CN1784245A - Method for forming bactericidal water containing hypochlorous acid or chlorous acid, raw bactericidal material package and kit for forming bactericidal water, and method and apparatus for sterilizing - Google Patents

Abstract

The method allows a general consumer to carry out the sterilization by hypochlorous acid or chlorous acid without the use of a mechanical apparatus through the preparation of a bactericidal water at the site of use with ease.and a method for forming a bactericidal water for carrying out the sterilization by hypochlorous acid or chlorous acid which comprises using the above combination. A combination of a first container containing a hypochlorite as a first component and a second container containing an acid, wherein the first and the second components are so adjusted as to form a bactericidal water having a predetermined effective chlorine content and having a pH of a weekly acidic region or a neutral region when they are mixed.

Description

The generation method, raw bactericidal material assembly and the sterilization water that contain hypochlorous acid or chlorous sterilization water generate complexes and space method for disinfection and device thereof

Technical field

The present invention broadly relates to by hypochlorous acid or the caused sterilization of chlorous acid, more detailed, the generation method, raw bactericidal material assembly and the sterilization water that the present invention relates to contain hypochlorous acid or chlorous sterilization water generate complexes and space method for disinfection and device thereof.

Background technology

Bactericidal liquid is as a kind of mode easy to use, and is present, has Compressed Gas or liquid gas are filled in the portable bottle container jointly, and portable bottled ethanol dilution bactericidal liquid is sold on market.This bottle, general, be furnished with spray nozzle, press this spray nozzle and will make inner bactericidal liquid spraying.Therefore, this bottled bactericidal liquid is very convenient aspect simple sterilization, but can not be used for the sterilization of food.

On the other hand, utilize the germ-resistant sterilization spray device of ethanol for disinfection, particularly be extensive use of at the medical treatment situation that comprises hospital.But ethanol for disinfection be owing to can make pachylosis, in user particularly in women's user and be out of favour.In addition, the sterilization of ethanol for disinfection easily causes the appearance of resistant bacterium.

As the method for disinfection that addresses this is that, known available hypochlorous acid (HClO) or chlorous acid (HClO ₂) sterilization carried out.This method for disinfection has sterilization object extensively can be from virus to the fungus or anthrax and their performances bactericidal effect of promptly imitating, all advantages that do not produce resistant bacterium.Particularly, contain hypochlorous acid or chlorous sterilization water, just have and do not make pachylosis and do not produce anaphylactoid advantage as it being transferred to faintly acid.For containing the safety of hypochlorous sterilization water to human body, known hypochlorous acid can be generated in human body by neutral leukocyte (being also referred to as many property nuclear leukocyte), plays germ-resistant effect in vivo.Therefore, from sterilizing ability and to the viewpoint of the innocuousness of human body, the hypochlorous acid sterilization is an optimal method in the present various method for disinfection.

But, also have several problems that should solve in the sterilization of hypochlorous acid or chlorous acid, one of them is, contain hypochlorous sterilization water through the time sterilizing ability problem that disappears.Another problem is to produce toxic gas according to the pH size.Below describe these problems in detail.

For example, known, hypochlorous acid can only hypochlorous sodium etc. the aqueous solution of adjusting through appropriate pH of hypochlorite exist and obtain.Generally, sodium hypochlorite from manufacturer with transfer to typical 6% or the state of the aqueous solution of 12% concentration dispatch from the factory.The aqueous sodium hypochlorite solution of this state is alkaline, contains water and hypochlorous element Na, H, O and Cl, and they are respectively with Na ⁺, H ⁺, OH ^-, OCl ^-The ionic condition stable existence.Aqueous sodium hypochlorite solution is very weak as the effect of sterilization water in this state.If pH is transferred to neutrality or faintly acid, then can contain a high proportion of hypochlorous acid (HOCl) in the aqueous sodium hypochlorite solution, can be used as HOCl sterilization waterishlogging and wave effect.Figure 54 carries from title to be " water purifying technology " (publishing house: the 104th page figure skill newspaper hall publication Co., Ltd.).Figure 54 shows, kills 99% coliform, hypochlorite ion OCl ^-Required time is 80 times of HOCl (hypochlorous acid) required time.In other words, Figure 54 shows that hypochlorous sterilizing ability is OCl ^-Ionic 80 times.

Therefore, for obtaining being rich in the sterilization water of HOCl, the pH size of adjusting aqueous sodium hypochlorite solution by the such acid of interpolation hydrochloric acid is very important.But too much as the addition of fruit acid, then aqueous sodium hypochlorite solution becomes acidity, can produce deleterious chlorine.

And, this aqueous solution, even under the situation that is adjusted to the hypochlorous acid (HOCl) that contains abundant amount, its pH size, also easy time to time change, hypochlorous acid (HOCl) can not be kept its state for a long time.

That is 3 kinds of chemical species Cl, ₂, HOCl, OCl ^-Between, there is the equilibrium relation shown in the following structural formula.

(1)

(2)

At this, the pH value on the left side is little, and the pH value on the right is big.

As above-mentioned, the ratio that exists of various chemical specieses is determined by pH value.By structural formula (1) as can be known, pH is low more, chlorine (Cl ₂) ratio high more.The ratio of hypochlorous acid in faintly acid and neutral range (HOCl) increases (structural formula (1)), and hypochlorous acid in alkaline range (HOCl) resolves into H ⁺Ion and OCl ^-Ion, OCl ^-Ionic ratio increases (structural formula (2)).

Therefore, understood and wished to get effective bactericidal effect, better be to use the fresh sterilization water that is rich in HOCl, must assurance not make user touch harmful gas through correct adjustment pH value.

But in acid range, sodium hypochlorite generates chlorine (Cl ₂), on the other hand, sodium chlorite generates chlorine dioxide (ClO ₂).Chlorine and chlorine dioxide all are toxic gas.Chlorine dioxide particularly, its toxicity is 10 times of chlorine.

So far, user in sodium hypochlorite, add acid operation should forbid that this has become general knowledge.For example, Kao Corp's (Middle District, Tokyo, Japan Japan bridge thatch field raised path between farm fields) is making the bleaching bacteria-removing liquid for kitchen use towards ordinary consumer of merchandising " Ha イ one " (registered trade mark) by name.This bacteria-removing liquid contains the sodium hypochlorite as main component, thereby has " mixing on this container! Dangerous " the red signal language caution consumer of " using generation chlorine, danger " with acidic materials.

The Japan Patent spy opens and discloses carrying in the above-mentioned general knowledge scope in the 2003-34375 communique and use sterilization container.This is a kind of flask, by acid such as interpolation hydrochloric acid in sodium hypochlorite, pH is transferred to 4～8, and make concentration of residual chlorine in the scope of 10～2000ppm, the sterilization water that so can directly use is filled in this flask with Compressed Gas or liquid gas.This flask is furnished with spray nozzle, presses the spray nozzle bactericidal liquid because air-blast atomizing.But, descend owing to prolong sterilizing power in time through above-mentioned synthetic sterilization water, therefore the bottled sterilization water of this present technology can not guarantee that user uses the sterilization water with abundant sterilizing power in the required time.

Because above situation is being sold in using the on-the-spot sterilization water generating device that is provided with at present.Figure 55 has shown present sterilization water generating device.This water generating device that sterilizes, in the 1st operation, the dilute with water sodium hypochlorite, on the other hand, after dilute with water hydrochloric acid, by two kinds of diluents are mixed, being created on faintly acid or neutral range and effective chlorine density is the sterilization water of 50～200ppm in the 2nd operation.This sterilization water generating device owing to can obtain the fresh mixed liquor of desirable sterilization water in the time of necessity, is of great use therefore.But ordinary consumer is bought for oneself uses, and these are too expensive.This sterilization water generating device only must cleaned a large amount of vegetables of sterilization and meat at present, perhaps must clean sterilization a large amount of apparatus, stage property, utensil, and use in the limited place of hospital or factory.

The announcement of invention

If the present invention is the present inventor from can suppressing the generation of toxic gas, just user can be own each composition (below, will be used for generating sterilization water and blended material is called " composition ") mixed and be generated sterilization this imagination of water and the invention that proposes.This imagination is based on the bold leap of the present general knowledge of industry practitioner.

The objective of the invention is in order to provide, do not need plant equipment, all can generate fresh sterilization water at any time at the scene easily, can bring into play hypochlorous acid or chlorous strong bactericidal effect, the pH size transfers to the generation method of the sterilization water of faintly acid or neutral range, and raw bactericidal material assembly and sterilization water generate complexes.

Another object of the present invention is in order to be provided at any time and the place all can generate fresh sterilization water at the scene easily, is suitable for bringing into play hypochlorous acid or chlorous strong bactericidal effect, the raw bactericidal material assembly that is suitable for carrying.

Other purpose of the present invention is for but long preservation is provided, and all can generate sterilization water at any time at the scene easily, can bring into play hypochlorous acid or chlorous strong bactericidal effect, and raw bactericidal material assembly and sterilization water generate complexes.

Raw material applicatory in the present invention is hypochlorite or the chlorite that contains sodium hypochlorite, sodium chlorite and calcium hypochlorite as typical case.For example, sodium hypochlorite can obtain with crystalline state, but general, manufacturing firm provides with the state of the aqueous solution of typical 6% (60000ppm) or 12% (120000ppm).

In addition, calcium hypochlorite is provided by manufacturing firm with typical Powdered.

In the explanation of the present invention, about by in the explanation of manufacturing firm with liquid time (Asia) chlorate that provides, the original solution state that is provided by manufacturing firm is called " original liquid concentration " or " stock solution ", and what add that entry makes that concentration reduced in should " stock solution " again is called " diluted concentration " or " diluent ".

In addition, being applicable to other raw materials of the present invention, is for example acid such as hydrochloric acid.Other examples as acid applicatory can exemplify as organic acid such as mineral acids such as sulphuric acid, carbonic acid or acetic acid.In the following description, the acid of the original content that is provided by manufacturing firm is called " stock solution ", this " stock solution " Zhong Jiashui make its lowering of concentration be called " diluted concentration ".For example, hydrochloric acid, with the concentration below 10%, is provided by manufacturing firm as home-use with 36% concentration as industrial.Therefore,, be referred to as " stock solution " as this concentration that can obtain by manufacturing firm of direct use, add therein again entry make lowering of concentration be called " diluted concentration ".

According to the 1st viewpoint of the present invention, use in order to make consumer oneself, the 1st container that time (Asia) chlorate (hereinafter referred to as the 1st composition) is housed and the combination that the 2nd container of acid (hereinafter referred to as the 2nd composition) is housed are provided.Generation sterilization water can mix with the 1st, the 2nd composition in the 1st, the 2nd container according to Fig. 1, shown in Figure 2 in consumer, above-mentioned the 1st, the 2nd composition can be modulated into the pH with faintly acid or neutral range, and have given effective chlorine density.

In a kind of generation method of the water that sterilizes, with stock solution or solid (being typically powder) or diluted concentration the 1st composition place in the 1st container, the 2nd composition of diluted concentration places in the 2nd container (Fig. 1).The generation method of other sterilization water places the 1st composition of diluted concentration in the 1st container, and the 2nd composition of stock solution or diluted concentration places in the 2nd container (Fig. 2).

Time (Asia) chlorate of the 1st composition and the acid of the 2nd composition are mixed, for make the sterilization water pH value at faintly acid or neutral range, can adjust the 1st, the 2nd composition in advance, if but too responsive through the adjustment pH of the 2nd composition (acid), then worry can enter acid range the danger that produces chlorine.In addition, the sterilization water of generation then easily causes the pH of sterilization water to reduce if do not use through long-term the placement, generates chlorine, and bactericidal effect descends.For solving such problem, be preferably and add the buffer agent be used for relaxing the pH that causes by the 2nd composition (acid) and adjust (Fig. 3～Fig. 5).For example, the buffer agent as bicarbonate when mixing, the 1st, the 2nd composition can be added (Fig. 3, Fig. 4).In addition, as other example, can in placing the 1st placing room of the 1st composition, sneak into the buffer agent (Fig. 5) as bicarbonate so in advance.As the example of bicarbonate, typically can exemplify as, sodium bicarbonate (NaHCO ₃), other can exemplify as potassium bicarbonate, calcium bicarbonate, magnesium bicarbonate.

Adjust by adding buffer agents such as sodium bicarbonate, potassium bicarbonate, can relax the pH that is caused by the 2nd composition (acid), the pH of the water that can prevent to sterilize arrives the strong acid scope.In addition,, use until exhausted up to the sterilization water that is generated and all can suppress the variation of pH value, make sterilization water stably remain on faintly acid or neutral range, can keep the bactericidal effect of time (Asia) chloric acid by these because the sterilization water that is generated contains buffer agent.

Hypochlorite has the tendency that pH reduces along with the time.Acid is stable in contrast.Even the 1st composition and the 2nd composition are placed in container respectively independently thus, these containers are under medium-term and long-term situations of placing such as warehouse, the 1st composition (inferior (Asia) chlorate) may part through the time decompose and pH descends, the pH that mixes the sterilization water of the 1st composition and the 2 one-tenths branch generations can be lower than the pH that begins to be scheduled to.In contrast, adding buffer agent state such as sodium bicarbonate the 1st, the 2nd composition is mixed, can obtain the sterilization water of stable faintly acid or neutral range, in addition, this can guarantee consumer.This is very important for container and the sale that sale the 1st, the 2nd composition is placed in separate space by the commodity that consumer carries out mixture operation.

In addition, add the sterilization water of buffer agent, when its dilution is used, also can suppress the variation of pH.In addition, departing from neutrality as the water that dilutes usefulness, for example is 9 aqueous alkali for pH, then the danger that sterilization water has alcaliotropism one side to change after diluting.Corresponding therewith, be preferably, in the container that the acid (for example HCl) used when being placed with dilution and buffer agent (for example sodium bicarbonate) are provided to user, provide the guide that records use amount (manual) to user.Also can provide the CO 2 high pressure gas bomb to replace buffer agent to user.When dilution,, can suppress to follow the bigger pH that dilutes the sterilization water that causes to change, and the sterilization water after will diluting easily maintain neutrality and faintly acid because acid and buffer agent are put into jointly.

According to the 2nd viewpoint of the present invention, use in order to make consumer oneself, the 1st container that the 1st composition is housed, the combination of the 2nd container of the 2nd composition being housed and the 3rd container of gauge water being housed are provided.Consumer can generate sterilization water by adding the 1st, the 2nd composition and mix in the gauge water of the 3rd container according to shown in Figure 6, the amount that can modulate the 1st, the 2nd composition and water makes it have pH value at faintly acid or neutral range and the effective cl concn with regulation.

Variation as the invention of the 2nd viewpoint, with above-mentioned the 1st container and the 2nd container, provide the container that appends that is equipped with as the buffer agent as sodium bicarbonate of the 3rd composition to consumer, consumer can add the 1st～the 3rd composition and mixes as shown in Figure 7 in the 3rd container of water is housed.So, when mixing, enter the highly acid scope as above-mentioned preventing, in addition, can be when the sterilization water dilution that will generate be used, the pH that suppresses sterilization water changes.

According to the 3rd viewpoint of the present invention, use in order to make consumer oneself, the 1st container that the 1st composition is housed, the combination of the 2nd container of the 2nd composition being housed and recording the guide of the lime light when mixing are provided.Consumer can according to shown in the guide by in the water of indicatrix, adding the 1st, the 2nd composition and mixing the sterilization water that generates, can modulate the 1st, the 2nd composition and make it have pH value at faintly acid or neutral range and effective cl concn with regulation.

In above-mentioned the 2nd, the 3rd viewpoint, use, the combination of the 1st container with the 2nd container of the 2nd composition that places stock solution or diluted concentration of the 1st composition that places stock solution, solid (being typically powder) or diluted concentration is provided in order to make consumer oneself.

Among the present invention of the 3rd viewpoint, can provide to consumer to place as the container of the buffer agent as bicarbonate (being typically sodium bicarbonate) of the 3rd composition or the CO 2 high pressure gas bomb that appends.Consumer when adding the 1st, the 2nd composition in the water of indicatrix, also can add buffer agent or carbon dioxide as the 3rd composition according to the indication of guide.Can on guide, write down the buffer agent that add or the amount of carbon dioxide.

When directly being used in idiosyncrasy patient's affected part, can adjust the 1st, the 2nd composition, making the effective chlorine density of the sterilization water that generates according to the present invention is about 30ppm.But, when being object, estimate remaining cost with general user, can adjust the 1st, the 2nd composition, making effective chlorine density is about 50～300ppm.When using to object with army, can adjust the 1st, the 2nd composition, the effective chlorine density that makes the sterilization water of generation is about 50～1000ppm.In addition, according to the sterilization water that the present invention generates, dilutable water re-uses.During this situation, as considering the space sterilization, can adjust the 1st, the 2nd composition, making the effective chlorine density of the sterilization water that generates according to the present invention is about 50～60000ppm, is preferably 50～10000ppm, and more preferably 50～2000ppm is preferably 50～1000ppm.At this, effective chlorine density and free chloro concentration substantially are synonyms.

, when consumer provides the 1st composition, be specially with liquid condition, with the state of the low concentration below the 2000ppm when consumer provides sodium hypochlorite, can add therein alkali (for example NaOH) adjust pH to 10 above after, supply again.Because the alkaline range of sodium hypochlorite more than pH10 be more stable, adjust liquid by alkali and adjust more than the pH to 10, just can postpone sodium hypochlorite through the time the sterilizing power reduction.In other words, for the state with the higher concentration of the ratio of for example about 10000ppm (1%) provides sodium hypochlorite to consumer, usually, the sodium hypochlorite of this higher concentration has been the high-alkali state that contains sodium hydroxide (NaOH), therefore there is no need to add alkali.But may when the high-temperature atmosphere long preservation,, can add alkali where necessary and adjust liquid for example in order in army, to use.

In addition, for example,, make the concentration of sterilization water of generation identical, for example can in the 1st composition or the 2nd composition, add sodium chloride (NaCl) with normal saline for being used for the germ-resistant user of hand.Equally,, make in the sterilization water of generation and contain surfactant, can in the 1st composition, the 2nd composition or thinned water, add surfactant for the user that is used to sterilize and cleans.

In the typical embodiment of the present invention, prepared to place inboard container, can support oneself or softish outside container, provide to consumer with the state that the 1st, the 2nd composition is housed respectively in outer container in this.Obtain the consumer of this device, can carry out autotelic operation, the 1st composition in the inboard container or the 2nd composition are blended in the container of the outside.

To be blended into the autotelic operational example of the outside in the container as described below for the composition that will place in the inboard container.

(1) a kind of mixed method by falling, decontrol in the composition that inboard container places to the container of the outside, is blended into the composition in the inboard container in the container of the outside.

(2) other mixed method, the inboard container that will place in the container of the outside links to each other by force with outside container, and the composition in the inboard container is blended in the container of the outside.

(3) other mixed method applies brute force to outside container, makes on the inboard container that is positioned at its inside to form hole etc., by this hole composition in the inboard container is blended in the composition in the container of the outside.

Generate container or the raw bactericidal material assembly that contains in the complexes at sterilization water of the present invention, can provide to consumer with the spray nozzle that may adorn thereon as auxiliary equipment.Perhaps, sterilization water generates container or the raw bactericidal material assembly that contains in the complexes, also can contain the spray nozzle that embeds in advance in this airtight medicated cap (cap).

Use sterilization water of the present invention to generate the sterilization water of complexes or the generation of raw bactericidal material assembly, same with present sterilization water, can be used in the space sterilization of clean and sterilization, the hospital etc. of food such as a large amount of vegetables or edible meat, so just there is no need to be provided with expensive sterilization water generating device.

In addition, sterilization water of the present invention generates complexes or raw bactericidal material assembly, can locate to store in army, hospital, general family etc., can in officely why will generate fresh sterilization water the time.In addition, put into women's handbag and carry, can generate fresh sterilization water at the anywhere, anytime of necessity as raw bactericidal material of the present invention being placed container, can be by time (Asia) chloric acid sterilization.

Above-mentioned purpose of the present invention, other purposes and action effect will describe in detail with following concrete example.

The simple declaration of accompanying drawing

Fig. 1 is the figure that explanation comprises an example of basic conception of the present invention.

Fig. 2 is the figure that explanation comprises another example of basic conception of the present invention.

Fig. 3 is the figure of the variation of key diagram 1, basic conception shown in Figure 2.

Fig. 4 is the figure of another variation of key diagram 1, basic conception shown in Figure 2.

Fig. 5 is the figure of another variation of key diagram 1, basic conception shown in Figure 2.

Fig. 6 is the figure that explanation comprises another example of basic conception of the present invention.

Fig. 7 is the figure of the variation of explanation basic conception shown in Figure 6.

Fig. 8 is the fragmentary cross-sectional view of the raw bactericidal material assembly of embodiment 1.

Fig. 9 is the enlarged drawing of the major part of raw bactericidal material assembly shown in Figure 8.

Figure 10 is the enlarged drawing of major part of the variation of embodiment 1.

Figure 11 is the enlarged drawing of major part of the another variation of embodiment 1.

Figure 12 is the enlarged drawing of major part of another variation of embodiment 1.

Figure 13 is the enlarged drawing of major part of another variation again of embodiment 1, has shown the state that the circumferential groove of the cylinder that places the 1st composition is sealed.

Figure 14 is the figure with Figure 13 associated, has shown the state that the circumferential groove of the cylinder that places the 1st composition is exposed in the bottle interior space.

Figure 15 is the enlarged drawing of major part of the another variation of embodiment 1.

Figure 16 has shown the raw bactericidal material assembly of embodiment 2, is the cut-out aid that shows by wherein containing, the process that the upper part of inboard container is cut off.

Figure 17 has shown the major part of the raw bactericidal material assembly of Figure 16, is that the cut-out sword of explanation aid when storing the raw bactericidal material assembly is placed diagrammatic sketch in the raw bactericidal material assembly with the state that makes progress.

Figure 18 is the figure of the variation of explanation embodiment 2.

Figure 19 has shown another variation of embodiment 2, is the elongated cut-out sword process that the undercutting of inboard container is disconnected in order to illustrate that utilization wherein contains.

Figure 20 is the enlarged drawing of the major part of Figure 19, is the figure of the state of explanation user when storing the raw bactericidal material assembly of Figure 19.

Figure 21 is the figure of the raw bactericidal material assembly of explanation embodiment 3.

Figure 22 is the figure of the raw bactericidal material assembly of explanation embodiment 4.

Figure 23 is the figure of the variation of explanation embodiment 4.

Figure 24 is the figure of the raw bactericidal material assembly of explanation embodiment 5.

Figure 25 is the figure of the raw bactericidal material assembly of explanation embodiment 6.

Figure 26 is the major part profile of the raw bactericidal material assembly of the embodiment 6 that the arrow labelling * 26 places are seen from Figure 25.

Figure 27 is the figure of the raw bactericidal material assembly of explanation embodiment 7.

Figure 28 is the enlarged drawing of major part of the raw bactericidal material assembly of Figure 27.

Figure 29 is the sterilization water generation complexes as embodiment 8 explanations.

Figure 30 is the figure that the sterilization water of the variation of explanation embodiment 8 generates complexes.

Figure 31 is the figure that the sterilization water of another embodiment of explanation embodiment 8 generates complexes.

Figure 32 is the figure that the sterilization water of the another embodiment of explanation embodiment 8 generates complexes.

Figure 33 is the sterilization water that will use the raw bactericidal material assembly of embodiment to be generated, in the aerosol apparatus in this raw bactericidal material assembly of packing into, and the exemplary plot of the method that spray disinfection water uses.

Figure 34 is the sterilization water that will use the raw bactericidal material assembly of embodiment to be generated, in the aerosol apparatus of another form in this raw bactericidal material assembly of packing into, and the exemplary plot of the method that spray disinfection water uses.

Figure 35 is the oblique view that the mixing adorned on the sterilization water out of the aerosol apparatus shown in Figure 34 promotes member.

Figure 36 is the amplification profile of the sterilization water out of the aerosol apparatus shown in Figure 34.

Figure 37 is that explanation uses raw bactericidal material assembly with the aerosol apparatus shown in Figure 34 to be used for sterilize a kind of figure of method of wound.

Figure 38 is that explanation uses the raw bactericidal material assembly of embodiment or sterilization water to generate the figure that sterilization water that complexes generated is used for the germ-resistant suitable space sterilizing unit in space.

Figure 39 is the figure of variation of the space sterilizing unit of explanation Figure 38, has shown the occupation mode of supplying with sterilization water from the cartridge type jar.

Figure 40 is the figure of variation of the space sterilizing unit of explanation Figure 38, has shown the occupation mode of supplying with sterilization water by pipe arrangement.

Figure 41 is the figure of space sterilizing unit of electrolysis mode of variation of the space sterilizing unit of explanation Figure 38.

Figure 42 is the figure that the variation of the bottle that disposes internal container is described.

Figure 43 is the figure in the distortion of vessel example of explanation configuration internal container.

Figure 44 is the figure in another variation of the bottle of explanation configuration internal container.

Figure 45 is the figure of another variation again of the bottle in explanation configuration internal container.

Figure 46 is the figure of variation of the bottle of explanation Figure 45.

Figure 47 is the figure that explanation is arranged at the bottle that buffer agent is housed in the inboard container.

Figure 48 is the figure that the admixture of the 1st composition, the 2nd composition and buffer agent in the bottle that buffer agent is housed in Figure 47 is described.

Figure 49 is the enlarged drawing of major part of the bottle that buffer agent is housed of Figure 47.

Figure 50 is the profile of Figure 49 edge * 50-* 50 lines.

Figure 51 is the enlarged drawing of major part of variation that the bottle of buffer agent is housed.

Figure 52 is the enlarged drawing of major part that another variation of bottle of buffer agent is housed.

The curve chart that the pH of the sterilization water when Figure 53 adds hydrochloric acid in being added with the sodium hypochlorite of buffer agent changes.

Figure 54 is the figure of expression by the potent sterilizing ability of hypochlorite generation.

Figure 55 is the figure that the sterilization water generation order of present sterilization water generating device is used in expression.

The best mode that carries out an invention

Before describing embodiment preferably of the present invention in detail, summarize explanation as doing one to these embodiment, then as described below.

Better raw bactericidal material assembly such as Fig. 8～Figure 20 of embodiment, Figure 22～Figure 23, Figure 25～shown in Figure 28, have the 1st composition that contains hypochlorite or hypochlorite,

Contain acid the 2nd composition,

For do not make above-mentioned the 1st composition and above-mentioned the 2nd composition mix with the next door open separate the single container that places,

By displacement member in this external container people possibility displacement for applying strength,

By the displacement of this displacement member, above-mentioned the 1st composition and above-mentioned the 2nd composition can mix formation sterilization water in said vesse,

Adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, make both when mixing, can generate effective chlorine density and be faintly acid or neutral sterilization water with regulation.Also can contain in the hypochlorite of the 1st composition or the chlorite as ternary buffer agent as sodium bicarbonate.

More specifically say to have as the raw bactericidal material assembly of Fig. 8～Figure 15, embodiment shown in Figure 27

Place the outside container that contains any composition in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition,

By being placed in this outside container, place another composition in above-mentioned the 1st composition or above-mentioned the 2nd composition inboard container,

Airtight should the inboard container airtight member,

With above-mentioned outside container associated design, can enter the control member of (access) from this outside external container,

By operating this control member, above-mentioned inboard container can break away from from above-mentioned airtight member, and above-mentioned another composition in this inboard container flow into and generates sterilization water in the container of the above-mentioned outside,

Adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, make both when mixing, can generate effective chlorine density and be faintly acid or neutral sterilization water with regulation.Also can contain the buffer agent as sodium bicarbonate in the hypochlorite of the 1st composition or the chlorite as the 3rd composition.

The aforesaid operations member for example in the example of Fig. 8, is the airtight medicated cap of outside container, for example with reference to as described later as Figure 22, Figure 23 of variation, but the push rod that also externally exposes.In addition, above-mentioned inboard container as shown in figure 27, also can be arranged on the oral area of outside container.

In addition, when above-mentioned inboard container broke away from from above-mentioned airtight member, inboard container can fall in the container of the outside.In order to reach this purpose, can in inboard container, have plummet.

In addition, the concrete example of raw bactericidal material assembly of the present invention, as Figure 42, shown in Figure 43, have place the outside container that contains any composition in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition,

By being placed in this outside container, place another composition in above-mentioned the 1st composition or above-mentioned the 2nd composition inboard container,

That in this inboard container, form and be flush-mounted in the opening part that communicates with the inner space of above-mentioned outside container stopper,

With above-mentioned outside container associated design, the control member that can enter from this outside external container,

By operating this control member, extract above-mentioned stopper with the moving phase connection of this control member from the above-mentioned opening of above-mentioned inboard container, above-mentioned another composition in the above-mentioned inboard container flow into above-mentioned outside container, can generate sterilization water,

Adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, make both when mixing, can generate effective chlorine density and be faintly acid or neutral sterilization water with regulation.Can contain the hypochlorite of the 1st composition or the buffer agent as sodium bicarbonate outside the chlorite in outside container or the inboard container.

Embodiment

Embodiment 1 (Fig. 8, Fig. 9)

Raw bactericidal material assembly 1 has, and the portable and bottle 2 that can support oneself, this bottle 2 are that the plastic material by resistance to chemical reagents makes.Bottle 2 is preferably by the light screening material manufacturing.Bottle 2 has diameter can hold the drum of taking for singlehanded, and internal capacity is about 100cc.

Particularly with reference to figure 9, the top of bottle 2 have towards above open section be circular mouth cylindrical part 3, form rib-loop tooth 4 at the outer peripheral face of this mouth cylindrical part 3, utilize these rib-loop tooth 4 spiral shells airtight medicated cap 5.Airtight medicated cap 5 among the marginal portion 5a of airtight medicated cap 5, forms one in its lower end and locating snap ring 6 by the plastic material manufacturing.This locating snap ring 6 is around the full Zhou Yanshen of mouth cylindrical part 3, and it plays the effect of block or liner (spacer) as can be known from following explanation, also can separate with the marginal portion 5a of airtight medicated cap 5.

Airtight medicated cap 5, also have spray nozzle 7, shown in the arrow labelling by pressing the top 7a of spray nozzle 7, the liquid in the bottle 2 is promptly sprayable.Because this spray nozzle 7 is known at present, omit detailed description thereof.In addition, when the raw bactericidal material assembly 1 with spray nozzle 7 transported it, as shown in Figure 9, protective cap C covered spray nozzle 7, perhaps also can use resinous band (band) D (Figure 13) will be with spray nozzle 7 coverings of protective cap.During this situation, also can be in resinous band D integrally formed locating snap ring 6 (Figure 13).

Be embedded with cylinder 8 around the main body 7b of the spray nozzle that is positioned bottle 3, the upper end of this cylinder 8 contacts with the 5b of medicated cap portion of airtight medicated cap 5.Forming the circumferential projection 8a that can engage on the cylinder 8 with ora terminalis on its airtight member 9 of circumference on every side.In addition, it is circumferential groove 10 that cylinder 8 has recess at its outer peripheral face, as long as locating snap ring 6 do not plucked, this circumferential groove 10 just keeps the state airtight with airtight member 9.Be that circumferential groove 10 forms airtight inner space by airtight member 9 in the inside of bottle 2.

In bottle 2, can place in the 1st composition or the 2nd composition any, among this embodiment, place the hydrochloric acid (the 2nd composition) of diluted concentration.On the other hand, in this embodiment, place the 1st composition sodium hypochlorite of stock solution or diluted concentration in the circumferential groove 10 of cylinder 8, be preferably and placed sodium bicarbonate.

The using method of the raw bactericidal material assembly 1 of embodiment 1 is, obtains the user of this assembly, removes locating snap ring 6 from the lower end of airtight medicated cap 5, then, to the direction rotation of tightening airtight medicated cap, this airtight medicated cap 5 displacement downwards, its distance be only limited to remove locating snap ring 6 this part.

The displacement downwards of airtight medicated cap 5, just can cylinder 8 be depressed downwards by the 5b of medicated cap portion of airtight medicated cap 5, so, the circumferential projection 8a of cylinder 8 enters in the airtight member 9, while circumferential groove 10 moves to the below of airtight member 9 to be exposed in the inner space of bottle 2, and the 1st composition that places in circumferential groove 10 flow in the bottle 2.

User, jolting bottle 2 can be by generating the liquid mixing in the bottle 2 in the sterilization water of 100cc.The sterilization glassware for drinking water that is generated has the pH value of faintly acid or neutral range, and in addition, effective chlorine density generally is about arbitrary concentration of 50～300ppm.For example, in other words, be adjusted at the 2nd composition of filling in the bottle 2 and the 1st composition of in circumferential groove 10, filling, make them after mixing, have the pH of faintly acid or neutral range and arbitrary concentration that effective chlorine density is about 50～300ppm.In addition, be object, also can adjust the 1st, the 2nd composition and make effective chlorine density concentration be about 800ppm as using with army etc.

The raw bactericidal material assembly 1 of embodiment 1 is in this way towards women or home-use and make, and also can add sodium chloride in bottle 2 for example and make the sterilization water that is generated have identical concentration (about 0.9%) with normal saline.Buy the women of raw bactericidal material assembly 1, for example the raw bactericidal material assembly is put into handbag and carry, can implement the potent sterilization of hypochlorous acid in any at any time place.In addition, if raw bactericidal material assembly 1 is for home-use and make, for example can be by in bottle 2, adding surfactant in advance, tableware is germ-resistantly removed oil stain simultaneously like a cork implementing.

The variation of embodiment 1 (Figure 10～Figure 15)

In the foregoing description 1, circumferential groove 10 by cylinder 8 forms airtight inner space in bottle 2, as Figure 10～shown in Figure 12, chimeric independently additional member 12 is set in the lower end of cylinder 8, also can form airtight space 13 by the lower end of this additional member 12 and cylinder 8.By so, user as rotate airtight medicated cap 5 to the direction of tightening, then can press down cylinder by the 5b of medicated cap portion of airtight medicated cap 5 after removing locating snap ring 6.The shoulder 8b of the bottom by this cylinder 8 can press down additional member 12 then, if additional member 12 breaks away from from airtight member 9, then additional member 12 drops in the bottle 2, and the composition that places in the additional member 12 also flow in the bottle 2.User can quicken the mixing of content by jolting bottle 2.The figure of Figure 11 bottom has shown the additional member 12 after falling.

In addition, Figure 10～Figure 12 removes that other key elements substantially are the same outside the shape of additional member 12, relatively Figure 10～Figure 12 can understand, additional member 12 shown in Figure 11 is bigger than the volume of the inner space 13 of the formation of Figure 10, in addition, the additional member shown in Figure 12 12 is bigger than the volume of the inner space 13 of the formation of Figure 11.When employing can draw the additional member 12 of so big internal capacity, with the state that hydrochloric acid grade in an imperial examination 2 compositions fully dilute it is filled, available the 1st composition is filled in the bottle 2.In addition, Figure 12 is the example that does not have the airtight medicated cap 5 of spray nozzle, and additional member 12 has the inner space 13 of cup-shaped.

In the variation of Figure 13, Figure 14, the airtight member 9 that is positioned bottle 3 extends downwards.Then, be provided with therebetween the opening 16 of the above-below direction of part in the airtight member 9, by than this opening 16 more the part 9a of below with the circumferential groove 10 airtight (Figure 13) of cylinder 8.When mixing the 1st composition and the 2nd composition, remove locating snap ring 6 and resinous band D, move down (Figure 14) by tightening the cylinder 8 that step that airtight medicated cap 5 makes spray nozzle main body 7b partly adorning, circumferential groove 10 is exposed in the inner space of bottle 2 from the lower end of airtight member 9a, and the 1st composition that places in circumferential groove 10 flow in the bottle 2.Reference marks 17 is passages, the 18th, and the enclosed material of airtight medicated cap 5 sides.

Just can understand with Fig. 9 contrast, Figure 15 is that the outer peripheral face at cylinder is provided with the 1st, the 2nd circumferential groove 10,14 up and down discretely, in addition, the example of the 1st, the 2nd locating snap ring 6,15 is set in the lower end of airtight medicated cap 5.Thus, only remove the 1st locating snap ring 6, after in bottle 2, sneaking into the 1st composition in the 1st circumferential groove 10, for example, when the sterilizing ability of the sterilization water in the bottle 2 of long-term use back descends, get and remove the 2nd not assurance band (strip) 15 in Kaifeng, can make sterilizing ability return to the ability at initial stage by in bottle 2, sneaking into the 1st composition that in the 2nd circumferential groove 14, appends again.

For example in the 1st circumferential groove 10 shown in Fig. 9, Figure 13 etc., when filling the sodium hypochlorite as the 1st composition, also can outside this, recharge sodium bicarbonate.In addition, Fig. 9, Figure 13 etc. is single circumferential groove 10, and the additional circumferential groove same with the 2nd circumferential groove 14 of Figure 15 is set, and has placed sodium bicarbonate in this additional circumferential groove, can make it to contain sodium bicarbonate when mixing the 1st, the 2nd composition.This situation is identical with the example of Figure 15, when the composition that uses sodium bicarbonate to replace sodium hypochlorite to fill the 2nd circumferential groove 14, the 1 circumferential groove 10 is blended in the bottle 2, can sneak into the sodium bicarbonate of the 2nd circumferential groove 14 outside this.

Embodiment 2 (Figure 16, Figure 17)

With reference to Figure 16, Figure 17, the raw bactericidal material assembly 20 of embodiment 2 has the bottle 21 that can support oneself.This bottle 21, the jar more than 1 liter or 10 liters of portability carrying for example also can be considered from the cost aspect be made by the plastic material of resistance to chemical reagents.

In the bottle 21, inboard container 23 is placed with airtight state, the volume of this inboard container 23, for example, in inboard container 23, place the 1st composition of pulverulence, and placed the Powdered carbonic acid hydrogen sodium that in this pulverous the 1st composition, adds, can be less.Inboard container 23, typically, by the plastic material or the membrane material manufacturing of resistance to chemical reagents.That is, inboard container 23 can be an ampuliform, perhaps also bag shape.

Inboard container 23, ora terminalis has the outside bamp joint 23a that is connected with the section of bottle 24 thereon.Outside bamp joint 23a is connected with the airtight member 25 that airtight medicated cap 5 is seized on both sides by the arms with upper surface by bottle 24, and thus, inboard container 23 forms independently confined space in bottle 21.

Be provided with the cut-out aid 26 that cuts off sword 26a is installed in the 5b of medicated cap portion of airtight medicated cap 5 in the mode that can shirk the back side.During sales to consumers bottle 21, on airtight medicated cap 5, this state has the function (Figure 17) of utilizing the medicated cap that the main body 26b that cuts off aid 26 clogs the mouth of inboard container 23 to the cut-out sword 26a that cuts off aid 26 with the state device that makes progress.Place the 1st or the 2nd composition in the bottle 21, placed another composition in the inboard container 23.

Obtain the user of the raw bactericidal material assembly 20 of embodiment 2, take off airtight medicated cap 5, make cut-out aid 26 promptly cut off sword 26a (Figure 16) downwards, then, airtight medicated cap 5 at bottle 24 spiral shells with the state of counter-rotating.So, the 5b of medicated cap portion by airtight medicated cap 5 will cut off aid 26 and press down, and cut off the horizontal segment part 23b that sword 26a is trapped in inboard container 23, with its cut-out.So, inboard container 23 falls in the bottle 21, and wherein composition also flow in the bottle 21.For falling of auxiliary inside container 23, can plummet be set in for example bottom of inboard container 23.User can be by shaking the mixing that bottle 21 quickens in bottle 21 up and down.In addition, do not use the cut-out sword 26a that cuts off aid 26 to cut off the horizontal segment part 23b of inboard container 23, can line of weakness be set, line of weakness is cut off by pressing down cut-out aid 26 at horizontal segment part 23b.

The raw bactericidal material assembly 20 of embodiment 2 can provide than relatively large raw material to user easily.By aforesaid operations, when mixing the composition in the bottle 21, can adjust the 1st, the 2nd composition and make the sterilization glassware for drinking water that is generated that for example effective chlorine density of 10000ppm be arranged.User can be divided into aliquot after utilizing airtight medicated cap 5 to generate sterilization water in the bottle 21 of air-tight state, uses with suitable water dilution.This occupation mode is well suited for for for example hospital of a large amount of uses sterilization water etc.

Thinned water for example is placed in the alkaline environment, and the pH change for the sterilization water that suppresses to be caused by dilution can provide the acid that adds in the container to user, in addition, also can be provided at the container that wherein adds the buffer agent as sodium bicarbonate to user.

The variation of embodiment 2 (Figure 18～Figure 20)

User utilizes when the raw bactericidal material assembly 20 of the foregoing description 2 generates the sterilization water, and it is necessary disposablely taking off airtight medicated cap 5, will cutting off the operation that aid 26 reverses.But, also can be as shown in figure 18, the fixing cut-out in the aid 26, on the 5b of medicated cap portion of airtight medicated cap 5 at the integrally formed locating snap ring 6 of the marginal portion of airtight medicated cap 5 5a.User can be by dropping down onto in the bottle 21 inboard container 23 to companion's the decline of cut-out aid 26 with getting except that locating snap ring 6 and tighten airtight medicated cap 5.Can be provided with when replace cutting off the 26a of aid 26 with for example bar that extends to the below, constitute the end of inboard container 23 with shut off valve, by airtight medicated cap 5 to pressing down this cut-out aid 26, utilization is cut off the bar that aid 26 extends downwards from this, to the shut off valve that presses down the end that constitutes inboard container 23, inboard container 23 is opened.

Variation as the raw bactericidal material assembly 20 of the foregoing description 2 as Figure 19, shown in Figure 20, places the aid 28 of medicated cap shape in airtight medicated cap 5, by this medicated cap shape aid 28 that reverses, can operate elongated cut-out sword 29.Specifically, elongated cut-out sword 29 has projection 30 in the top, by chimeric separatably this projection 30 in the hole 28a of medicated cap shape aid 28, can fix on medicated cap shape aid 28 and cut off sword 29.When user generates sterilization water, take off airtight medicated cap 5, as shown in figure 20, the chimeric medicated cap shape aid 28 of recess of the 5b of medicated cap portion that takes off at airtight medicated cap 5 from airtight medicated cap 5.Then, take off cut-out sword 29, behind counter-rotating medicated cap shape aid 28, will cut off sword 29 again and be installed on medicated cap shape aid 28, will cut off sword 29 then and be inserted in the inboard container 23 from medicated cap shape aid 28.Then, as again on bottle 24 spiral shell airtight medicated cap 5 (Figure 19), can press down by medicated cap shape aid 28 and cut off sword 29, the blade 29a of its front end is trapped in the bottom of inboard container 23, and it is cut off, the composition in the inboard container 23 also flows in the bottle 21.In this cut-out, be included in the situation of the bottom opening of inboard container 23.Variation shown in this Figure 19, Figure 20, as inboard container 23, be preferably the bag that employing is made by enclosed material, during this situation, be preferably on cut-out sword 29 vertical ribs is set, the inboard container 23 of bag shape is not damaged when making around inboard container 23 is attached to cut-out sword 29.

Embodiment 3 (Figure 21)

Figure 21 has shown the raw bactericidal material assembly 30 of embodiment 3.Among this embodiment, partly be provided with for example outside bamp joint (flange) 31, seize the state of this outside bamp joint 31 on both sides by the arms and provide to be sealed enclosed material 25 between medicated cap 5 and bottle 21 upper surfaces to consumer in the upper end open of inboard container 23.

Obtain the user of the raw bactericidal material assembly 30 of embodiment 3, take off airtight medicated cap 5, after being pressed into the outside bamp joint 31 of inboard container 23 in the bottle 21 with finger, spiral shell airtight medicated cap 5 on bottle 21 again, by fine jolting bottle 21 inboard container 23 is fallen afterwards, the composition in this inboard container 23 can be sneaked in the bottle 21.For reaching this purpose, inboard container 23 is preferably at least its top by bending deformed soft material manufacturing.

Embodiment 4 (Figure 22)

The raw bactericidal material assembly 40 of embodiment 4 has the push rod 41 that can enter from the outside, by pressing down this push rod 41, inboard container 23 can be cut off, and the composition in this inboard container 23 is flowed in the bottle 21.On push rod 41, add a lever,, utilize " lever principle " that push rod 41 is moved downwards by pressing down this lever.

In illustrated raw bactericidal material assembly 40, the 5b of medicated cap portion of airtight medicated cap 5 has the push rod 41 with its break-through.Integrally formed locating snap ring 42 on push rod 41.Also be fixed with on the push rod 41 and cut off aid 26, as after getting except that locating snap ring 42, brute force is depressed push rod 41, and then cutting off aid 26 can move down, and cuts off the horizontal segment part 23b that sword 26 is absorbed in inboard container 23, with its cut-out.By so, inboard container 23 falls in bottle 21, and composition wherein also flows in the bottle 21.The for example bar that extends downwards is set replaces cutting off the sword 26a of aid 26, constitute the end of inboard container 23 simultaneously with shut off valve, press down cut-out aid 26 by airtight medicated cap 5, utilization is cut off the bar that aid 26 extends downwards from this, press down the shut off valve at the end that constitutes inboard container 23, inboard container 23 is opened.

The variation of embodiment 4 (Figure 23)

In the raw bactericidal material assembly 40 shown in above-mentioned Figure 22, cut off the inboard container 23 of aid 26 cut-outs by pressing down, composition in the inboard container 23 is flow in the bottle 21, as variation as shown in Figure 23, on push rod 41, fixedly press down member 43, brute force is depressed push rod 41 and is applied downforce by pressing down member 43 at the horizontal segment part 23b of inboard container 23, by so, can make inboard container 23 force to fall.In order to reach this purpose, the top at least that is preferably inboard container 23 is by just can easy diastrophic soft material manufacturing with finger strength.

As another variation, in Figure 23, inboard container 23 is omitted, and generation at the above-mentioned outer peripheral face that presses down member 43 circumferential groove 10 shown in Fig. 8 grade is set, can place the 1st or the 2nd composition in this circumferential groove 10.

Embodiment 5 (Figure 24)

In raw bactericidal material assembly 50 shown in Figure 24, though not necessarily also can be in the lower end of inboard container 23 the integrally formed part 51 of plucking, can pluck part 51 by backing out this, form intercommunicating pore 53 in the lower end of inboard container 23.The front end of axle (shaft) 52 that extends up and down in inboard container 23 enters into intercommunicating pore 53, like this intercommunicating pore 53 is closed.Promptly axle 52 front ends constitute mobilizable valve body.In addition, be fixed with operation flange 54 on the upper end of axle 52.Inboard container 23 cuts out with the piston 55 of setting-in after filling the 1st or the 2nd composition by portion within it, and above-mentioned axle 52 break-through pistons.

Obtain the user of raw bactericidal material assembly 50, take out airtight medicated cap 5 after, then take out inboard container 23 from bottle 24, be pulled upwardly operation flange 54, axle 52 also by on draw.End portion at axle 52 forms flange 56, and as above pulling shaft 52 these flanges 56 engage with interior all ditch 55a of piston 55, and is integrated by axle 52 like this and piston 55.Then, remove the plucked part 51 of the lower end of inboard container 23.

Press operation flange 54 descends piston 55 under the user, and the 1st or the 2nd composition of filling in inboard container 23 is injected in the bottle 21.This implant operation can perhaps, make the front end face of inboard container 23 implement to bottle 24 so that inboard container 23 localized states are implemented in bottle 24.

As finish above-mentioned implant operation, bottle 21 is airtight by airtight medicated cap 5, can the compositions in the bottle 21 be mixed by firmly shaking bottle 21.When using the sterilization water that so generates, the inboard container 23 that possesses piston 55 can be used as syringe and applies flexibly.Promptly piston is risen, thereby after in inboard container 23, importing an amount of sterilization water, take out inboard container 23,,, the sterilization water in the inboard container 23 are sprayed to affected part by following press operation flange 54 for example facing to this disinfectant affected part by last pulling process flange 54.

As the variation of raw bactericidal material assembly 50, inboard container 23 is become bottom structure, and user is taken airtight medicated cap 5 and taken out inboard container 23, and the composition in this inboard container 23 is joined in the bottle 21.This method is very suitable when placing pulverous the 1st composition in inboard container 23.

Embodiment 6 (Figure 25, Figure 26)

Embodiment 6 is fit to the concrete example that inside and outside 2 layers of container are made by the soft sheet material of resistance to chemical reagents material, shown in Figure 25,26.In the illustrated raw bactericidal material assembly 60, outside container 61 and inboard container 62 are made of flat sack, and this sack is made of the sheet material of resistance to chemical reagents.Because such sack often uses as the container of cooking food, just omits detailed description thereof.

The part of interior side pocket 62 is fused to the marginal portion of outer side pocket 61.The 2nd oral area the 64, the 1, the 2nd oral area 63, the 64 airtight outer peripheral edges of outer side pocket 61 and the outer peripheral edges of interior side pocket 62 of being fused to that raw bactericidal material assembly 60 has the 1st oral area 63 that communicates with the inside of outer side pocket 61 and communicates with the inside of interior side pocket 62.

The parting tool 65 of side pocket 62 in the inside of outer side pocket 61 keeps and is used to cut off.Parting tool 65 has the lever 67 of energizing through spring 66, and depress lever 67 just can be cut off interior side pocket 62 by the cut-out sword 68 that is provided with in lever 67.

Raw bactericidal material assembly 60 provides to consumer with following state, at first extract stopcock (peen) from the 1st, the 2nd oral area 63,64, the the 1st, the 2nd oral area 63,64 is opened, filling the 1st composition outside in the side pocket 61 (is preferably, added the buffer agent as sodium bicarbonate so therein) or the 2nd composition, then, in interior side pocket 62, behind another composition of filling, in the 1st, the 2nd oral area 63,64, insert stopcock 69 and make it to close.

Obtain the user of raw bactericidal material assembly 60, for example raw bactericidal material assembly 60 is placed bed or ground, then from the top of outer side pocket 61 parting tool 65 is depressed with foot.Thus, interior side pocket 62 its part at least is cut off, and its inner composition flow in the outer side pocket 61, by mixing the 1st, the 2nd composition generation sterilization water in the side pocket 61 outside.Sterilization water in the raw bactericidal material assembly 60 can be removed by the stopcock 69 of extracting the outside oral area 63 used of container.

When user tramps with one's feet when stepping on raw bactericidal material assembly 60, for the damage of the outer side pocket 61 that prevents to cause, for example can make spring 66 by bent stick by lever 67 grades, when trampling lever 67, because bent stick 66 displacement laterally just can be protected outer side pocket 61,

Embodiment 7 (Figure 27, Figure 28)

The raw bactericidal material assembly 70 of embodiment 7 is to utilize the inside of oral area 63 of outer side pocket 61 as the assembly of the 2nd airtight placing room.That is, oral area 63 has cylindric, therein, has placed the inboard container 71 of the cylindrical shape that the end is arranged, and in addition, in inboard container 71, parting tool 72 is placed to cut off the downward state of sword 72a.

Obtain the user of raw bactericidal material assembly 70, after airtight medicated cap 5 takes off locating snap ring 6, parting tool 72 is pressed down, cut off the end of inboard container 71 by tightening airtight medicated cap 5.By so, the 1st or the 2nd composition in the inboard container 71 is flow in the outer side pocket 61.In order to guarantee its outflow, be preferably through hole 73 is set in parting tool 72.

As the variation of the raw bactericidal material assembly 70 of this embodiment 7, the light plastic container of available no independence replaces softish outer side pocket 61.When using this softish outer side pocket 61 or replacing its light plastic container, the state that is preferably to be placed in carton provides raw bactericidal material assembly 70 to consumer.

Embodiment 8 (Figure 29)

Figure 29 has shown that as embodiment 8 sterilization water of the present invention generates complexes.Sterilization water generates complexes 80 and comprises the 1st bottle 81 of placing the 1st composition, places the 2nd bottle 82 of the 2nd composition and place the 3rd bottle 83 of water that other better also comprise the guide 84 of lime light when record mixes.On the 1st～the 3rd bottle 81～83, better has scale 85.Being preferably at least the 1, the 2nd bottle 81,82 is made by the plastic material with resistance to chemical reagents and light-proofness.

In the guide 84, guide look has for example been write down, the amount of the amount of the amount of water, the 1st composition, the 2nd composition and it is mixed the amount of the sterilization water generated and the relation between the concentration, user is being seen these, indication according to guide, in the 3rd bottle 83, add the water of ormal weight, can generate sterilization water by the 1st, the 2nd composition that in the 3rd bottle, adds ormal weight from the 1st bottle the 81, the 2nd bottle 82.

Also can provide the 3rd bottle 83 to consumer by empty state.The water that obtains sterilizing generates the user of complexes 80, sees guide, can add the water of ormal weight at first as indicated in the 3rd bottle 83, then, adds the 1st, the 2nd composition of the 1st, the 2nd bottle 81,82 in the 3rd bottle 83, generates sterilization water.

Sterilization water generates complexes 80, and the state in the carton 86 of for example can packing into provides to consumer, and in addition, the user that obtains bulk sterilization water generation complexes 80 also can for example keeping in the warehouse.

Also can in the 3rd bottle 83, add pH and adjust liquid.For example, in the 3rd bottle 83, add pH such as dilute hydrochloric acid or dilution NaOH in advance and adjust liquid, as after the water that sterilizes generated complexes 80 and deposit under rugged environment, when user utilized it to make sterilization water again, the pH adjustment liquid that just can utilize the 3rd bottle 83 was finely tuned the pH of this sterilization water.In addition, can in placing the 1st bottle 81 of the 1st composition, sneak into buffer agent as sodium bicarbonate.Replace, when generating to above-mentioned sterilization water, user adds the 4th bottle or the CO 2 high pressure gas bomb that places bicarbonate (being typically sodium bicarbonate) in the complexes 80, when making sterilization water, can add sodium bicarbonate or add carbon dioxide from the 4th bottle to the 1st, the 2nd composition and mix from the CO 2 high pressure gas bomb.

The variation of embodiment 8 (Figure 30～32)

Sterilization water generates complexes 80, as shown in figure 30, is made up of the 1st, the 2nd bottle 81,82 and the guide 84 that place the 1st, the 2nd composition, provides to consumer in the water-proof bag of for example can packing into.Obtain the user of this device,, in proper container, behind the water of adding ormal weight,, can generate the faintly acid or the neutral sterilization water of normal concentration by adding the composition of the 1st, the 2nd container 81,82 according to the indication of guide 84.Except that the 1st composition, can place sodium bicarbonate in the 1st bottle 81.Replace, in complexes 80, add the 3rd bottle (not shown) or the CO 2 high pressure gas bomb that places the such buffer of sodium bicarbonate when user, when generating sterilization water, can be mixed together sodium bicarbonate or carbon dioxide with the 1st, the 2nd composition.

Sterilization water generates complexes 80, as shown in figure 31, the inner space of a container can be divided into 3, utilize this container to constitute above-mentioned the 1st～the 3rd bottle 81～83 again, pasting guide 84 thereon, perhaps, can in being divided into 3 container, form sack, provide to consumer with the state that in this sack, places guide 84.Perhaps, sterilization water generates complexes 80 shown in figure 32, the inner space of a container can be divided into 2, constitutes above-mentioned the 1st～the 2nd bottle 81～82.Perhaps also can be divided into 2 the apposition guide 84 on the container of drawing at this.

In addition, when user uses the sterilization water dilution that is generated, as the water that uses for alkalescence or when acid, can provide to place to user and be used for the acid that its neutralization is used or the container of alkali, in addition, be preferably, container or the CO 2 high pressure gas bomb that is added with the buffer agent as sodium bicarbonate is provided to user.

The sterilization water of Figure 29～Figure 32 generate complexes 80 with and variation in, can add the 4th bottle that places the alkali regulator such (pH regulator agent) just like sodium hydroxide, in addition, the pH that also can add as litmus paper confirms means.Sterilization water is generated the result who stores in complexes 80 long-time occasions that store or the rugged environment, even as record in the guide 84, mix, imagination sterilization water may more be partial to acidity than pH5, at this moment, the alkali that adds the 4th bottle in advance in water is adjusted liquid, confirm means while confirming that pH makes sterilization water by pH, user can be adjusted to the pH of this sterilization water about 5.5.

The present invention is certainly formed by the various key element combination in any that adopt in the above-mentioned concrete example.For example, outside container 2,21,61 or inboard container 23 or the 1st～the 3rd bottle 81～83 can constitute with the shell plastic containers that are not able to support oneself.

Because the sterilization water that is generated is neutral or weakly acidic pH, when the 1st, the 2nd composition mixes, can prevent the generation of toxic gas such as chlorine in the above-mentioned various concrete example.In addition, during married operation, owing to be to carry out in the container of the airtight conditions that airtight medicated cap 5 is tightened basically, it is safe that user can contact chemical drugs (the 1st, the 2nd composition) without hands.

In addition, point out in the nearest report, the sterilization that causes by hypochlorous acid or chlorous acid, for example pH be 5.5 and also effective chlorine density be under the condition of 50ppm, confirm can effectively sterilize to yeast, staphylococcus aureus, CNS, bacillus cereus, micrococcus luteus, acinetobacter calcoaceticus, MRSA etc.But, as concrete example of the present invention, all can carry out the germ-resistant words that cause by hypochlorous acid or chlorous acid simply as any place at any time, just can not need special device in time to tackle for for example in social problems such as nosocomial infection of hospital etc.

In addition, at present, the sterilization that in general family, can not utilize neutrality or weakly acidic hypochlorous acid or chlorous acid to carry out, but concrete example of the present invention can provide to consumer's cheapness, obtain the ordinary consumer of this product, can carry out hypochlorous acid or chlorous acid sterilization on general household convenient ground.In addition, in general family, as with it as storage, each family also can take the self-protection measure for spreading of the sudden illness as SARS.The sterilization that hypochlorous acid causes as described above, and is similar to the bactericidal mechanism of neutrophilic leukocyte in human body, and it all is harmless entering human body by breathing or food.Therefore, can carry out the space sterilization, in addition,, can in the room, carry out deodorization owing to can bring into play deodorizing effect using having of home-use humidifier (being preferably ultrasonic humidifier) to spray sterilization water in the active room of people.Certainly also can in to inlet food or wash dishes and sterilization, use.

In addition, in army, each tent all stores concrete example of the present invention, can realize terrified and take some countermeasures in that emergency medical service is on to biological weapons.

Use the sterilization of concrete example of the present invention, in the mouth cylindrical part 24 of the bottle 21 that uses when for example mixing, as shown in figure 33, adorning aerosol apparatus 90, use this aerosol apparatus 90 sterilization water can be sprayed.This aerosol apparatus 90 can be with the sterilization water spray in the bottle 21 by medicated cap 91 is pressed down.In addition, can use the aerosol apparatus 93 ejection sterilization water of type shown in Figure 34.Aerosol apparatus 93 pulling handles 94 shown in this Figure 34 can make the sterilization water spray in the bottle 21.In addition, though in Figure 33, Figure 34, shown the bottle 21 of the concrete example that is used in Figure 19, be not limited only to this.

Aerosol apparatus 90,93 shown in Figure 33, Figure 34 better is mixing shown in Figure 35 to be set promote member 95 on this sterilization water ejiction opening, uses medicated cap 96 as shown in figure 36 that spray pattern can be controlled simultaneously.

Promptly, mix and promote member 95, have rotation interflow part 95a at its front end face, the sterilization water that drinks up from bottle 21 rotates interflow part 95a by flowing into 2 relative breach 95b, the 95b of front end face that mix promotion member 95, ejection after this rotation interflow part 95a mixing.In addition, by adjusting the degree of tightening of medicated cap 96, the sterilization water that can make ejection is changed to spray pattern from the spray regime of linearity.

For example, after installing, can in treatment, use (with reference to Figure 37) at the aerosol apparatus shown in Figure 34 93 with the encirclement cover 97 of its encirclement.When treatment, according to the state of wound U, can make the linearly injection of sterilization water by the degree of tightening of adjusting medicated cap 96, reach the wound sterilization and remove pus.Sterilization water after the processing then compares health as being received in the receptor 98.

With the relevant embodiment of space sterilization

When for example being implemented in the space sterilization in the ward of hospital, be preferably, the sterilization water of implementing wide scope under the state of quietness sprays.Figure 38 has shown the portable interior space sterilizing unit 100 that adapts therewith.Space sterilizing unit 100 has the pallet that contains hypochlorous sterilization water 102 that is captured in the boxlike jar 101.The medicated cap 103 of boxlike jar 101 has movable bolt 104, by the action of this movable bolt 104 flow export of medicated cap 103 is opened.The water level of pallet 102 is as reducing to medicated cap 103 bottom surfaces, and then air enters in the boxlike jar 101 by medicated cap 103, so can keep the water level in the pallet 102 certain.Pallet 102 is provided in the apparatus main body 105 in advance, and the sterilization water in the pallet 102 is by supersonic generator 106 micronizes.Space sterilizing unit 100 has the main fan that disposes 108 that drives by motor 107 in open space, main fan 108 and motor 107 are provided in the top of apparatus main body 105, can axle 109 adjusts upward at upper and lower for the center.

By supersonic generator 106 micronized sterilization water, contiguous and be transported to the place ahead to main fan 108 by installing the 1st path 110 that main body 105 extends to the top certainly.In order to promote this to flow; the part of the wind that is produced by the rotation of main fan 108 is fed in the apparatus main body 105 by the 2nd path 111; utilization is supplied to wind in the apparatus main body 105 from the 2nd path 111, by supersonic generator 106 micronized sterilization water smokes be transported to main fan 108 near.

The outlet 110a of the 1st path 110 is preferably, and forwards open, this outlet 110a can be adjacent to the core of main fan 108 and be disposed at its place ahead.The position of this outlet 110a and towards can by constitute a part the 1st path 110 bellows 110b adjust.Main fan 108 is better to implement the Security Countermeasures with net 112 encirclements such as grade etc. around it.

Motor 107 and supersonic generator 106 can be controlled by the power pack and the control section 113 that place in apparatus main body 105.

This space sterilizing unit 100 can not have air-supply sound ground by the main fan 108 that is provided with and will sterilize water transport to wider range, applicable to the space sterilization in the ward that has air-supply mail topic at present in open space.When implementing the space sterilization in wards by space sterilizing unit 100, can there be the worry that the air-supply sound causes, by life there being the space disinfection in weakly patient's ward, can implement prevention, even can eliminate the problem of the foul smell in the ward by its excellent deodorizing effect nosocomial infection.Raw bactericidal material assembly of the application of the invention or sterilization water generate complexes, can be easily and also with device 100 make the sterilization water that is used for additional boxlike jar 101 nearby.During this situation, to directly pack into and can implement the space sterilization in the boxlike jar 101 by the hypochlorous sterilization water that contains that raw bactericidal material assembly or sterilization water generate that complexes generate, be preferably, will be by containing in the boxlike jar 101 of packing into after hypochlorous sterilization water suitably dilutes that raw bactericidal material assembly or sterilization water generation complexes generate.In addition, generate complexes, use scale 85, generate the sterilization water of the concentration that is fit to for the space sterilization, re-use space sterilizing unit 100 and can be implemented in indoor sprinkling for sterilization water.In addition, also available above-mentioned bottle 21 replaces boxlike jar 101.

In addition, the main fan 108 as space sterilizing unit 100 can adopt cross-flow scavenging fan (Figure 39,40).This cross-flow scavenging fan is as is generally known be to suck the ventilation fan that homogeneous on the rectangular direction of direction produces average flow with gas, having the little characteristics of air-supply sound.In addition; in apparatus main body 105, be provided with the 2nd more small-sized motor driven fan; by using the wind that produces by the 2nd fan that micronized sterilization water smoke is transported to the nearside of main fan 108,, sterilization water can be sprayed to a distant place by the wind that makes the sterilization water smoke that is handled upside down follow main fan 108 to generate.

In addition, prevent that indoor excess moisture from rising, can in space sterilizing unit 100 control member be set, for example, spray disinfection water 3 minutes then quit work 10 minutes, the spraying of the water of can so intermittently implementing to sterilize.In this spraying control member, in addition, the detecting sensor of indoor humidity and temperature is arranged, can control spray time and work dwell time according to indoor humidity and temperature as combination.In addition, the control knob of combined programming by this control knob, can be able to be controlled spray time and work dwell time with changing in advance.

What place in the boxlike jar 101 of space sterilizing unit 100 contains hypochlorous sterilization water, no specific restriction, but effective chlorine density is comparatively suitable at 50～200ppm.

Above-mentioned space sterilizing unit 100, illustration mancarried device, supply with the fixed of sterilization water but also can be acceptance by pipe arrangement.During this situation,, be preferably and be designed to select arbitrarily supply with form and supply with the device of forms by boxlike jar 101 by pipe arrangement as form from the sterilization water to supersonic generator 106 that supply with.

Shown among Figure 39, Figure 40, by auxiliary equipment is housed, the space sterilizing unit 120 that can select to utilize the supply form (Figure 39) of boxlike jar arbitrarily and utilize the supply form (Figure 40) of pipe arrangement.Alternative device the 1st, the 2nd auxiliary equipment 122,123 in the box 121 when device has the 1st auxiliary equipment 122 as shown in figure 39, can take out boxlike jar 101 by outside taking-up cover 122a outside.On the other hand, when device has the 2nd auxiliary equipment 123, can accept to supply with (Figure 40) by the sterilization water of pipe arrangement 124.In the reference marks shown in Figure 40 125 is electromagnetic valve, and 126 is level sensor.The water level that can keep sterilization water by level sensor 126 and electromagnetic valve 125 makes it roughly certain.

Adopted cross-flow scavenging fan in the space sterilizing unit 120 shown in Figure 39, Figure 40, be provided with shutter 127 among the air outlet 108a of this main fan 108 as main fan 108.By adjusting the direction of shutter 127, can change the direction of the wind that main fan 108 generated.The air outlet 108a of main fan 108 does not have ajutage in the face of open space.Have air intlet 128 in the outer box 121, this air intlet 128 is preferably and equates with the aperture area of air outlet 108a or bigger again than it.

Be provided with the 2nd motor driven fan 130 in the space sterilizing unit 120 shown in Figure 39, Figure 40,, micronized sterilization water smoke be transported near the main fan 108 by this motor driven fan 130.

Device shown in Figure 38～Figure 40 has the space sterilizing unit 100,120 of main fan or cross-flow scavenging fan 108, can equip electrolytic sterilization water and generate member.Among Figure 41 illustration be provided with the space sterilizing unit 135 that electrolytic sterilization water generates member.This space sterilizing unit 135 places useful water-reducible hydrochloric acid (HCl) in advance in loading and unloading type boxlike jar 101, hydrochloric acid water flows through aseptate electrolysis portion 136 and generates hypochlorous acid (HClO).Electrolysis portion 136 has positive pole 137 and the negative pole 138 that is made of 2 different metal tubes cylindraceous of radius (for example with the platinized pipe of titanium material).Electrolysis portion 136 is preferably has heat release or cooling component 139, by this heat release or cooling component 139, can better suppress the heating of electrolysis portion 136.For example, as heat release or cooling component 139, as the combination of employing at electrolysis portion 136 internal configurations and corrosion-resistant plate that conductivity of heat is good (for example, the titanium plate) 139a and Po Er card (Peltier) element 139b, but then aphonia ground cools off electrolysis portion 136.

Owing in the micronize sterilization water that sprays, do not contain salt in fact, so the space sterilizing unit 135 of electrolytic sterilizes applicable to the space in the hospital.In addition,, be not limited to Peltier's element 139b, also can adopt air-cooled type, can also adopt water-cooled about the cooling means of electrolysis portion 136.

Various variation

More than, concrete example of the present invention has been described, but the present invention is not restricted to these concrete examples.Inboard container 23 by in bottle 21, being provided with for example shown in Figure 42, as, be hung on the sleeve 140 of the upper end-face edge of bottle 24, and in this sleeve 140 2 stoppers 142,143 up and down of setting-in, form confined space between these 2 stoppers 142,143, this confined space can be used as inboard container 23 and utilizes.During open this inboard container 23, for example utilize the axle 144 that extends up and down that 2 stoppers 142,143 are interconnected, in order to press down this axle 144, for example can be on airtight medicated cap 5, be provided with certainly the sagging bar 145 of this airtight medicated cap 5.This bar 145 with the structure of separating of as shown in figure 42 airtight medicated cap 5, can also be and airtight medicated cap 5 Construction integrations.Take out locating snap ring 6,, stopper 142,143 is pressed down, below stopper 143 is broken away from from the lower end of sleeve 140, thereby the composition in the sleeve 140 is flow in the bottle 21 as bar 145 being descended by tightening airtight medicated cap 5.

Use is with reference to the structure of the inboard container of departing stopper 142 formation of Figure 42 explanation, applicable to the inboard container 71 of configuration in the oral area 63 of the outer side pocket 61 shown in Figure 27, Figure 28.That is, as shown in figure 43, constitute in the lower ending opening of sleeve of sidewall of inboard container 71 and be embedded with stopper 142, it is open with inboard container 71 to press down stopper 142 by the bar 145 related with airtight medicated cap 5.This stopper 142 is preferably, airtight sleeve lower end inner peripheral surface and/or the lower end outer peripheral face that constitutes inboard container 71 sidewalls that be embedded in.

Figure 44 is the diagrammatic sketch that prevents one of means that stopper 142 breaks away from from inboard container 23 unintentionally example.In the example among this Figure 44, bar 145 is fixed on the stopper 142, with the end tying of the handle 148 of these bar 145 Construction integrations in the step portion 149 of sleeve 140.By so, handle 142 can prevent that the decline of king-rod 145 is moved unintentionally, thereby avoid the case accident of stopper 142 to take place as the descend brake of moving and working of control stick 145.In addition, remove locating snap ring 6, in order not hinder by this regular mixture operation of the decline of tightening airtight medicated cap 5 caused bars 145, the part of handle 142 forms weak body 150 (for example coupling part of handle 142 and bar 145), when tightening airtight medicated cap 5, be preferably and fracture by the weak body of handle 142 or crooked.

Figure 44 has shown that also the airtight medicated cap 5 of the medicated cap that substantially constitutes inboard container 23 is provided with the example of relief valve.During intrinsic pressure risings of inboard container 23, the pressure of inboard container 23 can be remained on certain limit substantially by unlatching relief valve 152.Adjust means by the such pressure of relief valve 152 are set in inboard container 23, for example can prevent that this intrinsic pressure meeting presses down stopper 142, and stopper 142 is come off when sodium hypochlorite generates oxygen and makes the intrinsic pressure rising of inboard container 23.

The open means of the pressure that in Figure 44, shows, constitute by ball and spring, also can replace and utilize gas-liquid separation membrane, inboard container 23 gas inside are put to air by gas-liquid separation membrane, perhaps, the soft packing filler of the softish resin manufacture of separated foam (for example by) that will have a resiliency is used as the enclosed material of airtight medicated cap 5, can be by adjusting the compression degree of filler, gas can be spilt, and blocking-up liquid pass through.

As from the top different viewpoint of variation that is shown in Figure 42, make inboard container 23 by 2 relatively the member of displacement (the 1st member 140 and the 2nd member 144,142,143) form, with the state that is fixed in outside container 21 and make other member 144,142,143 displacements make inboard container 23 open, the composition in the inboard container 23 is flowed out in the container 21 of the outside by a part of member 140.According to the particular instantiation of this viewpoint in Figure 45,46.

Be shown in the variation of Figure 45, have that to be fixed on outside container be sleeve 140 (the 1st member) in the bottle 21, and be arranged at intervals with the 2nd member 150 of 2 flanges 142,143 up and down, by being inlaid in, the 2nd member 150 forms inboard container 23 in the sleeve 140.

Remove locating snap ring 6, as tighten airtight medicated cap 5 bar 145 is descended, can press down the 2nd member 150 by this bar 145, the result can partly open inboard container 23, and the compositions in the inboard container 23 are flow in the bottle 21.As shown in figure 45, the main body 152 of the 2nd member 150 is cylindric in this way, and the through hole shown in reference marks 152 can be set.

In the variation shown in Figure 46, the 2nd member 150 is positioned at the outside of sleeve 140, by the end 155 lower end of the cylindrical body 151 of the 2nd member 150 being closed, this end 155 and sleeve 140 airtight contacts, and the upper end of cylindrical body 151 has medial flange 156, the inner of medial flange 156 and sleeve 140 airtight contacts by so, form inboard container 23 in the outside of sleeve 140.

Remove locating snap ring 6, as tighten airtight medicated cap 5 bar 145 is descended, can press down the 2nd member 150 by this bar 145, the result, the end 155 of the 2nd member 150 is separated from the lower end of sleeve 140, inboard container 23 parts are opened, the composition in the inboard container 23 flow in the bottle 21.

About the cut-out aid 26 that in concrete examples such as Figure 16, contains, as shown in Figure 47～Figure 50, recess 26b is set at its top, can in this recess 26b, place Powdered carbonic acid hydrogen sodium.After removing locating snap ring 42, as press down push rod 41, force downwards to move, the horizontal segment part 23b of inboard container 23 can be cut off, inboard container 23 is fallen, cut off aid 26 simultaneously and also together drop into (Figure 48) in the bottle 21 just cut off aid 26.Thus, remove the composition that places in the inboard container, cut off the sodium bicarbonate that places among the recess 26b of aid 26 and also flow in the bottle 21,3 kinds of compositions that comprise sodium bicarbonate in bottle 21 mix, and can generate the sterilization water that contains as the sodium bicarbonate of buffer agent.

Cut-out sword 26a in that the lower end that cuts off aid 26 forms is preferably the profile that has from the intelligible inclination of Figure 47.In addition, cut off sword 26a and can be provided with outstanding sharp front end 26c bottom downwards at it.When the cut-out aid 26 with cut-out sword 26a is pressed down by push rod 41, sharp front end 26c bottom is trapped among the horizontal segment part 23b of inboard container 23 and its part of break-through, then use the cut-out sword 26a of slope profile constantly to cut horizontal segment part 23b, finally, will all cut off around the horizontal segment part 23b.So inboard container 23 can be cut, in addition, can reduce the size that this cuts required power by cutting off sword 26a.

When in inboard container 23, placing sodium hypochlorite, bottle 21 for keeping, if the gas that is generated by sodium hypochlorite is discharged to the outside, so can be shown in Figure 51, bottom at the recess 26b that cuts off aid 26 is provided with open-work 160, the 2nd open-work 161 also is set in the push rod 41 of the lid that plays recess 26b simultaneously, and gas can pass through these open-works 160,161 and discharge to the outside.Reference marks 163 has shown the 1st air penetrating film that hides the 1st open-work 160 shown in Figure 51, and 164 have shown the 2nd air penetrating film that hides the 2nd open-work 161.

Variation as Figure 51, shown in Figure 52, connect the gas that the core that cuts off aid 26 is provided with the tubular that extends downwards from the core of push rod 41 and emit path 166, the gas that the sodium hypochlorite in the inboard container 23 are emitted can be released into the outside by the path 166 of emitting of this gas.The reference marks 167 of Figure 52 is check-valves.

Cushioning effect

Figure 53 has shown the variation of the pH value that causes by mixing hydrochloric acid in sodium hypochlorite.The ■ labelling is the pH value when sneaking into hydrochloric acid in the aqueous solution that contains sodium hypochlorite and sodium bicarbonate, and ▲ labelling is the pH value when only sneaking into hydrochloric acid in sodium hypochlorite.Used each composition is as follows in this experiment.

(1) tap water 250mL

(2) sodium hypochlorite (concentration is 12%) 0.4mL

(3) hydrochloric acid (concentration is 7.2%)

(4) sodium bicarbonate 0.3g

During the data of gathering the ■ labelling be, in tap water, be mixed with in the aqueous solution of sodium hypochlorite and sodium bicarbonate, constantly a small amount of drop into hydrochloric acid after, the pH that measures sterilization water changes.Take ▲ during the data of labelling be, in tap water, be mixed with in the aqueous solution of sodium hypochlorite, constantly a small amount of drop into hydrochloric acid after, the pH that measures sterilization water changes.

Shown in Figure 53, in the experiment that does not add sodium bicarbonate, the pH value of the water that sterilizes as can be known is very responsive for the increase of hydrochloric acid content, and its pH value descends rapidly and drops to the highly acid scope quickly.Be sharply to descend to pH3 particularly from pH6.Relative therewith, the reduction of the water pH that in the experiment that adds sodium bicarbonate, can suppress to sterilize, particularly the decline to pH5 is slowly.The practitioner of the industry can understand by this experimental result, is adjusted to neutral range or faintly acid scope though can add will the sterilize pH value of water of hydrochloric acid in sodium hypochlorite, and it is easier to add sodium bicarbonate.And, can suppress the pH change of the sterilization water that generated.In addition, when using behind the sterilization water dilute with water that is generated, the water of use for example is alkaline well water, adds acid such as hydrochloric acid when adding the buffer agent of sodium bicarbonate etc. and makes it to generate carbonic acid, can obtain identical buffering effect.In addition, also can obtain buffering effect by in the sterilization water that is generated, adding the carbonate aqueous solution of carbon dioxide or high concentration.

Claims (35)

1. generate the method for sterilization water by hypochlorous acid or chlorous acid, it is characterized in that, preparation contains hypochlorite or chlorite and is placed in the 1st composition of the 1st confined space and contain acid and placed the 2nd composition in the 2nd confined space, by above-mentioned the 1st composition and above-mentioned the 2nd composition are mixed generation sterilization water, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, make it when mixing, to generate and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

2. the method by hypochlorous acid or chlorous acid generation sterilization water as claimed in claim 1, its feature is that also the buffer agent and above-mentioned the 1st composition that contain bicarbonate are placed jointly in above-mentioned the 1st confined space.

3. the method that generates sterilization water by hypochlorous acid or chlorous acid as claimed in claim 1, its feature also is, also prepare to contain buffer agent and placed the 3rd composition in the 3rd confined space, contain bicarbonate in this buffer agent, when above-mentioned the 1st composition and the mixing of above-mentioned the 2nd composition, add above-mentioned the 3rd composition and mix.

4. as each described method that generates sterilization water by hypochlorous acid or chlorous acid in the claim 1～3, its feature also is, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, make to be placed in whole above-mentioned the 1st composition of above-mentioned the 1st confined space and placed that generation has the effective chlorine density of regulation and is faintly acid or neutral sterilization water when whole above-mentioned the 2nd composition of above-mentioned the 2nd confined space mixes.

5. the method by hypochlorous acid or chlorous acid generation sterilization water as claimed in claim 1, its feature is that also above-mentioned the 1st confined space is formed by the 1st container, above-mentioned the 2nd confined space is formed by the 2nd container.

6. the method by hypochlorous acid or chlorous acid generation sterilization water as claimed in claim 1, its feature is that also above-mentioned the 1st confined space and above-mentioned the 2nd confined space form in single container.

7. as each described method by hypochlorous acid or chlorous acid generation sterilization water in the claim 1～4, its feature is that also above-mentioned the 1st composition is the above alkaline solution of pH10.

8. generate the method for sterilization water by hypochlorous acid or chlorous acid, it is characterized in that, preparation contain hypochlorite or chloritic and by place in the 1st composition of the 1st confined space and contain acid and placed the 2nd composition in the 2nd confined space, by being mixed with the water of ormal weight, above-mentioned the 1st composition and above-mentioned the 2nd composition generate sterilization water, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water with the water of afore mentioned rules amount.

9. the method by hypochlorous acid or chlorous acid generation sterilization water as claimed in claim 8, its feature is that also the buffer agent and above-mentioned the 1st composition that contain bicarbonate are placed jointly in above-mentioned the 1st confined space.

10. the method that generates sterilization water by hypochlorous acid or chlorous acid as claimed in claim 8, its feature also is, that also prepare to contain buffer agent and placed the 3rd composition in the 3rd confined space, contain bicarbonate in this buffer agent, when above-mentioned the 1st composition and above-mentioned the 2nd composition mix with water, add above-mentioned the 3rd composition and mix.

11. the method that generates sterilization water by hypochlorous acid or chlorous acid as claimed in claim 8, its feature also is, also prepare the guide of the above-mentioned water yield of record,, add above-mentioned the 1st composition and above-mentioned the 2nd composition in the water of the afore mentioned rules amount that in this guide, writes down referring to this guide.

12. raw bactericidal material assembly, it is characterized in that, possess the hypochlorite of containing or chloritic the 1st composition, acidiferous the 2nd composition, avoid above-mentioned the 1st composition and above-mentioned the 2nd composition blended with it being separated the single container that places and by in the artificial reinforcing of this external container and the displacement member of variable bit in the next door, displacement by this displacement member, above-mentioned the 1st composition and above-mentioned the 2nd composition can be mixed in said vesse generate sterilization water, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

13. raw bactericidal material assembly as claimed in claim 12, its feature also is, also has the 3rd composition that contains buffer agent, contain bicarbonate in this buffer agent, above-mentioned the 1st composition, the 2nd composition, the 3rd composition are not separated with the next door with not mixing mutually, by making this displacement member displacement,, above-mentioned the 1st composition, above-mentioned the 2nd composition, above-mentioned the 3rd composition generate sterilization water in said vesse thereby being mixed to the above-mentioned displacement member application of force.

14. raw bactericidal material assembly as claimed in claim 12, its feature are that also above-mentioned displacement member has sword, destroy above-mentioned next door by this sword above-mentioned the 1st composition and above-mentioned the 2nd composition are mixed.

15. raw bactericidal material assembly, it is characterized in that, has outside container, inboard container, airtight airtight member and control member that should the inboard container, this outside container places the arbitrary composition that contains in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, this inboard container placed in this outside container and place above-mentioned the 1st composition or above-mentioned the 2nd composition in another composition, this control member links to each other with above-mentioned outside container and designs and can enter from this outside external container, by handling this control member, above-mentioned inboard container can break away from from above-mentioned airtight member, above-mentioned another composition in this inboard container can flow into and generate sterilization water in the container of the above-mentioned outside, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

16. raw bactericidal material assembly as claimed in claim 15, its feature also is, have the 1st, the 2nd separate space in the above-mentioned inboard container, in the 1st space, placed above-mentioned the 1st composition or above-mentioned the 2nd composition, place the buffer agent of potassium-containing hydrogen salt in above-mentioned the 2nd space.

17. as claim 15 or 16 described raw bactericidal material assemblies, its feature is that also the aforesaid operations member comprises the airtight medicated cap of above-mentioned outside container.

18. as claim 15 or 16 described raw bactericidal material assemblies, its feature is that also the aforesaid operations member has the push rod that exposed portions serve is arranged on the container of the above-mentioned outside.

19. as claim 15 or 16 described raw bactericidal material assemblies, its feature also is, above-mentioned outside container has oral area, in addition, this raw bactericidal material assembly also has the airtight member of circumference that is provided with in the inside of this oral area, have by the movable link of the airtight circumferential groove of the airtight member of this circumference and the airtight medicated cap of inaccessible above-mentioned oral area, above-mentioned inboard container is made of the circumferential groove of above-mentioned movable link, by operating above-mentioned airtight medicated cap above-mentioned movable link is descended, above-mentioned circumferential groove is broken away from from above-mentioned airtight member, thereby above-mentioned another composition in this circumferential groove is flow in the container of the above-mentioned outside.

20. raw bactericidal material assembly, it is characterized in that, has outside container, inboard container, stopper and control member, this outside container places the arbitrary composition that contains in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, this inboard container is placed in this outside container and is placed another composition in above-mentioned the 1st composition or the 2nd composition, this stopper forms and is flush-mounted in the opening that is communicated with the inner space of above-mentioned outside container in this inboard container, this control member can enter from the outside of above-mentioned outside container and link to each other with above-mentioned stopper, by on purpose handling this control member, mobile interlock with the aforesaid operations member, above-mentioned stopper is broken away from from the above-mentioned opening of above-mentioned inboard container, above-mentioned another composition of taking this in this above-mentioned inboard container can flow into generation sterilization water in the container of the above-mentioned outside, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

21. raw bactericidal material assembly as claimed in claim 20, its feature are that also the aforesaid operations member contains the airtight medicated cap of above-mentioned outside container.

22. raw bactericidal material assembly, described assembly possesses and places the outside container that contains the arbitrary composition in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, the inboard container that places another composition in above-mentioned the 1st composition or above-mentioned the 2nd composition that in this outside container, places, it is characterized in that, in the inner space of above-mentioned inboard container, form the 1st member that is fixed in above-mentioned outside container, the 2nd member that can move with respect to the 1st member, in addition, have that to enter from the outside of above-mentioned outside container and the control member interlock of above-mentioned the 2nd member, by this control member on purpose being operated the mobile interlock that can make above-mentioned the 2nd member and this control member, above-mentioned inboard container part is opened, thereby make above-mentioned another composition in the above-mentioned inboard container can flow into generation sterilization water in the container of the above-mentioned outside, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

23. raw bactericidal material assembly as claimed in claim 22, its feature are that also the aforesaid operations member contains the airtight medicated cap of above-mentioned outside container.

24. raw bactericidal material assembly, it is characterized in that, has outside container, inboard container and airtight medicated cap, above-mentioned outside container has the outside oral area used of container and places the arbitrary composition that contains in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, above-mentioned inboard vessel upward open upper end open portion is arranged and place above-mentioned the 1st composition or above-mentioned the 2nd composition in another composition, this upper end open portion is fixed in the container of the above-mentioned outside by engaging with oral area that above-mentioned outside container is used, above-mentioned airtight medicated cap can be closed the upper end open portion of above-mentioned inboard container when closing the oral area that above-mentioned outside container uses, after taking off this airtight medicated cap, by pressing the above-mentioned upper end open portion that states inboard container downwards, remove the engaging of this upper end open portion and above-mentioned outside container with oral area, above-mentioned inboard container is dropped in the container of the above-mentioned outside, above-mentioned another composition in the above-mentioned inboard container can flow into and generate sterilization water in the container of the above-mentioned outside, can adjust above-mentioned the 1st composition and above-mentioned the 2nd composition, generate when making it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

25. raw bactericidal material assembly as claimed in claim 24, its feature also be, above-mentioned at least upper end open portion is by with referring to that power just can make by easily diastrophic soft material in the above-mentioned inboard container.

26. raw bactericidal material assembly, it is characterized in that, has outside container, inboard container and airtight medicated cap, above-mentioned outside container has the outside oral area used of container and places the arbitrary composition that contains in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, above-mentioned inboard vessel upward open upper end open portion is arranged and place above-mentioned the 1st composition or above-mentioned the 2nd composition in another composition, this upper end open portion is fixed in the container of the above-mentioned outside by engaging with oral area with above-mentioned outside container, above-mentioned airtight medicated cap can closed the upper end open portion that above-mentioned outside container cuts out above-mentioned inboard container in oral area, after taking off this airtight medicated cap, above-mentioned inboard container is taken out from above-mentioned outside container, thereby above-mentioned another composition in the above-mentioned inboard container is flow into generate sterilization water in the container of the above-mentioned outside, generate in the time of can adjusting above-mentioned the 1st composition and above-mentioned the 2nd composition and make it to mix and have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

27. sterilization water generates complexes, it is characterized in that, has the 1st container, the 2nd container and guide, the 1st container places the arbitrary composition that contains in hypochlorite or chloritic the 1st composition or acidiferous the 2nd composition, the 2nd container places another composition in above-mentioned the 1st composition or above-mentioned the 2nd composition, this guide records has the amount of above-mentioned the 1st composition, the amount of above-mentioned the 2nd composition and mix the above-mentioned the 1st, the amount of the water of the 2nd composition, indication according to this guide, in the water of ormal weight, by mixing the above-mentioned the 1st, the 2nd composition can generate sterilization water, can adjust to generate when above-mentioned the 1st composition and above-mentioned the 2nd composition make it to mix with the water of afore mentioned rules amount to have the effective chlorine density of regulation and be faintly acid or neutral sterilization water.

28. space sterilizing unit; it is characterized in that; have supersonic generator, electronic main fan and the 2nd electric fan; above-mentioned supersonic generator can make sterilization water micronize; above-mentioned sterilization water contains and has the germ-resistant effective chlorine density in the space of being suitable for and for faintly acid or neutral hypochlorous acid; above-mentioned electronic main fan is blown to open space; above-mentioned the 2nd electric fan will be transported to by the micronize sterilization water smoke that above-mentioned supersonic generator generates above-mentioned main fan near, above-mentioned micronize sterilization water smoke can spray by the wind that above-mentioned main fan generates.

29. space as claimed in claim 28 sterilizing unit; its feature also is; also have the 1st composition, the 2nd composition and boxlike jar; above-mentioned the 1st composition contains prior hypochlorite and the quilt of having adjusted concentration and is placed in the 1st confined space; above-mentioned the 2nd composition contains prior acid and the quilt of having adjusted concentration and is placed in the 2nd confined space; above-mentioned boxlike jar place through user mix above-mentioned two compositions and generate contain above-mentioned hypochlorous sterilization water, the sterilization water of being supplied with by this boxlike jar is by above-mentioned supersonic generator micronize.

30. space as claimed in claim 29 sterilizing unit, its feature also be, above-mentioned space sterilizing unit can select to utilize above-mentioned boxlike jar above-mentioned sterilization water the supply form or utilize the supply form of pipe arrangement.

31. portable space sterilizing unit; it is characterized in that; has the boxlike jar; supersonic generator; electronic main fan and the 2nd electric fan; above-mentioned boxlike jar place through user mix the 1st composition and the 2nd composition and generate have the germ-resistant effective chlorine density in the space of being suitable for and be faintly acid or neutral sterilization water; above-mentioned the 1st composition contains prior hypochlorite and the quilt of having adjusted concentration and is placed in the 1st confined space; above-mentioned the 2nd composition contains prior acid and the quilt of having adjusted concentration and is placed in the 2nd confined space; above-mentioned supersonic generator can make the sterilization water micronize of being supplied with by this boxlike jar; above-mentioned electronic main fan can be blown to open space; above-mentioned the 2nd electric fan the micronize sterilization water smoke that is generated by above-mentioned supersonic generator can be transported to above-mentioned main fan near, above-mentioned micronize sterilization water smoke can spray by the wind that above-mentioned main fan generates.

32. portable space sterilizing unit as claimed in claim 31, its feature also is, during with above-mentioned the 1st composition and the mixing of the 2nd composition, perhaps above-mentioned the 1st composition and the dilute with water generation of the 2nd composition mixing back had the sterilization water that is suitable for the germ-resistant effective chlorine density in space.

33. the portable space sterilizing unit described in claim 31 or 32, its feature are that also above-mentioned main fan and above-mentioned the 2nd electric fan are formed by general motor driven fan.

34. space method for disinfection; it is characterized in that; have sterilization water and generate operation; sterilization water places operation; the sterilization mist generates operation; pass on operation and sterilization water and spray operation; above-mentioned sterilization water generates the operation person of being to use to be mixed the 1st composition and the 2nd composition and generates to have and be suitable for the germ-resistant effective chlorine density in space and be the operation of faintly acid or neutral sterilization water; above-mentioned the 1st composition contains prior hypochlorite and the quilt of having adjusted concentration and is placed in the 1st confined space; above-mentioned the 2nd composition contains prior acid and the quilt of having adjusted concentration and is placed in the 2nd confined space; above-mentioned sterilization water places operation for being placed the operation in jar by the sterilization water that this water that sterilizes generates the operation generation; it is to make by the above-mentioned jar of above-mentioned sterilization water micronize of supplying with to make sterilization water generate the operation of spray that above-mentioned sterilization mist generates operation; the above-mentioned operation of passing on is that above-mentioned sterilization spray stream is transferred near operation to the main fan of open space air-supply, and it is to follow the wind that is generated with above-mentioned main fan with the operation of being sprayed to a distant place near the sterilization spray stream that transfers to the above-mentioned electric fan that above-mentioned sterilization water sprays operation.

35. space as claimed in claim 34 method for disinfection, its feature also be, when mixing above-mentioned the 1st composition and the 2nd composition or after mixing above-mentioned the 1st composition and the 2nd composition, and the mixed diluting water.

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