CN1749350A - Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof - Google Patents
Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof Download PDFInfo
- Publication number
- CN1749350A CN1749350A CN 200410079225 CN200410079225A CN1749350A CN 1749350 A CN1749350 A CN 1749350A CN 200410079225 CN200410079225 CN 200410079225 CN 200410079225 A CN200410079225 A CN 200410079225A CN 1749350 A CN1749350 A CN 1749350A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- drilling fluid
- asphalt
- anhydride
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 39
- 238000005553 drilling Methods 0.000 title claims abstract description 29
- 239000012530 fluid Substances 0.000 title claims abstract description 26
- 150000001768 cations Chemical class 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 54
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 27
- 239000000178 monomer Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 125000002091 cationic group Chemical group 0.000 claims abstract description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 10
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims abstract description 10
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 14
- OCNZHGHKKQOQCZ-CLFAGFIQSA-N [(z)-octadec-9-enoyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC(=O)CCCCCCC\C=C/CCCCCCCC OCNZHGHKKQOQCZ-CLFAGFIQSA-N 0.000 claims description 14
- 150000008064 anhydrides Chemical class 0.000 claims description 14
- 239000000600 sorbitol Substances 0.000 claims description 14
- 238000013019 agitation Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000004945 emulsification Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 230000004069 differentiation Effects 0.000 claims description 3
- 238000012921 fluorescence analysis Methods 0.000 claims description 3
- 229920006317 cationic polymer Polymers 0.000 abstract description 3
- 230000036571 hydration Effects 0.000 abstract description 3
- 238000006703 hydration reaction Methods 0.000 abstract description 3
- 230000005764 inhibitory process Effects 0.000 abstract description 3
- 238000005187 foaming Methods 0.000 abstract description 2
- 230000001050 lubricating effect Effects 0.000 abstract description 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229940035049 sorbitan monooleate Drugs 0.000 abstract 1
- 235000011069 sorbitan monooleate Nutrition 0.000 abstract 1
- 239000001593 sorbitan monooleate Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 4
- 235000019219 chocolate Nutrition 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000009775 high-speed stirring Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 208000013201 Stress fracture Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
Landscapes
- Road Paving Structures (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a cation and emulsified asphalt anti-sloughing agent for drilling fluid and a production method thereof. The invention is prepared by the following raw materials by weight percentage: 20-40% of asphalt, 4-9% of potassium hydroxide, 1-3% of hexadecyl trimethyl ammonium chloride (industrial grade), 15-30% of industrial auxiliary oil, 5-8% of acrylic acid monomer, 15-30% of deionized water, 0.1-0.2% of dibenzoyl peroxide, 5-8% of epoxy propyl trimethyl ammonium chloride and 2-5% of sorbitan monooleate. The production method of the anti-collapse agent comprises the following steps: A. preparing a polymer emulsion; B. preparing a cationic asphalt emulsion; C. a polymer cationic asphalt emulsion. The anti-sloughing agent has good compatibility with the cationic polymer drilling fluid, the drilling fluid has stable performance, and no foaming and no viscosity increase are caused after the anti-sloughing agent is added. The pollution resistance is strong. The drilling fluid has strong inhibition performance, can effectively inhibit hydration of the shale and collapse of a hard and brittle stratum, effectively inhibit hydration of the shale, obviously improve the lubricating performance and the mud cake quality of the drilling fluid, reduce the filtration loss and reduce the cost of the drilling fluid.
Description
Technical field
The present invention relates to a kind of drilling fluid treatment agent and production method thereof.
Background technology
In the blue or green western area of Yumen Oilfield two structures in the Liu Gou village and mountain, hole are arranged; the well depth of institute's drilling well all is the deep-well more than 4000 meters; and nearly all be long uncased hole; mountain, hole structure belongs to piedmont tectonic belts and the contrary nappe of covering; construction brings some technical barriers to this geologic condition to drilling fluid; as leakage, undergauge, cave in, hole diameter is irregular and problem such as crack property oil layer protection, has seriously restricted the raising of drilling well and oil field overall efficiency.
Summary of the invention
The purpose of this invention is to provide a kind of cation emulsion asphalt anti-collapse agent for well drilling fluid.
Another object of the present invention provides a kind of this production method of anti-collapse dose.
Cation emulsion asphalt anti-collapse agent for well drilling fluid of the present invention is to be made by the raw material of following weight percentage scope:
Pitch 20%-40%, potassium hydroxide 4%-9%, palmityl trimethyl ammonium chloride (technical grade) 1%-3%, industry auxiliary agent oil 15%-30%, Acrylic Acid Monomer 5%-8%, deionized water 15%-30%, dibenzoyl peroxide 0.1%-0.2%, epoxypropyl trimethylammonium chloride ammonium 5%-8%, sorbitol anhydride monooleic anhydride 2%-5%.
The preferred weight percentage composition scope of each raw material of the present invention is: pitch 25%-35%, potassium hydroxide 5%-7%, palmityl trimethyl ammonium chloride (technical grade) 2%-2.5%, industry auxiliary agent oil 20%-25%, Acrylic Acid Monomer 6%-7%, deionized water 20%-25%, dibenzoyl peroxide 0.1%-0.2%, epoxypropyl trimethylammonium chloride ammonium 6%-7%, sorbitol anhydride monooleic anhydride 3%-4%.
The production method of above-mentioned each component being made anti-collapse dose of the present invention is:
The preparation of A, polymer emulsion
1. in industrial auxiliary agent oil, add the abundant mixing of sorbitol anhydride monooleic anhydride,
2. in deionized water, add Acrylic Acid Monomer,, be mixed with monomer solution with the potassium hydroxide neutralization;
3. under agitation condition, the monomer solution that step is mixed with in is 2. poured in the mixing liquid of step in 1., is warming up to 70-80 ℃, forms oily emulsion, drips the dibenzoyl peroxide initiator solution, leaves standstill after polyreaction 3-4 hour, makes polymer emulsion;
The preparation of B, cationic asphalt emulsion
1. by fluorescence analysis, various asphalt stocks are screened, select a kind of and used in-place oil fluorescent characteristic that the asphalt stock of obvious differentiation is arranged; With the pitch heat fused, pour in the industrial auxiliary agent oil, add an amount of sorbitol anhydride monooleic anhydride, stir, keep 80-85 ℃ of temperature;
2. add palmityl trimethyl ammonium chloride after deionized water being heated to 80 ℃;
3. the solution that under agitation step is mixed with in 2. joins slowly that emulsification disperses to form suspension emulsion in the mixing liquid of step in 1.;
C, polymer cation bitumen emulsion
Under 85-90 ℃ of temperature, under agitation polymer emulsion that steps A is made and epoxypropyl trimethylammonium chloride ammonium join respectively in the cationic asphalt emulsion that step B makes, and continue to stir uniformly emulsify 1-2 hour.
The index that the present invention is anti-collapse dose
| Project | Index |
| Outward appearance | The black jelly |
| Dispersed | Homodisperse does not have floating decorating film |
| Relative inhibition ,≤ | 1.0 |
| Colloidal stability, % 〉= | 95.0 |
| Working substance content, % 〉= | 50 |
| The frictional coefficient reduced rate, % 〉= | 50 |
The mechanism of action of the present invention:
(1), adhesive aggregation is mended the wall effect
Anti-collapse dose of the present invention is under the bottom temperature effect, splitting action takes place easily, moisture in the bitumen emulsion is separated gradually, pitch particle is coalescent mutually, simultaneously with the adsorption of rock of borehole, pitch particle carries out physical adsorption by molecular chain and rock surface, and the result makes rock of borehole surface form the firm asphalt film of one deck, and it can stop in the drilling fluid free water to be permeated to the stratum on the one hand.When the pitch particulate forms the asphalt membrane with certain intensity on the borehole wall on the other hand, with the influence that can not washed away by drilling fluid.
(2) strengthen the mud cake lubrication
Anti-collapse dose of particle of the present invention is because self viscosity and elasticity produce deformation under fluid column pressure, and further shutoff mud cake mesoporosity forms thin and fine and close mud cake.Its oleophilic moiety is forming the Oil solvent film on the mud cake surface, and its oil dispersible asphalt particle plays good lubrication in drilling fluid.
(3) leak-off and restraining effect fall in reinforcement
Contain a certain amount of polyacrylate among anti-collapse dose of the present invention, polyacrylate exists with emulsion form, and contain a certain amount of potassium ion, in drilling fluid, play and fall leak-off and restraining effect, simultaneously provide complexing action for pitch in the microporosity, stratum and the borehole wall, make the polyacrylate breast grain separated viscosity and the resilient energy intensity that in microporosity, stratum and microfissure, improves the pitch adhesive membrane, improvement of mud cake by self.
The rig-site utilization situation
Anti-collapse dose of the present invention has effectively reduced the down hole problem generation in drilling process, mainly show:
(1) anti-collapse dose of the present invention is good with the cationic polymer drilling fluid compatibleness, and property of drilling fluid is stable, and its adding is non-foaming, it is sticking not carry, and do not influence original property of drilling fluid.Be convenient to safeguard that contamination resistance is strong in the on-the-spot use.
(2) improved the inhibition ability of cationic polymer drilling fluid, effectively suppressed caving in of shale hydration and hard resistance stratum, avoided falling the generation of the lock of tool drilling that piece brings because of the borehole wall that leakage causes.The hole diameter amplification degree significantly descends, and has realized the stable of the borehole wall.
(3) polymer cation pitch helps the shutoff to the stratum microfracture, can effectively reduce wastage, helps reducing drilling fluid cost.
(4) the polymer cation bituminous uses, and the coefficient of friction resistance of drilling fluid mud cake is reduced, and makes it to have good lubricating property.
Embodiment
The following examples can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Embodiment 1:
Equipment used in the production: reactor, test tank, condenser, homogenizer, thermal medium boiler.
The production process that the present invention is anti-collapse dose is:
The preparation of A, polymer emulsion
1. get industrial auxiliary agent oil 200kg No. 15, add the abundant mixing of 30kg sorbitol anhydride monooleic anhydride;
2. in the 200kg deionized water, add the 90kg Acrylic Acid Monomer,, be mixed with monomer solution with the neutralization of 70kg technical grade potassium hydroxide;
3. under agitation condition, the monomer solution that step is mixed with in is 2. poured in the mixing liquid of step in 1., is warming up to 70-80 ℃, form oily emulsion, drip 1kg dibenzoyl peroxide initiator solution, leave standstill after polyreaction 3-4 hour, make polymer emulsion;
The preparation of B, cationic asphalt emulsion
1. by fluorescence analysis, various asphalt stocks are screened, selects a kind of and used in-place oil fluorescent characteristic that the asphalt stock of obvious differentiation is arranged, to reduce interference to the geological logging measurement.With 400kg pitch heat fused, pour in 200kg15 number industrial auxiliary agent oil, add 40kg sorbitol anhydride monooleic anhydride, stir, keep 80-85 ℃ of temperature;
2. add 20kg technical grade palmityl trimethyl ammonium chloride after the 100kg deionized water being heated to 80 ℃, stirring and dissolving;
3. the solution that under high-speed stirring step is mixed with in 2. joins slowly that emulsification disperses to form suspension emulsion in the mixing liquid of step in 1.;
C, polymer cation bitumen emulsion
Under 85-90 ℃ of temperature, under agitation polymer emulsion that steps A is made and 80kg epoxypropyl trimethylammonium chloride ammonium successively join in the cationic asphalt emulsion that step B makes, and continue to stir uniformly emulsify 1-2 hour.
Make the polymer cation bitumen emulsion, be the chocolate body of paste.
No. 10, No. 15 industrial auxiliary agent oil of the present invention are the currently available productss by the viscosity criterion classification.
Embodiment 2
The production process that the present invention is anti-collapse dose is:
The preparation of A, polymer emulsion
1. get industrial auxiliary agent oil 300kg No. 10, add the abundant mixing of 50kg sorbitol anhydride monooleic anhydride,
2. in the 150kg deionized water, add the 100kg Acrylic Acid Monomer,, be mixed with monomer solution with the neutralization of 80kg technical grade potassium hydroxide;
3. under agitation condition, the monomer solution that step is mixed with in is 2. poured in the mixing liquid of step in 1., is warming up to 70-80 ℃, form oily emulsion, drip 2kg dibenzoyl peroxide initiator solution, leave standstill after polyreaction 3-4 hour, make polymer emulsion;
The preparation of B, cationic asphalt emulsion
1. with 450kg pitch heat fused, pour in 200kg10 number industrial auxiliary agent oil, add 50kg sorbitol anhydride monooleic anhydride, stir, keep 80-85 ℃ of temperature;
2. add 40kg technical grade palmityl trimethyl ammonium chloride after the 300kg deionized water being heated to 80 ℃;
3. the solution that under high-speed stirring step is mixed with in 2. joins slowly that emulsification disperses to form suspension emulsion in the mixing liquid of step in 1.;
C, polymer cation bitumen emulsion
Under 85-90 ℃ of temperature, under agitation polymer emulsion that steps A is made and 100kg epoxypropyl trimethylammonium chloride ammonium successively join in the cationic asphalt emulsion that step B makes, and continue to stir uniformly emulsify 1-2 hour.
Make the polymer cation bitumen emulsion, be the chocolate body of paste.
Embodiment 3
The production process that the present invention is anti-collapse dose is:
The preparation of A, polymer emulsion
1. get industrial auxiliary agent oil 250kg No. 15, add the abundant mixing of 40kg sorbitol anhydride monooleic anhydride,
2. in the 180kg deionized water, add the 95kg Acrylic Acid Monomer,, be mixed with monomer solution with the neutralization of 75kg technical grade potassium hydroxide;
3. under agitation condition, the monomer solution that step is mixed with in is 2. poured in the mixing liquid of step in 1., is warming up to 70-80 ℃, form oily emulsion, drip 1.5kg dibenzoyl peroxide initiator solution, leave standstill after polyreaction 3-4 hour, make polymer emulsion;
The preparation of B, cationic asphalt emulsion
1. with 420kg pitch heat fused, pour in 200kg15 number industrial auxiliary agent oil, add 50kg sorbitol anhydride monooleic anhydride, stir, keep 80-85 ℃ of temperature;
2. add 30kg technical grade palmityl trimethyl ammonium chloride after the 200kg deionized water being heated to 80 ℃, stirring and dissolving;
3. the solution that under agitation step is mixed with in 2. joins slowly that emulsification disperses to form suspension emulsion in the mixing liquid of step in 1.;
C, polymer cation bitumen emulsion
Under 85-90 ℃ of temperature, under agitation polymer emulsion that steps A is made and 90kg epoxypropyl trimethylammonium chloride ammonium successively join in the cationic asphalt emulsion that step B makes, and continue to stir uniformly emulsify 1-2 hour.
Make the polymer cation bitumen emulsion, be the chocolate body of paste.
Claims (3)
1, a kind of cation emulsion asphalt anti-collapse agent for well drilling fluid is characterized in that: it is to be made by the raw material of following weight percentage scope,
Pitch 20%-40%, potassium hydroxide 4%-9%, palmityl trimethyl ammonium chloride (technical grade) 1%-3%, industry auxiliary agent oil 15%-30%, Acrylic Acid Monomer 5%-8%, deionized water 15%-30%, dibenzoyl peroxide 0.1%-0.2%, epoxypropyl trimethylammonium chloride ammonium 5%-8%, sorbitol anhydride monooleic anhydride 2%-5%.
2, cation emulsion asphalt anti-collapse agent for well drilling fluid according to claim 1, it is characterized in that: the weight percentage scope of each raw material is, pitch 25%-35%, potassium hydroxide 5%-7%, palmityl trimethyl ammonium chloride (technical grade) 2%-2.5%, industry auxiliary agent oil 20%-25%, Acrylic Acid Monomer 6%-7%, deionized water 20%-25%, dibenzoyl peroxide 0.1%-0.2%, epoxypropyl trimethylammonium chloride ammonium 6%-7%, sorbitol anhydride monooleic anhydride 3%-4%.
3, the production method of claim 1 or 2 described cation emulsion asphalt anti-collapse agent for well drilling fluid, it is characterized in that: it may further comprise the steps,
The preparation of A, polymer emulsion
1. in industrial auxiliary agent oil, add the abundant mixing of sorbitol anhydride monooleic anhydride,
2. in deionized water, add Acrylic Acid Monomer,, be mixed with monomer solution with the potassium hydroxide neutralization;
3. under agitation condition, the monomer solution that step is mixed with in is 2. poured in the mixing liquid of step in 1., is warming up to 70-80 ℃, forms oily emulsion, drips the dibenzoyl peroxide initiator solution, leaves standstill after polyreaction 3-4 hour, makes polymer emulsion;
The preparation of B, cationic asphalt emulsion
1. by fluorescence analysis, various asphalt stocks are screened, select a kind of and used in-place oil fluorescent characteristic that the asphalt stock of obvious differentiation is arranged; With the pitch heat fused, pour in the industrial auxiliary agent oil, add an amount of sorbitol anhydride monooleic anhydride, stir, keep 80-85 ℃ of temperature;
2. add palmityl trimethyl ammonium chloride after deionized water being heated to 80 ℃;
3. the solution that under agitation step is mixed with in 2. joins slowly that emulsification disperses to form suspension emulsion in the mixing liquid of step in 1.;
C, polymer cation bitumen emulsion
Under 85-90 ℃ of temperature, under agitation polymer emulsion that steps A is made and epoxypropyl trimethylammonium chloride ammonium join respectively in the cationic asphalt emulsion that step B makes, and continue to stir uniformly emulsify 1-2 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100792257A CN1322093C (en) | 2004-09-15 | 2004-09-15 | Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100792257A CN1322093C (en) | 2004-09-15 | 2004-09-15 | Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1749350A true CN1749350A (en) | 2006-03-22 |
| CN1322093C CN1322093C (en) | 2007-06-20 |
Family
ID=36605010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100792257A Expired - Fee Related CN1322093C (en) | 2004-09-15 | 2004-09-15 | Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1322093C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275070B (en) * | 2007-12-26 | 2010-06-02 | 中国石油集团钻井工程技术研究院 | Organic silicate semi-permeable diaphragm agent and preparation thereof |
| CN101108963B (en) * | 2006-07-19 | 2010-12-29 | 西部钻探克拉玛依钻井工艺研究院 | Modified product of native asphalt bitumen used as drilling fluid anti-sloughing agentand method of manufacturing the same |
| CN102952526A (en) * | 2011-08-26 | 2013-03-06 | 中国石油化工股份有限公司 | High-softening point emulsified asphalt water-based drilling fluid additive and preparation method thereof |
| CN104151493A (en) * | 2014-08-04 | 2014-11-19 | 成都理工大学 | Emulsion collapse agent and preparation method thereof |
| CN107418529A (en) * | 2017-06-28 | 2017-12-01 | 常州明华运输有限公司 | A kind of anti-caving agent for drilling fluid |
| WO2018160478A1 (en) * | 2017-03-02 | 2018-09-07 | Baker Hughes, A Ge Company, Llc | Polymer-modified asphalt for drilling fluid applications |
| CN108659804A (en) * | 2018-06-13 | 2018-10-16 | 西南石油大学 | A kind of water filling clay expansion-resisting agent with washing oil and bactericidal effect |
| CN108690578A (en) * | 2017-04-10 | 2018-10-23 | 中国石油化工股份有限公司 | A kind of water-base drilling fluid and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4897587A (en) * | 1988-12-08 | 1990-01-30 | Pitney Bowes Inc. | Microprocessor motor controller having discrete processing cycles |
| JP2796867B2 (en) * | 1990-01-12 | 1998-09-10 | 三井サイテック株式会社 | Petroleum recovery with cationic and anionic polymers |
| CN1037852C (en) * | 1991-08-27 | 1998-03-25 | 石油勘探开发科学研究院钻井工艺研究所 | Cationic boring liquid |
| CN1116381C (en) * | 2001-08-28 | 2003-07-30 | 罗萌 | Multifunctional soil and water conserving agent and its compounding process |
-
2004
- 2004-09-15 CN CNB2004100792257A patent/CN1322093C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108963B (en) * | 2006-07-19 | 2010-12-29 | 西部钻探克拉玛依钻井工艺研究院 | Modified product of native asphalt bitumen used as drilling fluid anti-sloughing agentand method of manufacturing the same |
| CN101275070B (en) * | 2007-12-26 | 2010-06-02 | 中国石油集团钻井工程技术研究院 | Organic silicate semi-permeable diaphragm agent and preparation thereof |
| CN102952526A (en) * | 2011-08-26 | 2013-03-06 | 中国石油化工股份有限公司 | High-softening point emulsified asphalt water-based drilling fluid additive and preparation method thereof |
| CN102952526B (en) * | 2011-08-26 | 2015-03-18 | 中国石油化工股份有限公司 | High-softening point emulsified asphalt water-based drilling fluid additive and preparation method thereof |
| CN104151493A (en) * | 2014-08-04 | 2014-11-19 | 成都理工大学 | Emulsion collapse agent and preparation method thereof |
| CN104151493B (en) * | 2014-08-04 | 2016-08-24 | 成都理工大学 | A kind of emulsion anti-sloughing agent and preparation method thereof |
| WO2018160478A1 (en) * | 2017-03-02 | 2018-09-07 | Baker Hughes, A Ge Company, Llc | Polymer-modified asphalt for drilling fluid applications |
| CN108690578A (en) * | 2017-04-10 | 2018-10-23 | 中国石油化工股份有限公司 | A kind of water-base drilling fluid and preparation method thereof |
| CN108690578B (en) * | 2017-04-10 | 2020-11-10 | 中国石油化工股份有限公司 | Water-based drilling fluid and preparation method thereof |
| CN107418529A (en) * | 2017-06-28 | 2017-12-01 | 常州明华运输有限公司 | A kind of anti-caving agent for drilling fluid |
| CN108659804A (en) * | 2018-06-13 | 2018-10-16 | 西南石油大学 | A kind of water filling clay expansion-resisting agent with washing oil and bactericidal effect |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1322093C (en) | 2007-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1858146A (en) | Anti-pollution high efficiency isolation liquid and preparing method | |
| CN1309798C (en) | Follow-drilling plugging agent and its preparation method and use | |
| CN1712383A (en) | Corrosion proof high performance marine concrete and its production | |
| CN104388066B (en) | Preparation method of plugging agent for drilling fluid | |
| CN1807542A (en) | Temperature-resistant viscosity-reducing agent for boring fluid | |
| CN1749350A (en) | Cation emulsified asphalt anti-collapse agent for drilling fluid and production method thereof | |
| CN107434378A (en) | A kind of sponge city low-carbon environment-friendly waste asphalt mixture composite permeable mortar and preparation method thereof | |
| CN1037852C (en) | Cationic boring liquid | |
| CN112714755A (en) | Silica-based additive for well cementing composition, well cementing composition and well cementing method | |
| CN113698143A (en) | Semi-flexible asphalt mixture filled with metakaolin-based polymer and preparation method thereof | |
| CN1309675C (en) | Desalting sea sand high-performance concreet mixing materials and preparing method thereof | |
| CN1908069A (en) | Mixture of special-shaped section hollow polymer fiber and modified asphalt | |
| CN1775897A (en) | Water dispersion composite sand-fixing agent formula | |
| CN101037592A (en) | High-density mud conversion to cement slurry cementing fluid | |
| CN1276052C (en) | Lost circulation additives and drilling fluid in serious thief zone | |
| Gang et al. | A green shale inhibitor developed from lignin sulfonate and the mechanism study | |
| CN1200068C (en) | Water retaining composition for cement for oil well | |
| CN1260769A (en) | Aqueous suspensions of metakaolin and method of producing cementitious | |
| CN115259735B (en) | Viscosity-reducing phase-change material for concrete and preparation method and application thereof | |
| CN1814691A (en) | Surfactant formula system compounded by ampho-surfactant and use in the third oil production | |
| US10876034B1 (en) | Modified silicon dioxide material of fluorocarbon active agent type super-amphiphobic cutting-carrying agent suitable for water-based drilling fluid and preparation method thereof | |
| CN1179990C (en) | Amphoteric ion polymer and its preparing process and use | |
| CN115650631B (en) | Waterproof compacting agent for concrete and preparation method thereof | |
| CN102352226A (en) | Low-temperature early-strength oil well cement paste | |
| CN1923940A (en) | Multi-purpose polymer adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |