CN1757993A - Lithium bromide absorption type refrigerator and its gas phase addition method of surfactant - Google Patents

Lithium bromide absorption type refrigerator and its gas phase addition method of surfactant Download PDF

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Publication number
CN1757993A
CN1757993A CNA2005100476038A CN200510047603A CN1757993A CN 1757993 A CN1757993 A CN 1757993A CN A2005100476038 A CNA2005100476038 A CN A2005100476038A CN 200510047603 A CN200510047603 A CN 200510047603A CN 1757993 A CN1757993 A CN 1757993A
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China
Prior art keywords
absorber
gas phase
generator
lithium
interfacial agent
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Pending
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CNA2005100476038A
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Chinese (zh)
Inventor
高洪涛
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Dalian Maritime University
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Dalian Maritime University
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Priority to CNA2005100476038A priority Critical patent/CN1757993A/en
Publication of CN1757993A publication Critical patent/CN1757993A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

Abstract

A lithium bromide absorption type refrigerator with a feeder for feeding interface activator in gas state is disclosed. A method for feeding said interface activator includes such steps as loading the activator into said feeder, heating for evaporating the activator, and feeding the vapor of activator into refrigerating system to intensify the absorption function.

Description

The gas phase addition method of a kind of lithium-bromide absorption-type refrigerating machine and interfacial agent thereof
Technical field
The invention belongs to the Refrigeration ﹠ Air-Conditioning technical field.
Background technology
In history, since lithium bromide water solution when seething with excitement, can numerous air-bubble take place and make very unstability of solution surface in the generator of Absorption Refrigerator.For suppressing the generation of bubble, people attempt to use interfacial agent to reduce the surface tension of solution.And in experimentation, what the inhibition effect of bubble was more noticeable in the comparison generator is, because the adding of interfacial agent makes that absorber performance is improved greatly.So interfacial agent is used as sorbefacient and begins to be used.Like this, though actual set has been brought into use interfacial agent very early, people were almost completely unclear to the sorbefacient mechanism of interfacial agent at that time.Traditionally, people strengthen STUDY ON TRANSDERMAL ABSORPTION to interfacial agent, normally interfacial agent are mixed with lithium-bromide solution in advance, and then check its effect that strengthen to absorb, analyze its mechanism of action.Up to the present, explain, also do not obtain a generally acknowledged mechanism interpretation though there is the people to propose some.And the present invention proposes to add interfacial agent with the gas phase form, and interfacial agent is strengthened absorption mechanism research provides new method.
Summary of the invention
Purpose of the present invention is exactly at the method that people adopt liquid phase to add interfacial agent to be strengthened the situation that STUDY ON TRANSDERMAL ABSORPTION does not draw generally acknowledged mechanism interpretation, proposes the method that a kind of new research circle's surface-active agent is strengthened absorption mechanism.
Technical solution of the present invention is, a kind of lithium-bromide absorption-type refrigerating machine is made of absorber 1, evaporimeter 2, condenser 3, generator 4, interfacial agent gas phase adding set 5, tube connector 6, refrigerant vapor pipe 7, refrigerant tube 8, refrigerant vapor pipe 9, concentrated solution pipe 10 and weak solution pipe 11; Generator 4 links to each other by refrigerant vapor pipe 9 with condenser 3; Condenser 3 is being communicated with evaporimeter 2 by refrigerant tube 8; Evaporimeter 2 usefulness refrigerant vapor pipes 7 link to each other with absorber 1; Having two-way to be connected between absorber 1 and the generator 4, is respectively concentrated solution pipe 10 and weak solution pipe 11; Be connected by tube connector 6 between interfacial agent gas phase adding set 5 and the absorber 1, the interfacial agent steam is provided in absorber.
Use a kind of gas phase addition method of interfacial agent of lithium-bromide absorption-type refrigerating machine, lithium bromide water solution is heated in the generator 4, the steam that produces enters condenser 3 and is cooled, the water as refrigerant that is cooled enters sweat cooling in the evaporimeter 2, become steam and enter absorber 1, the bromize lithium concentrated solution that is come from generator 4 in absorber 1 absorbs, and the weak solution of formation is introduced heating evaporation in the generator 4 again.
When refrigeration system was moved, the activating agent of 50-400ppm was heated evaporation in the interfacial agent gas phase adding set 5, and the activating agent steam of generation enters in the absorber 1, strengthened the absorption of bromize lithium concentrated solution for the water as refrigerant steam that comes flash-pot 2.
Used activating agent is isooctanol 2-Ethyl-1-Hexanol, octanol 1-octanol, enanthol 1-Heptanol or hexanol 1-Hexanol.
The invention has the beneficial effects as follows, add interfacial agent with the gas phase form, directly act on sorbent surface, the effect that absorbs is strengthened in performance, for the absorption mechanism of research circle's surface-active agent provides new method.
Description of drawings
The present invention is further described below in conjunction with the drawings and specific embodiments.
Fig. 1 is a system architecture sketch of the present invention.
Wherein, 1. absorber, 2. evaporimeter, 3. condenser, 4. generator, 5. interfacial agent gas phase adding set, 6. tube connector, 7. refrigerant vapor pipe, 8. refrigerant tube, 9. refrigerant vapor pipe, 10. concentrated solution pipe, 11. weak solution pipes.
The specific embodiment
A kind of lithium-bromide absorption-type refrigerating machine is made of absorber 1, evaporimeter 2, condenser 3, generator 4, interfacial agent gas phase adding set 5, tube connector 6, refrigerant vapor pipe 7, refrigerant tube 8, refrigerant vapor pipe 9, concentrated solution pipe 10 and weak solution pipe 11; Generator 4 links to each other by refrigerant vapor pipe 9 with condenser 3; Condenser 3 is being communicated with evaporimeter 2 by refrigerant tube 8; Evaporimeter 2 usefulness refrigerant vapor pipes 7 link to each other with absorber 1; Having two-way to be connected between absorber 1 and the generator 4, is respectively concentrated solution pipe 10 and weak solution pipe 11; Be connected by tube connector 6 between interfacial agent gas phase adding set 5 and the absorber 1, the interfacial agent steam is provided in absorber.
Use a kind of gas phase addition method of interfacial agent of lithium-bromide absorption-type refrigerating machine, lithium bromide water solution is heated in the generator 4, the steam that produces enters condenser 3 and is cooled, the water as refrigerant that is cooled enters sweat cooling in the evaporimeter 2, become steam and enter absorber 1, the bromize lithium concentrated solution that is come from generator 4 in absorber 1 absorbs, and the weak solution of formation is introduced heating evaporation in the generator 4 again.
Whole system is vacuumized, vacuum 60Pa, start refrigeration system, connect power supply then, the isooctanol 2-Ethyl-1-Hexanol of the 200ppm of bromize lithium concentrated solution is heated evaporation in the interfacial agent gas phase adding set 5, the isooctanol 2-Ethyl-1-Hexanol steam that produces enters in the absorber 1, strengthens the absorption of bromize lithium concentrated solution for the water as refrigerant steam that comes flash-pot 2.
Tube connector 6, refrigerant vapor pipe 7, refrigerant tube 8, refrigerant vapor pipe 9, concentrated solution pipe 10 and weak solution pipe 11 are stainless steel tube.

Claims (3)

1. lithium-bromide absorption-type refrigerating machine, it is characterized in that, constitute by absorber (1), evaporimeter (2), condenser (3), generator (4), interfacial agent gas phase adding set (5), tube connector (6), refrigerant vapor pipe (7), refrigerant tube (8), refrigerant vapor pipe (9), concentrated solution pipe (10) and weak solution pipe (11); Generator (4) links to each other by refrigerant vapor pipe (9) with condenser (3); Condenser (3) is being communicated with evaporimeter (2) by refrigerant tube (8); Evaporimeter (2) links to each other with absorber (1) with refrigerant vapor pipe (7); Having two-way to be connected between absorber (1) and the generator (4), is respectively concentrated solution pipe (10) and weak solution pipe (11); Be connected by tube connector (6) between interfacial agent gas phase adding set (5) and the absorber (1), the interfacial agent steam is provided in absorber.
2. use the gas phase addition method of the interfacial agent of the described a kind of lithium-bromide absorption-type refrigerating machine of claim 1, it is characterized in that, lithium bromide water solution is heated in the generator (4), the steam that produces enters condenser (3) and is cooled, the water as refrigerant that is cooled enters sweat cooling in the evaporimeter (2), become steam and enter absorber (1), the bromize lithium concentrated solution that is come from generator (4) in absorber (1) absorbs, and the weak solution of formation is introduced heating evaporation in the generator (4) again; When refrigeration system is moved, the activating agent of 50-400ppm is heated evaporation in the interfacial agent gas phase adding set (5), the activating agent steam that produces enters in the absorber (1), strengthens the absorption of bromize lithium concentrated solution for the water as refrigerant steam that comes flash-pot (2).
3. the gas phase addition method of the interfacial agent of a kind of lithium-bromide absorption-type refrigerating machine according to claim 2 is characterized in that, used activating agent is 2-Ethyl-1-Hexanol, 1-octanol, 1-Heptanol or 1-Hexanol.
CNA2005100476038A 2005-10-29 2005-10-29 Lithium bromide absorption type refrigerator and its gas phase addition method of surfactant Pending CN1757993A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2005100476038A CN1757993A (en) 2005-10-29 2005-10-29 Lithium bromide absorption type refrigerator and its gas phase addition method of surfactant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2005100476038A CN1757993A (en) 2005-10-29 2005-10-29 Lithium bromide absorption type refrigerator and its gas phase addition method of surfactant

Publications (1)

Publication Number Publication Date
CN1757993A true CN1757993A (en) 2006-04-12

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CN (1) CN1757993A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100402951C (en) * 2006-08-08 2008-07-16 大连三洋制冷有限公司 Steam or hot water type lithium bromide absorption cooling and warming water machine
CN102207317A (en) * 2010-08-04 2011-10-05 周存文 Refrigerating and heating comprehensive supplying system of solar air conditioner
CN103512324A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Absorption type lithium bromide rapid clean drying system
CN103512267A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Lithium bromide solution absorption refrigeration device for gas phase adding interfacial agent
CN103512266A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Lithium bromide absorption type refrigerating machine and refrigerating method thereof
CN103528259A (en) * 2013-09-28 2014-01-22 昆山市周市溴化锂溶液厂 Lithium bromide absorption refrigerator of pre-mixture of flash steam and gas-phase surface active agent
CN103525372A (en) * 2013-09-28 2014-01-22 昆山市周市溴化锂溶液厂 Lithium bromide aqueous solution used for refrigerating machine
CN103542592A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Direct combustion type lithium bromide absorption cold and hot water unit with heat recycling function
CN103542591A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Lithium bromide absorption refrigerator with surface active agent gas phase adding device
CN103542593A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Smoke heat recycling type lithium bromide absorption cold-hot water unit

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100402951C (en) * 2006-08-08 2008-07-16 大连三洋制冷有限公司 Steam or hot water type lithium bromide absorption cooling and warming water machine
CN102207317A (en) * 2010-08-04 2011-10-05 周存文 Refrigerating and heating comprehensive supplying system of solar air conditioner
CN102207317B (en) * 2010-08-04 2013-05-01 周存文 Refrigerating and heating comprehensive supplying system of solar air conditioner
CN103512324A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Absorption type lithium bromide rapid clean drying system
CN103512267A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Lithium bromide solution absorption refrigeration device for gas phase adding interfacial agent
CN103512266A (en) * 2013-09-28 2014-01-15 昆山市周市溴化锂溶液厂 Lithium bromide absorption type refrigerating machine and refrigerating method thereof
CN103528259A (en) * 2013-09-28 2014-01-22 昆山市周市溴化锂溶液厂 Lithium bromide absorption refrigerator of pre-mixture of flash steam and gas-phase surface active agent
CN103525372A (en) * 2013-09-28 2014-01-22 昆山市周市溴化锂溶液厂 Lithium bromide aqueous solution used for refrigerating machine
CN103542592A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Direct combustion type lithium bromide absorption cold and hot water unit with heat recycling function
CN103542591A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Lithium bromide absorption refrigerator with surface active agent gas phase adding device
CN103542593A (en) * 2013-09-28 2014-01-29 昆山市周市溴化锂溶液厂 Smoke heat recycling type lithium bromide absorption cold-hot water unit

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