CN1752133A - 105 degree C butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic - Google Patents
105 degree C butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic Download PDFInfo
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- CN1752133A CN1752133A CN 200510094665 CN200510094665A CN1752133A CN 1752133 A CN1752133 A CN 1752133A CN 200510094665 CN200510094665 CN 200510094665 CN 200510094665 A CN200510094665 A CN 200510094665A CN 1752133 A CN1752133 A CN 1752133A
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- fire retardant
- polyvinyl chloride
- composite fire
- retardant insulating
- grade polyvinyl
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Abstract
A PVC plastic for the flame-retarding and insulating layer of butanenitrile working at105 deg.C is prepared from PVC resin, composite butanenitrile rubber P830, plasticizer, thermal stabilizer, lubricant, antioxidizing agent, optical mask, flame-retarding agent, and smoke inhibitor through mixing and extruding-plasticizing-granulating. It is suitable for electric cable.
Description
Technical field
The present invention relates to a kind of moiety of electric wire and cable jacket material, belong to the cable material technical field.
Background technology
Continuous development along with modern cable industry, various modern electrical equipment facilities (as communications service, elevator, sound equipment microphone, locomotive fixture wire etc.) are also more and more higher to the requirement of each side with electric wire, require very high as oil resistant, heat-resisting, soft, anti-solvent, over-all properties such as low temperature resistant.Paracril has superior oil resistant, solvent resistance because of having the polarity itrile group in the molecule.Polyvinyl chloride cable material with its modification can be used for the fixture wire of communication cable outer protective sleeve, microphone electric wire rope, motor lead and various power tool electrical apparatus products and the sheath of all size low tension wire.Along with the continuous generation of fire failure, people more and more require electric wire to have good flame retardant property.Therefore be that the butyronitrile composite fire retardant igelite of main properties-correcting agent arises at the historic moment with paracril.The used cable outer layer of this electric appliances normally adopted rubber type of material in the past, when using rubber type of material to produce cable sheath, not only to use specific rubber extrusion equipment electrogenesis in next life line cable, also to vulcanize, usually use sulphur as vulcanizing agent, this not only processing requirement strictness, scrap rate height, and also produce certain waste gas in the sulfidation, influence the healthy of workman.Use materials such as aluminium hydroxide in addition in a large number in order to reach flame retardant effect, these materials easily produce cracking and cause cable to use, and for this reason, it is easy to study a kind of technology, and the type material of being convenient to produce just becomes the challenge problem of cable material industry.
Summary of the invention
Technical problem to be solved by this invention is: overcome the defective of prior art, a kind of novel 105 ℃ of butyronitrile composite fire retardant insulating grade polyvinyl chloride plastics are provided, reach over-all propertieies such as oil resistant, heat-resisting, soft, anti-solvent, cold-resistant, fire-retardant and low cigarette.
Technical scheme of the present invention is: butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic, it is characterized in that being provided with in these plastics in parts by weight: 100 parts polyvinyl chloride (PVC) RESINS, the compounded nitrile rubber P830 of 20-40 part, the softening agent of 40-60 part, the thermo-stabilizer of 5-8 part, the lubricant of 0.3-0.7 part, 0.05-0.3 the oxidation inhibitor of part, 0.3-0.7 part photomask agent, the fire retardant of 5-8 part, 0.2-0.4 part press down fumicants.
Also be provided with in these plastics in parts by weight: the lime carbonate of 0-30 part.Described softening agent comprises trioctyl trimellitate and Di Iso Decyl Phthalate.Oxidation inhibitor comprises antioxidant 1010 and dihydroxyphenyl propane.Photomask agent comprises high-carbon black pigment and medium abrasion resistant carbon black.Thermo-stabilizer comprises three salt and disalt.Lubricant comprises barium stearate and paraffin.Fire retardant comprises zinc borate, antimonous oxide and tetrabromo-bisphenol.Pressing down fumicants is ferrocene.Lime carbonate comprises light calcium carbonate and the calcium of living.Described polyvinyl chloride (PVC) RESINS can be selected SG-2 or SG-3 type for use.
Technique effect of the present invention is: formulation ratio is scientific and reasonable, above-mentioned component mixes through the plastic high-speed mixer machine, after the extruder plastication granulation, become flame-resistant high-temperature-resistant electric wire product through wire ﹠ cable factory's secondary processing again, have excellent oil resistant, heat-resisting, soft, anti-solvent, over-all properties such as cold-resistant, fire-retardant, high temperature resistant.Environment friendly and pollution-free, the protection producers' is healthy, prolongs the work-ing life of product.Its correlated performance experimental result tabulation:
| Sequence number | Project name | Unit | Representative value | |
| 1 | The low-temperature impact embrittlement temperature | -35℃ | By | |
| 2 | Air chest thermal ageing ℃ * h (125 * 168) | |||
| The tensile strength velocity of variation | ％ | -6 | ||
| The elongation at break velocity of variation | ％ | -8 | ||
| 3 | The thermal ageing mass loss, | Test conditions | ℃×h | 115×168 |
| Mass loss | g/m | 20 | ||
| 4 | Oil resistant thermal ageing ℃ * h (100 * 15) | |||
| The tensile strength velocity of variation | ％ | +7 | ||
| The elongation at break velocity of variation | ％ | +6 | ||
| 5 | Oxygen index | ％ | 30 | |
Embodiment
The present invention is described in further detail below in conjunction with specific embodiment, so that advantage of the present invention is more obvious.Only in order to help to understand the present invention, protection scope of the present invention embodies in claims embodiment.Among the embodiment: polyvinyl chloride (PVC) RESINS can be selected SG-2 or SG-3 type for use; Screener can adopt high-carbon black pigment or medium abrasion resistant carbon black; Lubricant can adopt barium stearate or paraffin; Fire retardant can adopt zinc borate, antimonous oxide and tetrabromo-bisphenol; Press down fumicants and can adopt ferrocene; Softening agent can adopt trioctyl trimellitate and Di Iso Decyl Phthalate; Oxidation inhibitor can adopt antioxidant 1010 and dihydroxyphenyl propane.Thermo-stabilizer can adopt three salt and disalt.Lime carbonate can adopt light calcium carbonate and the calcium of living.Whole components of each embodiment are mixed through the plastic high-speed mixer machine, make 105 ℃ of butyronitrile composite fire retardant insulating grade polyvinyl chloride plastics after the extruder plastication granulation.
Embodiment 1:
Composition consumption part (weight part)
Polyvinyl chloride (PVC) RESINS 100
Compounded nitrile rubber P830 20
Softening agent 60
Thermo-stabilizer 8
Lime carbonate 0
Lubricant 0.5
Photomask agent 0.5
Oxidation inhibitor 0.05
Fire retardant 8
Press down fumicants 0.4.
Embodiment 2:
Composition consumption part (weight part)
Polyvinyl chloride (PVC) RESINS 100
Compounded nitrile rubber P830 30
Softening agent 50
Lime carbonate 20
Thermo-stabilizer 5
Lubricant 0.5
Photomask agent 0.5
Oxidation inhibitor 0.1
Fire retardant 7
Press down fumicants 0.3.
Embodiment 3:
Composition consumption part (weight part)
Polyvinyl chloride (PVC) RESINS 100
Compounded nitrile rubber P830 35
Softening agent 50
Lime carbonate 30
Thermo-stabilizer 6
Lubricant 0.5
Photomask agent 0.5
Oxidation inhibitor 0.2
Fire retardant 6
Press down fumicants 0.3.
Embodiment 4:
Composition consumption part (weight part)
Polyvinyl chloride (PVC) RESINS 100
Compounded nitrile rubber P830 35
Softening agent 40
Lime carbonate 30
Thermo-stabilizer 6
Lubricant 0.5
Photomask agent 0.5
Oxidation inhibitor 0.3
Fire retardant 5
Press down fumicants 0.2.
Claims (10)
1, a kind of butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic, it is characterized in that being provided with in these plastics in parts by weight: 100 parts polyvinyl chloride (PVC) RESINS, the compounded nitrile rubber P830 of 20-40 part, the softening agent of 40-60 part, the thermo-stabilizer of 5-8 part, the lubricant of 0.3-0.7 part, 0.05-0.3 the oxidation inhibitor of part, 0.3-0.7 part photomask agent, the fire retardant of 5-8 part, 0.2-0.4 part press down fumicants.
2, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that also being provided with in the plastics in parts by weight: the lime carbonate of 0-30 part.
3, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described softening agent comprises trioctyl trimellitate and Di Iso Decyl Phthalate.
4, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described oxidation inhibitor comprises antioxidant 1010 and dihydroxyphenyl propane.
5, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described photomask agent comprises high-carbon black pigment and medium abrasion resistant carbon black.
6, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described thermo-stabilizer comprises three salt and disalt.
7, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described lubricant comprises barium stearate and paraffin.
8, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described fire retardant comprises zinc borate, antimonous oxide and tetrabromo-bisphenol.
9, butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic according to claim 1 is characterized in that described but fumicants is a ferrocene.
10,, it is characterized in that described lime carbonate comprises light calcium carbonate and the calcium of living according to claim 1,2 described butyronitrile composite fire retardant insulating grade polyvinyl chloride plastics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510094665 CN1752133A (en) | 2005-09-28 | 2005-09-28 | 105 degree C butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510094665 CN1752133A (en) | 2005-09-28 | 2005-09-28 | 105 degree C butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1752133A true CN1752133A (en) | 2006-03-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510094665 Pending CN1752133A (en) | 2005-09-28 | 2005-09-28 | 105 degree C butyronitrile composite fire retardant insulating grade polyvinyl chloride plastic |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101888005A (en) * | 2010-05-05 | 2010-11-17 | 深圳市联嘉祥科技股份有限公司 | Novel radio-frequency coaxial cable and production method thereof |
| CN102050971A (en) * | 2011-01-13 | 2011-05-11 | 广东日丰电缆股份有限公司 | Flame-retardant thermosetting nitrile/polyvinyl chloride (PVC) rubber for wires and cables |
| CN101527186B (en) * | 2009-03-30 | 2011-12-07 | 开开电缆科技有限公司 | Special butyronitrile PVC composite cable sheath for aerogenerator |
| CN102675776A (en) * | 2012-06-12 | 2012-09-19 | 宁波先锋新材料股份有限公司 | High-fluidity high-fire resistance polyvinyl chloride composite material and method for preparing same |
| CN102746592A (en) * | 2012-06-07 | 2012-10-24 | 安徽胜华电缆集团有限公司 | Fire-resistant and high temperature-resistant type anti-corrosion control cable material and method for preparing the same |
| CN102051006B (en) * | 2009-10-27 | 2013-05-01 | 中国石油化工股份有限公司 | Radiation-resistance high-elastic resilience polyvinyl chloride composition and preparation method thereof |
| CN103289245A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation HPVC foaming sole material |
| CN103342528A (en) * | 2013-06-03 | 2013-10-09 | 铜陵丰泽建材科技有限公司 | Aerated concrete block reinforced by fibers and preparation method thereof |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
| CN103578641A (en) * | 2013-11-08 | 2014-02-12 | 江苏远洋东泽电缆股份有限公司 | Hydrocarbon-ageing-resistant power cable for petrochemical unit and manufacturing method of hydrocarbon-ageing-resistant power cable |
| CN103589097A (en) * | 2013-11-08 | 2014-02-19 | 江苏远洋东泽电缆股份有限公司 | Hydrocarbon-aging-resistant cable sheath rubber for petrochemical plant and manufacturing method of hydrocarbon-aging-resistant cable sheath rubber |
| CN104212096A (en) * | 2014-09-10 | 2014-12-17 | 苏州新区枫盛塑料制品厂 | PVC plastic particle formula |
| CN104212094A (en) * | 2014-09-10 | 2014-12-17 | 苏州新区枫盛塑料制品厂 | PVC plastic colloidal particle formula |
| CN104877284A (en) * | 2015-04-01 | 2015-09-02 | 无锡龙舜实业有限公司 | Manufacturing process of semi-hard plastic casing sleeve tube for optical cable |
| CN105504593A (en) * | 2016-01-05 | 2016-04-20 | 惠州乐庭电子线缆有限公司 | Temperature-resistant oil-resistant polyvinyl chloride elastomer cable material and preparing method thereof |
| CN106009100A (en) * | 2016-05-20 | 2016-10-12 | 安徽龙庵电缆集团有限公司 | High-performance oil-resistant flame retardant rubber sheath material and preparation method thereof |
| CN107082993A (en) * | 2017-06-20 | 2017-08-22 | 合肥博创机械制造有限公司 | A kind of wire cable material and preparation method thereof |
| CN107686613A (en) * | 2017-09-06 | 2018-02-13 | 宁波宁港线缆制造有限公司 | A kind of polyvinyl chloride composite materials and its preparation technology |
| CN108586810A (en) * | 2018-05-08 | 2018-09-28 | 朱红艳 | A kind of graphene-based non-halogen flame-proof smoke-restraining agent preparation method and applications |
| CN110229437A (en) * | 2019-05-29 | 2019-09-13 | 周宁东 | A kind of modified PVC CABLE MATERIALS and preparation method thereof |
| CN111040333A (en) * | 2019-11-27 | 2020-04-21 | 中广核三角洲（中山）高聚物有限公司 | High-temperature-resistant polyvinyl chloride/nitrile rubber composite cable material |
-
2005
- 2005-09-28 CN CN 200510094665 patent/CN1752133A/en active Pending
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101527186B (en) * | 2009-03-30 | 2011-12-07 | 开开电缆科技有限公司 | Special butyronitrile PVC composite cable sheath for aerogenerator |
| CN102051006B (en) * | 2009-10-27 | 2013-05-01 | 中国石油化工股份有限公司 | Radiation-resistance high-elastic resilience polyvinyl chloride composition and preparation method thereof |
| CN101888005B (en) * | 2010-05-05 | 2013-08-28 | 深圳市联嘉祥科技股份有限公司 | Novel radio-frequency coaxial cable and production method thereof |
| CN101888005A (en) * | 2010-05-05 | 2010-11-17 | 深圳市联嘉祥科技股份有限公司 | Novel radio-frequency coaxial cable and production method thereof |
| CN102050971A (en) * | 2011-01-13 | 2011-05-11 | 广东日丰电缆股份有限公司 | Flame-retardant thermosetting nitrile/polyvinyl chloride (PVC) rubber for wires and cables |
| CN102746592B (en) * | 2012-06-07 | 2016-01-06 | 安徽胜华电缆集团有限公司 | A kind of Refractory high-temperature resistant anticorrosion control cable material and preparation method thereof |
| CN102746592A (en) * | 2012-06-07 | 2012-10-24 | 安徽胜华电缆集团有限公司 | Fire-resistant and high temperature-resistant type anti-corrosion control cable material and method for preparing the same |
| CN102675776A (en) * | 2012-06-12 | 2012-09-19 | 宁波先锋新材料股份有限公司 | High-fluidity high-fire resistance polyvinyl chloride composite material and method for preparing same |
| CN103342528B (en) * | 2013-06-03 | 2016-02-24 | 铜陵丰泽建材科技有限公司 | Air-entrained concrete building block that a kind of fiber is strengthened and preparation method thereof |
| CN103342528A (en) * | 2013-06-03 | 2013-10-09 | 铜陵丰泽建材科技有限公司 | Aerated concrete block reinforced by fibers and preparation method thereof |
| CN103289245A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation HPVC foaming sole material |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
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| CN104877284A (en) * | 2015-04-01 | 2015-09-02 | 无锡龙舜实业有限公司 | Manufacturing process of semi-hard plastic casing sleeve tube for optical cable |
| CN105504593A (en) * | 2016-01-05 | 2016-04-20 | 惠州乐庭电子线缆有限公司 | Temperature-resistant oil-resistant polyvinyl chloride elastomer cable material and preparing method thereof |
| CN106009100A (en) * | 2016-05-20 | 2016-10-12 | 安徽龙庵电缆集团有限公司 | High-performance oil-resistant flame retardant rubber sheath material and preparation method thereof |
| CN107082993A (en) * | 2017-06-20 | 2017-08-22 | 合肥博创机械制造有限公司 | A kind of wire cable material and preparation method thereof |
| CN107686613A (en) * | 2017-09-06 | 2018-02-13 | 宁波宁港线缆制造有限公司 | A kind of polyvinyl chloride composite materials and its preparation technology |
| CN108586810A (en) * | 2018-05-08 | 2018-09-28 | 朱红艳 | A kind of graphene-based non-halogen flame-proof smoke-restraining agent preparation method and applications |
| CN110229437A (en) * | 2019-05-29 | 2019-09-13 | 周宁东 | A kind of modified PVC CABLE MATERIALS and preparation method thereof |
| CN111040333A (en) * | 2019-11-27 | 2020-04-21 | 中广核三角洲（中山）高聚物有限公司 | High-temperature-resistant polyvinyl chloride/nitrile rubber composite cable material |
| CN111040333B (en) * | 2019-11-27 | 2022-07-19 | 中广核三角洲（中山）高聚物有限公司 | High-temperature-resistant polyvinyl chloride/nitrile rubber composite cable material |
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