 1785495A
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- damping
- internal construction
- construction member
- bubbling column
- column reactor
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- 238000013016 damping Methods 0.000 title claims abstract description 127
- 230000005587 bubbling Effects 0.000 title claims abstract description 26
- 238000010276 construction Methods 0.000 title claims description 58
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000012530 fluid Substances 0.000 claims description 11
- 230000002093 peripheral effect Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 abstract description 26
- 238000012546 transfer Methods 0.000 abstract description 17
- 239000007789 gas Substances 0.000 description 26
- 238000002474 experimental method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000005764 inhibitory process Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 230000009102 absorption Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000011800 void material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000003321 amplification Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006315 carbonylation Effects 0.000 description 1
- 238000005810 carbonylation reaction Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000005514 two-phase flow Effects 0.000 description 1
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Abstract
A bubbling column reactor with internal damping member features that said internal damping member is coaxially installed in the reaction region above gas distributor for suppressing the flow speed in central region to make the radial speed distribution more uniform and interferring the flow field to promote local turbulence and increase gas-liquid mass transfer speed.
Description
Technical field
The present invention relates to a kind of solution-air bubbling column reactor or gas-liquid-solid three-phase bubble column reactors, especially have the bubbling column reactor of damping internal construction member, be used for the heterogeneous reaction or the gas absorption operation of various chemical process.
Background technology
Bubbling column reactor is widely used in many fields such as chemical industry, the energy, environment, biochemistry, is used for the mass transfer and the operation of gas-liquid two-phase or gas-liquid-solid three-phase, processes such as for example oxidation, hydrogenation, carbonylation, halogenation, fermentation, absorption.The industry bubbling column reactor maximizes at present day by day.A major issue during bubble tower amplifies, be the fluid axial flow velocity distribute diametrically inhomogeneous: in the tower central area, the solution-air two-phase upwards flows, and flow velocity is higher; In the zone near the tower wall, solution-air flows downward, and flow velocity is lower.Center gas holdup height, the near wall region gas holdup is low.Simultaneously, tower center two-phase flow velocity also increases along with the increase of tower diameter.Like this, when bubble tower amplifies, under high gas speed, velocity flow profile and gas holdup distribute will become more inhomogeneous especially.Computer simulation results shows, is the large-scale bubble tower of 6m for diameter, and when empty tower gas velocity during at 0.3 meter, central liquid speed may reach 4～5m/s, and gas speed is then higher.This just may cause gas from the short circuit of tower center, makes the gas-liquid loose contact, causes difficulty to amplification.For some oxidation reactions, the short circuit of gas also can cause the rising of tail gas oxygen concentration, brings potential safety hazard.Bubble tower inner member that propose and industrial employing mostly is for the consideration that improves the gas-liquid mixed state in the document at present, for example guide shell, multilayer insulating panel, paddle, or the like, also do not see and adopt inner member to improve the radially-arranged report of gas-liquid flow velocity with mobile obstacle effect.
Summary of the invention
The object of the present invention is to provide a kind of bubbling column reactor that has damping internal construction member that suppresses solution-air flow velocity inequality in the bubble tower, prevents the gas short circuit, strengthens mass transfer, amplifies easily.
The bubbling column reactor that has damping internal construction member of the present invention mainly comprises tower body, gas distributor, it is characterized in that damping internal construction member, damping internal construction member and the tower body coaxial line of device obstruction fluid motion in the reaction zone above gas distributor.
Need only satisfied for the damping internal construction member that is provided with: 1) have certain damping area perpendicular to fluid flow direction; 2) have certain circulation area, pass through to allow fluid; 3) there is the distribution of a definite form diametrically in the damping area, and in the central area, the damping area density is bigger, and outer peripheral areas damping area density is less.This is because central area rate of flow of fluid height need more damping area to come just can make flow velocity to be inhibited, and the outer peripheral areas rate of flow of fluid is less, does not need too many damping area.Therefore the damping internal construction member of the present invention's proposition has intensive, the peripheral sparse feature in center.
In principle, the peripheral maximum gauge of damping internal construction member or radical length and bubbling column reactor diameter ratio can be got any numerical value (0 is the center, and 1 is the wall position) between 0～1.If but damping internal construction member diameter or length are too small then sphere of action is limited, be difficult to make the flow velocity of central area effectively to be suppressed; If there is no need,, do not need to suppress because the flow velocity outside the central area is less and the damping internal construction member diameter is excessive.Measure according to velocity flow profile, suitable damping internal construction member peripheral diameter or radical length and bubbling column reactor diameter ratio are 0.1～1.0, and preferred diameter ratio is 0.2～0.6.
Damping internal construction member comprises a plurality of damping units, the number of damping unit or packing density require to determine according to the damping to velocity flow profile: if damping unit is crossed the requirement that does not reach effective inhibition center flow velocity at least, if and damping unit too much may make flow velocity be subjected to excessive inhibition, form new uneven distribution, even form flow dead in the central area.The present invention adopts the notion of damping area density to determine the packing density of damping unit, the damping area density is defined as the damping area of damping internal construction member in the unit reactor volume, and its computing formula is: all the overall reactor of the damping area of damping internal construction members/contain inner member is long-pending.Calculate test according to a large amount of flow measurements and hydrodynamics, the suitable damping area density that the present invention provides is 0.05～5.0m
2/ m
3, preferred damping area density is 0.20～2.0m
2/ m
3In case after the value of damping area density is determined, just can calculate the size and the quantity of required damping unit.
The present invention is because at the bubble tower reaction zone, the damping internal construction member that has been the reactor liquid level is following, gas distributor is above regional center device, convection cell mobile applies certain inhibition, can suppress the too fast flow velocity in central area effectively, makes the radial distribution of speed more even.Simultaneously,, promote local turbulence, improve gas-liquid mass transfer speed, process is strengthened by the interference of damping internal construction member stream field.The present invention is applicable to any type of gas-liquid or the solid bubbling column reactor of gas-liquid, for example top has the bubbling column reactor of expanding reach, top has the bubbling column reactor of rectifying section, GAS ABSORPTION section, particle and liquid foam segregation section, and any improvement to the reactor other parts does not influence the scope of application of the present invention.
Description of drawings
Fig. 1 is the bubbling column reactor schematic diagram of band damping internal construction member of the present invention;
Fig. 2 is a radial pattern structural damping sheet schematic diagram;
Fig. 3 is the annular ring damping fin schematic diagram that concentric circles connects;
Fig. 4 is netted damping fin schematic diagram;
Fig. 5 is the fin-type structural damping sheet schematic diagram that is staggered;
Fig. 6 is liquid axial velocity profile figure, and abscissa R is the dimensionless radial coordinate among the figure, is defined as radial coordinate/bubble tower radius, and R=0 is the center, and R=1 is the wall position; The liquid axial velocity of ordinate for measuring, speed are upwards to flow on the occasion of expression, and negative value is represented to flow downward.
The specific embodiment
With reference to Fig. 1, have the bubbling column reactor of damping internal construction member, comprise tower body 1, gas distributor 3, it is characterized in that the damping internal construction member 2 of device obstruction fluid motion in the reaction zone above gas distributor, damping internal construction member 2 and tower body coaxial line.In the diagram instantiation, damping member 2 is made up of vertical rod and a plurality of damping unit that the bottom is fixed on bubble tower bottom or the gas distributor.A plurality of damping units perpendicular to vertical rod and vertically each interval be installed in the vertical rod.The damping unit fluid flow plays inhibition, its shape can be a various ways, for example can be radial pattern structure sheet (Fig. 2), also can be the annular ring (Fig. 3) that connects of concentric circles or central area damping circular net (Fig. 4) greater than the outer peripheral areas damping, or staggered fin-type structure (Fig. 5).
The installation of damping internal construction member 2 can be adopted multiple mode, for example also can each damping unit or damping unit combination radially be strained unsettled being fixed on the bubble tower wall with many one metal wires or thin bar.
Embodiment 1
At diameter is the axle central area of the bubbling column reactor of 500mm, high 4000mm, in the conversion zone of the top of gas distributor and bubble tower liquid level below by the fixing damping member of a central upright stanchion, damping member has 14 actinomorphic damping units as shown in Figure 2, its diameter is 250mm, adjacent damping unit spacing is 200mm, damping unit bottom is apart from gas distributor 200mm, and damping unit topmost flushes with liquid level.The damping area density is 0.35m
2/ m
3
Experiment is carried out in air-aqueous systems, and the later liquid level of bubbling is 3000mm, empty tower gas velocity 0.62m/s.Midpoint between distance distributor 2250mm, two damping units is measured Different Diameter to locational axial velocity, and the fluid velocity radial distribution after more not adding damping internal construction member then and damping internal construction member being installed the results are shown in Fig. 6.
The velocity flow profile of void tower reactor is inhomogeneous, central area liquid speed is up to 1.2m/s, and after adding damping internal construction member, outwards move the position that Peak Flow Rate occurs, maximum also drops to 0.88m/s, illustrates that adding damping internal construction member has suppressed the too high rate of flow of fluid in central area afterwards effectively.
Embodiment 2
Experiment condition is identical with embodiment 1, adopts chemical absorption method to measure gas-liquid mass transfer speed, the gas Liquid Mass Transfer Coefficient k after more not adding damping internal construction member then and damping internal construction member being installed
lα the results are shown in table 1.
The gas Liquid Mass Transfer Coefficient of void tower reactor is 0.41, adds after the damping internal construction member described in the embodiment 1, and mass tranfer coefficient is increased to 0.49, and mass transfer rate has improved 20%.Hydrodynamic turbulence has been strengthened in the interference that the damping internal construction member stream field is described, has significantly improved mass transfer rate.
The bubble tower gas Liquid Mass Transfer Coefficient that table 1 void tower is measured when adopting different inner member size
| Experiment condition | The undamped member | Embodiment 2 | Comparative Examples 3 | Comparative Examples 4 |
| Mass tranfer coefficient k lα(l/s) | 0.41 | 0.49 | 0.43 | 0.55 |
Comparative Examples 1
In flow-speed measurement experiment, the number of damping unit in the reactor is doubled, adjacent damping unit spacing narrows down to 100mm, the damping area of the damping internal construction member that the unit volume reactor comprises, promptly the damping area density is 0.7m
2/ m
3, other condition is identical with embodiment 1.Measurement result also is shown in Fig. 6.Can see that therefrom though the flow velocity of central area significantly reduces after the adding damping internal construction member, flow velocity is subjected to excessive inhibition, especially in the position near central axis, almost forms the dead band.The damping area density that this routine damping internal construction member is described is excessive.Certainly, if improve the inner member cellular construction, suitably reduce the damping area at center position, the damping member of this area density also is desirable.
Comparative Examples 2
In flow-speed measurement experiment, with one times of the decreased number of damping unit in the reactor, adjacent damping unit spacing increases to 400mm, and the damping area density is 0.18m
2/ m
3, other condition is identical with embodiment 1.Measurement result also is shown in Fig. 6.Can see that therefrom owing to the damping area density of damping internal construction member is too little, the flow rate of liquid distribution approaches the distribution under the void tower situation, illustrates that the damping unit number is very few, the damping area density is not enough, to the not effectively inhibition of formation of flow velocity of central area.
Comparative Examples 3
In gas-liquid mass transfer experiment, the diameter of damping unit is reduced to 120mm from 250mm, the damping area density is from 0.35m
2/ m
3Be reduced to 0.18m
2/ m
3, other condition is identical with embodiment 1.The gas Liquid Mass Transfer Coefficient k that measures
lThe α value is also listed in table 1.Can see that because the damping internal construction member diameter is too small, the influence that the convection cell turbulence applies is limited, significant change does not take place in mass tranfer coefficient.
Comparative Examples 4
In gas-liquid mass transfer experiment, the diameter of damping unit is increased to 480mm from 250mm, the damping area density is from 0.35m
2/ m
3Increase to 0.65m
2/ m
3, other condition is identical with embodiment 1.The gas Liquid Mass Transfer Coefficient k that measures
lThe α value is also listed in table 1.Can see that adopt diameter to approach the damping internal construction member of tower diameter, mass tranfer coefficient can be increased, but its amplitude reduces.As adopt the damping internal construction member of 250mm diameter can improve mass transfer rate 20%, and adopt the damping internal construction member of 480mm diameter can only improve mass transfer rate 10% on this basis again.
After above-mentioned example explanation adds damping internal construction member, both the excessive flow velocity of bubble tower core can be suppressed effectively, and gas-liquid mass transfer speed can be significantly improved again.Also be not difficult to infer from above-mentioned example, adopt the more complicated inner member of shape, make its damping area radial distribution meet certain requirements, can also obtain more even velocity distribution of center, enumerate no longer one by one.Any improvement for the damping internal construction member shape all belongs to the scope of the present invention's definition, can not change technical characterictic of the present invention.
Claims (8)
1. the bubbling column reactor that has damping internal construction member mainly comprises tower body (1), gas distributor (3), it is characterized in that the damping internal construction member (2) of device obstruction fluid motion in the reaction zone above gas distributor, damping internal construction member (2) and tower body coaxial line.
2. the bubbling column reactor that has damping internal construction member according to claim 1, it is characterized in that damping internal construction member (2) is made up of the vertical rod that is fixed on tower body axle center and a plurality of damping unit, a plurality of damping units perpendicular to vertical rod and vertically each interval be installed in the vertical rod.
3. the bubbling column reactor that has damping internal construction member according to claim 2, it is characterized in that said damping unit is a radial pattern structure sheet, or the annular ring that connects of concentric circles, or the central area damping is greater than the circular net of outer peripheral areas damping, or staggered fin.
4. the bubbling column reactor that has damping internal construction member according to claim 1 and 2, the damping area that it is characterized in that damping internal construction member (2) at radial center zone damping area density greater than outer peripheral areas damping area density.
5. the bubbling column reactor that has damping internal construction member according to claim 1 and 2 is characterized in that the maximum gauge of damping internal construction member (2) or radical length and the ratio of reactor diameter are 0.1～1.0.
6. the bubbling column reactor that has damping internal construction member according to claim 1 and 2 is characterized in that the maximum gauge of damping internal construction member (2) or radical length and the ratio of reactor diameter are 0.2～0.6.
7, the bubbling column reactor that has damping internal construction member according to claim 1 and 2, the damping area that it is characterized in that the damping internal construction member that the unit reactor volume is comprised is 0.05～5.0m
2/ m
3
8, the bubbling column reactor that has damping internal construction member according to claim 1 and 2, the damping area that it is characterized in that the damping internal construction member that the unit reactor volume is comprised is 0.20～2.0m
2/ m
3
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100616029A CN100417437C (en) | 2005-11-18 | 2005-11-18 | Bubbling tower reactor having damping internal construction member |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100616029A CN100417437C (en) | 2005-11-18 | 2005-11-18 | Bubbling tower reactor having damping internal construction member |
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| Publication Number | Publication Date |
|---|---|
| CN1785495A true CN1785495A (en) | 2006-06-14 |
| CN100417437C CN100417437C (en) | 2008-09-10 |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7659427B2 (en) | 2004-09-02 | 2010-02-09 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7683210B2 (en) | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7884232B2 (en) | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7901636B2 (en) | 2004-09-02 | 2011-03-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7902396B2 (en) | 2004-09-02 | 2011-03-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7910769B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7910071B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7960581B2 (en) | 2004-09-02 | 2011-06-14 | Grupo Petrotemex, S.A. De C.V. | Optimized liquid-phase oxidation |
| US7977505B2 (en) | 2004-09-02 | 2011-07-12 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US8114356B2 (en) | 2004-09-02 | 2012-02-14 | Grupo Pretrotemex, S.A. de C.V. | Optimized liquid-phase oxidation |
| US8470257B2 (en) | 2004-09-02 | 2013-06-25 | Grupo Petrotemex, S.A. De C.V. | Optimized liquid-phase oxidation |
| CN106111025A (en) * | 2016-08-09 | 2016-11-16 | 东南大学 | New bubble tower reactor that a kind of nozzle is combined with multilamellar Perforated plate distributor and method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5211924A (en) * | 1988-02-29 | 1993-05-18 | Amoco Corporation | Method and apparatus for increasing conversion efficiency and reducing power costs for oxidation of an aromatic alkyl to an aromatic carboxylic acid |
| CN1208301C (en) * | 2003-08-08 | 2005-06-29 | 中国纺织工业设计院 | Air lift externally circulating bubble fower oxidation unit for producing terephthalic acid |
-
2005
- 2005-11-18 CN CNB2005100616029A patent/CN100417437C/en not_active Expired - Fee Related
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7910769B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US8178054B2 (en) | 2004-09-02 | 2012-05-15 | Grupo Petrotemex, S. A. DE C. V. | Optimized liquid-phase oxidation |
| US7910071B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7960581B2 (en) | 2004-09-02 | 2011-06-14 | Grupo Petrotemex, S.A. De C.V. | Optimized liquid-phase oxidation |
| US7741515B2 (en) | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7659427B2 (en) | 2004-09-02 | 2010-02-09 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7901636B2 (en) | 2004-09-02 | 2011-03-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7902396B2 (en) | 2004-09-02 | 2011-03-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US8470257B2 (en) | 2004-09-02 | 2013-06-25 | Grupo Petrotemex, S.A. De C.V. | Optimized liquid-phase oxidation |
| US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7683210B2 (en) | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7977505B2 (en) | 2004-09-02 | 2011-07-12 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US8114356B2 (en) | 2004-09-02 | 2012-02-14 | Grupo Pretrotemex, S.A. de C.V. | Optimized liquid-phase oxidation |
| US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US8501986B2 (en) | 2004-11-29 | 2013-08-06 | Grupo Petrotemex, S.A. De C.V. | Optimized liquid-phase oxidation |
| US7884232B2 (en) | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| CN106111025B (en) * | 2016-08-09 | 2019-03-05 | 东南大学 | The bubbling column reactor and method of a kind of nozzle in conjunction with multilayer Perforated plate distributor |
| CN106111025A (en) * | 2016-08-09 | 2016-11-16 | 东南大学 | New bubble tower reactor that a kind of nozzle is combined with multilamellar Perforated plate distributor and method |
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| Publication number | Publication date |
|---|---|
| CN100417437C (en) | 2008-09-10 |
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