CN1760329A - Fire retardant, anticorrosive insecticide, and preparation method - Google Patents
Fire retardant, anticorrosive insecticide, and preparation method Download PDFInfo
- Publication number
- CN1760329A CN1760329A CN 200510115889 CN200510115889A CN1760329A CN 1760329 A CN1760329 A CN 1760329A CN 200510115889 CN200510115889 CN 200510115889 CN 200510115889 A CN200510115889 A CN 200510115889A CN 1760329 A CN1760329 A CN 1760329A
- Authority
- CN
- China
- Prior art keywords
- weight parts
- component
- fire retardant
- solution
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Fireproofing Substances (AREA)
Abstract
A flame-retarding antiseptic insecticide is a solution composed of the component A consisting of diammonium hydrogen phosphate, ammonium sulfate, borax and boric acid, the component B consisting of sodium fluoride and sodium octaborate, and the component C (water). It is prepared through adding component A to C, heating while stirring until the solution becomes transparent, adding component B, heating while stirring, and cooling.
Description
Technical field
The present invention relates to a kind of fire retardant, anticorrosive insecticide, is a kind of multi-usage fire retardant, anticorrosive insecticide that can be applied to timber, textiles and paper.
Background technology
Occurring in nature overwhelming majority natural organic has inflammableness and perishability, these two kinds of defectives cause this class material or its derived material for example yarn fabric and paper all have characteristics inflammable, perishable, that easily damage by worms, make the historical material that much has historical value or historical relic, buildings fail to preserve.
In order to make full use of these materials, be necessary these materials are carried out study on the modification, make its performance obtain extending and development, more help being used by the mankind.In all age, the mankind are exploring this always untiringly, for these materials are protected, have created various methods, have the method for physics chemical method also to be arranged, the method that also has physical chemistry to combine.
Fire-retardant and anticorrosion two aspects handling as modification are always considered separately and are handled by separated at present, or handle step by step, have produced the problem on many performances, use and the cost thus.For example adopt fire retardant and sanitas step by step material to be handled separately, executive cost is higher, and material is to the absorption problem of treatment agent of construction at twice, and the acidity of using in the treatment agent or alkali electroless composition are to the strength of materials and other original Effect on Performance, also have environmentally harmful material pollution on the environment, all make this treatment agent have such or such deficiency.
Summary of the invention
The object of the present invention is to provide the fire retardant, anticorrosive insecticide of a kind of tool, make and to carry out fire-retardant and can carry out simultaneously during rotproofing, and the application of the material after handling is wider with fire-retardant, anticorrosion and insecticidal function.
Fire-retardant, anticorrosive insecticide provided by the invention, form the solution that part is mixed and made into by following A, B, C three: the A component is made up of Secondary ammonium phosphate 80-240 weight part, ammonium sulfate 40-120 weight part, borax 25-50 weight part, boric acid 8-25 weight part, the B component is made up of Sodium Fluoride 1-12 weight part, eight Sodium Tetraborate 1-7 weight parts, and the C component is water 1000 weight parts.
Most preferred mode is, described A component is made up of Secondary ammonium phosphate 100 weight parts, ammonium sulfate 50 weight parts, borax 20 weight parts, boric acid 10 weight parts, correspondingly the B component is made up of Sodium Fluoride 10 weight parts, eight Sodium Tetraboratees, 5 weight parts, and the C component is water 1000 weight parts.The fire retardant, anticorrosive insecticide that adopts this prescription to make is based on the characteristics exploitation of timber, be specially adapted to all kinds of fire retardant anticorrosion desinsections with infiltrative natural timber each several part artificial board, the for example fire prevention of solid wood board, wood-based plate, furniture, anticorrosion, mildew-resistant processing do not have broken ring to the native texture and the outward appearance of timber.
Characteristics according to the dry goods material, described A component is made up of Secondary ammonium phosphate 160 weight parts, ammonium sulfate 80 weight parts, borax 20 weight parts, boric acid 10 weight parts, correspondingly the B component is made up of Sodium Fluoride 3 weight parts, eight Sodium Tetraboratees, 1.64 weight parts, and the C component is water 1000 weight parts.The fire retardant, anticorrosive insecticide of being made by this prescription is particularly suitable for the dry goods material and uses, and handles as the fire prevention of linen-cotton kind fabric, synthetic class organic fabric, anticorrosion, insect protected, mildew-resistant.
Characteristics according to paper-like materials, described A component is made up of Secondary ammonium phosphate 200 weight parts, ammonium sulfate 100 weight parts, borax 40 weight parts, boric acid 20 weight parts, correspondingly the B component is made up of Sodium Fluoride 2 weight parts, eight Sodium Tetraboratees, 1.64 weight parts, and the C component is water 1000 weight parts.The fire retardant, anticorrosive insecticide of being made by this prescription is particularly suitable for paper-like materials and uses, as be used for the fire prevention of important literature, artistic products, bank note, anticorrosion, insect protected, antirust, mildew-resistant is handled.
The present invention also provides the production method of above-mentioned fire retardant, anticorrosive insecticide, comprises the steps: that (1) joins described A component in the C component, in reactor temperature is raised to 50 ℃, heats while stirring, and is the fusion vitreous state to solution; (2) add B component in above-mentioned solution, lasting stirring heating makes solution reach the fusion vitreous state; (3) above-mentioned solution is cooled to normal temperature.
This fire retardant, anticorrosive insecticide outward appearance provided by the invention is transparent settled solution, and proportion is 1.10-1.28, and pH value is 4.0-7.0.This fire retardant, anticorrosive insecticide, adopt plurality of raw materials to utilize its synergy, it is fire-retardant that it is had simultaneously, anticorrosion, mildew-resistant, antirust, insecticidal action, can be used for timber, paper, fabric fire-retardant, anticorrosion, mildew-resistant, biological proofing, can directly soak or spary, test by national building engineering quality supervision inspection center, its fire-retardant index can reach " GB50222-1995 code for fire prevention design of interior decoration of buildings " B1 level (difficult combustion level) requirement, anticorrosion index reaches " GB50206-2002 timber structure construction quality acceptance specification " HJI level-HJIII level requirement, and environmental protection index reaches total volatile organism TVOC and formaldehyde content requirement that " GB50325-2001 civil building engineering indoor environmental pollution control standard " requires.So can disposable material requested be handled, make it reach the fire retardant, anticorrosive double effects, and this preparation is minimum to the strength of materials and other original Effect on Performance for being neutrality or slightly acidic.In addition, this preparation also has certain mildew-resistant, insect protected performance.So the material after handling had both had security, has weather resistance again, and environment is had no adverse effects, make the material range of application after the processing wider, the characteristics advantage that self has can obtain performance to a greater extent, and economic and social benefit is met jointly.This fire retardant, anticorrosive insecticide is tried out in a plurality of key state projects, has obtained net effect preferably.
Embodiment
Below in conjunction with specific embodiment fire retardant, anticorrosive insecticide of the present invention and preparation method thereof is described further.
Embodiment 1
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to the wood type material: handle as the fire prevention of solid wood board, wood-based plate, furniture, anticorrosion, insect protected, mildew-resistant.
Component A is Secondary ammonium phosphate 100 grams, ammonium sulfate 50 grams, borax 20 grams, boric acid 10 grams;
B component is Sodium Fluoride 10 grams, eight Sodium Tetraboratees, 5 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion vitreous state; B component is joined in the solution of the first step reaction, continue stirring heating 30 minutes, make solution reach the fusion vitreous state, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Embodiment 2
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to the dry goods material: handle as the fire prevention of linen-cotton kind fabric, synthetic class organic fabric, anticorrosion, insect protected, antirust, mildew-resistant.
Component A is Secondary ammonium phosphate 160 grams, ammonium sulfate 80 grams, borax 20 grams, boric acid 10 grams;
B component is Sodium Fluoride 3 grams, eight Sodium Tetraboratees, 1.64 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion vitreous state; B component is joined in the solution of the first step reaction, continue stirring heating 30 minutes, make solution reach the fusion vitreous state, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Embodiment 3
Fire retardant, anticorrosive insecticide in the present embodiment is applicable to paper-like materials: as be used for the fire prevention of important literature, artistic products, bank note, anticorrosion, insect protected, mildew-resistant and handle.
Component A is Secondary ammonium phosphate 200 grams, ammonium sulfate 100 grams, borax 40 grams, boric acid 20 grams;
B component is Sodium Fluoride 2 grams, eight Sodium Tetraboratees, 1.64 grams;
Component C is water 1000 grams.
The A component is joined in the C component, in reactor temperature is risen to 50 ℃, heat while stirring, the time is 40 minutes, to solution fusion vitreous state; B component is joined in the solution of the first step reaction, continue stirring heating 30 minutes, make solution reach the fusion vitreous state, be cooled to normal temperature then, obtaining product density is that 1.10-1.28, pH value are the transparent clear liquid state product of 4.0-7.0.
Claims (5)
1, a kind of fire retardant, anticorrosive insecticide, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: the A component is made up of Secondary ammonium phosphate 80-240 weight part, ammonium sulfate 40-120 weight part, borax 25-50 weight part, boric acid 8-25 weight part, the B component is made up of Sodium Fluoride 1-12 weight part, eight Sodium Tetraborate 1-7 weight parts, and the C component is water 1000 weight parts.
2, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of Secondary ammonium phosphate 100 weight parts, ammonium sulfate 50 weight parts, borax 20 weight parts, boric acid 10 weight parts, correspondingly the B component is made up of Sodium Fluoride 10 weight parts, eight Sodium Tetraboratees, 5 weight parts, and the C component is water 1000 weight parts.
3, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of Secondary ammonium phosphate 160 weight parts, ammonium sulfate 80 weight parts, borax 20 weight parts, boric acid 10 weight parts, correspondingly the B component is made up of Sodium Fluoride 3 weight parts, eight Sodium Tetraboratees, 1.64 weight parts, and the C component is water 1000 weight parts.
4, fire retardant, anticorrosive insecticide as claimed in claim 1, it is characterized in that: form the solution that part is mixed and made into by following A, B, C three: described A component is made up of Secondary ammonium phosphate 200 weight parts, ammonium sulfate 100 weight parts, borax 40 weight parts, boric acid 20 weight parts, correspondingly the B component is made up of Sodium Fluoride 2 weight parts, eight Sodium Tetraboratees, 1.64 weight parts, and the C component is water 1000 weight parts.
5, the preparation method of described fire retardant, anticorrosive insecticide one of in a kind of claim 1 to 4, it is characterized in that this method comprises the steps: that (1) joins described A component in the C component, in reactor, temperature is raised to 50 ℃, heats while stirring, to solution fusion vitreous state; (2) add B component in above-mentioned solution, lasting stirring heating makes solution reach the fusion vitreous state; (3) above-mentioned solution is cooled to normal temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101158899A CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101158899A CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1760329A true CN1760329A (en) | 2006-04-19 |
| CN100333644C CN100333644C (en) | 2007-08-29 |
Family
ID=36706553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101158899A Expired - Fee Related CN100333644C (en) | 2005-11-10 | 2005-11-10 | Fire retardant, anticorrosive insecticide, and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100333644C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103612305A (en) * | 2013-11-07 | 2014-03-05 | 陕西师范大学 | Fireproofing and insect-proofing modifying liquid for collection tools of files and cultural relics and application of modifying liquid |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031494C (en) * | 1994-01-08 | 1996-04-10 | 谭永良 | Flame retarding anticorrosive agent for wood (bamboo) or plywood |
| CN1124272A (en) * | 1994-12-04 | 1996-06-12 | 卢力华 | Fire-proof flame-retarded agent and its producing method and use |
| CN1439766A (en) * | 2002-02-23 | 2003-09-03 | 孙晓平 | Fire-proofing agent |
| JP2003246985A (en) * | 2002-02-25 | 2003-09-05 | Itoki Crebio Corp | Antibacterial and flameproofing agent |
-
2005
- 2005-11-10 CN CNB2005101158899A patent/CN100333644C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103612305A (en) * | 2013-11-07 | 2014-03-05 | 陕西师范大学 | Fireproofing and insect-proofing modifying liquid for collection tools of files and cultural relics and application of modifying liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100333644C (en) | 2007-08-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6620349B1 (en) | Fire retardant compositions and methods for preserving wood products | |
| CN107880708B (en) | Waterproof durable fireproof wood and preparation method thereof | |
| Vakhitova | Fire retardant nanocoating for wood protection | |
| Mali et al. | Morphology of wood degradation and flame retardants wood coating technology: an overview | |
| US8481168B2 (en) | Alginate-based building materials | |
| WO2003037531A1 (en) | Method and composition for treating substrates | |
| Elvira-León et al. | Epsomite as flame retardant treatment for wood: Preliminary study | |
| Beh et al. | Fire resistance and mechanical properties of intumescent coating using novel bioash for steel | |
| Han et al. | Performance of zinc borate-treated oriented structural straw board against mold fungi, decay fungi, and termites-a preliminary trial. | |
| US20210170623A1 (en) | Green process for modifying wood | |
| Ali et al. | Fire Test and Effects of Fire Retardant on the Natural Ability of Timber: A Review. | |
| Ozkaya et al. | The effect of potassium carbonate, borax and wolmanit on the burning characteristics of oriented strandboard (OSB) | |
| CN103817755A (en) | Preparation method for corrosion-resistant and flame retardant crude wood | |
| Ryszard et al. | Smart environmentally friendly composite coatings for wood protection | |
| KR101947139B1 (en) | Vegetation board treated with flame-retardant and method for manufacturing the same | |
| CN108912939A (en) | A kind of transparency swelling type water flame-proof paint and its preparation method and application | |
| KR102255282B1 (en) | Flame retardant composition for wood, method for manufacturing flame-retardant wood using the same, and method for manufacturing flame-retardant and semi-non-combustible wood using the same | |
| CN1760329A (en) | Fire retardant, anticorrosive insecticide, and preparation method | |
| Badejo et al. | Static bending and moisture response of cement-bonded particleboard produced at different levels of percent chemical additive content in board | |
| CA3160581A1 (en) | A green process for modifying wood | |
| Li et al. | Flame retardance and antibacterial performance of wooden wallpaper treated with compasite modifying agent | |
| Gunbekler et al. | Increasing the physical and combustion performance of Oriental beech by impregnating borates and coating liquid glass | |
| Mitterová | Wood in building structures and its fire protection | |
| CN113664931B (en) | Single plate, laminated wood and preparation method thereof | |
| CN106393352A (en) | Waterborne plant straw fireproof emulsion and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070829 Termination date: 20091210 |